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The results of the stress-strain state during drawing of hexagonal steel rods are presented. The effect of the drawing die angle and the degree of reduction on the distribution of the stress-strain state parameters and the elastic aftereffect of the deformed metal is studied.

This paper describes the results of modeling when the processes of stranding, reduction, straightening and thermo-mechanical treatment (TMT) of prestressing strands were simulated with the help of finite-element method. The distribution of residual stresses used in the simulation models refers to the stresses created at the preliminary stage of wire drawing. The simulation study looked at the effect of thermo-mechanical treatment on the internal wire stresses: residual stresses resultant from the drawing process and further stranding stresses. All studied methods demonstrated a positive effect not only in terms of eliminating internal stresses, but also from the point of view of their redistribution. Reduction of a strand in a solid tool at the ratios of 1–3 % allows to create tensile stresses at the surface of the wire and retain compressive stresses in its core. Straightening in a 5-roller group helped reach a double relaxation in outer wires. TMT, a process combining different physical effects, enabled to control within a broad range the redistribution of residual stresses in steel that was subjected to prior drawing at high deformation ratios. Such residual stresses occur as a result of stranding stresses that accompany the stranding operation and can affect the geometry of the strand. The study showed that tension as a TMT parameter plays a greater role in the elimination of longitudinal residual stresses. That’s why, at the minimum tension, almost no redistribution of residual stresses occur either in the central or in the near-surface layers irrespective of the TMT temperature regime applied. However, when the tension exceeding 70 kN is applied at the temperatures of 380–400 °C, the central and surface residual stresses balance off in the wire or almost disappear. This research was carried out under the Decree No. 220 dated 9th April 2010 of the Government of the Russian Federation (Contract No. 075-15-2019-869 dated 12th May 2019) and was funded by the Russian Science Foundation (Project No. 20-69-46042 dated 20th May 2020) and by the Russian Ministry of Education and Science with the goal of developing high-tech production (contract nos. 02.G25.31.078, December 1, 2015; and MK204895, July 27, 2015).

The modern construction industry widely uses reinforced concrete structures, where high-strength prestressing strands are used. Key parameters determining strength and relaxation resistance are a steel microstructure and internal stresses. The aim of the work was a computer research of a stage-by-stage formation of internal stresses during production of prestressing strands of structure 1х7(1+6), 12.5 mm diameter, 1770 MPa strength grade, made of pearlitic steel, as well as study of various modes of mechanical and thermal treatment (MTT) influence on their distribution. To study the effect of every strand manufacturing operation on internal stresses of its wires, the authors developed three models: stranding and reducing a 7-wire strand; straightening of a laid strand, stranding and MTT of a 7-wire strand. It was shown that absolute values of residual stresses and their distribution in a wire used for strands of a specified structure significantly influence performance properties of strands. The use of MTT makes it possible to control in a wide range a redistribution of residual stresses in steel resulting from drawing and strand laying processes. It was established that during drawing of up to 80% degree, compressive stresses of 1100-1200 MPa degree are generated in the central layers of wire. The residual stresses on the wire surface accounted for 450-500 MPa and were tension in nature. The tension within a range of 70 kN to 82 kN combined with a temperature range of 360-380°С contributes to a two-fold decrease in residual stresses both in the central and surface layers of wire. When increasing temperature up to 400°С and maintaining the tension, it is possible to achieve maximum balance of residual stresses. Stranding stresses, whose high values entail failure of lay length and geometry of the studied strand may be fully eliminated only at tension of 82 kN and temperature of 400°С. Otherwise, stranding stresses result in opening of strands.

The practicality of three armature designs for tractional electric motors (power 560–755 kW, tractional force 5326 kgf) is analyzed. The use of an armature shaft of variable (reinforced) cross section in place of the armature with a sleeve is proposed, and suggestions are made regarding the assembly of the bearings. Reinforcement of the working shaft by smoothing may be recommended.

Recently in order to create new generation technology there is extensive use of materials based on multifunctional alloys with special physicomechanical properties. This concerns Invar alloy materials, exhibiting minimum thermal expansion values with high strength properties (σu and HV). Scientists of the Magnitogorsk State Technical University together with specialists of the Motovilikhinskie Zavody company (Perm) are implementing a project for creating a mini-plant for manufacturing billets of innovative high-strength Invar class multifunctional alloys. On the example of Invar alloy of the Fe–Ni–Co–V–C system results are presented in this article for the effect of heat treatment regimes on test alloy structure formation and thermal expansion. A fundamental production scheme is demonstrated applied to Motovilikhinskie Zavody conditions for manufacturing nanostructured billets of a new generation of multifunctional alloys, providing the achievement of an increased level of mechanical properties (σu ≈ 1100 MPa) and anomalously low values of linear thermal expansion coefficient (LTEC ≤ 1·10–6 K–1).

New technology for the production of high-strength Invar alloys containing carbon, cobalt, and vanadium is considered. The formation of the alloys’ mechanical properties is discussed. A basic system for the production of Invar blanks at metallurgical plants is described.

Complexes of covalent and noncovalent adducts of polyethylene glycol (PEG) and alpha-chymotrypsin (ChT), PEG-ChT, were generated in the presence of beta-cyclodextrin derivatives of polyoxyethylene (beta CD-PEO), and their thermal stability was studied. The covalent [PEG-ChT]c conjugates were obtained by chemical modification of the protein amino groups with the monoaldehyde derivatives of monomethoxypolyethylene glycol. The noncovalent [PEG-ChT]n complexes were obtained by the treatment of ChT-PEG mixtures with increasing pressure (1.1-400 MPa). Supramolecular structures resulting from complex formation between PEG chains of the PEG-ChT adducts (PEGad) and beta CD-PEO were studied. The decrease in the rate constant of the slow stage of ChT thermal inactivation in PEG-ChT adducts (k2) can serve as confirmation of complex formation between beta CD-PEO and PEGad. The stoichiometric composition of our supramolecular structures was determined from the k2 dependence on the molar ratio of beta CD-PEO to PEGad. It was shown that each polymeric chain in the [PEG-ChT]c conjugates forms an inclusion complex with beta CD-PEO, whereas only half of the PEGad polymeric chains participate in the formation of supramolecular structures in the case of [PEG-ChT]n complexes. Although covalent and noncovalent PEG-ChT adducts of the same composition significantly differ in their thermal stability, the maximal values of the k2 rate constants for [PEG-ChT]c and [PEG-ChT]n adducts in the triple system attainable at the (beta CD-PEO) to (PEGad) ratio corresponding to the stoichiometry of the resulting ternary systems are practically the same (k2 = 0.007 c-1 at 45 degrees C in 0.02 M Tris-HCl buffer solution, pH 8.0). Structures for the supramolecular dendrite-like ensembles formed upon the interaction of covalent and noncovalent PEG-ChT adducts with beta CD-PEO were suggested.