1. Epitaxial growth of tantalum carbides by low carbon flow carburizing
- Author
-
Philippe Jacquet, Dominique Cotton, Sébastien Faure, Vincent Vignal, LabECAM, ECAM Lyon (ECAM Lyon), Laboratoire Bourguignon des Matériaux et Procédés (LABOMAP), Arts et Métiers Sciences et Technologies, HESAM Université (HESAM)-HESAM Université (HESAM), Laboratoire Interdisciplinaire Carnot de Bourgogne ( LICB ), Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ), VALDUC ( DAM/VALDUC ), Commissariat à l'énergie atomique et aux énergies alternatives ( CEA ), ECAM Lyon ( ECAM Lyon ), Laboratoire Bourguignon des Matériaux et Procédés ( LaBoMaP ), École Nationale Supérieure d'Arts et Métiers ( ENSAM ), CEA and the Regional Council of Burgundy, Laboratoire Interdisciplinaire Carnot de Bourgogne (LICB), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), VALDUC (DAM/VALDUC), Direction des Applications Militaires (DAM), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB), and HESAM Université - Communauté d'universités et d'établissements Hautes écoles Sorbonne Arts et métiers université (HESAM)-HESAM Université - Communauté d'universités et d'établissements Hautes écoles Sorbonne Arts et métiers université (HESAM)
- Subjects
matière Condensée: Science des matériaux [Physique] ,Materials science ,Misorientation ,Analytical chemistry ,Tantalum ,[ PHYS.COND.CM-MS ] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] ,chemistry.chemical_element ,Nanotechnology ,02 engineering and technology ,Substrate (electronics) ,Epitaxy ,01 natural sciences ,Carburizing ,Carbide ,Diffusion ,[SPI]Engineering Sciences [physics] ,Electron diffraction ,Coatings ,0103 physical sciences ,Epitaxial growth ,General Materials Science ,ComputingMilieux_MISCELLANEOUS ,010302 applied physics ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,chemistry ,Multilayers ,13. Climate action ,[ CHIM.MATE ] Chemical Sciences/Material chemistry ,[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] ,Carbides ,0210 nano-technology ,Electron backscatter diffraction - Abstract
The carburizing of tantalum samples under different carbon flow rates has highlighted the influence of the carbon flow rate on the structure of tantalum carbides. XRD analyses enabled the identification of surface structures that were revealed by optical micrographs. Four carbon flow rates were tested. The lowest carbon flow rate produced a Ta2C layer that grew epitaxially on the tantalum substrate according to the relationship: {View the MathML source101¯}Ta// View the MathML source{1¯101}Ta2C; View the MathML source〈101¯〉Ta// View the MathML source〈17¯17010〉Ta2C. An increase in the carbon flow rate resulted in the appearance of TaC nuclei through the carbon enrichment of the Ta2C layer. These nuclei appeared in the form of islets and highly oriented needles. EBSD (Electron Back Scattered Diffraction) analyses and pole figures revealed that the carbide layers grew epitaxially towards their substrates. The Ta2C layer grew according to the relationship View the MathML source{101¯}Ta// View the MathML source{1¯101}Ta2C while the TaC structures nucleated according to the following relationships: {111}TaC//{0001}Ta2C; 〈111〉TaC//〈0001〉Ta2C; {100}TaC// View the MathML source{202¯3}Ta2C; 〈100〉TaC// View the MathML source〈909¯8〉Ta2C and {110}TaC// View the MathML source{101¯3}Ta2C; 〈110〉TaC// View the MathML source〈909¯16〉Ta2C. The highest carbon flow produced stoichiometric TaC grains at the surface, which appeared to be equiaxed. The diversity of the TaC crystallographic orientations stems from the underlying Ta2C layer, the TaC grains having nucleated epitaxially from the Ta2C layer. This misorientation of the Ta2C grains with respect to Ta is governed by the exceeding of a carbon flow limit. CEA and the Regional Council of Burgundy
- Published
- 2017