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Heavy metals and dyes cause serious harm for water environment, geopolymer materials with the large pores and specific surface area, and easy modification of pore surface have received extensive attention in wastewater treatment. Herein, using loess‐clay (LC) as natural mineral materials, we developed an eco‐friendly geopolymer of loess‐clay (GpLC) with excellent adsorption properties and promotion plant growth was prepared by alkali excitement. Its morphology and structure were exhibited by scanning electron microscopy, Fourier transform infrared spectroscopy, XRD, and Brunauer–Emmett–Teller. Moreover, its adsorption property for removing metal ions and different dyes was measured, and the adsorption kinetics and thermodynamics were investigated. GpLC presented excellent adsorption ability for Pb2+, which the removal rate got to 98.7 %. It had the universality of removing organic pollutants, and the removal rate reached to 98.0 %. It was dominated chemisorption and single‐layer adsorption, which GpLC conformed to quasi‐second‐order adsorption kinetics, and being more consistent with Langmuir isothermal model. Furthermore, it was found that GpLC could promote growth of crops as it contain P and K element with essential element of plants. In summary, it provides insights and strategy for developing a kind of eco‐friendly functional materials with strong adsorption capacity and promoting plant growth, and it is an effective method for reusing loess resources. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive investigation into the predictive modeling of eco-friendly composite materials reinforced by Abaca fibers, Halloysite Nanotubes (HNT), and Egg Shell Powder (ESP) additives. Deep Neural Networks (DNNs) were employed to capture the complex behaviors of these materials under various testing conditions, including Cone Calorimeter Tests (CCT), micro-indentation with Vickers and Conical indenters, and three-point bending tests. The trained DNNs exhibited remarkable accuracy in predicting critical parameters such as Heat Release Rate (HRR), Average Rate of Heat Emission (ARHE), Total Heat Release (THR), Total Smoke Production (TSP), and Total Oxygen Consumption (TOC) during CCT. Additionally, the DNNs successfully replicated force-depth diagrams from Vickers and Conical indentations, showcasing their proficiency in modeling loading and unloading profiles. Furthermore, the flexural responses during three-point bending tests were accurately predicted, encompassing flexural modulus, the maximum flexural stress, strain at break, and energy. Validation through metrics such as Mean Squared Error (MSE) and coefficient of determination (R2) demonstrated the reliability of the DNNs in capturing material behaviors. Consequently, the study showcases the potential of machine learning, particularly DNNs, as a robust tool for predictive modeling in material science so that R2 values below 0.995 were not obtained for the trained DNNs as well as MSEs in the order of e−4. [ABSTRACT FROM AUTHOR]

Water-based coating has gained much attention globally due to environmental issues. This work aims to develop a waterborne epoxy coating incorporated with modified natural rubber (NR) latex for improved performance. For this purpose, the NR latex was modified into three types of low molecular weight epoxidized natural rubber (LENR) latex. The waterborne epoxy resin was prepared by simply mixing the epoxy resin with an amine curing agent in water and various LENR latex contents (10 to 50 wt%). The waterborne epoxy/LENR blend was coated on a tin substrate and the cured coating demonstrated better adhesion and bending properties than the neat epoxy. Phase morphological properties displayed a rough surface with a heterogeneous surface structure of the dispersed rubber and epoxy matrix. Two glass transition temperatures were observed, corresponding to the rubber modifier and the epoxy matrix. The mechanical properties of the thermosetting epoxy/LENR blends were assessed, revealing a maximum increment in elongation ability by approximately 370% for adding 50 wt% LENR, compared to the neat epoxy. These results hold the potential avenue for utilizing NR-based material in the waterborne epoxy-based resin for coating applications. Furthermore, it contributes to the NR, a renewable and eco-friendly material, in the coating technology, embracing a sustainable future. [ABSTRACT FROM AUTHOR]

Background: Chicken eggshells, a common poultry byproduct, are rich in calcium and provide a sustainable source for producing calcium oxide nanoparticles (CaO NPs). Their use in eco-friendly synthesis aligns with the growing emphasis on sustainable materials for environmental and biomedical applications. Objectives: This study develops an eco-friendly method for synthesizing CaO NPs from chicken eggshells, characterizes their physicochemical properties, and evaluates their antibacterial and antifungal activities. It also tests their effectiveness in removing heavy metal ions (Pb2+, Cr2+, Cd2+, and Hg2+) from aqueous solutions. Methods: CaO NPs were synthesized by calcining chicken eggshells at 700°C for 7 h. Comprehensive characterization included analysis of crystalline structure, morphology, optical properties, bandgap energy, chemical composition, and thermal stability. Antibacterial and antifungal activities were tested using the wellagar diffusion method. Batch adsorption experiments evaluated heavy metal ion removal under varying conditions of pH, temperature, stirring time, and adsorbent concentration Results: The synthesis produced spherical, single-crystal CaO NPs with diameters ranging from 5 to 30 nm and a crystalline size of approximately 20 nm. The nanoparticles had a bandgap energy of about 4.7 eV. Significant antibacterial activity was observed against Staphylococcus aureus, Klebsiella pneumoniae, and Escherichia coli, with increasing inhibition zones correlating with nanoparticle concentration. The CaO NPs also effectively inhibited Candida albicans. For efficient metal ion removal, the optimal conditions were found to be 30 min at pH 6 with 40 mg of CaO NPs at 25°C, achieving recovery rates of 98% for Pb2+, 97% for Cd2+, 97% for Cr2+, and 97% for Hg2+. For near-complete removal, extending the process to 70 min at pH 6 with 40 mg of CaO NPs at 45°C achieved the highest recovery rates: 99% for Pb2+, 98% for Cd2+, 99% for Cr2+, and 99% for Hg2+, though this approach involves higher energy and cost. Conclusion: CaO NPs derived from chicken eggshells are effective antibacterial agents and adsorbents for heavy metal removal. These findings highlight their potential for sustainable applications in environmental and biomedical fields. [ABSTRACT FROM AUTHOR]

Abstract Water-based coating has gained much attention globally due to environmental issues. This work aims to develop a waterborne epoxy coating incorporated with modified natural rubber (NR) latex for improved performance. For this purpose, the NR latex was modified into three types of low molecular weight epoxidized natural rubber (LENR) latex. The waterborne epoxy resin was prepared by simply mixing the epoxy resin with an amine curing agent in water and various LENR latex contents (10 to 50 wt%). The waterborne epoxy/LENR blend was coated on a tin substrate and the cured coating demonstrated better adhesion and bending properties than the neat epoxy. Phase morphological properties displayed a rough surface with a heterogeneous surface structure of the dispersed rubber and epoxy matrix. Two glass transition temperatures were observed, corresponding to the rubber modifier and the epoxy matrix. The mechanical properties of the thermosetting epoxy/LENR blends were assessed, revealing a maximum increment in elongation ability by approximately 370% for adding 50 wt% LENR, compared to the neat epoxy. These results hold the potential avenue for utilizing NR-based material in the waterborne epoxy-based resin for coating applications. Furthermore, it contributes to the NR, a renewable and eco-friendly material, in the coating technology, embracing a sustainable future.

The use of conventional building materials in the construction sector significantly contributes to air pollution and greenhouse gas emissions, resulting in considerable environmental damage across Pakistan. Embracing sustainable building materials is crucial for mitigating pollution, conserving energy, and enhancing indoor air quality through the utilization of recycled and renewable resources, reducing environmental pollution. The focus of this study is to explore the adoption of green building materials within Pakistan's construction sector, particularly aiming to mitigate environmental impacts, including air pollution and greenhouse gas emissions. The objectives include identification of sustainable materials, evaluation of their benefits and drawbacks, and the provision of recommendations for effective implementation. The research methodology includes the administration of closed-ended questionnaires, the conduct of interviews, and the observation process, utilizing both planned and random sampling techniques to ensure the collection of reliable data. The findings indicate a limited interest in eco-friendly materials, constrained by factors such as high costs, low market demand, and logistical challenges. Cronbach's alpha value is 0.926, which shows high internal consistency and reliability. The study highlights that 73% of construction firms in Pakistan do not use green building materials. This research distinguishes itself through a thorough evaluation of sustainable materials specifically suited to Pakistan’s industry, providing strategic insights to address current challenges and foster green building practices. Doi: 10.28991/HEF-2024-05-03-015 Full Text: PDF

Abstract Utilizing steel slag aggregate (SA) as a substitute for river sand in 3D concrete printing (3DCP) has emerged as a new technique as natural resources become increasingly scarce. This study investigates the feasibility of using steel slag (SS) as fine aggregate for 3DCP. Ninety mixtures with varying steel slag aggregate-to-cement ratios (SA/C), water-to-cement ratios (W/C), and silica fume (SF) contents were designed to study the workability and compressive strength of the 3D-printed concrete. Additionally, the actual components were printed to evaluate the printability of these mixtures. The experimental results indicate that it is feasible to fully employ SA in concrete for 3D printing. Mixtures with slump values ranging from 40 to 80 mm and slump flow values varying from 190 to 210 mm are recommended for 3D printing. The optimal mix is determined to have SA/C and W/C ratios of 1.0 and 0.51, respectively, and an SF content of 10% by cement weight. A statistical approach was utilized to construct the prediction models for slump and slump flow. Moreover, to predict the plastic failure of the 3D-printed concrete structure, the modified prediction model with an SA roughness coefficient of 4 was found to fit well with the experimental data. This research provides new insights into using eco-friendly materials for 3D concrete printing.

Of the 37% of carbon dioxide emissions generated by the construction industry, 5–7% comes from cement processing. In response to this problem, ways to utilize soil, a material with low energy consumption, are being explored as an eco-friendly option. In particular, eco-friendly design is being emphasized in the construction field through 3D printing technology. The research method proceeds in two stages. The first measures the changes in drying shrinkage, volume mass, compressive strength, and flexural strength over 7 days for a test specimen created by mixing coffee, charcoal, and rice bran with Hwangto. In the second step, slaked lime, a solidifying material, is mixed and tested under the same test specimen conditions as in the first. As a result of the experiment, the higher the mixing ratio of Hwangto, the greater the compressive strength and flexural strength. In particular, coffee exhibited the highest compressive strength at 1.50MPa, while charcoal demonstrated the highest flexural strength at 0.51MPa. However, when solidifying materials were mixed, the overall strength decreased, especially in the case of coffee (1.50MPa for the first time/0.87MPa for the second time), which showed a 42% decrease. Overall, charcoal was the most suitable mixing material and exhibited consistent and stable strength values in all experiments. Based on these experimental results, a 1/50 scale pavilion was produced through 3D printing. The stable shape and appropriate strength of the result were confirmed, making it suitable for educational or practical purposes. It suggests the possibility of use across industries.

Utilizing steel slag aggregate (SA) as a substitute for river sand in 3D concrete printing (3DCP) has emerged as a new technique as natural resources become increasingly scarce. This study investigates the feasibility of using steel slag (SS) as fine aggregate for 3DCP. Ninety mixtures with varying steel slag aggregate-to-cement ratios (SA/C), water-to-cement ratios (W/C), and silica fume (SF) contents were designed to study the workability and compressive strength of the 3D-printed concrete. Additionally, the actual components were printed to evaluate the printability of these mixtures. The experimental results indicate that it is feasible to fully employ SA in concrete for 3D printing. Mixtures with slump values ranging from 40 to 80 mm and slump flow values varying from 190 to 210 mm are recommended for 3D printing. The optimal mix is determined to have SA/C and W/C ratios of 1.0 and 0.51, respectively, and an SF content of 10% by cement weight. A statistical approach was utilized to construct the prediction models for slump and slump flow. Moreover, to predict the plastic failure of the 3D-printed concrete structure, the modified prediction model with an SA roughness coefficient of 4 was found to fit well with the experimental data. This research provides new insights into using eco-friendly materials for 3D concrete printing. [ABSTRACT FROM AUTHOR]

Although soil stabilization with cement and lime is widely used to overcome the low shear strength of soft clay, which can cause severe damage to the infrastructures founded on such soils, such binders have severe impacts on the environment in terms of increasing emissions of carbon dioxide and the consumption of energy. Therefore, it is necessary to investigate soil improvement using sustainable materials such as byproducts or natural resources as alternatives to conventional binders—cement and lime. In this study, the combination of cement kiln dust as a byproduct and zeolite was used to produce an alkali-activated matrix. The results showed that the strength increased from 124 kPa for the untreated clay to 572 kPa for clay treated with 30% activated stabilizer agent (activated cement kiln dust). Moreover, incorporating zeolite as a partial replacement of the activated cement kiln dust increased the strength drastically to 960 and 2530 kPa for zeolite ratios of 0.1 and 0.6, respectively, which then decreased sharply to 1167 and 800 kPa with further increasing zeolite/pr to 0.8 and 1.0, respectively. The soil that was improved with the activated stabilizer agents was tested under footings subjected to eccentric loading. The results of large-scale loading tests showed clear improvements in terms of increasing the bearing capacity and decreasing the tilt of the footings. Also, a reduction occurred due to the eccentricity decreasing as a result of increasing the thickness of the treated soil layer beneath the footing. [ABSTRACT FROM AUTHOR]

Natural reinforcement (for example: flax and jute) have already shown that it can be applied in composite parts to decrease the weight (up to 30 %) and the cost of vehicle production (by approximately 20 %), ultimately reducing the environmental burden. Their early utilization in the automotive sector dates to the 1990s in Europe. Natural fibers constitute an adequate substitute for E-glass due to their lower specific gravity, which means that natural fibers can provide more specific strength over stiffness when combined with a plastic matrix. These advantages help replace non-biodegradable (synthesis) composites and are beneficial for consumers. Taking advantage of the "environmentally friendly composites", car manufacturers utilize them in the manufacture of components such as headliners, dashboards, door panels, and trunk-liners. The present paper summarizes research findings on natural fiber properties and their utilization in natural-fiber composites (NFC, or NFRC – natural-fiber reinforced composite) with a focus on the field of automotive production. [ABSTRACT FROM AUTHOR]

This review presents a comprehensive exploration of the advancements in polymer composites, focusing on their performance, manufacturing processes, recycling techniques, and sustainable practices. With the increasing demand for high-performance materials in various industries, including aerospace, automotive, and construction, polymer composites have emerged as a pivotal solution, offering unparalleled strength, durability, and lightweight properties. This review explores the essential characteristics of polymer composite materials and blends, highlighting the synergy between various matrices and reinforcements that lead to improved material properties. Significant emphasis is given to high-performance composites, where the integration of innovative materials and additives has led to revolutionary applications. By examining the material properties and performance, this review highlights the capabilities of polymer composites to meet rigorous requirements in special cases and extreme conditions. Furthermore, it explores the environmental impact of these materials, promoting sustainable practices throughout their lifecycle. The critical role of recycling in the manufacturing process is dissected to unveil strategies that not only mitigate environmental harm but also promote the circular economy in the composite industry. It addresses both the challenges and opportunities presented by these materials, offering insights into future directions for research and application. [ABSTRACT FROM AUTHOR]

Green roofs are nature-based solutions with multiple benefits for the urban environment, but they have specific polymeric components in their structure that cause a carbon footprint. This scoping review highlights the technological advance in reusing or recycling alternative materials in green roof structures worldwide, making them a part of the circular economy (CE), and the search strategies to promote them to find whether there is a relation between them. The data were collected using the Web of Science from 2012 to 2022; we also used the Bibliometrix package to analyse research development by country and the development of the topic by author's keywords. We selected 68 open-access articles from twenty-four countries and reviewed the grey literature from the top five productive countries on this topic. Our findings show that CE strategies are performed nationally, while the green roof promotion ones are concentrated at the city level. The theme co-occurrence analysis showed that the substrate is the primary layer used with alternative materials, and the three materials most applied for it are rubber, biochar, and hydrogel. It was found that the primary purpose of optimising green roofs with alternative materials is to increase the ecosystem services they provide and indirectly function within the circular economy; still, there is a gap in estimating the environmental impact of doing this as a potential CE activity. [ABSTRACT FROM AUTHOR]

Ink-jet-printed silk, a premium textile material, was achieved by utilizing a bio-based gardenia blue dye. However, the sharpness of the printing pattern is difficult to control due to the limited water-retention capacity of silk. To address this issue, three polysaccharide derivatives, namely, sodium alginate (SA), low-viscosity hydroxypropyl methyl cellulose (HPMC-I), and high-viscosity hydroxypropyl methyl cellulose (HPMC-II), were employed as thickeners to modify the silk by the dipping–padding method. Firstly, the preparation of the gardenia blue ink and the rheology assessment of the thickener solution were conducted. Furthermore, the impacts of different thickeners on the micro-morphology, element composition, and hydrophilicity of the silk, along with the wetting behavior of the ink on the silk, were analyzed comparatively in order to identify an appropriate thickener for preserving pattern outlines. Lastly, the color features, color fastness, and wearing characteristics of the printed silk were discussed to evaluate the overall printing quality. Research results showed that the optimized ink formulation, comprising 12% gardenia blue, 21% alcohols, and 5.5% surfactant, met the requirements for ink-jet printing (with a viscosity of 4.48 mPa·s, a surface tension of 34.12 mN/m, and a particle size of 153 nm). The HPMC-II solution exhibited prominent shear-thinning behavior, high elasticity, and thixotropy, facilitating the achievement of an even modification effect. The treatment of the silk with HPMC-II resulted in the most notable decrease in hydrophilicity. This can be attributed to the presence of filled gaps and a dense film on the fibers' surface after the HPMC-II treatment, as observed by scanning electron microscopy. Additionally, X-ray photoelectron spectroscopy analysis confirmed that the HPMC-II treatment introduced the highest content of hydrophobic groups on the fiber surface. The reduced hydrophilicity inhibited the excessive diffusion and penetration of gardenia blue ink, contributing to a distinct printing image and enhanced apparent color depth. Moreover, the printed silk demonstrated qualified color fastness to rubbing and soaping (exceeding grade four), a soft handle feeling, an ignorable strength loss (below 5%), and a favorable air/moisture penetrability. In general, the surface modification with the HPMC-II treatment has been proven as an effective strategy for upgrading the image quality of bio-based dye-printed silk. [ABSTRACT FROM AUTHOR]

This research aims to enhance natural rubber (NR) properties by incorporating spent coffee grounds (SCGs). Scanning electron microscope (SEM) reveals well‐dispersed SCG particles in the NR matrix without interaction. Shore A hardness notably increases by up to 49.90 (19% higher than unmodified), but tensile and tear strength decline with higher SCG levels. Optimal tear strength occurs at 10 phr of SCG due to uniform dispersion. The 300% modulus remains unchanged. The odor of composites (CO2 absorption) sees a 69.2% increase at 25 phr, while odor absorption efficiency peaks at 2%. Additionally, unmodified SCG affects scorch time (2.12%–23.40% increase from 1 to 20 phr) and cure time (3.12% to 76.82% improvement from 1 to 20 phr). These findings showcase improved hardness, enhanced CO2 absorption capacity, and effective odor control. Additionally, this study sheds light on the influence of SCG on processing times, contributing valuable insights for eco‐friendly applications. [ABSTRACT FROM AUTHOR]

It is nowadays recognized that the building sector causes the greatest environmental impact in terms of both waste production and carbon emissions. Within the context of ecologically sustainable development (ESD), the construction sector is looking for more eco-friendly materials, such as natural fibres. Natural fibers are worldwide recognized as ideal replacement for traditional construction materials, providing excellent thermal and acoustic insulation for building but also for adoption as reinforcement fibers in cement mortars, composite materials, solid boards/panels, raw biomasses, multi-layers, filled loosen/foaming types, particles, slurry types, coils, bricks, etc. The aim of this work is to provide a clear overview on the natural fibers currently employed in the green production of building components, with the main focus on wool fibers deriving from the livestock sector, where wool waste disposal is a crucial problem. This article is a review conducted using the Systematic Literature Review (SLR) approach, a globally recognized method that is not inherently innovative. The innovation of this article lies in the addressed topic, which is relatively new and has only recently gained significant attention, resulting in a limited number of highly relevant articles in the literature.A systematic literature review of the use of wool fibers for green building components is conducted herein to highlight the characteristics that make such material a usable resource in the construction sector and the limits of its use. Given the findings from the reviewed papers, the authors could document that most of the reviewed articles aimed at analyzing the mechanical, thermal, and acoustic properties of building components containing wool fibres. The review highlights that the strength of the wool fiber relies on its thermal properties which can be exploited for building thermal insulation. The wool fiber is also featured to provide good resistance to flexural loads; conversely, all the studies highlighted a negative effect of wool fibers on the compressive behavior of the investigated building components. The analysis of the acoustic properties showed that given the strong capacity of the wool fiber to absorb sound, wool is a great alternative to the conventional materials derived from non-renewable resources.Nevertheless, despite the eligibility of such fiber to be employed soon in the building sector, the analysis about the economic viability of the manufacturing process suggests that the high costs for the raw material, labor, electricity, and above all the high volume of water have to be drastically reduced by prompting the development of sheep wool fiber waterless processing. The achieved results could represent a first step in planning the sustainable re-use of wool waste as natural, renewable, and biodegradable fiber in the construction sector, providing the possibility of creating a new supply chain and solving the problem of its disposal.

IntroductionThe demand for sustainable food packaging materials has led to the exploration of bioactive composite films. This study aimed to prepare and evaluate a composite film made from sweet potato peel polyphenols extract and sweet potato starch (SPS) for its potential use in food packaging.MethodsThe composite film was prepared by uniformly dispersing 0.4% sweet potato peel polyphenols in the SPS matrix. Physicochemical properties and functional characteristics were assessed, including mechanical properties, UV barrier, water and gas barrier properties, antioxidant activity, and antimicrobial abilities against Bacillus subtilis, Escherichia coli, and Staphylococcus aureus. The film's efficacy in food packaging was tested using fresh cherry tomatoes, stored at 4°C, to determine its impact on shelf life.ResultsThe starch-based sweet potato peel polyphenols film demonstrated enhanced mechanical properties and excellent UV barrier properties. It showed improved water and gas barrier properties and strong antioxidant activity, with clearance rates above 90% for DPPH and ABTS radicals. The film also exhibited effective antimicrobial abilities against the tested bacteria. Food packaging experiments indicated that the film could extend the shelf life of fresh cherry tomatoes to 7 days when stored at 4°C.DiscussionThe results suggest that the developed composite film has significant potential as an eco-friendly food packaging material. Its multifunctional properties, including UV protection, barrier enhancement, antioxidant activity, and antimicrobial capabilities, make it a promising candidate for extending the shelf life of perishable foods. The film's performance in slowing spoilage and extending the shelf life of cherry tomatoes highlights its practical application prospects in the food industry.

Abstract In a context where sustainable construction and ecology are increasingly central, the construction industry is constantly seeking alternative materials that are both economical and eco-friendly. Concurrently, global rice production generates significant amounts of rice husks, often considered as low-value waste. This study deviates from traditional approaches that favor the use of rice husk ash (RHA) as a mineral additive, to explore the potential of rice husks themselves as a complete substitute for sand in concrete formulations. After meticulous characterization of the physicochemical properties of rice husks, several concrete formulations were designed and subjected to a battery of tests. The results are promising. They show that concrete based on rice husks exhibits satisfactory mechanical properties for a wide range of applications, from slabs to load-bearing walls. The compressive strength varies between 0.56 MPa and 5.41 MPa depending on the composition, while the thermal conductivity falls within a range of 0.070 W m−1 K−1 to 0.129 W m−1 K−1, which is comparable to other agro-concretes. This research highlights the promising potential of rice husks as a sand substitute material in concrete. It thus paves the way for more ecologically responsible and economically viable construction alternatives, while proposing a value-added solution for a widely available agricultural byproduct.

Combining organometallic frameworks with graphene oxide presents a fresh strategy to enhance the electrochemical capabilities of supercapacitors, contributing to the advancement of sustainable energy solutions. Continued refinement of materials and device design holds promise for broader applications across energy storage and conversion systems. This featured application underscores the inventive utilization of organometallic frameworks on graphene oxide, shedding light on the creation of superior energy storage devices for eco-friendly solutions. This review article delves into the synergistic advancements resulting from the fusion of organometallic frameworks with graphene oxide, offering a thorough exploration of their utility in sustainable eco-energy solutions. This review encompasses various facets, including synthesis methodologies, amplified catalytic performances, and structural elucidations. Through collaborative efforts, notable progressions in photocatalysis, photovoltaics, and energy storage are showcased, illustrating the transformative potential of these hybrids in reshaping solar energy conversion and storage technologies. Moreover, the environmentally conscious features of organometallic–graphene oxide hybrids are underscored through their contributions to environmental remediation, addressing challenges in pollutant elimination, water purification, and air quality enhancement. The intricate structural characteristics of these hybrids are expounded upon to highlight their role in tailoring material properties for specific eco-energy applications. Despite promising advancements, challenges such as scalability and stability are candidly addressed, offering a pragmatic view of the current research landscape. The manuscript concludes by providing insights into prospective research avenues, guiding the scientific community towards surmounting hurdles and fully leveraging the potential of organometallic–graphene oxide hybrids for a sustainable and energy-efficient future. [ABSTRACT FROM AUTHOR]

This work aimed to manufacture bioplastics with mechanical and electrical properties for monitoring the Rhizopus stolonifer growth in tomato fruit packaging. Bioplastics were based on chitosan/polyvinyl alcohol (Ch/PVA), chitosan/polyvinyl pyrrolidone (Ch/PVP), and nanoparticles (NPs) of plant extracts at 10% and 30% of concentrations. Bioplastics were exposed to tomato inoculated with R. stolonifer for 6 d at 25°C. Water vapor permeability (WVP), mechanical properties, FTIR, UV–vis, morphology, electrical resistance of bioplastics, and the NPs size were assessed. In bioplastics added with plant extracts, 1.5 times more WVP than in the control group (18–35 gs−1m−1Pa−1) were quantified. Ch/PVA bioplastic showed 51% more tensile strength, 44% more elongation at break, and 40% more Young's modulus than Ch/PVP, regardless of the plant extract. The electrical resistance in Ch/PVA bioplastics with 30% mushroom extract and 10% radish allowed the differentiation between inoculated (109–1010 Ω) and non‐inoculated tomatoes (1010–1011 Ω). The FTIR assay confirmed the presence of each compound used in the bioplastic, and UV–vis confirmed phenols at 300 nm. The NPs measured less than 50 nm. Only Ch/PVA with 30% mushroom and 10% radish can be useful to monitor fungi in tomatoes based on their electrical behavior. [ABSTRACT FROM AUTHOR]

In a context where sustainable construction and ecology are increasingly central, the construction industry is constantly seeking alternative materials that are both economical and eco-friendly. Concurrently, global rice production generates significant amounts of rice husks, often considered as low-value waste. This study deviates from traditional approaches that favor the use of rice husk ash (RHA) as a mineral additive, to explore the potential of rice husks themselves as a complete substitute for sand in concrete formulations. After meticulous characterization of the physicochemical properties of rice husks, several concrete formulations were designed and subjected to a battery of tests. The results are promising. They show that concrete based on rice husks exhibits satisfactory mechanical properties for a wide range of applications, from slabs to load-bearing walls. The compressive strength varies between 0.56 MPa and 5.41 MPa depending on the composition, while the thermal conductivity falls within a range of 0.070 W m−1 K−1 to 0.129 W m−1 K−1, which is comparable to other agro-concretes. This research highlights the promising potential of rice husks as a sand substitute material in concrete. It thus paves the way for more ecologically responsible and economically viable construction alternatives, while proposing a value-added solution for a widely available agricultural byproduct. [ABSTRACT FROM AUTHOR]

Natural fibers, known for their accessibility and biodegradability, have been explored as alternatives in fiberboard production. This research focuses on harnessing pineapple leaves for crafting paper and fiberboard sheets. Three classifications of pineapple leaves underwent NaOH treatment (ranging from 0.5 to 2%) to facilitate paper production. Optimal NaOH concentrations were determined to be 2% for dried pineapple leaves, 0.5% for fresh pineapple leaves, and 0.5% for a mix of fresh pineapple leaves and straw. In the context of fiberboard sheets, thicknesses were standardized using an extrusion force of 8 kef/cm2, resulting in 6, 9, and 12 mm variants. Flexural strength, tested in line with ASTM C293, peaked at 15.120 MPa for the 12 mm variant. Notably, water absorption capability improved by 65% when using the 12 mm pineapple leaf fiberboard. The observed thermal conductivity of this fiberboard lay between 0.03957 and 0.04295 W/m.K, denoting low thermal conductivity. These findings pave the way for the production of fiberboards tailored for residential constructions and energy-efficient applications, capitalizing on agricultural byproducts. [ABSTRACT FROM AUTHOR]

Recent earthquakes and escalating energy demands are exposing building stock deficiencies, particularly in terms of seismic resilience and energy efficiency. Many aged constructions do not fulfil current regulations both in terms of seismic and thermal design principles, thus requiring suitable retrofitting solutions. Integrated approaches for concurrent seismic and energy renovation have emerged as promising strategies in recent years, offering holistic solutions that optimize interventions and maximize benefits. While these combined methods hold significant potential for practical applications, there remain opportunities for further research to enhance their advantages. Furthermore, addressing climate concerns requires concentrated effort within the construction sector, where synergetic refurbishments can serve a dual purpose by reducing emissions and promoting the use of more sustainable materials. This study discusses strategies proposed in the literature for integrated retrofitting, considering their environmental impact, both in terms of energy performance and embodied carbon. The overview shows the innovation potential for the development of materials and systems combining acceptable performance with eco-friendly attributes. Yet, their application in integrated retrofitting systems, either as structural components or insulators, is still limited, underscoring the need for continued investigation and advancement. This paper concludes with recommendations to inspire further research and advancements in this critical field. [ABSTRACT FROM AUTHOR]

In the context of large museum centers, numerous national and international methodological experiments show the need to consider, in wayfinding design, both the intangible issues of experience arising from perception and involvement (user-centered design), and social and environmental issues (environment-centered design). The aim of this research is to propose a tool for organizing integrated information on so-called smart materials that takes both perspectives into account. This study was performed by conducting a two-phase systematic literature and library review of materials. Specifically, 63 scientific articles—selected by keywords, publication date and content—and 7 national and international material libraries were investigated. The investigation highlighted how the sensory characteristics of wayfinding materials in museums are treated separately from the environmental characteristics and how the quality of the technical information of the materials filed in the material libraries could be improved. The result of the research concerns the structuring of a 'standard sheet' for the cataloguing of materials that integrates technical (sensory and environmental) information while also offering a contextualization of the material within wayfinding application cases in known museums. The proposed tool facilitates designers in the selection of materials to be adopted in the wayfinding project, offering information both on their ability to offer alternative communication channels in response to different users' sense–perceptual functioning and on their quantitative environmental impact properties. This study conducted through the integration of different multidisciplinary fields (technological approach to design, inclusive design, environmental psychology, material science, visual communication, environmental protection related to people's well-being) offers a significant contribution in the context of museum wayfinding design, providing stakeholders with practical tools to select materials that promote inclusion and sustainability. [ABSTRACT FROM AUTHOR]

A simple, low-cost, and environmentally benign process for synthesizing nanostructured NiO/NiAl2O4 on multiple kinds of carbon nanostructures (CNS) is presented. This method develops polylactic acid (PLA) based waste plastic materials for the producing CNS. These composites (NiO@NiAl2O4/CNS) were examined as potential electrodes in supercapacitors (SC) as they exhibit good charge/discharge reversibility and provide adequate specific capacitance values with a maximum being 1984 F/g at 0.5 A g-1. It is noteworthy that the cycling stability of this sample at 10 A g-1 maintained 101.7% of its initial capacity even after 5000 GCD cycles. An asymmetric supercapacitor (ASC) was built and analyzed, with NiO@NiAl2O4/CNS serving as the cathode and activated carbon serving as the anode of the device. The concluded device has an energy density of 58 Wh kg-1 with a power density of 986 W kg-1 and a SCs of 216.5 F/g. The results showed that the materials mentioned are a great option to use as electrode materials in applications involving the storage of energy. [ABSTRACT FROM AUTHOR]

BackgroundChicken eggshells, a common poultry byproduct, are rich in calcium and provide a sustainable source for producing calcium oxide nanoparticles (CaO NPs). Their use in eco-friendly synthesis aligns with the growing emphasis on sustainable materials for environmental and biomedical applications. Objectives: This study develops an eco-friendly method for synthesizing CaO NPs from chicken eggshells, characterizes their physicochemical properties, and evaluates their antibacterial and antifungal activities. It also tests their effectiveness in removing heavy metal ions (Pb2⁺, Cr2⁺, Cd2⁺, and Hg2⁺) from aqueous solutions.MethodsCaO NPs were synthesized by calcining chicken eggshells at 700°C for 7 h. Comprehensive characterization included analysis of crystalline structure, morphology, optical properties, bandgap energy, chemical composition, and thermal stability. Antibacterial and antifungal activities were tested using the well-agar diffusion method. Batch adsorption experiments evaluated heavy metal ion removal under varying conditions of pH, temperature, stirring time, and adsorbent concentrationResultsThe synthesis produced spherical, single-crystal CaO NPs with diameters ranging from 5 to 30 nm and a crystalline size of approximately 20 nm. The nanoparticles had a bandgap energy of about 4.7 eV. Significant antibacterial activity was observed against Staphylococcus aureus, Klebsiella pneumoniae, and Escherichia coli, with increasing inhibition zones correlating with nanoparticle concentration. The CaO NPs also effectively inhibited Candida albicans. For efficient metal ion removal, the optimal conditions were found to be 30 min at pH 6 with 40 mg of CaO NPs at 25°C, achieving recovery rates of 98% for Pb2⁺, 97% for Cd2⁺, 97% for Cr2⁺, and 97% for Hg2⁺. For near-complete removal, extending the process to 70 min at pH 6 with 40 mg of CaO NPs at 45°C achieved the highest recovery rates: 99% for Pb2⁺, 98% for Cd2⁺, 99% for Cr2⁺, and 99% for Hg2⁺, though this approach involves higher energy and cost.ConclusionCaO NPs derived from chicken eggshells are effective antibacterial agents and adsorbents for heavy metal removal. These findings highlight their potential for sustainable applications in environmental and biomedical fields.

The fight against climate change has delineated new objectives, among which one of the most crucial is the replacement of high-energy-intensity materials in the construction sector with more sustainable and thermally efficient alternatives to reduce indirect emissions. Consequently, the thermal properties of materials assume fundamental importance. In this regard, the large-scale use of earth represents a promising option, not only due to its widespread availability but especially for its minimal embodied energy. However, to enhance its durability, it is necessary to stabilize the mixtures of raw materials. This study analyzes experimental systems based on earth stabilized with bio-based polymers to evaluate their thermal properties and how these vary depending on the selected mix-design. The experimental measurements showed thermal properties comparable to conventional materials. As expected, thermal conductivity increases when porosity decreases. The minimum value is equal to 0.216 W/m·K vs. a porosity of 43.5%, while the maximum is 0.507 W/m·K vs. a porosity of 33.2%. However, the data obtained for individual systems may vary depending on the topological characteristics, which were analyzed through a model for granular materials. The modeling suggests correlations between microstructures and thermal behaviour, which can be useful to develop tools for the mix-design procedure. [ABSTRACT FROM AUTHOR]

This paper introduces a novel modular retrofitting solution to enhance the energy efficiency and seismic resilience of building façades, particularly within the Portuguese context. In the context of Europe's "Renovation Wave" strategy, and as a product of the nationally funded ZeroSkin+ project, the proposed renovation solution addresses the urgent need for sustainable building renovations to help mitigate climate change and meet European climate neutrality goals by 2050. Unlike traditional methods that often rely on non-eco-friendly materials without integrating seismic and thermal performances, the renovation solution leverages fused deposition modelling (FDM) 3D printing technology to introduce a dual-layered panel system. This system features a durable, UV-resistant PET-G thermoplastic outer layer and a cork interior to ensure additional thermal insulation. The integrated renovation solution shows a 42% improvement in seismic reinforcement's out-of-plane capacity and achieves U-values as low as 0.30 W/m2·K, exceeding Portugal's thermal efficiency standards (0.35 to 0.50 W/m2·K). The proposed renovation solution also embraces circular economy principles, emphasising waste reduction and recyclability. [ABSTRACT FROM AUTHOR]

Increasing industrialization and rapid change in market demand has led to aggressive competition impacting both business and environmental sustainability globally. In view of the new legislations, regulations and restrictions on the usage of hazardous materials, it becomes mandatory to use eco-friendly materials. In the present work, various petroleum-based and different modified vegetable oils are characterised for chemical and analytical properties. Styrene butadiene rubber (SBR) is extended with these oils at laboratory scale through emulsion polymerisation technique. Totally four number of petroleum-based oils like distillate aromatic extract (DAE), treated distillate aromatic extract (TDAE), residual aromatic extract (RAE) and naphthenic type oil and two number of modified vegetable oils, NO_2 and NO_6, are evaluated. All oils have shown compatibility with SBR latex which is confirmed by checking solvent extractables as well as oil leaching checking by visual inspection of oil extended rubber samples. These raw rubber samples are characterised for raw rubber properties as well as in ASTM-based rubber compound recipe to check their processing behaviour. Compounds prepared with both vegetable oil-based styrene butadiene rubber have shown comparable or slightly better processing properties as compared to compounds prepared with petroleum oil-based rubbers. Experimental compounds are also showing comparable carbon black dispersion and better polymer–filler interaction which may be due to the presence of various surface functional groups in vegetable oils. Microscopic pictures also confirm the comparable carbon black dispersion for all the samples. [ABSTRACT FROM AUTHOR]

A comparative "cradle to grave" Life Cycle Analysis between the production processes of ceramic stoneware products and geopolymeric materials obtained by valorizing ceramic wastes is reported. This study presents an effective eco-design approach to obtain sustainable materials through a low energy consumption manufacturing process, a feature that is essential in a historical period of high geopolitical instability which makes the supplying of fossil fuels difficult and particularly expensive. In particular, the possibility of lowering production costs (saving on the cost of waste disposal, using a raw-second material, and a low-temperature production process) could represent a strong contribution to the environmental and economic sustainability of the Italian ceramic industry, which is going through a time of severe financial crisis which due to the unprecedent high cost of raw materials and energy. Finally, the new geopolymeric systems proposed in this paper could be profitably used in the field of green building, art, eco-design, and technical-artistic value-added applications, such as restoration, conservation, and/or rehabilitation of historic monuments, or simply as materials for building revetments. [ABSTRACT FROM AUTHOR]

In response to the growing global concern for environmental sustainability, a Life Cycle Assessment (LCA) study was conducted to evaluate the environmental benefits of the "Formula Servizi" GREEN protocol compared to a conventional cleaning protocol, as mandated by the updated Criteria for Environmental Sustainability (CAM—Criteri Ambientali Minimi) for cleaning services. The CAM, effective on 19 June 2021, requires companies to demonstrate the environmental advantages of their cleaning protocols over traditional methods. This study aligns with the new CAM guidelines and employs UNI EN ISO 14040–14044 technical standards for a comprehensive comparative analysis. The study highlights the significance of maintaining hygiene to ensure safety in various contexts, emphasizing the importance of environmental sampling and monitoring to prevent contamination and infection transmission. Despite the complexity and expenses associated with microbiological monitoring, this research affirms its crucial role in validating cleaning procedures, particularly in healthcare facilities, food service areas, and industrial settings. The findings reveal that both the "Traditional" and "GREEN" cleaning protocols demonstrate satisfactory effectiveness in controlling microbiological contamination according to established guidelines. Moreover, the LCA results indicate that the "GREEN" protocol, while exhibiting higher water consumption and wastewater treatment, showcases a strategic use of more sustainable cleaning and laundry detergents. Despite the increased water usage in certain phases, the significantly lower environmental impact per unit of weight demonstrates the potential for optimizing both environmental sustainability and operational efficiency in future Life Cycle Sustainability Assessment (LCSA) endeavors. The comparative LCA further reveals that the "GREEN" protocol enables an annual avoidance of 260 g of CO2-e emissions per square meter of cleaned surface. The most significant reduction in absolute terms is associated with the use of eco-labeled detergents in the laundry system, resulting in the avoidance of 654.1 kg of CO2-e per year of service (−77% compared to traditional laundry detergents). [ABSTRACT FROM AUTHOR]

Fragility and the presence of a poisonous substance (lead) are the two major issues with traditional piezoceramics and structures that include them. This work suggests an active structure that is lightweight, flexible, and eco-friendly such that a polymeric foam plate is sandwiched between two piezoelectrically activated nanocomposite layers. A combination of a polymer and piezoelectric nanowires (NWs) of zinc oxide (ZnO) is used in the nanocomposite layers. For the proposed active structure, two types of void distributions and functionally graded (FG) distributions of the NWs have been assumed in each corresponding layer. The buckling characterization of the proposed eco-friendly active sandwich plate (EFASP) under biaxial mechanical loads has been conducted using an extended meshless solution based on a third-order theory. An in-depth parametric study on the EFASPs' biaxial buckling resistance revealed that increasing NW content considerably enhances buckling resistance, with this enhancement strongly reliant on the distribution profile of the NWs. Moreover, it was observed that embedding voids in the substrate layer can lead to a large structural weight reduction while only marginally lowering the buckling performance of suggested EFASPs. [ABSTRACT FROM AUTHOR]

The recycling of the enormous number of used tires that are discarded annually after the end of their service is a high-priority issue in order to conserve the environment and reduce the raw material costs of products, particularly in cases where high strength requirements are not necessary. In this study, crumbed tire rubber (CTR) was used as a filler with different weight fractions (10%, 20%, 30%, and 40%) to prepare CTR/epoxy composites. Mechanical, thermal, and acoustic insulation properties were tested to gather sufficient data on the development of these properties with increasing CTR content. The results indicate a decline in mechanical properties with increasing CTR content. The composite with 40 wt. % CTR showed a decrease in hardness, tensile strength, and flexural strength compared to neat epoxy by 75%, 70%, and 75% respectively. Additionally, the thermal conductivity of this composite was 36.3% higher than that of epoxy. Finally, the acoustic insulation test for the composite with a 40% CTR weight fraction showed improved sound insulation over a wide range of applied frequencies (0-10000) Hz. [ABSTRACT FROM AUTHOR]

The high-power lasers have important implications for present and future light-based technologies; therefore, the protection measures against their high-intensity radiation are extremely important. Currently, a great deal of interest is directed towards the development of new nonlinear optical materials for passive optical limiters, which are used to protect the human eye and sensitive optical and optoelectronic devices from laser-induced damage. Biopolymers doped with natural dyes are emerging as a new class of optical materials with interesting photosensitive properties. In this paper, the optical limiting capability of deoxyribonucleic acid bio-polymer functionalized with Turmeric natural dye has been demonstrated for the first time, to the best of our knowledge. The experimental investigation of the optical limit has been done by the Intensity-scan method in the NIR spectral domain at the important telecommunication wavelength of 1550 nm, using ultrashort laser pulses (~120 fs). Several optical properties of this natural dye are presented and discussed. The values of the optical transmittance in the linear regime, the saturation intensity of the nonlinear transmittance curves, and the coefficient of the nonlinear absorption have been determined. The influence of the DNA biopolymer and natural dye concentration on the optical limiting properties of the investigated biomaterials is reported and discussed. The photostability and thermal stability of the investigated solutions have also been evaluated by monitoring the temporal decay of the normalized absorption spectra under illumination with UVA light and heating, respectively. Our results evidence the positive influence of the DNA, which embeds Turmeric natural dye, on the optical limiting functionality itself and on the photostability and thermal stability of this novel material. The performed study reveals the potential of the investigated novel biomaterial for applications in nonlinear photonics, in particular in optical limiting. [ABSTRACT FROM AUTHOR]

In recent years, the growth of Internet of Things devices has increased the use of sustainable energy sources. An alternative technology is offered by triboelectric nanogenerators (TENGs) that can harvest green energy and convert it into electrical energy. Herein, we assessed three different nopal powder types that were used as triboelectric layers of eco-friendly and sustainable TENGs for renewable energy harvesting from environmental vibrations and powering electronic devices. These nanogenerators were fabricated using waste and recycled materials with a compact design for easy transportation and collocation on non-homogeneous surfaces of different vibration or motion sources. In addition, these TENGs have advantages such as high output performance, stable output voltage, lightweight, low-cost materials, and a simple fabrication process. These nanogenerators use the contact-separation mode between two triboelectric layers to convert the vibration energy into electrical energy. TENG with the best output performance is based on dehydrated nopal powder, generating an output power density of 2.145 mWm−2 with a load resistance of 39.97 MΩ under 3g acceleration and 25 Hz operating frequency. The proposed TENGs have stable output voltages during 22500 operating cycles. These nanogenerators can light 116 ultra-bright blue commercial LEDs and power a digital calculator. Also, the TENGs can be used as a chess clock connected to a mobile phone app for smart motion sensing. These nanogenerators can harvest renewable vibration energy and power electronic devices, sensors, and smart motion sensing.

Although soil stabilization with cement and lime is widely used to overcome the low shear strength of soft clay, which can cause severe damage to the infrastructures founded on such soils, such binders have severe impacts on the environment in terms of increasing emissions of carbon dioxide and the consumption of energy. Therefore, it is necessary to investigate soil improvement using sustainable materials such as byproducts or natural resources as alternatives to conventional binders—cement and lime. In this study, the combination of cement kiln dust as a byproduct and zeolite was used to produce an alkali-activated matrix. The results showed that the strength increased from 124 kPa for the untreated clay to 572 kPa for clay treated with 30% activated stabilizer agent (activated cement kiln dust). Moreover, incorporating zeolite as a partial replacement of the activated cement kiln dust increased the strength drastically to 960 and 2530 kPa for zeolite ratios of 0.1 and 0.6, respectively, which then decreased sharply to 1167 and 800 kPa with further increasing zeolite/pr to 0.8 and 1.0, respectively. The soil that was improved with the activated stabilizer agents was tested under footings subjected to eccentric loading. The results of large-scale loading tests showed clear improvements in terms of increasing the bearing capacity and decreasing the tilt of the footings. Also, a reduction occurred due to the eccentricity decreasing as a result of increasing the thickness of the treated soil layer beneath the footing.

Green roofs are nature-based solutions with multiple benefits for the urban environment, but they have specific polymeric components in their structure that cause a carbon footprint. This scoping review highlights the technological advance in reusing or recycling alternative materials in green roof structures worldwide, making them a part of the circular economy (CE), and the search strategies to promote them to find whether there is a relation between them. The data were collected using the Web of Science from 2012 to 2022; we also used the Bibliometrix package to analyse research development by country and the development of the topic by author’s keywords. We selected 68 open-access articles from twenty-four countries and reviewed the grey literature from the top five productive countries on this topic. Our findings show that CE strategies are performed nationally, while the green roof promotion ones are concentrated at the city level. The theme co-occurrence analysis showed that the substrate is the primary layer used with alternative materials, and the three materials most applied for it are rubber, biochar, and hydrogel. It was found that the primary purpose of optimising green roofs with alternative materials is to increase the ecosystem services they provide and indirectly function within the circular economy; still, there is a gap in estimating the environmental impact of doing this as a potential CE activity.

The possibility of plants growing on serpentine soils and the ability of serpentine minerals to accumulate significant amounts of metals was the basis for developing a method for using serpentine-containing materials to restore vegetation in areas with a high level of metal pollution. Serpentine-containing products obtained from phlogopite mining overburden (Kovdor, Murmansk region, Russia) with and without thermal activation were used in a field experiment on the remediation of industrially polluted peat soil. According to the geochemical mobility of the components, one of four fractions was allocated depending on the acidic (HCl) concentration of the solution used for the material treatment: readily mobile (0.001 mol/L), mobile (0.01 mol/L), potentially mobile (0.1 mol/L), and acid-soluble (1.0 mol/L). This study showed that the addition of serpentinites to peat soil changed the fraction composition. The most significant changes were noted for serpentinite components such as Ca and Mg: their concentrations increased 2–3 times even in the smallest portion of serpentine material. On the contrary, the contents of metals in the readily mobile fraction decreased 3–18, 3–23, 5–26, and 2–42 times for Cu, Ni, Fe, and Al, respectively. The main factor causing the decrease in metal mobility was the pH rise due to the release of Ca and Mg compounds into the soil solution. This study showed that the addition of serpentine-containing material at 25 vol.% to peat soil was sufficient to create a geochemical barrier with a stable-functioning vegetation cover. All serpentine-containing materials are recommended for the remediation of large industrially polluted areas. [ABSTRACT FROM AUTHOR]

This preliminary study investigates the emission characteristics of formaldehyde (HCHO) and total volatile organic compounds (TVOC) in indoor environments, comparing the effects of eco-friendly materials and general materials. The study analyzes the concentration changes over time in the living rooms of experimental units to assess the effectiveness of eco-friendly materials in reducing indoor air pollutants. The results show that eco-friendly materials exhibit lower initial emissions of TVOC than general materials, gradually decreasing over time. Compared to the eco-friendly material unit, the general material unit takes longer to reach acceptable TVOC concentrations. The emission pattern of HCHO differs from TVOC, with the highest peak occurring on the seventh day. Major individual VOCs, except for benzene, exhibit a similar decreasing trend for TVOC over time. Eco-friendly materials demonstrate significant reductions in emissions compared to general materials in various material applications, including parquet flooring, wallpaper, built-in furniture, and kitchen furniture. However, the difference in emissions for door and window frames using eco-friendly materials is minimal. These findings emphasize the effectiveness of eco-friendly materials in reducing indoor air pollutants and provide valuable insights for creating healthier living environments. Further research is needed to optimize the application of eco-friendly materials in specific components and investigate their long-term impact on indoor air quality and occupant health. [ABSTRACT FROM AUTHOR]

Combining organometallic frameworks with graphene oxide presents a fresh strategy to enhance the electrochemical capabilities of supercapacitors, contributing to the advancement of sustainable energy solutions. Continued refinement of materials and device design holds promise for broader applications across energy storage and conversion systems. This featured application underscores the inventive utilization of organometallic frameworks on graphene oxide, shedding light on the creation of superior energy storage devices for eco-friendly solutions. This review article delves into the synergistic advancements resulting from the fusion of organometallic frameworks with graphene oxide, offering a thorough exploration of their utility in sustainable eco-energy solutions. This review encompasses various facets, including synthesis methodologies, amplified catalytic performances, and structural elucidations. Through collaborative efforts, notable progressions in photocatalysis, photovoltaics, and energy storage are showcased, illustrating the transformative potential of these hybrids in reshaping solar energy conversion and storage technologies. Moreover, the environmentally conscious features of organometallic–graphene oxide hybrids are underscored through their contributions to environmental remediation, addressing challenges in pollutant elimination, water purification, and air quality enhancement. The intricate structural characteristics of these hybrids are expounded upon to highlight their role in tailoring material properties for specific eco-energy applications. Despite promising advancements, challenges such as scalability and stability are candidly addressed, offering a pragmatic view of the current research landscape. The manuscript concludes by providing insights into prospective research avenues, guiding the scientific community towards surmounting hurdles and fully leveraging the potential of organometallic–graphene oxide hybrids for a sustainable and energy-efficient future.