1. Relativistic coupled-cluster study of RaF as a candidate for parity and time reversal violating interaction
- Author
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Malaya K. Nayak, Sourav Pal, Sudip Sasmal, Nayana Vaval, and Himadri Pathak
- Subjects
Atoms ,Odd ,Atomic Physics (physics.atom-ph) ,FOS: Physical sciences ,Electron ,01 natural sciences ,Physics - Atomic Physics ,Physics - Chemical Physics ,Electric field ,0103 physical sciences ,Hyperfine-Structure ,Ybf Molecule ,010306 general physics ,Hyperfine structure ,Physics ,Chemical Physics (physics.chem-ph) ,Elementary-Particles ,010304 chemical physics ,Enhancement ,Parity (physics) ,Wave-Function ,Electric-Dipole Moment ,Electric dipole moment ,Coupled cluster ,Unpaired electron ,Analytic Energy Derivatives ,Atomic physics ,Ground state ,Radium - Abstract
We have employed both Z-vector method and the expectation value approach in the relativistic coupled-cluster framework to calculate the scalar-pseudoscalar (S-PS) P, T -odd interaction constant (W_s) and the effective electric field (Eeff) experienced by the unpaired electron in the ground electronic state of RaF. Further, the magnetic hyperfine structure constants of ^{223}Ra in RaF and ^{223}Ra+ are also calculated and compared with the experimental values wherever available to judge the extent of accuracy obtained in the employed methods. The outcome of our study reveals that the Z-vector method is superior than the expectation value approach in terms of accuracy obtained for the calculation of ground state property. The Z-vector calculation shows that RaF has a high E_eff (52.5 GV/cm) and W_s (141.2 kHz) which makes it a potential candidate for the eEDM experiment., Comment: 8 pages, 3 figures more...
- Published
- 2016
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