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Developing cost-effective methods for hydrological observations is an identified research objective of the WMO Hydrological Research Strategy 2022-2030. Network settings of hydrological observational networks are central for data collection and monitoring efforts to fulfill observation needs. In this work, we ask the question: Where and how densely (location and time) measurement stations need to be placed to gain sound scientific insights into hydro-meteorological conditions of a region? We address this question through information theory concepts and calculate entropy, joint entropy, and mutual information for an existing large dataset of hydro-meteorological parameters. The dataset spans 36 years (1981-2017) of daily data for Sweden based on the national S-HYPE hydrological model. Hydrological data include runoff, inflow, and streamflow as computed values and meteorological data encompass temperature and precipitation as measured and corrected data. We chose Sweden as a study domain to look at a Nordic region with a large number of water basins and an overall well-sampled region allowing to assess interesting network settings through sub-sampling. Sub-sampling and analysis for potential network settings is done for the seven hydrological clusters across Sweden as they are defined in Girons Lopez et al. (2021). Random sub-sampling (by 10%, 25%, 50%, 75%, and 90%) of each of the seven clusters shows a narrow range of (Shannon) entropy indicating excellent assignment of catchments to the seven clusters. Focusing on three clusters, which span Sweden’s North-South extend and mainly feature forested areas and a cluster covering mostly coastal lakes, we assess how much information remains in the data set if sub-sampled by hydro-geological parameters, such as baseflow and flashiness. Such tests allow us to determine ideal and minimum network settings with respect to observational and computational efforts based on different criteria relevant to scientific investigations and decision-making needs. Girons Lopez, M., Crochemore, L., and Pechlivanidis, I. G.: Benchmarking an operational hydrological model for providing seasonal forecasts in Sweden, Hydrol. Earth Syst. Sci., 25, 1189–1209, https://doi.org/10.5194/hess-25-1189-2021, 2021

The formation of ice particles in Earth's atmosphere strongly influences the dynamics and optical properties of clouds and their impacts on the climate system. Ice formation in clouds is often triggered heterogeneously by ice-nucleating particles (INPs) that represent a very low number of particles in the atmosphere. To date, many sources of INPs, such as mineral and soil dust, have been investigated and identified in the low and mid latitudes. Although less is known about the sources of ice nucleation at high latitudes, efforts have been made to identify the sources of INPs in the Arctic and boreal environments. In this study, we investigate the INP emission potential from high-latitude boreal forests in the mixed-phase cloud regime. We introduce the HyICE-2018 measurement campaign conducted in the boreal forest of Hyytiala, Finland, between February and June 2018. The campaign utilized the infrastructure of the Station for Measuring Ecosystem-Atmosphere Relations (SMEAR) II, with additional INP instruments, including the Portable Ice Nucleation Chamber I and II (PINC and PINCii), the SPectrometer for Ice Nuclei (SPIN), the Portable Ice Nucleation Experiment (PINE), the Ice Nucleation SpEctrometer of the Karlsruhe Institute of Technology (INSEKT) and the Microlitre Nucleation by Immersed Particle Instrument (mu L-NIPI), used to quantify the INP concentrations and sources in the boreal environment. In this contribution, we describe the measurement infrastructure and operating procedures during HyICE-2018, and we report results from specific time periods where INP instruments were run in parallel for inter-comparison purposes. Our results show that the suite of instruments deployed during HyICE-2018 reports consistent results and therefore lays the foundation for forthcoming results to be considered holistically. In addition, we compare measured INP concentrations to INP parameterizations, and we observe good agreement with the Tobo et al. (2013) parameterization developed from measurements conducted in a ponderosa pine forest ecosystem in Colorado, USA., Atmospheric Chemistry and Physics, 22 (8), ISSN:1680-7375, ISSN:1680-7367

Atmospheric subpollen particles (SPPs) released from pollen grains can act as ice nucleating particles. Using a droplet–freezing approach to assess immersion freezing–ice nucleating (IN) activity, ...

The formation of ice particles in Earth’s atmosphere strongly influences the dynamics and optical properties of clouds and their impacts on the climate system. Ice formation in clouds is often triggered heterogeneously by ice nucleating particles (INPs) that represent a very low number of particles in the atmosphere. To date, many sources of INPs, such as mineral and soil dust, have been investigated and identified in the lower latitudes. Although less is known about the sources of ice nucleation at higher latitudes, efforts have been made to identify the sources of INPs in the Arctic and boreal environments. In this study, we investigate the INP emission potential from high latitude boreal forests. We introduce the HyICE-2018 measurement campaign conducted in the boreal forest of Hyytiälä, Finland between February and June 2018. The campaign utilized the infrastructure of the SMEAR II research station with additional instrumentation for measuring INPs to quantify the concentrations and sources of INPs in the boreal environment. In this contribution, we describe the measurement infrastructure and operating procedures during HyICE-2018 and we report results from specific time periods where INP instruments were run in parallel for inter-comparison purposes. Our results show that the suite of instruments deployed during HyICE-2018 reports consistent results and therefore lays the foundation for forthcoming results to be considered holistically. In addition, we compare the INP concentration we measured to INP parameterizations, and we show a very good agreement with the Tobo et al. (2013) parameterization developed from measurements conducted in a ponderosa pine forest ecosystem in Colorado, USA.

Atmospheric ice nucleating particles (INPs) influence global climate by altering cloud formation, lifetime, and precipitation efficiency. The role of secondary organic aerosol (SOA) material as a source of INPs in the ambient atmosphere has not been well defined. Here, we demonstrate the potential for biogenic SOA to activate as depositional INPs in the upper troposphere by combining field measurements with laboratory experiments. Ambient INPs were measured in a remote mountaintop location at –46 °C and an ice supersaturation of 30% with concentrations ranging from 0.1 to 70 L–1. Concentrations of depositional INPs were positively correlated with the mass fractions and loadings of isoprene-derived secondary organic aerosols. Compositional analysis of ice residuals showed that ambient particles with isoprene-derived SOA material can act as depositional ice nuclei. Laboratory experiments further demonstrated the ability of isoprene-derived SOA to nucleate ice under a range of atmospheric conditions. We further show that ambient concentrations of isoprene-derived SOA can be competitive with other INP sources. This demonstrates that isoprene and potentially other biogenically-derived SOA materials could influence cirrus formation and properties., Ice nucleating particles impact the global climate by altering cloud formation and properties, but the sources of these emissions are not completely characterized. Here, the authors show that secondary organic aerosols formed from the oxidation of organic gases in the atmosphere can be a source of ice nucleating particles.

Formic and acetic acid are ubiquitous and abundant in the Earth's atmosphere and are important contributors to cloud water acidity, especially in remote regions. Their global sources are not well understood, as evidenced by the inability of models to reproduce the magnitude of measured mixing ratios, particularly at high northern latitudes. The scarcity of measurements at those latitudes is also a hindrance to understanding these acids and their sources. Here, we present ground-based gas-phase measurements of formic acid (FA) and acetic acid (AA) in the Canadian Arctic collected at 0.5 Hz with a high-resolution chemical ionization time-of-flight mass spectrometer using the iodide reagent ion (iodide HR-ToF-CIMS, Aerodyne). This study was conducted at Alert, Nunavut, in the early summer of 2016. FA and AA mixing ratios for this period show high temporal variability and occasional excursions to very high values (up to 11 and 40 ppbv respectively). High levels of FA and AA were observed under two very different conditions: under overcast, cold conditions during which physical equilibrium partitioning should not favor their emission, and during warm and sunny periods. During the latter, sunny periods, the FA and AA mixing ratios also displayed diurnal cycles in keeping with a photochemical source near the ground. These observations highlight the complexity of the sources of FA and AA, and suggest that current chemical transport model implementations of the sources of FA and AA in the Arctic may be incomplete.

The authors would like to acknowledge the Natural Sciences and Engineering Research Council (NSERC) for funding under grant RGPIN-2017-05972. The authors declare no conflict of interest regarding affiliation or funding. We acknowledge Z. Drab from Pharmallerga for providing the pollen. Figure source data for all plots shown in this publication have been deposited in the University of Toronto Dataverse (doi:10.5683/SP/JLPHBI; Gute & Abbatt, 2018)

Ice nucleating particle (INP) measurements were performed in the boreal environment of southern Finland at the Station for Measuring Ecosystem-Atmosphere Relations SMEAR II in the winter-spring of 2018. Measurements with the Portable Ice Nucleation Chamber (PINC) were conducted at 242 K and 105 % relative humidity with respect to water. The median INP number concentration [INP] during a six-week measurement period was found to be 13 L−1. [INP] spanned 3 orders of magnitude and showed a general increase from mid-February until early April. No persistent local or regional sources of INPs in the boreal environment of southern Finland could be identified. Rather, it is hypothesised that the INPs at SMEAR II are a result of dilution during long-range transport. Despite high variability, the measured [INP] values fall within the range expected for INP number concentrations measured elsewhere at similar thermodynamic conditions. [INP] did not correlate with any of the examined relevant parameters during the entire field campaign, indicating that no one single parameter can be used to predict the INP number concentration at the measurement location during the examined time period. The absence of correlation across the entire field campaign also suggests that a variety of particles are acting as INPs at different times, although it was indirectly determined that, on average, ambient INPs are most likely in the size range of 0.1–0.5 μm in diameter. On shorter time scales, several particle species correlated well with [INP] implying their potential role as INPs. Depending on the meteorological conditions, signatures of black carbon (BC), supermicron biological particles and sub-0.1 μm particles, most likely nanoscale biological fragments such as ice nucleating macromolecules (INMs), have been found in the INP signal. However, an increase in the concentration of any of these particle species may not necessarily lead to the increase in [INP], reasons for which remain unknown. Limitations of the instrumental setup and the necessity of the future field INP studies are addressed.

The custom-built Portable Fine Particle Concentrator (PFPC) is evaluated for the measurement of ice nucleating particles (INPs) in the atmosphere. The concentrations of INPs in remote regions of the atmosphere are very low, often close to instrumental detection limits. The PFPC is a dual slit-nozzle virtual impactor where particles are concentrated from an input flow of 250 LPM (litres per minute) into an output flow of 10 LPM. The enrichment factors (EFs) for ambient particles with diameters between 0.4 and 2.5 µm were found to be 21 ± 5 at sea level and 18 ± 2 at a field station 3580 meters above sea level for the PFPC operated in horizontal configuration. Similar enhancement factors (16 ± 5) in the concentrations of INPs measured by the Horizontal Ice Nucleation Chamber at the high-altitude station were observed when the air mass was characterized by high numbers of particles larger than 0.5 µm. When the number size distribution was dominated by particles smaller than 0.5 µm, the INP EF was considerably lower. Corroborating short-term measurements were provided by additional INP-measuring instruments, the Fast Ice Nucleus CHamber and the Frankfurt Ice Deposition Freezing Experiment. Results from two aerosol mass spectrometers also indicate significant particle enhancement using the PFPC. These results indicate that the PFPC can be usefully deployed to improve the detection efficiency of ambient INP measurements. Copyright © 2019 American Association for Aerosol Research

Biological particles, including pollen, are released into the atmosphere in large amounts and carry components which can initiate ice nucleation (IN) under cloud conditions. In this study, we investigate in immersion mode the ice nucleation ability of eleven different tree pollen from deciduous and evergreen trees. Droplet freezing experiments are conducted, where we find the IN ability of filtered tree pollen aqueous suspensions to vary over more than 10 °C and ice nucleation to be triggered by subpollen particles that are smaller than 0.45 μm in size. The presence of full pollen grains in the sample does not significantly change the median freezing temperature. The IN activity of the pollen samples is complemented by total organic carbon (TOC) analysis, which allows calculation of the number of ice nucleating particles per mass of carbon. Infrared analysis of the bulk samples does not clearly indicate whether specific functional groups are correlated to the ability of the subpollen particles to nucleate ice.

Formic and acetic acid are ubiquitous and abundant in the Earth's atmosphere and are important contributors to cloud water acidity, especially in remote regions. Their global sources are not well understood, as evidenced by the inability of models to reproduce the magnitude of measured mixing ratios, particularly at high northern latitudes. The scarcity of measurements at those latitudes is also a hindrance to understanding these acids and their sources. Here, we present ground-based gas-phase measurements of formic acid (FA) and acetic acid (AA) in the Canadian Arctic collected at 0.5 Hz with a high resolution chemical ionization time-of-flight mass spectrometer using the iodide reagent ion (Iodide HR-ToF-CIMS, Aerodyne). This study was conducted at Alert, Nunavut, in the early summer of 2016. FA and AA mixing ratios for this period show high temporal variability and occasional excursions to very high values (up to 11 and 40 ppbv respectively). High levels of FA and AA were observed under two very different conditions: under overcast, cold conditions during which physical equilibrium partitioning should not favour their emission, and during warm and sunny periods. During the latter, sunny periods, the FA and AA mixing ratios also displayed diurnal cycles in keeping with a photochemical source near the ground. These observations highlight the complexity of the sources of FA and AA, and suggest that current chemical transport model implementations of the sources of FA and AA in the Arctic may be incomplete.

Clouds containing ice are vital for precipitation formation and are important in determining the Earth's radiative budget. However, primary formation of ice in clouds is not fully understood. In the presence of ice nucleating particles (INPs), the phase change to ice is promoted, but identification and quantification of INPs in a natural environment remains challenging because of their low numbers. In this paper, we quantify INP number concentrations in the free troposphere (FT) as measured at the High Altitude Research Station Jungfraujoch (JFJ), during the winter, spring, and summer of the years 2014–2017. INPs were measured at conditions relevant for mixed‐phase cloud formation at T = 241/242 K. To date, this is the longest timeline of semiregular measurements akin to online INP monitoring at this site and sampling conditions. We find that INP concentrations in the background FT are on average capped at 10/stdL (liter of air at standard conditions [T = 273 K and p = 1013 hPa]) with an interquartile range of 0.4–9.6/stdL, as compared to measurements during times when other air mass origins (e.g., Sahara or marine boundary layer) prevailed. Elevated concentrations were measured in the field campaigns of 2016, which might be due to enhanced influence from Saharan dust and marine boundary layer air arriving at the JFJ. The upper limit of INP concentrations in the background FT is supported by measurements performed at similar conditions, but at different locations in the FT, where we find INP concentrations to be below 13/stdL most of the time. ISSN:0148-0227 ISSN:2169-897X

The transport of air masses originating from the Asian monsoon anticyclone into the extratropical upper troposphere and lower stratosphere (Ex-UTLS) above potential temperatures Θ = 380 K was identified during the HALO aircraft mission TACTS in August and September 2012. In situ measurements of CO, O3 and N2O during TACTS flight 2 on 30 August 2012 show the irreversible mixing of aged stratospheric air masses with younger (recently transported from the troposphere) ones within the Ex-UTLS. Backward trajectories calculated with the trajectory module of CLaMS indicate that these tropospherically affected air masses originate from the Asian monsoon anticyclone. These air masses are subsequently transported above potential temperatures Θ = 380 K from the monsoon circulation region into the Ex-UTLS, where they subsequently mix with stratospheric air masses. The overall trace gas distribution measured during TACTS shows that this transport pathway had affected the chemical composition of the Ex-UTLS during boreal summer and autumn 2012. This leads to an intensification of the tropospheric influence on the extratropical lower stratosphere with PV > 8 pvu within 3 weeks during the TACTS mission. During the same time period a weakening of the tropospheric influence on the lowermost stratosphere (LMS) is determined. The study shows that the transport of air masses originating from the Asian summer monsoon region within the lower stratosphere affects the change in the chemical composition of the Ex-UTLS over Europe and thus contributes to the flushing of the LMS during summer 2012.