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The escalation of heavy metal pollutants in soils and effluents, driven by industrialization and human activities, poses significant environmental and health risks. Conventional remediation methods are often costly and ineffective, prompting a shift towards sustainable alternatives such as biological treatments. Natural biosorbents, including microbial cells and their byproducts, have emerged as promising solutions. One such approach involves leveraging exopolysaccharides (EPS), complex high-molecular-weight biopolymers synthesized by microbes under environmental stress conditions. EPS are intricate organic macromolecules comprising proteins, polysaccharides, uronic acids, humic compounds, and lipids, either located within microbial cells or secreted into their surroundings. Their anionic functional groups enable efficient electrostatic binding of cationic heavy metals, making EPS effective biosorbents for soil remediation. This review thoroughly explores the pivotal role of bacterial EPS in the removal of heavy metals, focusing on EPS biosynthesis mechanisms, the dynamics of interaction with heavy metals, and case studies that illustrate their effectiveness in practical remediation strategies. By highlighting these aspects, the review underscores the innovation and practical implications of EPS-based bioremediation technologies, demonstrating their potential to address critical environmental challenges effectively while paving the way for sustainable environmental management practices. Key findings reveal that EPS exhibit robust metal-binding capacities, facilitated by their anionic functional groups, thereby offering a promising solution for mitigating metal pollution in diverse environmental matrices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

To safely protect workplaces and the workforce during and after the COVID-19 pandemic, a scalable integrated sensing solution is required in order to offer real-time situational awareness and early warnings for decision-makers. However, an information-based solution for industry reopening is ineffective when the necessary operational information is locked up in disparate real-time data silos. There is a lot of ongoing effort to combat the COVID-19 pandemic using different combinations of low-cost, location-based contact tracing, and sensing technologies. These ad hoc Internet of Things (IoT) solutions for COVID-19 were developed using different data models and protocols without an interoperable way to interconnect these heterogeneous systems and exchange data on people and place interactions. This research aims to design and develop an interoperable Internet of COVID-19 Things (IoCT) architecture that is able to exchange, aggregate, and reuse disparate IoT sensor data sources in order for informed decisions to be made after understanding the real-time risks in workplaces based on person-to-place interactions. The IoCT architecture is based on the Sensor Web paradigm that connects various Things, Sensors, and Datastreams with an indoor geospatial data model. This paper presents a study of what, to the best of our knowledge, is the first real-world integrated implementation of the Open Geospatial Consortium (OGC) Sensor Web Enablement (SWE) and IndoorGML standards to calculate the risk of COVID-19 online using a workplace reopening case study. The proposed IoCT offers a new open standard-based information model, architecture, methodologies, and software tools that enable the interoperability of disparate COVID-19 monitoring systems with finer spatial-temporal granularity. A workplace cleaning use case was developed in order to demonstrate the capabilities of this proposed IoCT architecture. The implemented IoCT architecture included proximity-based contact tracing, people density sensors, a COVID-19 risky behavior monitoring system, and the contextual building geospatial data.

Titanate nanomaterials have been outstanding in the removal of emerging contaminants by the photocatalysis process. These photocatalysts, when modified through techniques such as doping with metals, they have advantages over TiO 2 , especially in the region of visible light. In this work, the photocatalytic performance of four recent reported catalysts, pristine titanate nanowires, cobalt-doped titanate nanowires, iron-doped titanate nanowires and ruthenium-doped titanate nanowires, for the removal of the antidepressant trazodone under visible light radiation was compared. The iron-doped titanate nanowires presented the best catalytic activity by the catalyst surface area. Additionally, thirteen transformation products (TPs) were identified by high-resolution mass spectrometry and, to the best of our knowledge, nine of them have never been described in the literature. It was shown that for each catalyst different TPs were formed with distinct time profiles. Finally, toxicity assessment by computational methods showed that TPs were not readily biodegradable and they presented toxicity to aquatic organisms with mutagenic potential. These findings reinforce the importance of taking into consideration the TPs formed during the removal of pollutants since many of them may be toxic and can be produced during photocatalysis., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Polycyclic aromatic hydrocarbons (PAHs) in soil are not only detrimental to environment but also to human health. Double dielectric barrier discharge (DDBD) plasma reactor used for the remediation of pyrene contaminated soil was studied. The performance of DDBD reactor was optimized with influential parameters including applied voltage, type of carrier gas, air feeding rate as well as pyrene initial concentration. The analysis of variance (ANOVA) results showed that input energy had a great effect on pyrene remediation efficiency followed by pyrene initial concentration, while, the effect of air feeding rate was insignificant. More specifically, the remediation efficiency of pyrene under air, nitrogen and argon as carrier gas were approximately 79.7, 40.7 and 38.2% respectively. Pyrene remediation efficiency is favored at high level of applied voltages and low level of pyrene initial concentration (10 mgkg -1 ) and air feeding rate (0.85 L/min). Moreover, computation of the energy efficiency of the DDBD system disclosed that an optimal applied voltage (35.8 kV) and higher initial pyrene concentration (200 mgkg -1 ) favored the high energy efficiency. A regression model predicting pyrene remediation under DDBD plasma condition was developed using the data from a face-centered central composite design (FCCD) experiment. Finally, the residual toxicity analysis depicted that the respiratory activity increased more than 21 times (from 0.04 to 0.849 mg O 2 g -1 ) with a pyrene remediation efficiency of 81.1%. The study demonstrated the DDBD plasma technology is a promising method not only for high efficiency of pyrene remediation, but also recovering biological function without changing the physical-chemical properties of soil., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Incorporating bioaccessibility into human health risk assessment is recognized as a valid way to reduce the conservative properties of conventional results, where the total concentration of a contaminant analysed by exhaustive chemical extraction is applied. Taking a coke production site in Beijing as an example, a mild chemical extraction technology was employed to profile the bioaccessibility of benzo[a]pyrene (BaP), indeno[1,2,3-cd]pyrene (IcP) and dibenz[ah]anthracene (DBA) in soils. The results that were regressed using two bi-phase desorption models (Karickhoff and Weibull) revealed that the rapid desorption fractions of BaP, IcP and DBA, which are taken for bioaccessible fractions, were basically less than half of the total contents in the soils. Probabilistic analysis (PA) was carried out with pre-set distributions of the exposure parameters to characterize the uncertainty in the assessment. The results incorporating bioaccessibility and PA were several times higher than the generic remediation goals which equal to national screening levels, and orders of magnitude higher than the baselines of the region and nation. The results of the Weibull fit were finally recommended as site-specific remediation goals (SSRGs) (10.59 mg/kg, 95.48 mg/kg and 9.24 mg/kg). Over-remediation was avoided while contributing to considerable economic and environmental benefits., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Two of the most prevalent Superfund-site contaminants are carcinogenic solvents PCE (perchloroethylene) and TCE (trichloroethylene). Because their cleanup is difficult and costly, remediators have repeatedly falsified site-cleanup data, as Tetra Tech apparently did recently in San Francisco. Especially for difficult-to-remediate toxins, this paper hypothesizes that scientific misrepresentations occur in toxic-site assessments, before remediation even begins. To begin to test this hypothesis, the paper (1) defines scientific-data audits (assessing whether published conclusions contradict source data), (2) performs a preliminary scientific-data audit of toxic-site assessments by consultants Ninyo and Moore for developer Trammell Crow. Trammel Crow wants to build 550 apartments on an unremediated Pasadena, California site - once a premier US Navy weapons-testing/development facility. The paper (3) examines four key Ninyo-and-Moore conclusions, that removing only localized metals-hotspots will (3.1) remediate TCE/PCE; (3.2) leave low levels of them; (3.3) clean the northern half of soil, making it usable for grading, and (3.4) ensure site residents have lifetime cancer risks no greater than 1 in 3,000. The paper (4) shows that source data contradict all four conclusions. After summarizing the benefits of routine, independent, scientific-data audits (RISDA), the paper (5) argues that, if these results are generalizable, RISDA might help prevent questionable toxic-site assessments, especially those of expensive-to-remediate toxins like PCE/TCE.

Remediation decisions for contaminated sediment sites are typically based on comparisons of in situ sediment concentrations to preliminary remediation goals (PRGs). Preliminary remediation goals are typically developed for protection of human health and the environment, with consideration of site-specific factors that play an important role in determining the sediment concentrations that are consistent with the human health and environmental protection objectives. Remediation goals are selected from among the PRGs. Sediment remediation goals for 4 common contaminants (PCBs, PAHs, Pb, and Hg) at contaminated sediment sites throughout the United States were compiled to determine significant trends and evaluate causes of those trends. Remediation goals were compiled from Records of Decision (RODs) and 5-year review reports for 77 contaminated sediment sites throughout the continental United States. Remediation goals were developed both as surface-weighted average concentrations (SWACs) and action levels (i.e., not-to-exceed values). One or both may be used to define areas requiring remediation. Remediation goals based on SWACs are typically applied to bioaccumulative chemicals for human health and wildlife receptors, whereas action levels are typically used for chemicals that result in an acute toxicity to small home range, sediment-dwelling biota. The findings from this review of remediation goals indicate that SWACs are an increasingly common approach for developing remediation goals. In addition, the findings from this review indicate that although remediation goals adopted for Pb have become more stringent over time, no trend is evident for PCBs, PAHs, and Hg. Remediation goals for PCBs, PAHs, and Hg vary among a number of factors, such as geography, habitat, human or ecological risks, and other local factors. Integr Environ Assess Manag 2019;15:772-782. © 2019 SETAC., (© 2019 SETAC.)

Mineral nutrition of plants greatly depends on both environmental conditions, particularly of soils, and the genetic background of the plant itself. Being sessile, plants adopted a range of strategies for sensing and responding to nutrient availability to optimize development and growth, as well as to protect their metabolisms from heavy metal toxicity. Such mechanisms, together with the soil environment, meaning the soil microorganisms and their interaction with plant roots, have been extensively studied with the goal of exploiting them to reclaim polluted lands; this approach, defined phytoremediation, will be the subject of this review. The main aspects and innovations in this field are considered, in particular with respect to the selection of efficient plant genotypes, the application of improved cultural strategies, and the symbiotic interaction with soil microorganisms, to manage heavy metal polluted soils.

Application of engineered nanomaterials for the treatment of industrial effluents and to deal with recalcitrant pollutants has been noticeably promoted in recent years. Laboratory, pilot and full-scale studies emphasize the potential of this technology to offer promising treatment options to meet the future needs for clean water resources and to comply with stringent environmental regulations. The technology is now in the stage of being transferred to the real applications. Therefore, the assessment of its performance according to sustainability criteria and their incorporation into the decision-making process is a key task to ensure that long term benefits are achieved from the nano-treatment technologies. In this study, the importance of sustainability criteria for the conventional and novel technologies for the treatment of industrial effluents was determined in a general approach assisted by a fuzzy-Delphi method. The criteria were categorized in technical, economic, environmental and social branches and the current situation of the nanotechnology regarding the criteria was critically discussed. The results indicate that the efficiency and safety are the most important parameters to make sustainable choices for the treatment of industrial effluents. Also, in addition to the need for scaling-up the nanotechnology in various stages, the study on their environmental footprint must continue in deeper scales under expected environmental conditions, in particular the synthesis of engineered nanomaterials and the development of reactors with the ability of recovery and reuse the nanomaterials. This paper will aid to select the most sustainable types of nanomaterials for the real applications and to guide the future studies in this field., (Copyright © 2019 The Authors. Published by Elsevier Ltd.. All rights reserved.)

The Beijing Municipal Environmental Protection Bureau (EPB) is considering strengthening the Emission Standard of Air Pollutants for Stationary Gas Turbines, originally published in 2011 (DB11/847-2011), with a focus on reducing nitrogen oxides (NOx) emissions. A feasibility study was conducted to evaluate the current operation of 12 existing combined-cycle gas turbine power plants and the design of two new plants in Beijing and their emission reduction potential, in comparison with a state-of-the-art power plant in California. The study found that best management practices (BMPs) could potentially improve the emission level of the power plants, and should be implemented to minimize emissions under current design characteristics. These BMPs include (1) more frequent tuning of turbine combustors; (2) onsite testing of natural gas characteristics in comparison to turbine manufacturer's specifics and tuning of turbine to natural gas quality; (3) onsite testing of aqueous ammonia to ensure adequate ammonia concentration in the mixed solution, and the purity of the solution; (4) more careful inspection of the heat recovery steam generator (HRSG), and the selective catalytic reduction (SCR) during operation and maintenance; (5) annual testing of the catalyst coupon on the SCR to ensure catalyst effectiveness; and (6) annual ammonia injection grid (AIG) tuning. The study found that without major modification to the plants, improving the management of the Beijing gas turbine power plants may potentially reduce the current hourly average NOx emission level of 5-10 parts per million (ppm; ranges reflects plant variation) by up to 20%. The exact improvement associated with each BMP for each facility requires more detailed analysis, and requires engagement of turbine, HRSG, and SCR manufacturers. This potential improvement is an important factor to consider when strengthening the emission standard. However, note that with the continuous needs of improving air quality within the area, more expensive control measures, such as retrofitting the turbines or the HRSGs, may be considered., Implications: This study analyzed the potential emission reductions associated with implementing the best management practices (BMPs) on the combined cycle and cogeneration power plants in Beijing. It determined that implementing the BMPs could potentially achieve up to 580 metric tonnes, or 0.6%, reductions of all NOx emissions in Beijing. Many other cities in China and Asia battling air quality issues may find the information useful in order to evaluate the emission reduction potential of their own gas turbine power plants.

A number of past industrial activities and accidents have resulted in the radioactive contamination of large areas at many sites around the world, giving rise to a need for remediation. According to the International Commission on Radiological Protection (ICRP) and International Atomic Energy Agency (IAEA), such situations should be managed as existing exposure situations (ExESs). Control of exposure to the public in ExESs is based on the application of appropriate reference levels (RLs) for residual doses. The implementation of this potentially fruitful concept for the optimisation of remediation in various regions is hampered by a lack of practical experience and relevant guidance. This paper suggests a generic methodology for the selection of numeric values of relevant RLs both in terms of residual annual effective dose and derived RLs (DRLs) based on an appropriate dose assessment. The value for an RL should be selected in the range of the annual residual effective dose of 1-20 mSv, depending on the prevailing circumstances for the exposure under consideration. Within this range, RL values should be chosen by the following assessment steps: (a) assessment of the projected dose, i.e. the dose to a representative person without remedial actions by means of a realistic model as opposed to a conservative model; (b) modelling of the residual dose to a representative person following application of feasible remedial actions; and (c) selection of an RL value between the projected and residual doses, taking account of the prevailing social and economic conditions. This paper also contains some recommendations for practical implementation of the selected RLs for the optimisation of public protection. The suggested methodology used for the selection of RLs (in terms of dose) and the calculation of DRLs (in terms of activity concentration in food, ambient dose rate, etc) has been illustrated by a retrospective analysis of post-Chernobyl monitoring and modelling data from the Bryansk region, Russia, 2001. From this example, it follows that analysis of real data leads to the selection of an RL from a relatively narrow annual dose range (in this case, about 2-3 mSv), from which relevant DRLs can be calculated and directly used for optimisation of the remediation programme.

The UK Marine Management Organisation (MMO) tasked the Centre for Environment, Fisheries & Aquaculture Science (Cefas) with reviewing the current UK dispersant efficacy testing procedures. The aim was to identify possibilities to increase standardisation, improve health and safety performance and explore harmonisation possibilities with international dispersant efficacy testing procedures. The US EPA 'Baffled Flask Test' (BFT) was adopted, implemented and validated as a new standard method in the UK. The outputs from this study suggest that dispersant efficacy results from the adopted BFT test and the currently used protocol are in a similar range and results presented by the US EPA. As a result, the transition to the adopted BFT test will require minimal changes in the assessment of the results or reporting and increase harmonisation between tests used in the UK and North America., (Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.)

A tension arises between society's disposition to protect people at risk from environmental pollution, and an aversion towards the potential harmful side-effects associated with cleanup activities. Here we explore how setting different cleanup standards may influence some of the environmental, social, and economic side-effects of remediation, and how they can be quantified for incorporation into cleanup target setting; these include (1) secondary environmental impacts, assessed by life cycle assessment (LCA); (2) fatalities and injuries, assessed by actuarial risk analysis; and (3) the cost effectiveness of stringent cleanup standards, assessed by the incremental cost-effectiveness ratio (ICER). We argue that only by using optimal cleanup standards that integrate quantified remediation side-effects with health risk assessment (HRA) can the green and sustainable remediation (GSR) movement maximize its potential. Together, the combined approaches may provide a more holistic management of risks for a more sustainable future.

Green and sustainable remediation (GSR) has become a global trend in the contaminated land remediation field. Growing numbers of countries have adopted GSR procedures published in regulatory and/or technical guidance. China is fast becoming one of the largest remediation markets in the world, and is beginning to engage with GSR. Among other efforts, a taskforce is currently developing the first Chinese technical standard on GSR. This paper presents the context positioning and development of a sustainable remediation assessment indicator set for China. This sustainability indicator set was formed based on existing sustainable remediation guidelines and literature. LCA was used to evaluate environmental impacts, and the results combined with social and economic appraisal via MCA. The indicator set was applied to a remediation 'mega-site' in China. The results showed that compared to excavation and landfill, an alternative treatment strategy of soil washing, thermal desorption and S/S brought about relatively less waste generation, better worker safety, and preferable local impacts, leading to higher scores in the environmental and social-economic domains. However, the social-economic scores were limited by a lack of public engagement. The results of the case study have shown that the indicator set is valid, with lessons learnt and suggestions for improvement discussed., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Hydro-climatic changes and the increasing release of pollutants into rivers by human activities tend to affect the quality of watercourses, to alter aquatic ecosystems and to reduce the amount of useable water. The ecological and chemical states of rivers and their evolution is thus of growing concern. In Europe and Switzerland, water policies are progressively shifting towards a holistic approach of river systems. The European Commission notably established a framework to highlight rivers' ecological deficits and to enhance regional or local water management plans. In Switzerland, a similar framework is currently under development. In this paper, both procedures are compared and implemented in a Swiss catchment dominated by agricultural activities. The aim is to define the challenges that still need to be addressed to assess and sustain river health. The hydromorphological, ecological, and ecotoxicological quality of the river was evaluated. Both frameworks highlighted the fact that no section of the river can currently be classified as being in a good environmental state and that the state deteriorates as tributaries and wastewater discharge flow into the main riverbed. Chemical issues and water quality changes due to hydro-climatic variations and management strategies were also pinpointed. Both frameworks are thus useful tools to survey changes in rivers quality in space and over time. However, challenges remain regarding the appropriate strategies to monitor and analyze chemicals, the definition of target values and conditions, the evaluation and integration of human-induced pressures, and the overall evaluation of the state of a river. The development of integrated indicators or of ecosystem services approaches is considered as a potential solution to explore river health and to define efficient restoration measures by water managers.

In this study, we evaluated the feasibility of using ferric salts including FeCl 3 and Fe(NO 3 ) 3 as extracting and oxidizing agents for a soil washing process to remediate Pb-contaminated soils. We treated various Pb minerals including PbO, PbCO 3 , Pb 3 (CO 3 ) 2 (OH) 2 , PbSO 4 , PbS, and Pb 5 (PO 4 ) 3 (OH) using ferric salts, and compared our results with those obtained using common washing agents of HCl, HNO 3 , disodium-ethylenediaminetetra-acetic acid (Na 2 -EDTA), and citric acid. The use of 50 mM Fe(NO 3 ) 3 extracted significantly more Pb (above 96% extraction) from Pb minerals except PbSO 4 (below 55% extraction) compared to the other washing agents. In contrast, washing processes using FeCl 3 and HCl were not effective for extraction from Pb minerals because of PbCl 2 precipitation. Yet, the newly formed PbCl 2 could be dissolved by subsequent wash with distilled water under acidic conditions. When applying our washing method to remediate field-contaminated soil from a shooting range that had high concentrations of Pb 3 (CO 3 ) 2 (OH) 2 and PbCO 3 , we extracted more Pb (approximately 99% extraction) from the soil using 100 mM Fe(NO 3 ) 3 than other washing agents at the same process conditions. Our results show that ferric salts can be alternative washing agents for Pb-contaminated soils in view of their extracting and oxidizing abilities., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

Cost-effective and eco-friendly washing agents are in demand for Cd contaminated soils. Here, we used leonardite-derived humic substances to wash different types of Cd-contaminated soils, namely, a silty loam (Soil 1), a silty clay loam (Soil 2), and a sandy loam (Soil 3). Washing conditions were investigated for their effects on Cd removal efficiency. Cadmium removal was enhanced by a high humic substance concentration, long washing time, near neutral pH, and large solution/soil ratio. Based on the tradeoff between efficiency and cost, an optimum working condition was established as follows: humic substance concentration (3150 mg C/L), solution pH (6.0), washing time (2 h) and a washing solution/soil ratio (5). A single washing removed 0.55 mg Cd/kg from Soil 1 (1.33 mg Cd/kg), 2.32 mg Cd/kg from Soil 2 (6.57 mg Cd/kg), and 1.97 mg Cd/kg from Soil 3 (2.63 mg Cd/kg). Cd in effluents was effectively treated by adding a small dose of calcium hydroxide, reducing its concentration below the discharge limit of 0.1 mg/L in China. Being cost-effective and safe, humic substances have a great potential to replace common washing agents for the remediation of Cd-contaminated soils. Besides being environmentally benign, humic substances can improve soil physical, chemical, and biological properties., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

To address the issue of membrane fouling by ubiquitous humic substances, a hydrophilic pore-former-blended polyethersulfone UF membrane was successfully synthesized via the phase inversion method. For the first time, extremely high concentrations of polyvinylpyrrolidone (PVP), up to 20 wt%, were tested as the hydrophilic pore-former in order to determine the optimum concentration for humic acid fouling. Intrinsic membrane parameters such as permeability and selectivity were evaluated using a cross-flow UF filtration setup. Interestingly, as little as 1 wt% added PVP can significantly improve membrane permeability. That tiny amount of added PVP increased membrane flux to 1107 L/m 2 h·bar from zero flux, with over 90% rejection of humic acid. In addition, pure water permeation increased to over 2400 L/m 2 h·bar without sacrificing humic acid rejection (around 90%) when 10 wt% PVP was added; pure water permeation decreased to around 1000 L/m 2 h·bar as added PVP was increased to 20 wt%. The order of water flux increased with the amount of added PVP up to 20 wt% during humic acid fouling while maintaining membrane selectivity. However, the membrane with 10 wt% added PVP showed the best fouling resistance in terms of flux recovery ratio (98%), total flux loss, reversible fouling ratio, and irreversible fouling ratio. Therefore, the addition of 10 wt% PVP is recommended considering cleaning efficiency and the moderately high flux during humic acid fouling for field operation in wastewater reclamation and water treatment processes., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

This paper presents the results of implementing an extrajudicial environmental mediation procedure in the socioenvironmental conflict associated with routine operation of the El Cabril Disposal Facility for low- and medium- activity radioactive waste (Spain). We analyse the socio-ethical perspective of this facility's operation with regard to its nearby residents, detailing the structure and development of the environmental mediation procedure through the participation of society and interested parties who are or may become involved in such a conflict. The research, action, and participation method was used to apply the environmental mediation procedure. This experience provides lessons that could help improve decision-making processes in nuclear or radioactive facility decommissioning projects or in environmental remediation projects dealing with ageing facilities or with those in which nuclear or radioactive accidents/incidents may have occurred., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

A former gas production site that was converted to a public park was chosen as the research location for the present study. Some of the contaminants at the site have been remediated; however, much of the soil is still contaminated with polycyclic aromatic hydrocarbons (PAHs). PAHs are toxic pollutants that have been shown to have numerous negative health effects. The primary form of remediation at the site has been capping, which is usually considered a temporary remediation strategy since it does not remove contaminants from the site but simply covers them, and this requires repeated re-capping efforts. Endophyte-assisted phytoremediation using willow shrubs is an alternative remediation strategy that could improve soil quality and permanently reduce contaminant levels in the soil. The goal of the present study was to explore the social acceptability of utilizing phytoremediation strategies. Surveys were used to explore public perceptions of the park and of using phytoremediation to clean up existing contamination. Results indicated a high level of social acceptability of phytoremediation at the park. Additionally, ecocentrism was shown to be a significant predictor of phytoremediation acceptability. Risk and anthropocentrism were not significant predictors of acceptability. Results suggest that messages intended to encourage the use and acceptability of phytoremediation should focus on the environmental benefits of phytoremediation.

On 29 December 1970, the Occupational Safety and Health Act of 1970 established the Occupational Safety and Health Administration (OSHA). This article on OSHA, Title 29, Part 1910.1096 Ionizing Radiation standard was written to increase awareness of the employer, the workforce, state and federal governments, and those in the radon industry who perform radon testing and radon mitigation of the existence of these regulations, particularly the radon relevant aspect of the regulations. This review paper was also written to try to explain what can sometimes be complicated regulations. As the author works within the Radon Division of the Pennsylvania Department of Environmental Protection, Bureau of Radiation Protection, the exclusive focus of the article is on radon. The 1910.1096 standard obviously covers many other aspects of radiation and radiation safety in the work place.

Restoration efforts in the Mediterranean Basin have been changing from a silvicultural to an ecological restoration approach. Yet, to what extent the projects are guided by ecological restoration principles remains largely unknown. To analyse this issue, we built an on-line survey addressed to restoration practitioners. We analysed 36 restoration projects, mostly from drylands (86%). The projects used mainly soil from local sources. The need to comply with legislation was more important as a restoration motive for European Union (EU) than for non-EU countries, while public opinion and health had a greater importance in the latter. Non-EU countries relied more on non-native plant species than EU countries, thus deviating from ecological restoration guidelines. Nursery-grown plants used were mostly of local or regional provenance, whilst seeds were mostly of national provenance. Unexpected restoration results (e.g. inadequate biodiversity) were reported for 50% of the projects and restoration success was never evaluated in 22%. Long term evaluation (>6years) was only performed in 31% of cases, and based primarily on plant diversity and cover. The use of non-native species and species of exogenous provenances may: i) entail the loss of local genetic and functional trait diversity, critical to cope with drought, particularly under the predicted climate change scenarios, and ii) lead to unexpected competition with native species and/or negatively impact local biotic interactions. Absent or inappropriate monitoring may prevent the understanding of restoration trajectories, precluding adaptive management strategies, often crucial to create functional ecosystems able to provide ecosystem services. The overview of ecological restoration projects in the Mediterranean Basin revealed high variability among practices and highlighted the need for improved scientific assistance and information exchange, greater use of native species of local provenance, and more long-term monitoring and evaluation, including functional and ecosystem services' indicators, to improve and spread the practice of ecological restoration., (Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.)

The scale of land-contamination problems, and of the responses to them, makes achieving sustainability in contaminated land remediation an important objective. The Sustainable Remediation Forum in the UK (SuRF-UK) was established in 2007 to support more sustainable remediation practice in the UK. The current international interest in 'sustainable remediation' has achieved a fairly rapid consensus on concepts, descriptions and definitions for sustainable remediation, which are now being incorporated into an ISO standard. However the sustainability assessment methods being used remain diverse with a range of (mainly) semi-quantitative and quantitative approaches and tools developed, or in development. Sustainability assessment is site specific and subjective. It depends on the inclusion of a wide range of considerations across different stakeholder perspectives. Taking a tiered approach to sustainability assessment offers important advantages, starting from a qualitative assessment and moving through to semi-quantitative and quantitative assessments on an 'as required' basis only. It is also clear that there are a number of 'easy wins' that could improve performance against sustainability criteria right across the site management process. SuRF-UK has provided a checklist of 'sustainable management practices' that describes some of these. This paper provides the rationale for, and an outline of, and recently published SuRF-UK guidance on preparing for and framing sustainability assessments; carrying out qualitative sustainability assessment; and simple good management practices to improve sustainability across contaminated land management activities., (Copyright © 2015 The Authors. Published by Elsevier B.V. All rights reserved.)

Seabirds are vulnerable to oil pollution, particularly in cold-water regions. We investigated the response of small spills (<7.95m(3)) at offshore production platforms in Newfoundland, a region recognized for seabird diversity and abundance. In three environmental assessments for oil production operations Environment Canada requested monitoring and mitigation of small spills potentially impacting seabird populations; suggestions supported by two independent reviews. An industry spill response plan states that operators would collect systematic observations on spills and deploy countermeasures where possible. Operators' spill reports were obtained under an Access to Information request. There were 220 daytime spills with sheens (out of 381 spills; 1997-2010). Of these, six reported time to oil dispersion and eleven the presence or absence of seabirds. Industry self-reporting has not permitted an evaluation of the impact of chronic oil spills on seabirds. We recommend that independent observers be placed on platforms to systematically collect data on spills and seabirds., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Chemical contamination has impaired ecosystems, reducing biodiversity and the provisioning of functions and services. This has spurred a movement to restore contaminated ecosystems and develop and implement national and international regulations that require it. Nevertheless, ecological restoration remains a young and rapidly growing discipline and its intersection with toxicology is even more nascent and underdeveloped. Consequently, we provide guidance to scientists and practitioners on when, where, and how to restore contaminated ecosystems. Although restoration has many benefits, it also can be expensive, and in many cases systems can recover without human intervention. Hence, the first question we address is: "When should we restore contaminated ecosystems?" Second, we provide suggestions on what to restore-biodiversity, functions, services, all 3, or something else--and where to restore given expected changes to habitats driven by global climate change. Finally, we provide guidance on how to restore contaminated ecosystems. To do this, we analyze critical aspects of the literature dealing with the ecology of restoring contaminated ecosystems. Additionally, we review approaches for translating the science of restoration to on-the-ground actions, which includes discussions of market incentives and the finances of restoration, stakeholder outreach and governance models for ecosystem restoration, and working with contractors to implement restoration plans. By explicitly considering the mechanisms and strategies that maximize the success of the restoration of contaminated sites, we hope that our synthesis serves to increase and improve collaborations between restoration ecologists and ecotoxicologists and set a roadmap for the restoration of contaminated ecosystems., (© 2015 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC.)

Patent classification systems have traditionally evolved independently at each patent jurisdiction to classify patents handled by their examiners to be able to search previous patents while dealing with new patent applications. As patent databases maintained by them went online for free access to public as also for global search of prior art by examiners, the need arose for a common platform and uniform structure of patent databases. The diversity of different classification, however, posed problems of integrating and searching relevant patents across patent jurisdictions. To address this problem of comparability of data from different sources and searching patents, WIPO in the recent past developed what is known as International Patent Classification (IPC) system which most countries readily adopted to code their patents with IPC codes along with their own codes. The Cooperative Patent Classification (CPC) is the latest patent classification system based on IPC/European Classification (ECLA) system, developed by the European Patent Office (EPO) and the United States Patent and Trademark Office (USPTO) which is likely to become a global standard. This paper discusses this new classification system with reference to patents on bioremediation.

At hazardous waste sites, volatile chemicals can migrate through groundwater and soil into buildings, a process known as vapor intrusion. Due to increasing recognition of vapor intrusion as a potential indoor air pollution source, in 2015 the U.S. Environmental Protection Agency (EPA) released a new vapor intrusion guidance document. The guidance specifies two conditions for demonstrating that remediation is needed: (1) proof of a vapor intrusion pathway; and (2) evidence that human health risks exceed established thresholds (for example, one excess cancer among 10,000 exposed people). However, the guidance lacks details on methods for demonstrating these conditions. We review current evidence suggesting that monitoring and modeling approaches commonly employed at vapor intrusion sites do not adequately characterize long-term exposure and in many cases may underestimate risks. On the basis of this evidence, we recommend specific approaches to monitoring and modeling to account for these uncertainties. We propose a value of information approach to integrate the lines of evidence at a site and determine if more information is needed before deciding whether the two conditions specified in the vapor intrusion guidance are satisfied. To facilitate data collection and decision-making, we recommend a multi-directional community engagement strategy and consideration of environment justice concerns.

We determined changes of 28 alkanes and 43 different PAHs in 418 wetland soil samples collected on ten sampling trips to three Louisiana estuaries before and after they were oiled from the 2010 Deepwater Horizon disaster. There was a significant decline in 22 of the 28 alkane analytes (0.42% day(-1)), no change in 6, over 2.5 years. The concentration of five aromatic petroleum hydrocarbons (PAHs) increased (range 0.25-0.70% day(-1)), whereas the total PAH pool did not change. Of these five, naphthalene and C-1-naphthalenes are suggested to be of higher toxicity than the other three because of their relatively higher volatility or solubility. The relative proportions of alkane analytes, but not PAHs, does not yet resemble that in the pre-oiled marshes after 3 years, The trajectories of nine indicators for degradation/weathering were either inconclusive or misleading (alkanes) or confirmed the relatively meager degradation of PAHs., (Copyright © 2014 Elsevier Ltd. All rights reserved.)

Highway runoff is known to be an important non-point source (NPS), increasing the load of pollutants in receiving water. For reducing NPS pollutants in runoff, removal of road deposited sediment (RDS) by sweeping is considered effective. However, the contribution of sweeping to the improvement of runoff quality has not been clearly and quantitatively demonstrated so far. In this study, a field test was carried out on a section of operating highway in Korea to investigate the effectiveness of sweeping on improving the quality of highway runoff. Results showed that the average reduction in the load of RDS by sweeping was 61.10% with a standard deviation of 1.74%. RDS removal efficiency decreased when the sweeping speed increased from 4-8 to 20 km h(-1), the load decreased from 12.5 to 1.25 g m(-2) and particle size decreased from sand to silt/clay size ranges. Runoff was induced by applying a 15 mm h(-1) artificial rainfall to both swept and non-swept sections. Analysis of runoff quality showed that the event mean concentrations of total suspended solid, biological oxygen demand, chemical oxygen demand, nutrients and most of the heavy metals were reduced by 31-87% after sweeping. In addition, field tests for RDS build-up indicated a sweeping frequency of once every four or five days to prevent re-suspension of RDS. The results of this study suggest that sweeping can be the best management practice for effectively reducing RDS on highways and improving the quality of highway runoff.

This special series in Integrated Environmental Assessment Management presents the results from 6 workgroups that were formed at the workshop on Ecological Soil Levels-Next Steps in the Development of Metal Clean-Up Values (17-21 September 2012, Sundance, Utah). This introductory article presents an overview of the issues assessors face when conducting risk assessments for metals in soils, key US Environmental Protection Agency (USEPA) documents on metals risk assessment, and discusses the importance of leveraging from recent major terrestrial research projects, primarily to address Registration, Evaluation, Authorization and Restriction of Chemical Substances (REACH) requirements in Europe, that have significantly advanced our understanding of the behavior and toxicity of metals in soils. These projects developed large data sets that are useful for the risk assessment of metals in soil environments. The workshop attendees met to work toward developing a process for establishing ecological soil clean-up values (Eco-SCVs). The goal of the workshop was to progress from ecological soil screening values (Eco-SSLs) to final clean-up values by providing regulators with the methods and processes to incorporate bioavailability, normalize toxicity thresholds, address food-web issues, and incorporate background concentrations. The REACH data sets were used by workshop participants as case studies in the development of the ecological standards for soils. The workshop attendees discussed scientific advancements in bioavailability, soil biota and wildlife case studies, soil processes, and food-chain modeling. In addition, one of the workgroups discussed the processes needed to frame the topics to gain regulatory acceptance as a directive or guidance by Canada, the USEPA, or the United States., (© 2013 SETAC.)

This article addresses the regulatory issues associated with the application of recent data to support Registration, Evaluation, Authorisation and Restriction of Chemical substances (REACH) requirements in Europe and the use of metal-specific parameters by other countries to generate remediation values for metals in soil. The purposes of this article are to: 1) present approaches and advances developed over the last decade in Europe for the REACH regulation and proposed in Australia by the National Environment Protection Council, 2) review current US and Canadian regulatory practices on ecological soil cleanup values, and 3) evaluate the application of new scientific approaches, methods, and soil criteria development processes used in other countries., (© 2013 SETAC.)

An integral component in the development of media-specific values for the ecological risk assessment of chemicals is the derivation of safe levels of exposure for wildlife. Although the derivation and subsequent application of these values can be used for screening purposes, there is a need to identify the threshold for effects when making remedial decisions during site-specific assessments. Methods for evaluation of wildlife exposure are included in the US Environmental Protection Agency (USEPA) ecological soil screening levels (Eco-SSLs), registration, evaluation, authorization, and restriction of chemicals (REACH), and other risk-based soil assessment approaches. The goal of these approaches is to ensure that soil-associated contaminants do not pose a risk to wildlife that directly ingest soil, or to species that may be exposed to contaminants that persist in the food chain. These approaches incorporate broad assumptions in the exposure and effects assessments and in the risk characterization process. Consequently, thresholds for concluding risk are frequently very low with conclusions of risk possible when soil metal concentrations fall in the range of natural background. A workshop held in September, 2012 evaluated existing methods and explored recent science about factors to consider when establishing appropriate remedial goals for concentrations of metals in soils. A Foodweb Exposure Workgroup was organized to evaluate methods for quantifying exposure of wildlife to soil-associated metals through soil and food consumption and to provide recommendations for the development of ecological soil cleanup values (Eco-SCVs) that are both practical and scientifically defensible. The specific goals of this article are to review the current practices for quantifying exposure of wildlife to soil-associated contaminants via bioaccumulation and trophic transfer, to identify potential opportunities for refining and improving these exposure estimates, and finally, to make recommendations for application of these improved models to the development of site-specific remedial goals protective of wildlife. Although the focus is on metals contamination, many of the methods and tools discussed are also applicable to organic contaminants. The conclusion of this workgroup was that existing exposure estimation models are generally appropriate when fully expanded and that methods are generally available to develop more robust site-specific exposure estimates. Improved realism in site-specific wildlife Eco-SCVs could be achieved by obtaining more realistic estimates for diet composition, bioaccumulation, bioavailability and/or bioaccessibility, soil ingestion, spatial aspects of exposure, and target organ exposure. These components of wildlife exposure estimation should be developed on a site-, species-, and analyte-specific basis to the extent that the expense for their derivation is justified by the value they add to Eco-SCV development., (© 2013 SETAC.)

Although it is widely recognized that microorganisms are essential for sustaining soil fertility, structure, nutrient cycling, groundwater purification, and other soil functions, soil microbial toxicity data were excluded from the derivation of Ecological Soil Screening Levels (Eco-SSL) in the United States. Among the reasons for such exclusion were claims that microbial toxicity tests were too difficult to interpret because of the high variability of microbial responses, uncertainty regarding the relevance of the various endpoints, and functional redundancy. Since the release of the first draft of the Eco-SSL Guidance document by the US Environmental Protection Agency in 2003, soil microbial toxicity testing and its use in ecological risk assessments have substantially improved. A wide range of standardized and nonstandardized methods became available for testing chemical toxicity to microbial functions in soil. Regulatory frameworks in the European Union and Australia have successfully incorporated microbial toxicity data into the derivation of soil threshold concentrations for ecological risk assessments. This article provides the 3-part rationale for including soil microbial processes in the development of soil clean-up values (SCVs): 1) presenting a brief overview of relevant test methods for assessing microbial functions in soil, 2) examining data sets for Cu, Ni, Zn, and Mo that incorporated soil microbial toxicity data into regulatory frameworks, and 3) offering recommendations on how to integrate the best available science into the method development for deriving site-specific SCVs that account for bioavailability of metals and metalloids in soil. Although the primary focus of this article is on the development of the approach for deriving SCVs for metals and metalloids in the United States, the recommendations provided in this article may also be applicable in other jurisdictions that aim at developing ecological soil threshold values for protection of microbial processes in contaminated soils., (© 2014 The Authors. Integrated Environmental Assessment and Management Published by SETAC.)

The development of media-specific ecological values for risk assessment includes the derivation of acceptable levels of exposure for terrestrial wildlife (e.g., birds, mammals, reptiles, and amphibians). Although the derivation and subsequent application of these values can be used for screening purposes, there is a need to identify toxicological effects thresholds specifically for making remedial decisions at individual contaminated sites. A workshop was held in the fall of 2012 to evaluate existing methods and recent scientific developments for refining ecological soil screening levels (Eco-SSLs) and improving the derivation of site-specific ecological soil clean-up values for metals (Eco-SCVs). This included a focused session on the development and derivation of toxicity reference values (TRVs) for terrestrial wildlife. Topics that were examined included: methods for toxicological endpoint selection, techniques for dose-response assessment, approaches for cross-species extrapolation, and tools to incorporate environmental factors (e.g., metal bioavailability and chemistry) into a reference value. The workgroup also made recommendations to risk assessors and regulators on how to incorporate site-specific wildlife life history and toxicity information into the derivation of TRVs to be used in the further development of soil cleanup levels., (© 2013 SETAC.)

Soil contaminant concentration limits for the protection of terrestrial plants and soil invertebrates are commonly based on thresholds derived using data from laboratory ecotoxicity tests. A comprehensive assessment has been made for the derivation of ecological soil screening levels (Eco-SSL) in the United States; however, these limits are conservative because of their focus on high bioavailability scenarios. Here, we explain and evaluate approaches to soil limit derivation taken by 4 jurisdictions, 2 of which allow for correction of data for factors affecting bioavailability among soils, and between spiked and field-contaminated soils (Registration Evaluation Authorisation and Restriction of Chemicals [REACH] Regulation, European Union [EU], and the National Environment Protection Council [NEPC], Australia). Scientifically advanced features from these methods have been integrated into a newly developed method for deriving soil clean-up values (SCVs) within the context of site-specific baseline ecological risk assessment. Resulting site-specific SCVs that account for bioavailability may permit a greater residual concentration in soil when compared to generic screening limit concentrations (e.g., Eco-SSL), while still affording acceptable protection. Two choices for selecting the level of protection are compared (i.e., allowing higher effect levels per species, or allowing a higher percentile of species that are potentially unprotected). Implementation of this new method is presented for the jurisdiction of the United States, with a focus on metal and metalloid contaminants; however, the new method can be used in any jurisdiction. A case study for molybdate shows the large effect of bioavailability corrections and smaller effects of protection level choices when deriving SCVs., (© 2014 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of SETAC.)

In situ chemical oxidation using permanganate has frequently been used to treat chlorinated solvents in fractured bedrock aquifers. However, in systems where matrix back-diffusion is an important process, the ability of the oxidant to migrate and treat target contaminants within the rock matrix will likely determine the overall effectiveness of this remedial approach. In this study, a series of diffusion experiments were performed to measure the permanganate diffusion and reaction in four different types of sedimentary rocks (dark gray mudstone, light gray mudstone, red sandstone, and tan sandstone). Results showed that, within the experimental time frame (~2 months), oxidant migration into the rock was limited to distances less than 500 μm. The observed diffusivities for permanganate into the rock matrices ranged from 5.3 × 10(-13) to 1.3 × 10(-11) cm(2)/s. These values were reasonably predicted by accounting for both the rock oxidant demand and the effective diffusivity of the rock. Various Mn minerals formed as surface coatings from reduction of permanganate coupled with oxidation of total organic carbon (TOC), and the nature of the formed Mn minerals was dependent upon the rock type. Post-treatment tracer testing showed that these Mn mineral coatings had a negligible impact on diffusion through the rock. Overall, our results showed that the extent of permanganate diffusion and reaction depended on rock properties, including porosity, mineralogy, and organic carbon. These results have important implications for our understanding of long-term organic contaminant remediation in sedimentary rocks using permanganate., (Copyright © 2014 Elsevier B.V. All rights reserved.)

Scarce data are available so far on emissions in a given scenario for excavation and thermal desorption, a common practice, of soils contaminated with polychlorinated biphenyls (PCBs). As part of China action of "Cleanup Plan for PCBs Burial Sites", this study roughly estimated PCBs emissions in the scenario for a capacitor-burial site. The concentrations of total PCBs (22 congeners) in soils were in the range of 2.1-16,000μg/g with a mean of 2300μg/g, among the same order of magnitude as the highest values obtained in various PCBs-contaminated sites. Only six congeners belonging to Di-, Tri-, and Tetra-CBs were observed above limits of detection in air samples in the scenario, partially which can be estimated by the USEPA air emission model. Comparing concentrations and composition profiles of PCBs in the soil and air samples further indicated a leaked source of commercial PCBs formulations of trichlorobiphenyl (China PCB no. 1). The measures taken if any to mitigate the volatilization and movement of PCBs and to minimize worker exposure were discussed for improvements of the excavation practice., (Copyright © 2013 Elsevier Inc. All rights reserved.)

With increasing pressure placed on natural systems by growing human populations, both scientists and resource managers need a better understanding of the relationships between cumulative stress from human activities and valued ecosystem services. Societies often seek to mitigate threats to these services through large-scale, costly restoration projects, such as the over one billion dollar Great Lakes Restoration Initiative currently underway. To help inform these efforts, we merged high-resolution spatial analyses of environmental stressors with mapping of ecosystem services for all five Great Lakes. Cumulative ecosystem stress is highest in near-shore habitats, but also extends offshore in Lakes Erie, Ontario, and Michigan. Variation in cumulative stress is driven largely by spatial concordance among multiple stressors, indicating the importance of considering all stressors when planning restoration activities. In addition, highly stressed areas reflect numerous different combinations of stressors rather than a single suite of problems, suggesting that a detailed understanding of the stressors needing alleviation could improve restoration planning. We also find that many important areas for fisheries and recreation are subject to high stress, indicating that ecosystem degradation could be threatening key services. Current restoration efforts have targeted high-stress sites almost exclusively, but generally without knowledge of the full range of stressors affecting these locations or differences among sites in service provisioning. Our results demonstrate that joint spatial analysis of stressors and ecosystem services can provide a critical foundation for maximizing social and ecological benefits from restoration investments.

To date, little information is known about the operation of the enhanced biological phosphorus removal (EBPR) process in tropical climates. Along with the global concerns on nutrient pollution and the increasing array of local regulatory requirements, the applicability and compliance accountability of the EBPR process for sewage treatment in tropical climates is being evaluated. A sequencing batch reactor (SBR) inoculated with seed sludge from a conventional activated sludge (CAS) process was successfully acclimatized to EBPR conditions at 28 °C after 13 days' operation. Enrichment of Candidatus Accumulibacter phosphatis in the SBR was confirmed through fluorescence in situ hybridization (FISH). The effects of operational pH and influent C:P ratio on EBPR were then investigated. At pH 7 or pH 8, phosphorus removal rates of the EBPR processes were relatively higher when operated at C:P ratio of 3 than C:P ratio of 10, with 0.019-0.020 and 0.011-0.012 g-P/g-MLVSS•day respectively. One-year operation of the 28 °C EBPR process at C:P ratio of 3 and pH 8 demonstrated stable phosphorus removal rate of 0.020 ± 0.003 g-P/g-MLVSS•day, corresponding to effluent with phosphorus concentration <0.5 mg/L. This study provides the first evidence on good EBPR activity at relatively high temperature, indicating its applicability in a tropical climate.

Of growing interest in the control of sediment phosphorus (P) release in lakes is the use of solid phase P-sorbing products (PSPs) including industrial by-products and naturally occurring or modified mineral complexes. However, there is a need to report on novel PSPs proposed by suppliers for use in lake remediation projects at the national scale. We comparatively assessed the elemental composition and P sorption properties of six industrial waste-products (waste-products from treatment of abandoned mine waters - 'red ochre' and 'black ochre'; waste products from building practices: 'gypsum', 'sander dust', 'mag dust' and 'vermiculite') and one commercially available modified lanthanum (La) bentonite product (Phoslock®), all of which have been proposed for use in remediation projects in UK lakes. P sorption was well described (r(2)>0.70) by Langmuir isotherms for all products with the exception of 'gypsum' for which no significant P sorption was reported. P sorption capacities ranged from 4 mgPg(-1) dry weight (d.w.) PSP ('black ochre') to 63 mgg(-1) d.w. ('sander dust'), with products composed mainly of calcium oxide (CaO) and silicon dioxide (SiO(2)) (i.e. 'vermiculite', 'mag dust' and 'sander dust' PSPs) having significantly higher sorption capacities than all other PSPs. Estimates of the equilibrium P concentration (EPC(0)) from Langmuir isotherms indicated that all PSPs, with the exception of 'gypsum', were capable of reducing soluble reactive P (SRP) concentrations to <5.1 μgL(-1). Further research and development required to underpin regulatory policy decisions regarding the use of PSPs is discussed. Dose estimates for each PSP required to treat a eutrophic shallow loch (40.6 ha) with persistent internal loading issues are reported., (Copyright © 2012. Published by Elsevier B.V.)

The reasons for decline of bioleaching efficiency of Zn and Mn from spent batteries at high pulp densities were analyzed; the measures for improving bioleaching efficiency were investigated. The results showed that extraction efficiency of Zn dropped from 100% at 1% of pulp density to 29.9% at 8% of pulp density, with Mn from 94% to only 2.5%. It was almost the linear reduction of the activity of the sulfur-oxidizing bacteria with increase of pulp density that witnessed declined bioleaching efficiency of Zn; it was the complete inactivation of the iron-oxidizing bacteria at 2% of pulp density or higher that witnessed declined bioleaching dose of Mn. By means of reducing initial pH value of leaching media, increasing concentration of energy matters and exogenous acid adjustment of media during bioleaching, the maximum extraction efficiency of almost 100% for Zn and 89% for Mn at 4% of pulp density was attained, respectively., (Copyright © 2012 Elsevier Ltd. All rights reserved.)

The paper provides a rationale for the need for developing the decontamination - actively health-promoting area of hygiene science and practice to neutralize (decontaminate) different pathogens just in the environment where they enter during its inadequate, ineffective, or quite impossible protection from contamination. As of now, there are no physical decontamination technologies or ineffective attempts to make harmless chemical pathogens in the environment; at the same time it is stated that there are scientifically grounded biological decontamination and disinfectology technologies to neutralize biological pathogens just in the environment and on its different objects. To solve these problems requires hygienic competence, particularly the substantiation of hygienic standards for disinfectants in the environment and the elaboration of hygienically safe regimens of their application. In this connection, disinfectology is the most hygienic branch of all antiepidemic ones of preventive medicine. The development of disinfectology as a fruitful alliance of hygiene and epidemiology allowed a system of governmental management and control of unspecific prophylaxis to be developed and introduced in Russia, which contributes to a reduction in or at least stabilization of the incidence of infectious diseases in the country.

To perform a general assessment of treatment efficiency, a mass balance study was undertaken for two types of constructed wetlands (CWs), planted gravel filters and plant root mat systems, for treating VOC (benzene; MTBE) polluted groundwater under field conditions. Contaminant fate was investigated in the respective water, plant, and atmosphere compartments by determining water and atmospheric contaminant loads and calculating contaminant plant uptake, thereby allowing for an extended efficiency assessment of CWs. Highest total VOC removal was achieved during summer, being pronounced for benzene compared to MTBE. According to the experimental results and the calculations generated by the balancing model, degradation in the rhizosphere and plant uptake accounted for the main benzene removal processes, of 76% and 13% for the gravel bed CW and 83% and 11% for the root mat system. Volatilization flux of benzene and MTBE was low (<5%) for the gravel bed CW, while in the root mat system direct contact of aqueous and gaseous phases favored total MTBE volatilization (24%). With this applied approach, we present detailed contaminant mass balances that allow for conclusive quantitative estimation of contaminant elimination and distribution processes (e.g., total, surface, and phytovolatilization, plant uptake, rhizodegradation) in CWs under field conditions.

Risk-based soil environmental standard is one of the important aspects in contaminated soil management which have already been widely used in many countries. However, because of diversity in geographical, biological, social-cultural, regulatory and scientific aspects among each country, there are great distinctions on both titles and values of these soil environmental standards between different countries. Risk-based soil environmental standards and derivation process were introduced and compared in detail. The variability was analyzed and explained through the comparison of sensitivity risk receptors, land utilizations and pathways of exposure among these countries. We suggest that the risk-based soil environmental standards among the developed countries could be classified as target value, screening value and intervention value, which aim to protect soil for sustainable development in the future, to determine whether there is potential unacceptable risk to specified acceptors, and whether further counter-actions should be conducted, respectively. At last, risk assessment of contaminated soils and establishment of risk-based soil environmental standards in China was proposed.

A common approach for remediation of groundwater contamination with volatile organic compounds (VOCs) is contaminant stripping by means of in situ air sparging (IAS). For VOC stripping, pressurized air is injected into the contaminated groundwater volume, followed by the extraction of the contaminant-loaded exhaust gas from the vadose soil zone and its immediate on-site treatment. Progress assessment of such remediation measure necessitates information (i) on the spatial range of the IAS influence and (ii) on temporal variations of the IAS efficiency. In the present study it was shown that the naturally occurring noble gas radon can be used as suitable environmental tracer for achieving the related spatial and temporal information. Due to the distinct water/air partitioning behaviour of radon and due to its straightforward on-site detectability, the radon distribution pattern in the groundwater can be used as appropriate measure for assessing the progression of an IAS measure as a function of space and time. The presented paper discusses both the theoretical background of the approach and the results of an IAS treatment accomplished at a VOC contaminated site lasting six months, during which radon was applied as efficiency indicator., (Copyright © 2010 Elsevier Ltd. All rights reserved.)