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Future fusion reactors must be able to breed the tritium they will consume. Several breeding and tritium extraction technologies are under investigation internationally. PbLi is of particular inter...

Permeation is investigated for the introduction of hydrogen isotopes into lead lithium (PbLi) for the Tritium Extraction eXperiment (TEX). TEX is a forced-convection PbLi loop under construction at Idaho National Laboratory that will test the vacuum permeator (VP) method of tritium extraction from PbLi. The source permeator (SP) delivers atomic hydrogen (H, D, and T) from a gas-phase reservoir into the PbLi via a permeable dense metal membrane. A modular system and a fixed SP system are presented. In the modular design, PbLi flows through the inside of a tubular membrane, and gas-phase hydrogen is introduced on the outside of the membrane. Atomic hydrogen permeates radially inward through the membrane into the PbLi. In the fixed design, PbLi flows into an expansion chamber with closed-ended tubular membranes inserted. Gas-phase hydrogen is introduced on the inside of the closed-ended membranes, and atomic hydrogen permeates radially outward into the flowing PbLi. Hydrogen transport models based on steady-state mass transport through PbLi and permeation through the metal membrane were developed to assess the operation of the SP relative to experimental variables and to allow understanding of uncertain parameter effects, such as PbLi hydrogen transport properties and the effective hydrogen permeability of the VP. This modeling effort considers iron as the SP material and vanadium as the VP material.

Objective This study sought to determine if there was a difference in the months of oral contraception prescribed by resident physicians living in U.S. states with a 12-month supply policy compared to resident physicians in states without a policy. Methods We conducted an exploratory descriptive study using a convenience sample of Obstetrics and Gynecology resident physicians (n = 275) in the United States. Standard bivariate analyses were used to compare the difference between groups. Results Few resident physicians in both groups (3.8% with a policy and 1.4% without a policy) routinely prescribed a 12-month supply of contraception. The mean coverage prescribed by providers in states with and without a policy was 2.81 and 2.07 months (p Conclusions The majority of resident physicians were unaware of 12-month contraceptive supply policies and unable to correctly write a prescription for 12-months of contraception, regardless of whether they lived in a state with a 12-month contraceptive supply policy. Physician education may be needed to effectively implement 12-month contraceptive supply policies.

Most ULXs are believed to be powered by super-Eddington accreting neutron stars and, perhaps, black holes. Above the Eddington rate the disc is expected to thicken and to launch powerful winds through radiation pressure. Winds have been recently discovered in several ULXs. However, it is yet unclear whether the thickening of the disc or the wind variability causes the switch between the classical soft and supersoft states observed in some ULXs. In order to understand such phenomenology and the overall super-Eddington mechanism, we undertook a large (800 ks) observing campaign with XMM-Newton to study NGC 247 ULX-1, which shifts between a supersoft and classical soft ULX state. The new observations show unambiguous evidence of a wind in the form of emission and absorption lines from highly-ionised ionic species, with the latter indicating a mildly-relativistic outflow (-0.17c) in line with the detections in other ULXs. Strong dipping activity is observed in the lightcurve and primarily during the brightest observations, which is typical among soft ULXs, and indicates a close relationship between the accretion rate and the appearance of the dips. The latter is likely due to a thickening of the disc scale-height and the wind as shown by a progressively increasing blueshift in the spectral lines., 18 pages, 16 figures, accepted for publication in MNRAS

Liquid ammonia is a high-density (17.7 wt %) hydrogen carrier with a well-established production and distribution infrastructure. Efficient decomposition and purification are essential for its use ...

Transition metal carbide coated vanadium membranes for hydrogen permeation have the unique ability to operate at both high temperatures and pressures. Titanium carbide deposited by magnetron sputte...

Mo2C has previously been demonstrated as an effective catalyst layer to enable stable H2 permeation through vanadium foils at high temperatures. In this study, this approach was extended to several group V metal foils (V, Nb, and Ta) as well as mixed gas testing. The best permeability was achieved with V, and an activation process was developed to recover the performance of V foils displaying evidence of oxidation. Nb foils yielded ~ 20% the permeability of V, while Ta was too brittle to operate effectively. Mo2C/V membranes were operated at feed conditions well above the ductile-to-brittle transition pressure without embrittlement; however, the H2 permeability of Mo2C/V membranes was significantly attenuated at lower temperatures (

A grand challenge of vanadium-based H2 permeable membranes is the development of effective, cheap, and stable catalysts to facilitate H2 dissociation and recombination. This work investigates a fac...

In this work, we discuss an observed reduction of magnesium from a MgO/MgAl 2 O 4 ceramic substrate by permeating hydrogen in thin-film Pd membranes. Membranes were fabricated via electroless plating of Pd on a porous MgO/MgAl 2 O 4 substrate and tested under pure hydrogen permeation conditions between 500 °C and 700 °C. It was observed that a rapid and severe hydrogen flux decline occurred at 700 °C, whereat up to 96% of the hydrogen flux was lost within 40 h of operation. Using energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy, it was concluded that the flux loss occurred due to alloying and a subsequent surface segregation of Mg in the Pd film. In contrast, a control test in which the membrane was soaked in hydrogen at 700 °C without permeation resulted in only very slight or potentially no MgO reduction or alloying with the Pd. The significantly enhanced reduction of MgO/MgAl 2 O 4 during membrane operation is attributed to the chemical potential provided by atomic hydrogen permeating through the membrane.

The effects of high pressure gas exposure on the hydrogen flux though Pd films were explored. It was observed that exposure of a Pd membrane to N 2 , Ar, or CO 2 at 3.0 MPa and 500 °C caused a substantial decline in hydrogen flux within 24 h that only recovered to ca. 60% of its initial value after 24 h of subsequent hydrogen exposure. Atomic force microscopy images revealed that the Pd surface became smoother with a reduction in density of nanoscale features after high pressure exposure, consistent with an observed transition in rate limiting step from bulk diffusion to surface kinetics. The rate of flux loss was found to have an apparent activation energy of 39 kJ mol −1 , which is consistent with values reported for Pd surface self-diffusion. This effect was not observed when the exposure gas was helium or at pressures 2 impurities (ca. 1%) in the feed.

A new combined positron annihilation lifetime spectroscopy (PALS) and coincidence Doppler broadening (CDB) system has been constructed at Idaho National Laboratory (INL). The design and commissioning process are discussed with practical guidelines that can be followed for the installation of new systems. In addition, the new system was used to investigate defect structure in titanium and titanium deuteride samples where the deuterium concentration ranges from 0.10 to 2 x 10−5. The TiD samples were found to be largely defect free based on the positron lifetimes and S- W curves. Ratio curves of the CDB spectra showed elemental sensitivity to the deuterium in the samples, that increased with deuterium concentration.

Dense vanadium-based membranes offer high permeability and perfect selectivity to hydrogen isotopes, maintain favorable neutronic properties, and are compatible with liquid metals such as PbLi. These properties make vanadium membranes a promising fusion fuel cycle technology for processes such as tritium extraction from PbLi and exhaust processing. Surface contamination has a deleterious effect on the gas-phase hydrogen permeation through vanadium, and the reported permeabilities range from 10-14 to 10-7 mol m-1 s-1 Pa-0.5. Thin dense films of palladium applied to clean vanadium surfaces enable a consistently high hydrogen permeability. In this study, uncoated vanadium resulted in deuterium permeabilities ranging from 2.8 × 10-11 to 6.4 × 10-9 mol m-1 s-1 Pa-0.5 at 300 °C–700 °C, respectively. Post-test analysis revealed a VOx surface layer and VCx subsurface layer formed on the feed side, while the as-received surface oxide dissolved leaving a submonolayer oxide on the permeate surface. The Pd-coated V resulted in a maximum deuterium permeability of 2.1 × 10-7 mol m-1 s-1 Pa-0.5 at 375 °C upon activation of the Pd surface by oxidation and reduction. The deuterium permeation declined upon heating to 500 °C due to intermetallic diffusion between the Pd and V. The Mo2C-coated V resulted in deuterium permeabilities ranging from 2.7 × 10-10 to 1.8 × 10-9 at 500 °C–700 °C, respectively, and a post-test analysis found the carbon in the Mo2C layer had dissolved into the V near the interface.

High-performance lithium-ion batteries require electrolytes that are stable over wide operating voltages. We used density functional theory to investigate the degradation of ethylene carbonate (EC) electrolytes activated by interactions with LiCoO2 cathode surfaces and PF5 species in the electrolyte. We report detailed mechanisms for the activation of EC ring-opening reactions by Lewis acids to form CO2, organics, or organofluorines. We find that Lewis acid–base complexation between EC and either PF5 or LiCoO2 weakens the C–O bonds of the EC ring and consequently lowers the barrier to and energy of EC ring-opening reactions. Our results predict that ring opening activated by the LiCoO2 cathode surface forms a cathode–electrolyte interphase primarily composed of an organic and organofluorine film. Simultaneous degradation of an EC molecule and PF6– forms PF5 and a surface organofluorine with an activation barrier of 1.28 eV and reaction energy of −0.26 eV. Ring opening of EC activated by the cathode to for...

We present simultaneous XMM-Newton and NuSTAR observations spanning 3-78 keV of the nearest radio galaxy, Centaurus A (Cen A). The accretion geometry around the central engine in Cen A is still debated, and we investigate possible configurations using detailed X-ray spectral modeling. NuSTAR imaged the central region of Cen A with sub-arcminute resolution at X-ray energies above 10 keV for the first time, but finds no evidence for an extended source or other off-nuclear point-sources. The XMM-Newton and NuSTAR spectra agree well and can be described with an absorbed power-law with a photon index {\Gamma} = 1.815 +/- 0.005 and a fluorescent Fe K{\alpha} line in good agreement with literature values. The spectrum does not require a high-energy exponential rollover, with a constraint of E_fold > 1 MeV. A thermal Comptonization continuum describes the data well, with parameters that agree with values measured by INTEGRAL, in particular an electron temperature kTe between ~100-300 keV, seed photon input temperatures between 5-50 eV. We do not find evidence for reflection or a broad iron line and put stringent upper limits of R < 0.01 on the reflection fraction and accretion disk illumination. We use archival Chandra data to estimate the contribution from diffuse emission, extra-nuclear point-sources, and the outer X-ray jet to the observed NuSTAR and XMM-Newton X-ray spectra and find the contribution to be negligible. We discuss different scenarios for the physical origin of the observed hard X-ray spectrum, and conclude that the inner disk is replaced by an advection-dominated accretion flow or that the X-rays are dominated by synchrotron self-Compton emission from the inner regions of the radio jet or a combination thereof., Comment: 13 pages, 6 figures, accepted for publication in ApJ

The effects of gold concentration on the carbon tolerance of palladium-based composite membranes was studied under the presence of high CO concentrations. Membranes with PdAu compositions up to 41% Au by mass were exposed to 50/50H2/CO gas atmospheres and both hydrogen flux and permeate purity were monitored over time. The highest gold concentration (41 wt%) had no measurable degradation in membrane performance in terms of either hydrogen permeate purity or hydrogen permeation flux during the 48 h exposure; in contrast, the pure palladium membrane suffered total degradation during the same exposure time. Furthermore, for lower gold concentrations, X-ray diffraction patterns suggested that carbon entered the membrane film and could be removed by exposure to hydrogen and a non-CO containing gas mixture over time; however, removal of the carbon adversely affected hydrogen permeate purity. Interestingly, some of the observed hydrogen permeate purity decline could be reversed upon re-exposure to the CO gas mixture. It is hypothesized that carbon loading in the palladium films causes lattice expansion and may even fill pore defects, thus lowering non-hydrogen leaks through the Pd membrane films. This study suggests that a membrane exposed to a CO mixture should not be cycled between CO and non-CO environments, but rather run continuously for best performance. Additionally, the choice of Pd-alloy metal and composition should be considered in regard to its carbon solubility to best predict lifetime performance.

We utilized density functional theory to examine HF generation in lithium-ion battery electrolytes from reactions between H2O and the decomposition products of three electrolyte additives: LiPF6, LiPOF4, and LiAsF6. Decomposition of these additives produces PF5, AsF5, and POF3 along with LiF precipitates. We found PF5 and AsF5 react with H2O in two sequential steps to form two HF molecules and POF3 and AsOF3, respectively. PF5 (or AsF5) complexes with H2O and undergoes ligand exchange to form HF and PF4OH (AsF4OH) with an activation barrier of 114.2 (30.5) kJ mol−1 and reaction enthalpy of 14.6 (−11.3) kJ mol−1. The ethylene carbonate (EC) electrolyte forms a Lewis acid–base complex with the PF4OH (AsF4OH) product, reducing the barrier to HF formation. Reactions of POF3 were examined and are not characterized by complexation of POF3 with H2O or EC, while PF5 and AsF5 complex favorably with H2O and EC. HF formation from POF3 occurs with a reaction enthalpy of −3.8 kJ mol−1 and a 157.7 kJ mol−1 barrier, 43.5 kJ mol−1 higher than forming HF from PF5. HF generation in electrolytes employing LiPOF4 should be significantly lower than those using LiPF6 or LiAsF6 and LiPOF4 should be further investigated as an alternative electrolyte additive.

The design, fabrication, and evaluation of flexible, multilayer optical coatings deposited by plasma-enhanced chemical vapor deposition at low temperature are demonstrated using hybrid nanolaminates consisting of TiO2 and silicone (SiOxCyHz) as the high and low refractive index materials, respectively. A broadband anti-reflection coating was designed and deposited onto a variety of substrates including flexible polyethylene terephthalate (PET) and CdTe solar cells which was shown to increase absolute transmission by an average of 3% over 410–850 nm wavelengths and results in a commensurate increase in short circuit current density. An infrared reflector was designed and applied to PET which was found to provide 70% reflectance in the near-IR while maintaining >80% transmittance for visible light. The optical performance of these flexible coatings on PET remained unchanged after automated bend testing, and were shown to be robust with respect to humidity and thermal shock tests.

We discuss the broad-band X-ray spectrum of GRS 1734−292 obtained from non-simultaneous XMM-Newton and NuSTAR (Nuclear Spectroscopic Telescope Array) observations, performed in 2009 and 2014, respectively. GRS1734−292 is a Seyfert 1 galaxy, located near the Galactic plane at z = 0.0214. The NuSTAR spectrum (3–80 keV) is dominated by a primary power-law continuum with Γ = 1.65 ± 0.05 and a high-energy cut-off Ec = 53(+11)(−8) keV, one of the lowest measured by NuSTAR in a Seyfert galaxy. Comptonization models show a temperature of the coronal plasma of kTe = 11.9 (+1.2)(−0.9) keV and an optical depth, assuming a slab geometry, τ=2.98(+0.16)(−0.19) or a similar temperature and τ=6.7(+0.3)(−0.4) assuming a spherical geometry. The 2009 XMM–Newton spectrum is well described by a flatter intrinsic continuum (Γ=1.47(+0.07)(−0.03)) and one absorption line due to Fe XXV Kα produced by a warm absorber. Both data sets show a modest iron Kα emission line at 6.4 keV and the associated Compton reflection, due to reprocessing from neutral circumnuclear material., Monthly Notices of the Royal Astronomical Society, 466 (4), ISSN:0035-8711, ISSN:1365-2966, ISSN:1365-8711

We present results from four new broadband X-ray observations of the extreme ultraluminous X-ray source Holmberg IX X-1 ($L_{\rm{X}} > 10^{40}$ erg/s), performed by $Suzaku$ and $NuSTAR$ in coordination. Combined with the archival data, we now have broadband observations of this remarkable source from six separate epochs. Two of these new observations probe lower fluxes than seen previously, allowing us to extend our knowledge of the broadband spectral variability exhibited. The spectra are well fit by two thermal blackbody components, which dominate the emission below 10 keV, as well as a steep ($\Gamma \sim 3.5$) powerlaw tail which dominates above $\sim$15 keV. Remarkably, while the 0.3-10.0 keV flux varies by a factor of $\sim$3 between all these epochs, the 15-40 keV flux varies by only $\sim$20%. Although the spectral variability is strongest in the $\sim$1-10 keV band, both of the thermal components are required to vary when all epochs are considered. We also re-visit the search for iron absorption features, leveraging the high-energy $NuSTAR$ data to improve our sensitivity to extreme velocity outflows in light of the ultra-fast outflow recently detected in NGC 1313 X-1. Iron absorption from a similar outflow along our line of sight can be ruled out in this case. We discuss these results in the context of super-Eddington accretion models that invoke a funnel-like geometry for the inner flow, and propose a scenario in which we have an almost face-on view of a funnel that expands to larger radii with increasing flux, resulting in an increasing degree of geometrical collimation for the emission from intermediate temperature regions., Comment: 11 pages, 6 Figures, accepted for publication in ApJ

We present broad-band, multi-epoch X-ray spectroscopy of the pulsating ultra-luminous X-ray source (ULX) in NGC 5907. Simultaneous XMM-Newton and NuSTAR data from 2014 are best described by a multi-color black-body model with a temperature gradient as a function of accretion disk radius significantly flatter than expected for a standard thin accretion disk (T(r) ~ r^{-p}, with p=0.608^{+0.014}_{-0.012}). Additionally, we detect a hard power-law tail at energies above 10 keV, which we interpret as being due to Comptonization. We compare this observation to archival XMM-Newton, Chandra, and NuSTAR data from 2003, 2012, and 2013, and investigate possible spectral changes as a function of phase over the 78d super-orbital period of this source. We find that observations taken around phases 0.3-0.4 show very similar temperature profiles, even though the observed flux varies significantly, while one observation taken around phase 0 has a significantly steeper profile. We discuss these findings in light of the recent discovery that the compact object is a neutron star and show that precession of the accretion disk or the neutron star can self-consistently explain most observed phenomena., 7 pages, 5 figures, submitted to ApJ; comments welcome

We present first results from a series of $NuSTAR$ observations of the black hole X-ray binary V404 Cyg obtained during its summer 2015 outburst, primarily focusing on observations during the height of this outburst activity. The $NuSTAR$ data show extreme variability in both the flux and spectral properties of the source. This is partly driven by strong and variable line-of-sight absorption, similar to previous outbursts. The latter stages of this observation are dominated by strong flares, reaching luminosities close to Eddington. During these flares, the central source appears to be relatively unobscured and the data show clear evidence for a strong contribution from relativistic reflection, providing a means to probe the geometry of the innermost accretion flow. Based on the flare properties, analogy with other Galactic black hole binaries, and also the simultaneous onset of radio activity, we argue that this intense X-ray flaring is related to transient jet activity during which the ejected plasma is the primary source of illumination for the accretion disk. If this is the case, then our reflection modelling implies that these jets are launched in close proximity to the black hole (as close as a few gravitational radii), consistent with expectations for jet launching models that tap either the spin of the central black hole, or the very innermost accretion disk. Our analysis also allows us to place the first constraints on the black hole spin for this source, which we find to be $a^* > 0.92$ (99% statistical uncertainty, based on an idealized lamppost geometry)., 23 pages, 16 figures, accepted for publication in ApJ

We utilized density functional theory (DFT) to systematically investigate the ability of B, C, and N interstitial and O substitutional surface and near-surface dopants in TiO2 to facilitate O2 reduction and adsorption. Periodic boundary condition calculations based on the PBE+U DFT functional show that dopants that create filled band gap states with energies higher than that of the near surface O2 πz* molecular orbital enable O2 adsorption and reduction. Sites that create unoccupied band gap states with energies below that of the O2 πz* orbital reduce TiO2’s reduction ability as these states result in photoexcited electrons with insufficient reduction potential to reduce O2. B dopants in interstitial and relaxed substitutional sites, whose gap states lie >1.5 eV above the valence band maximum (VBM) and hence above O2’s πz* level, facilitate the reduction of O2 to the peroxide state with adsorption energies on TiO2 of −1.22 to −2.77 eV. However, N dopants, whose gap states lie less than ∼1 eV above the VBM...

We present a broad band spectral analysis of the joint XMM-Newton and NuSTAR observational campaign of the Narrow Line Seyfert 1 SWIFT J2127.4+5654, consisting of 300 ks performed during three XMM-Newton orbits. We detect a relativistic broadened iron K$\alpha$ line originating from the innermost regions of the accretion disc surrounding the central black hole, from which we infer an intermediate spin of $a$=$0.58^{+0.11}_{-0.17}$. The intrinsic spectrum is steep ($\Gamma=2.08\pm0.01$) as commonly found in Narrow Line Seyfert 1 galaxies, while the cutoff energy (E$_{\rm c}=108^{+11}_{-10}$ keV) falls within the range observed in Broad Line Seyfert 1 Galaxies. We measure a low-frequency lag that increases steadily with energy, while at high frequencies, there is a clear lag following the shape of the broad Fe K emission line. Interestingly, the observed Fe K lag in SWIFT J2127.4+5654 is not as broad as in other sources that have maximally spinning black holes. The lag amplitude suggests a continuum-to-reprocessor distance of about $ 10-20\ r_{\mathrm{g}}$. These timing results independently support an intermediate black hole spin and a compact corona., Comment: 11 pages, 10 figures, accepted for publication on MNRAS

The current technology for hydrogen isotope separation requires enormous capital investment and energy consumption. Palladium-based membranes exhibit hydrogen isotope selectivity and provide a continuous method of isotope enrichment but have high material costs. Here, the authors investigate the potential of titanium carbide thin films coated on vanadium as a low-cost alternative, which enabled operation at high temperatures. Protium and deuterium exhibited nominally identical solubility in TiC coated vanadium over a range of 500–700 °C. Permeation tests from 600 to 700 °C revealed that protium permeated faster than deuterium, with the separation factor decreasing from 1.34 to 1.15 with increasing temperature. XPS depth-profiling showed a distinct interface between the TiC layer and the V foil in as-fabricated membranes. However, post-test analysis revealed significant V diffusion through TiC and segregation to the surface. Surface limitations resulting from this degradation accounted for changes in flux and may explain why the separation factor was lower than the value of 1.42 expected from high temperature interstitial diffusion of protium/deuterium in vanadium.The current technology for hydrogen isotope separation requires enormous capital investment and energy consumption. Palladium-based membranes exhibit hydrogen isotope selectivity and provide a continuous method of isotope enrichment but have high material costs. Here, the authors investigate the potential of titanium carbide thin films coated on vanadium as a low-cost alternative, which enabled operation at high temperatures. Protium and deuterium exhibited nominally identical solubility in TiC coated vanadium over a range of 500–700 °C. Permeation tests from 600 to 700 °C revealed that protium permeated faster than deuterium, with the separation factor decreasing from 1.34 to 1.15 with increasing temperature. XPS depth-profiling showed a distinct interface between the TiC layer and the V foil in as-fabricated membranes. However, post-test analysis revealed significant V diffusion through TiC and segregation to the surface. Surface limitations resulting from this degradation accounted for changes in flux ...

We report the detection of coherent pulsations from the ultraluminous X-ray source (ULX) NGC 7793 P13. The ≈0.42 s nearly sinusoidal pulsations were initially discovered in broadband X-ray observations using XMM-Newton and NuSTAR taken in 2016. We subsequently also found pulsations in archival XMM-Newton data taken in 2013 and 2014. The significant (≫5σ) detection of coherent pulsations demonstrates that the compact object in P13 is a neutron star, and given the observed peak luminosity of ≈10⁴⁰ erg s⁻¹ (assuming isotropy), it is well above the Eddington limit for a 1.4 M⨀ accretor. This makes P13 the second ULX known to be powered by an accreting neutron star. The pulse period varies between epochs, with a slow but persistent spin-up over the 2013–2016 period. This spin-up indicates a magnetic field of B ≈ 1.5 × 10¹² G, typical of many Galactic accreting pulsars. The most likely explanation for the extreme luminosity is a high degree of beaming; however, this is difficult to reconcile with the sinusoidal pulse profile., We would like the thank the referee for the helpful comments. M.J.M. acknowledges support from an STFC Ernest Rutherford fellowship and D.B. acknowledges financial support from the French Space Agency (CNES). This research has made use of data obtained with NuSTAR, a project led by Caltech, funded by NASA and managed by NASA/JPL, and has utilized the nustardas software package, jointly developed by the ASDC (Italy) and Caltech (USA). This research has also made use of data obtained with XMM-Newton, an ESA science mission with instruments and contributions directly funded by ESA Member States. This work made use of data supplied by the UK Swift Science Data Centre at the University of Leicester, and also made use of the XRT Data Analysis Software (XRTDAS) developed under the responsibility of the ASI Science Data Center (ASDC), Italy. This research has made use of a collection of ISIS functions (ISISscripts) provided by ECAP/Remeis observatory and MIT (http://www.sternwarte.uni-erlangen.de/isis/). Facilities: NuSTAR - The NuSTAR (Nuclear Spectroscopic Telescope Array) mission, XMM - , Swift - .

High-performance lithium-ion batteries require electrolytes that are stable over wide operating voltages. We used density functional theory to investigate the degradation of ethylene carbonate (EC) electrolytes activated by interactions with LiCoO

We present a detailed spectral analysis of XMM-Newton and NuSTAR observations of the accreting transient black hole GRS 1739-278 during a very faint low hard state at ~0.02% of the Eddington luminosity (for a distance of 8.5 kpc and a mass of 10 M_sun ). The broad-band X-ray spectrum between 0.5-60 keV can be well-described by a power law continuum with an exponential cutoff. The continuum is unusually hard for such a low luminosity, with a photon index of Gamma = 1.39 +/- 0.04. We find evidence for an additional reflection component from an optically thick accretion disk at the 98% likelihood level. The reflection fraction is low with R_refl = 0.043(+0.033,-0.023). In combination with measurements of the spin and inclination parameters made with NuSTAR during a brighter hard state by Miller and co-workers, we seek to constrain the accretion disk geometry. Depending on the assumed emissivity profile of the accretion disk, we find a truncation radius of 15-35 Rg (5-12 R_ISCO ) at the 90% confidence limit. These values depend strongly on the assumptions and we discuss possible systematic uncertainties., 7 pages, 3 figures, accepted for publication in ApJ

We report the detection of a $78.1\pm0.5$ day period in the X-ray lightcurve of the extreme ultraluminous X-ray source NGC 5907 ULX1 ($L_{\rm{X,peak}}\sim5\times10^{40}$ erg s$^{-1}$), discovered during an extensive monitoring program with Swift. These periodic variations are strong, with the observed flux changing by a factor of $\sim$3-4 between the peaks and the troughs of the cycle; our simulations suggest that the observed periodicity is detected comfortably in excess of 3$\sigma$ significance. We discuss possible origins for this X-ray period, but conclude that at the current time we cannot robustly distinguish between orbital and super-orbital variations., Comment: 6 pages, 3 figures, accepted for publication in ApJL

We present results from spectral fitting of the very high state of GX~339-4 with NuSTAR and Swift. We use relativistic reflection modelling to measure the spin of the black hole and inclination of the inner disk, and find a spin of $a=0.95^{+0.02}_{-0.08}$ and inclination of $30${\deg}$\pm1$ (statistical errors). These values agree well with previous results from reflection modelling. With the exceptional sensitivity of NuSTAR at the high-energy side of the disk spectrum, we are able to constrain multiple physical parameters simultaneously using continuum fitting. By using the constraints from reflection as input for the continuum fitting method, we invert the conventional fitting procedure to estimate the mass and distance of GX~339-4 using just the X-ray spectrum, finding a mass of $9.0^{+1.6}_{-1.2}M_\odot$ and distance of $8.4\pm0.9$ kpc (statistical errors)., Comment: 6 pages, 4 figures, accepted for publication in ApJ Letters

In the past five years, a flurry of X-ray reverberation lag measurements of accreting supermassive black holes have been made using the XMM-Newton telescope in the 0.3-10 keV energy range. In this work, we use the NuSTAR telescope to extend the lag analysis up to higher energies for two Seyfert galaxies, SWIFT J2127.4+5654 and NGC 1365. X-ray reverberation lags are due to the light travel time delays between the direct continuum emission and the reprocessed emission from the inner radii of an ionised accretion disc. XMM-Newton has been particularly adept at measuring the lag associated with the broad Fe K emission line, where the gravitationally redshifted wing of the line is observed to respond before the line centroid at 6.4 keV, produced at larger radii. Now we use NuSTAR to probe the lag at higher energies, where the spectrum shows clear evidence for Compton reflection, known as the Compton 'hump'. The XMM-Newton data show Fe K lags in both SWIFT J2127.4+5654 and NGC 1365. The NuSTAR data provide independent confirmation of these Fe K lags, and also show evidence for the corresponding Compton hump lags, especially in SWIFT J2127.4+5654. These broadband lag measurements confirm that the Compton hump and Fe K lag are produced at small radii. At low-frequencies in NGC 1365, where the spectrum shows evidence for eclipsing clouds in the line of sight, we find a clear negative (not positive) lag from 2--10 keV, which can be understood as the decrease in column density from a neutral eclipsing cloud moving out of our line of sight during the observation., Comment: 14 Pages, 12 figures, accepted to MNRAS

We present the results from coordinated X-ray observations of the ultraluminous X-ray source NGC 5204 X-1 performed by NuSTAR and XMM-Newton in early 2013. These observations provide the first detection of NGC 5204 X-1 above 10 keV, extending the broadband coverage to 0.3-20 keV. The observations were carried out in two epochs separated by approximately 10 days, and showed little spectral variation, with an observed luminosity of Lx = (4.95+/-0.11)e39 erg/s. The broadband spectrum confirms the presence of a clear spectral downturn above 10 keV seen in some previous observations. This cutoff is inconsistent with the standard low/hard state seen in Galactic black hole binaries, as would be expected from an intermediate mass black hole accreting at significantly sub-Eddington rates given the observed luminosity. The continuum is apparently dominated by two optically thick thermal-like components, potentially accompanied by a faint high energy tail. The broadband spectrum is likely associated with an accretion disk that differs from a standard Shakura & Sunyaev thin disk., 7 pages, 5 figures. Accepted for publication in ApJ

We present an analysis of a ~160 ks NuSTAR observation of the nearby bright Seyfert galaxy IC4329A. The high-quality broadband spectrum enables us to separate the effects of distant reflection from the direct coronal continuum, and to therefore accurately measure the high-energy cutoff to be $E_{cut}=178^{+74}_{-40}$ keV. The coronal emission arises from accretion disk photons Compton up-scattered by a thermal plasma, with the spectral index and cutoff being due to a combination of the finite plasma temperature and optical depth. Applying standard Comptonization models, we measure both physical properties independently using the best signal-to-noise obtained to date in an AGN over the 3-79 keV band. We derive $kT_e=37^{+7}_{-6}$ keV with $\tau=1.25^{+0.20}_{-0.10}$ assuming a slab geometry for the plasma, and $kT_e=33^{+6}_{-6}$ keV with $\tau=3.41^{+0.58}_{-0.38}$ for a spherical geometry, with both having an equivalent goodness-of-fit., Comment: 17 pages in preprint format, 4 figures, 1 table. Accepted by ApJ