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The ultraviolet/flame retardant protection cotton fabric is successfully prepared using a spray baking process with tannic acid (TA) and phytic acid (PA) as key ingredients to address the issues of cotton fabric such as high flammability and lack of ultraviolet (UV) resistance. With respect to the treated fabric by 4 wt% PA solution and 3 wt% TA solution, it presented 29.5% limited oxygen index (LOI) value, 8.0 cm damaged length and 26.4 ultraviolet protection factor (UPF), while they were 28.3%, 7.5 cm and 30.6 for treated fabric by 3 wt% PA solution and 4 wt% TA solution, which indicated that in the mixed system, although TA primarily acted as an anti‐UV agent, it also exhibited flame retardant properties, and PA primarily functioned as a flame retardant and could provide a certain degree of UV protection. The prepared cotton fabric through this facile method presented excellent UV/flame retardant protection capabilities, and improved the functional efficiency of TA and PA materials. Moreover, as‐prepared fabric showed great application potential, especially in outdoor‐applied fields such as sportswear, sunshade tents, sunshade hats, and so on. [ABSTRACT FROM AUTHOR]

Creating eco-friendly flame retardants (FRs) that are highly effective for textiles while requiring minimal quantities is crucial for both human well-being and environmental conservation. Traditionally, halogen FRs have been the mainstay in this field. Yet, due to their harmful impacts on both human health and the environment, there is a growing demand to discontinue their use. Herein, in this work, a novel eco-friendly intumescent-based flame retardant for cotton fabrics, consisting of ammonium polyphosphate (APP), single-walled carbon nanohorns (SWCNHs), and melamine (MEL) was explored. The addition of SWCNHs demonstrated a clear synergistic effect with APP and MEL in enhancing the flame retardancy of cotton fabrics. After four spraying cycles, the treated cotton fabric ASM4 demonstrated outstanding flame retardancy and self-extinguishing properties. Additionally, its LOI value could reach 24.1 ± 0.1% and the damage length dropped to 4.6 ± 0.2% cm from 30.0 ± 0.1% cm for the pristine cotton fabric, while preserving its original morphology with partial carbonization. The pHRR and THR of ASM4 were dramatically decreased by 90% and 51%, respectively in the cone calorimeter test. Moreover, investigating the thermal degradation kinetics of treated cotton fabric and the physicochemical properties of the char residues revealed the crucial influence of SWCNHs on improving the flame resistance of cotton fabrics. The incorporation of SWCNHs improved both the thermal stability and the degree of graphitization of the char layer, which served as a protective barrier. This barrier efficiently blocked the release of volatile combustible substances while allowing for the emission of nonflammable gases. This work provides a theoretical basis for the feasible application of SWCNHs in intumescent FRs. [ABSTRACT FROM AUTHOR]

• Screening non-fluorinated refrigerants with low GWP and reduced flammability. • Performance criterion characterizing heating capacity for low-charge heat pumps. • The most attractive refrigerants were identified through decision-making techniques. • DME-CO 2 mixtures resulted in improvements in efficiency and levelized cost of heat. • Further investigations were recommended on mixtures with DME, Propylene and CO 2. The study investigated the characteristics of different natural refrigerants and their mixtures in a residential heat pump with low refrigerant charge. Three main evaluation criteria were utilized for comparing different mixtures: Coefficient of Performance (COP), Volumetric Heating Capacity (VHC), and a newly proposed indicator, the heating capacity at charge limit. Propane was used as a reference refrigerant. It was found that some mixtures significantly improved both COP and the heating capacity at charge limit while maintaining similar volumetric heating capacity and operating conditions. Alternative multi-criteria decision-making techniques were adopted to rank the best refrigerant mixtures. Mixtures rich in Dimethyl Ether (DME), such as DME-CO 2 [0.96-0.04] and DME-Propylene [0.75-0.25] were found consistently among the best options. Those were followed by Propylene-rich mixtures such as Propylene-CO 2 , Propylene-Isobutane and Propylene-Butane. The levelized cost of heat (LCOH) could be improved by up to 12 %. To accelerate the transition to natural refrigerants, without compromises on efficiency and costs, further research and certification activities on non-fluorinated refrigerants based on Dimethyl Ether (R-E170), CO 2 (R-744) and Propylene (R-1270) are recommended. [ABSTRACT FROM AUTHOR]

Densified wood (DW) is a carbon-negative and energy-saving structural material with promising applications in high-rise timber buildings. However, its fire safety issues restrict its applications. In this paper, a bio-material, phytic acid, based flame retardant PPBNOH was prepared to improve the flame retardancy of DW. The structure characteristics, thermal stability, flammability, combustion behavior and mechanical performance of flame-retardant DW (PPBNOH/DW) were studied. Results show that the decomposition of PPBNOH catalyzes char formation and enhances thermal stability. Thus, PPBNOH/DW has a 57% reduced peak mass loss rate and a 27.9% increased char yield. Both the wood dense structure and PPBNOH catalyzation synergistically promote the formation of phosphorus-containing, crosslinked and aromatic char during wood combustion, which hinders heat/mass transfers and enhances flame retardancy. Thus, PPBNOH/DW has a 53.2% limiting oxygen index, a V-0 rating of UL-94 test. It presents delayed ignition time, reduced heat release characteristics and lower heat of combustion (5.37 MJ kg−1) in the cone calorimeter test. BNOH improves the smoke suppression performance of PPBNOH/DW with a 38.6% reduced total smoke production. The compatible and thermally insulating char also enhances the high-temperature heating resistance of PPBNOH/DW as it has the highest remaining mechanical strengths after heating. [ABSTRACT FROM AUTHOR]

In the pursuit of sustainable solutions, this study investigates the potential of bio‐based polyamide 5.6 (PA56) as a promising alternative to petroleum‐derived polyamide 6.6 (PA66). Novel composites of PA56 and PA66 were prepared with the incorporation of glass fibers and flame retardant additives by twin screw extruder. Subsequently, these composites were subjected to comprehensive characterization to determine their performance. The physical, mechanical, rheological, thermal, and flammability properties of PA56 composites were investigated and compared with those of PA66 composites with the same formulations. This article aims to unveil the remarkable potential of bio‐based PA56 composites in industrial applications. The results showed that bio‐based PA56 exhibits comparable, and in some cases superior, performance to PA66 while offering the added advantage of environmental sustainability. The findings suggest that bio‐based polyamide 5.6 can serve as a sustainable alternative to petroleum‐derived polyamide 6.6, contributing to a greener future in industrial applications. Highlights: Bio‐based PA56 exhibits comparable properties to petroleum‐derived PA66.Incorporation of glass fibers and flame retardants enhances the properties of PA56.Findings propose PA56 as a sustainable alternative to PA66 in various applications. [ABSTRACT FROM AUTHOR]

A large amount of toxic smoke and heat generated by the combustion of ethylene vinyl acetate copolymer (EVA) poses a significant threat to human fire escape evacuation. This work aims to use γ -ray to prepare e-MXene@Ag hybrid flame-retardant materials by the method of in-situ reduction, and EVA composites are prepared by melt blending to reduce the smoke and toxic gases produced during combustion significantly. Compared with pure EVA, the total heat release, total smoke release, and the production rate of CO and CO2 produced by the combustion of EVA composite with 1 wt% e-MXene@Ag1.0 decreased by 30.3%, 33.3%, 18.2%, and 20.1% respectively. The fire hazard reduction of EVA composite materials was due to the physical barrier, catalytic carbonization and adsorption of the e-MXene@Ag1.0 hybrid. In addition, e-MXene@Ag1.0 can also further increase the mechanical properties of EVA composites due to its own 'multi-contact point limit structure'. [ABSTRACT FROM AUTHOR]

The article presents the results of research on the impact of the use of an original, innovative method of deposition of Parylene C on the functional properties of fabrics with various potential applications (e.g., thermal and chemical protective clothing, packaging, covers and others). Verification of the effects of the method used was based on interdisciplinary research taking into account the impact of coating fabrics on changes in their structure (micro-CT), surface properties (contact angle), barrier properties (water and chemical liquid wetting), electrostatic properties (charge decay), biophysical properties describing heat and mass transfer (by the Alambeta system and thermal imaging) and flammable properties. Four fabrics made of synthetic organic fibres (meta-aramid, para-aramid) and natural inorganic fibres (basalt) were selected for testing. Given the complex structure of textile substrates, the results confirmed that the two assumed thicknesses of the Parylene C coating were consistent with the actual measurements. The findings indicated that the coatings significantly reduced water and acid absorption in the fabrics compared to unmodified ones. Thermal insulation property tests revealed that coated fabrics exhibited higher thermal conductivity than unmodified fabrics. Additionally, the presence of Parylene C on aramid fabrics resulted in a modest increase in their ignition resistance. [ABSTRACT FROM AUTHOR]

This paper presents a study of the flammability and thermal decomposition products of glass fiber-reinforced epoxy resin (GFRER) with the addition of cardanol-based phosphorus-containing benzoxazine monomer (CBz) and graphene and their combinations in different proportions (up to 20 wt.%). The addition of CBz alone or in combination with graphene resulted in an increase in the limiting oxygen index (LOI) and self-extinguishing in the UL-94 HB test. The flame-retardant samples had better tensile mechanical properties than the sample without additives. The differential mass-spectrometric thermal analysis (DMSTA) of the thermal decomposition products of GFRER without additives and with the addition of CBz and graphene was carried out. CBz addition promoted the thermal decomposition of high-molecular-weight products of epoxy resin decomposition in the condensed phase and at the same time decreased the time of release of low-molecular-weight thermal decomposition products into the gas phase. Graphene addition resulted in an increase in the relative intensities of high-molecular-mass peaks compared to GFRER without additives. [ABSTRACT FROM AUTHOR]

This research concentrates on the developmemnt of sustainable formulation of an environmentally friendly structural composite using an innovative approach, incorporating recycled materials. The primary aim of this research is to utilize the industrial wastes as re-circulated input to make structural materials without using new raw materials. Waste plastic, tanned waste leather, and waste glass fiber-reinforced plastic (GFRP) additives. The fabrication employs the hand layup method, and the composite undergoes comprehensive characterization following ASTM standards. According to the results, the composite designation "D" emerged as the most mechanically robust, with a tensile strength of 142 MPa, flexural strength of 195 MPa, compression strength of 156 MPa, interlaminar shear strength of 45 MPa, rail shear strength of 31 MPa, and an impact energy of 4.94 J. Concerning creep behavior, the "E" designation demonstrates minimal creep strain, recording values of 0.0057, 0.0076, and 0.0123 for 5000 s, 10000 s, and 15000 s time frame, respectively. This indicated the addition of 5 vol. % of GFRP additives improved the load-bearing effect. In terms of flammability, the "E" designation exhibits noteworthy flame resistance, with a low flame propagation speed of 10.83 mm/min. Additionally, the "E" designation demonstrates stable hydrophobic behavior, revealing a minimal water absorption percentage of 0.001. This study showcases the potential of the developed composite, emphasizing its mechanical strength, resistance to creep, flame retardancy, and hydrophobic properties, positioning it as an environmentally responsible and versatile material for diverse applications. [ABSTRACT FROM AUTHOR]

This research focuses on comparing the properties of molybdenum disulfide (MoS2) diffused coir fiber polyester composites (MCF‐PCs) with neat coir fiber polyester composites (NCF‐PCs) and exploring its applications in various industrial sectors such as automotive, construction and manufacturing, where mechanical strength and fire resistance are critical factors. The study aims to investigate the physical, mechanical, thermal degradation, fire performance, and vibration properties of these composites. Compression molding was used to develop composites with different coir fiber loadings (10%, 20%, and 30% by weight). MoS2 nanoparticles diffused on the fiber surface significantly improved mechanical characteristics, thermal stability, and fiber‐matrix compatibility. The findings indicate better crystallinity and physical properties in MCF‐PCs compared to NCF‐PCs. Morphological observations confirmed improved fiber‐matrix compatibility in MoS2‐diffused fiber composites with polyester. The MCF‐PC with 20% loading exhibited the highest tensile (28 ± 1.24 MPa), flexural (50 ± 0.50 MPa), and impact (15 ± 1.01 kJ/m2) strength. The flame retardancy of the composites was evaluated using a horizontal combustion test apparatus. In addition, MCF‐PCs exhibited better flame retardancy as evidenced by lower flame propagation velocity (9 ± 0.20 mm/min) and increased ignition time (13 ± 0.29 Sec). The MCF‐PC with 20% loading shows maximum natural frequencies of 77 ± 4.1 Hz. Highlights: This study investigated MoS2‐diffused coir fiber‐reinforced polyester composites.Fiber‐matrix adhesion can be improved with modified fiber‐reinforced composites.The MoS2 diffusion on fibers improved the physical and mechanical properties of polyester composites.The MoS2 diffusion on fibers enhanced the thermal and vibrational characteristics of polyester composites.MoS2‐diffused natural fiber composites offer considerable research potential. [ABSTRACT FROM AUTHOR]

Polylactic acid has good biodegradability and processability, but its flammability and serious droplet characteristics limit its development and application. Therefore, developing safer flame‐retardant PLA materials is crucial. This research develops a novel flame‐retardant polylactic acid (PLA) material blend, utilizing aluminum diethylphosphinate (AlPi), piperazine pyrophosphate (PAPP), and β‐cyclodextrin. Optimal synergy occurs at a 5:1 PAPP/β‐CD mass ratio with 4 wt.% AlPi. This combination significantly reduces the heat release peak from 294.89 to 144.21 kW·m−2 and generates non‐combustible residues. The sample forms a stable, uniform carbon layer during combustion due to hydrogen bond crosslinking and Lewis acid–base reactions. The activation energy (Eα) is raised from 264.99 to 281.08 kJ·mol−1 between 312 and 402°C. Thus, an AlPi‐PAPP‐β‐CD based P‐C‐N composite flame retardant is investigated, offering a promising research direction for developing fire‐safe polylactic acid materials. This research may yield valuable insights for diverse applications. [ABSTRACT FROM AUTHOR]

Currently, there are few reports of core–shell‐structured smoke suppressants that can provide a growth substrate and stabilize the char layer. In response to this problem, core–shell nanoparticles of halloysite nanotubes (HNTs) coated with copper itaconate complex were prepared by layer‐by‐layer assembly method. The electrostatic forces between HNTs and copper ions and the coordination between the itaconic acid and copper ions contributed this synthesis. The micromorphology, chemical composition, and structure of HNT@CuC5H4O4 were characterized, and its effects on the flame‐retardant and smoke‐inhibition properties, mechanical properties, and thermal stability of the soft polyvinyl chloride (PVC) were investigated. The results showed that the core–shell structure of HNT@CuC5H4O4 contributed to its homogeneous dispersion in PVC and the formation of interlocking mesh structure. Thus, the incorporation of HNT@CuC5H4O4 enhanced the strength and stiffness of soft PVC without sacrificing its ductility. Besides, copper ions on HNT@CuC5H4O4 could promote the cross‐linking carbonization of the PVC at high temperature. The formed char layer catalyzed by CuC5H4O4, together with its attached three‐dimensional network structure of HNT constituted a compact and continuous char layer with high thermal stability, which effectively prevented the release of combustible volatiles and toxic gases as well as heat transfer. [ABSTRACT FROM AUTHOR]

The present work is devoted to studying the effect of the synergistic action of Si-O-Si and NH-CO groups on the flammability and thermal properties of polylactide (PLA). For this purpose, using the Layer-by-Layer (LbL) technique, 5, 10, and 15 bilayers of chitosan (CS) and nanosilica (NS) were deposited onto the surface of PLA and PLA/NS composite (PLA/A200). More than a 20% reduction in flammability was achieved (sample (15BL) PLA/A200). Studying the effect of LbL-deposited bilayers on two types of surfaces, an identical relationship was found: the more layers adsorbed, the lower thermal stability, and vice versa the more layers, the higher flame retardancy. In turn, the lower the thermal stability, the faster the ability to form char, and the more solid residue, the lower the flammability and longer the burning time. This means that the application of CS-NS bilayers results in decomposition reactions in the condensed phase, which reduces the amount of flammable gases released. [ABSTRACT FROM AUTHOR]

The intumescent flame retardant (IFR) technique is an alternative to halogen-based flame retardants for reducing fire hazards in polymers. However, IFR has drawbacks like unsatisfactory flame-retardant efficiency and high loading requirements. In this study, MIL-125 (Ti-based metal–organic framework) is added to ABS/IFR composites to improve flame retardancy and reduce smoke emissions. Thermogravimetric analysis (TGA) results indicate that combining ammonium polyphosphate (APP) and expandable graphite (EG) increases charred residue and slows mass loss compared with the original ABS resin. The ABS/IFR/MIL-125 system stabilizes the char layer, serving as a protective shield against combustible gases during combustion. Additionally, MIL-125 enhances performance in microscale combustion calorimetry (MCC) flammability testing. In fire tests (UL-94, limiting oxygen index (LOI), and cone calorimeter), the ABS/IFR/MIL-125 system achieves a UL-94 V0 rating and the highest LOI value of 31.5% ± 0.1%. Peak heat lease rate (PHRR) values in the cone calorimeter are reduced by 72% with 20 wt.% of additives, and smoke production decreases by 53% compared with neat ABS. These results demonstrate the efficient synergistic effects of MIL-125 and IFR additives in improving the formation and stability of the intumescent char layer, thereby protecting ABS from intense burning. [ABSTRACT FROM AUTHOR]

Estimating live fuel moisture content (LFMC) is critical for assessing vegetation flammability and predicting potential fire behaviour, thus providing relevant information for wildfire prevention and management. Previous research has demonstrated that empirical modelling based on spectral data derived from remote sensing is useful for retrieving LFMC. However, these types of models are often very site-specific and generally considered difficult to extrapolate. In the present study, we analysed the performance of empirical models based on Sentinel-2 spectral data for estimating LFMC in fire-prone shrubland dominated by Cistus ladanifer. We used LFMC data collected in the field between June 2021 and September 2022 in 27 plots in the region of Andalusia (southern Spain). The specific objectives of the study included (i) to test previous existing models fitted for the same shrubland species in a different study area in the region of Madrid (central Spain); (ii) to calibrate empirical models with the field data from the region of Andalusia, comparing the model performance with that of existing models; and (iii) to test the capacity of the best empirical models to predict decreases in LFMC to critical threshold values in historical wildfire events. The results showed that the empirical models derived from Sentinel-2 data provided accurate LFMC monitoring, with a mean absolute error (MAE) of 15% in the estimation of LFMC variability throughout the year and with the MAE decreasing to 10% for the critical lower LFMC values (<100%). They also showed that previous models could be easily recalibrated for extrapolation to different geographical areas, yielding similar errors to the specific empirical models fitted in the study area in an independent validation. Finally, the results showed that decreases in LFMC in historical wildfire events were accurately predicted by the empirical models, with LFMC <80% in this fire-prone shrubland species. [ABSTRACT FROM AUTHOR]

In recent years, the frequency of wildfires worldwide has been gradually increasing, posing significant threats to global ecosystems and human society. Given that plants serve as the primary fuel in natural environments, accurately assessing the flammability of plants is crucial for wildfire management and fire ecology studies. Plant flammability is a multifaceted trait influenced by various physiological, physical, and chemical characteristics of plants. Currently, there is no universally accepted standard for quantifying plant flammability. By analyzing published research over the past few decades, this study found that 17.27% of studies assessed plant flammability by measuring flammability-related characteristics, such as moisture content, leaf size, bark thickness, oil content, and terpene content; a total of 34.55% of studies assessed plant flammability through burning experiments by measuring burning parameters, such as ignition time, duration of combustion, and flame spread rate. The remaining studies, approximately 50%, used a combination of burning experiments and flammability-related characteristic measurement to assess plant flammability. This study outlined the current status of plant flammability measurements, discussed the merits of each measurement method, and proposed suggestions for enhancing the assessment of plant flammability, with the aim of contributing to the standardization of plant flammability measurements. [ABSTRACT FROM AUTHOR]

The goal of this work was to develop acrylonitrile–butadiene (NBR) elastomer composites filled with hydroxyapatite (HAP) characterized by improved cure characteristics and resistance to burning. Silane, i.e., (3-aminopropyl)-triethoxysilane, ionic liquid, i.e., 1-decyl-3-methylimidazolium bromide and surfactant, i.e., cetyltrimethylammonium bromide, were used to improve the filler's dispersibility in the elastomer matrix and to reduce the time and temperature of vulcanization. The effects of HAP and dispersants on the cure characteristics, crosslink density and physico–chemical properties of NBR composites were explored. The additives used, especially the ionic liquid and surfactant, effectively improved the dispersion of HAP in the NBR matrix. The amount of HAP and the dispersant used strongly affected the cure characteristics and crosslink density of NBR. The optimal vulcanization time significantly increased with HAP content and was pronouncedly reduced when ionic liquid and surfactant were applied. In addition, ionic liquid and surfactant significantly lowered the onset vulcanization temperature and improved the crosslink density and hardness of the vulcanizates while impairing their elasticity. HAP and dispersants did not significantly affect the damping properties or chemical resistance of NBR vulcanizates. Above all, application of HAP considerably enhanced the resistance of vulcanizates to thermo-oxidative aging and reduced their flammability compared with the unfilled NBR. [ABSTRACT FROM AUTHOR]

Pultruded fiber reinforced polymer composites used in civil, power, and offshore/marine applications use fillers as resin extenders and for process efficiency. Although the primary use of fillers is in the form of an extender and processing aid, the appropriate selection of filler can result in enhancing mechanical performance characteristics, durability, and multifunctionality. This is of special interest in structural and high voltage applications where the previous use of specific fillers has been at levels that are too low to provide these enhancements. This study investigates the use of montmorillonite organoclay fillers of three different particle sizes as substitutes for conventional CaCO3 fillers with the intent of enhancing mechanical performance and hygrothermal durability. The study investigates moisture uptake and kinetics and reveals that uptake is well described by a two-stage process that incorporates both a diffusion dominated initial phase and a second slower phase representing relaxation and deterioration. The incorporation of the organoclay particles substantially decreases uptake levels in comparison to the use of CaCO3 fillers while also enhancing stage I, diffusion, dominated stability, with the use of the 1.5 mm organoclay fillers showing as much as a 41.5% reduction in peak uptake as compared to the CaCO3 fillers at the same 20% loading level (by weight of resin). The mechanical performance was characterized using tension, flexure, and short beam shear tests. The organoclay fillers showed a significant improvement in each, albeit with differences due to particle size. Overall, the best performance after exposure to four different temperatures of immersion in deionized water was shown by the 4.8 mm organoclay filler-based E-glass/vinylester composite system, which was the only one to have less than a 50% deterioration over all characteristics after immersion for a year in deionized water at the highest temperature investigated (70 °C). The fillers not only enhance resistance to uptake but also increase tortuosity in the path, thereby decreasing the overall effect of uptake. The observations demonstrate that the use of the exfoliated organoclay particles with intercalation, which have been previously used in very low amounts, and which are known to be beneficial in relation to enhanced thermal stability, flame retardancy, and decreased flammability, provide enhanced mechanical characteristics, decreased moisture uptake, and increased hygrothermal durability when used at particle loading levels comparable to those of conventional fillers, suggesting that these novel systems could be considered for critical structural applications. [ABSTRACT FROM AUTHOR]

The primary goal of the study was to develop a green composite material for safe environmental production of human prosthetics using sea urchin (Echinoidea) spike chitin macromolecules, basalt-encapsulated bamboo fiber and epoxy. The chitin biopolymer was extracted from marine waste sea urchin spikes as first time and characterized for its physicochemical properties. The composites' mechanical properties, wear resistance, thermal conductivity, flame retardancy and water absorption were assessed for their suitability in prosthetic applications. The fabrication process adheres to the hand-layup method and follows American society for testing and materials (ASTM) procedure for characterization. Results revealed that the composite EBC3 exhibits improved tensile strength of 165 MPa, flexural strength of 224 MPa, compression strength of 198 MPa, ILSS (interlaminar shear strength) of 31.9 MPa, and impact energy of 5.8 J. Furthermore, composite EBC4 demonstrated superior wear resistance under varying loads and sliding distances. Additionally, EBC4 exhibits a highest thermal conductivity of 0.72 W/mk and a lower flame propagation speed of 5.72 mm/min. Moreover, a low water absorption, indicated by a 101° contact angle in EBC4, guarantees long-term stability of composites. [ABSTRACT FROM AUTHOR]

Plastic is a revolutionary material. However, pollution caused by plastic damages the environment, human health, and economy of different countries. It is important to find the new methods for recycling and reusing plastic materials. In this present study, plastic waste coming from high‐density polyethylene (HDPE) cups (called HDPEr in the following) are used together with virgin cork for production of composite materials. Different fractions of virgin cork with HDPEr are tested and allow to obtain successfully composite materials. The properties of HDPEr and composite are compared. The morphology of elaborated composite is studied by scanning electron microscope (SEM). The thermal properties are investigated by thermogravimetric analysis (TGA) analysis; the flammability study is performed using a cone calorimeter. Moreover, the mechanical properties of the samples stored under different conditions are studied by tensile strength experiments. The results show that the cork content has an effect on the mechanical and thermal properties. The feasibility of the composites based on cork and HDPEr wastes opens the way of reusing of these wastes. The formulation of HDPEr composites must be optimized by adding a flame retardant and a coupling agent. [ABSTRACT FROM AUTHOR]

In this work, studies were performed on oxidative stability by determining the transmittance spectra, the components and trichomatic coordinates, and the color differences for grape seed oils (GSO) subjected to a forced oxidation treatment at temperatures of 100 °C and 120 °C, for 4, 8 and 10 h. For this purpose, a constant airflow of 30 L/min was used. GSO was also subjected to flammability tests on a heated cylindrical surface to determine the lowest temperature at which this oil ignites, correlated with the highest temperature at which the oil does not ignite. According to the results, these temperatures are 475 °C and 470 °C, respectively. At these temperatures, the tested oils were darker in color than the reference oil, with the L* parameter having lower values (91.53 and 89.56, respectively). In addition, the correlation coefficients between the evaluated parameters were significant (p ≤ 0.05). [ABSTRACT FROM AUTHOR]

In this study, rigid polyurethane foams (RPUF) were successfully modified using 30 wt.% aluminium hydroxides (ATH), 1.0 pphp silicone surfactant, and different concentrations of graphene, using a one-shot one-step foaming method. This study aims to improve the compressive strength, flame retardancy, and thermal properties of RPUF by creating a synergistic effect between ATH and graphene in fire-retardant RPUF hybrid composites. The effects of a fixed amount of ATH and silicone surfactant and various loadings of graphene on RPUF were investigated. The results show that 0.5 wt.% graphene loading confers the best compression performance on the hybrid composite. Their compressive strength value of 12.58 KPa was higher than virgin RPUF (4.07 KPa) and RPUF/ATH (9.89 KPa). FTIR confirmed the functional groups in the virgin RPUF but could not identify new functional groups in most modified composites. The smallest amount of graphene addition (0.5 wt.%) produced a more stable hybrid composite structure. At 3.0 wt.% graphene addition, the maximum decomposition temperature of the RPUF/ATH hybrid composite was recorded (539oC), which was enhanced by 50% compared to virgin RPUF (296oC), and the highest char residue of 17.46% was observed. The incorporation of graphene enhanced the thermal firmness of the hybrid composite. The study also revealed an enhancement in the fire resistance of the hybrid composite. The LOI and UL-94 results showed that incorporating 3.0 wt.% enables increased LOI value and V-0 classification compared to virgin samples. This hybrid composite can be used in high-performance building insulation applications. [ABSTRACT FROM AUTHOR]

The management of end‐of‐life tyres faces challenges due to insufficient recycling infrastructure and technologies, as well as limited markets for the materials recovered from them. To mitigate this, waste rubber can be upcycled and used as filler material for polymer matrix composites. Before rubber‐reinforced composites can be certified for fire‐prone applications, their thermal and flammability properties must be understood. This research investigates the effect of rubber fillers on the thermal stability, flammability and flame spread characteristics of epoxy matrix syntactic foam. Thermogravimetric analysis, Fourier Transform Infrared spectrometry (FTIR), scanning electron microscopy and attenuated total reflection FTIR spectrometry were employed to elucidate changes in thermal degradation behaviours. The influence of rubber fillers on the flammability of syntactic foam was assessed using the cone calorimeter. The fire reaction properties of rubber‐reinforced foam were affected by the intensity of the incident heat flux. Regardless of the incident heat flux, an increase in rubber content led to higher total heat release. At the lower heat flux of 35 kW/m2, the fire growth rate increased with rubber content, but at the higher heat flux of 50 kW/m2, the fire growth rate decreased as the rubber content increased. Importantly, all rubber‐reinforced syntactic foams achieved a UL94 HB ranking and exhibited reduced flame spread rates compared to the unmodified foam. This study demonstrated the potential for upcycling waste rubber into sustainable engineering products and expanded the knowledge base on fire reaction properties and flame spread characteristics of such hybrid composite materials. [ABSTRACT FROM AUTHOR]

Green manufacturing and reducing our cultural dependency on petrochemicals have been the global interest currently, especially in the polyurethane industry segments. We report the fabrication of rigid polyurethane foams (RPUFs) and their flame-retardant property from hemp seed oil as an alternative to petrochemical-based polyols. The cold-pressed hemp-seed oil (HSO) was first oxidized to epoxidized triglyceride oils with acetic acid and hydrogen peroxide, followed by a ring-opening reaction with methanol to fabricate hemp bio-polyols. The formation of polyols was characterized using FT-IR, hydroxyl, and acid values. The bio-polyol was used in different proportions with commercial polyols and other foaming ingredients to produce rigid polyurethane foams via a one-step process. Dimethyl methylphosphonate (DMMP), triethyl phosphate (TEP), and expandable graphite (EG) were added during the foam preparation to improve flame retardancy. The produced foams were analyzed for their apparent density, mechanical properties, thermal degradation behavior, closed cell content, flammability, and cellular morphology. The effect of different flame retardants had a significant influence on the cellular structures, closed-cell content, density, and compressive strength of the polyurethane. A significant improvement in anti-flaming properties was observed as the neat HSO-based foam showed a burning time of 110 s and a weight loss of 82%, whereas 10 wt% of TEP displayed a reduced burning time and weight loss of 19 s and 5%, respectively. DMMP and EG-based RPUFs exhibited similar flame retardancy and mechanical properties relative to neat HSO-based foam. The results demonstrated in this work proposed a potential combination of bio-polyols and commercial polyols as a strategy to fabricate flame-retardant polyurethane foam for high-performance applications. [ABSTRACT FROM AUTHOR]

Climate change, shrinking resources, and rising raw material costs have pushed the industry to create more sustainable, and lightweight materials. Natural fiber composites are materials of interest for replacing conventional materials such as steel. Sunflower husks (SH), among many other natural fibers, are readily accessible as agricultural waste and have advantageous properties. In this study, sunflower husks were mixed with polypropylene (PP) matrix using a twin‐screw extruder, and then tests specimens for experimental characterizations were manufactured through injection molding. The tensile tests revealed that the inclusion of SH into PP decreased the load‐bearing capacity of the composites by around 20% and increased their impact resistance by over 200%, while reducing the ductility by about eight times. Moreover, magnesium hydroxide (Mg(OH)2) was incorporated into the composites as a flame retardant, and it has improved the stiffness and impact resistance of the composites. Besides, incorporation of SH and Mg(OH)2 elevated significantly the glass transition temperature of the composites. The use of Mg(OH)2 delayed 60% the flame retention of the composites observed from UL‐94 HB flammability testing. In summary, they could be suitable for components such as spare wheel wells, seat backs, trunk floor, the acoustic panel behind the door, and airbag housing. [ABSTRACT FROM AUTHOR]

In order to obtain an efficient flame retardant and smoke suppressor without sacrificing mechanical properties of epoxy resin (EP). A cyano group‐containing 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) derivative (CP‐DOPO) was proposed and synthesized through one‐step Atherton–Todd reaction between DOPO and 4‐cyanophenol. The comprehensive performance analysis of CP‐DOPO‐based EP composite was conducted by measuring the flame retardancy, smoke suppression, and mechanical properties. The flame‐retardant test findings shows that the EP/4CP‐DOPO sample achieves UL‐94 V‐0 rating with 4 wt% low addition of CP‐DOPO. Moreover, EP/6CP‐DOPO sample presents a LOI of 36.5%, a 28.1% reduction in the peak heat release rate, and a 42.1% substantial decrease in total smoke production, demonstrating its desirable flame retardancy and smoke suppression properties. Significantly, different from the traditionally additive flame retardants, the mechanical properties of EP matrix will not be affected by the incorporation of CP‐DOPO but a 17.7% increasement of flexural properties compared to EP. This research not only provides an ingenious strategy for designing and preparing high‐effective flame retardant but also enhances the comprehensive performance of EP resins in practical applications. [ABSTRACT FROM AUTHOR]

This article discusses the effect of UV-C radiation on two types of cured polymer resins, epoxy and polyester, intended for use in disinfection chambers. The exposure of the samples to UV-C rays lasted 168 h. Our evaluation covered two aspects: the effect of UV-C rays on the flammability and flame retardancy of the resins, and the effect of UV-C rays on the adhesion of the resins to the steel substrate. It was found that the applied halogen and halogen-free organophosphate agents can be used for the tested resins under UV-C conditions (e.g. disinfection chambers), and no negative impact of UV-C radiation on the performance of these flame retardants was found. The use of the tested types of resins in the form of thin coatings on a steel substrate is feasible in disinfection chambers under UV-C radiation conditions, as the obtained results indicate that the radiation did not affect the adhesion of the coating. The visible effect of UV-C radiation on both the tested resins was discoloration, giving yellow and brown colors. Our results suggest that further studies, probably involving longer UV-C exposure, would be advisable. [ABSTRACT FROM AUTHOR]

Innovative and cost-effective paper sheets with superior fire safety and reinforcement properties have been developed. The paper sheets were fabricated via valorization of agricultural waste to paper and then coated with nanoparticles. Paper attained from rice straw was used to create the sheets. Afterward, bentonite sheets were incorporated in these sheets, and finally, PbO nanoparticles were coated on prepared paper nanocomposites. The mass ratio of bentonite sheets was altered. The flammability and mechanical properties of the developed paper nanocomposites were studied. The flame retardancy of developed paper nanocomposite was significantly improved achieving LOI value of 24% compared to 20% for bentonite and PbO nanoparticle-free sample. Additionally, the tensile strength was improved recording 44% enhancement compared to unmodified sample. Furthermore, the flame retardancy mechanism was proposed and studied. [ABSTRACT FROM AUTHOR]

The combustion characteristics of n-decane+air mixtures are experimentally investigated through laminar burning velocity measurements at 1 atm pressure and higher initial temperatures using an externally heated diverging channel (EHDC) method. Up to 610 K mixture temperature over an equivalence ratio range of 0.7–1.4, laminar burning velocities are reported with an accuracy of ± 5%. The current measurements exhibit a good match with existing experimental measurements, and agree closely with the predictions of Zhao, LLNL and PoliMi mechanisms at different mixture temperatures. The present measurements show an excellent match of temperature exponent (α) variation with equivalence ratio (ϕ) with the predictions of distinct kinetic models as well as experimental measurements. This study reveals that a substantial scatter exists among the predictions of different kinetic models. A variation of 20–30 cm/s in the burning velocity is observed at 610 K mixture temperature. Reaction R16 (H + HO2 = H2 + O2), which inherently reduces the burning velocity becomes insignificant at an elevated mixture temperature of 610 K, and the reaction R15 (H + HO2 = 2OH) plays a dominant role in accelerating the flame propagation. From reaction pathway diagrams, it is clear that a higher burning velocity at 610 K is associated with the increased reaction rate. The elemental-flux value associated with the formation of C2H3 from C2H4 at 610 K mixture temperature is ≅34% higher in comparison to the 470 K mixture temperature. [ABSTRACT FROM AUTHOR]

Flame retardants are commonly used to reduce fire risk in various products and environments, including textiles. While many of these additives contain harmful substances, efforts are underway to reduce their usage. Current research aims to minimize flame-retardant quantities and enhance durability against external factors. This involves utilizing anchor peptides or material-binding peptides (MBPs), which are versatile molecules that bind strongly to surfaces like textiles. MBPs can be equipped with functional molecules, e.g., flame-retardant additives, by chemical or enzymatic bioconjugation. In this research, biohybrid flame retardants and an adapted finishing process are developed. Specifically, biobased adhesion promoters, the so-called MBPs, are used to finish textiles with flame-retardant additives. To date, there is no finishing process for treating textiles with MBPs and so a laboratory-scale finishing process based on foulard was developed. Necessary parameters, such as the take-off speed or the contact pressure of the squeezing rollers, are determined experimentally. In order to develop an adapted finishing process, various trials are designed and carried out. Part of the trials is the testing and comparison of different textiles (e.g., glass woven fabrics and aramid woven fabrics) under different conditions (e.g., different ratios of MBPs and flame retardants). The finished textiles are then analysed and validated regarding their flammability and the amount of adhered flame retardants. [ABSTRACT FROM AUTHOR]

The development of polyurethane composites with significant flame retardancy and corrosion resistance for widening its practical application is a great importance. In this study, supramolecular wrapped α‐ZrP (MCP@ZrP) was prepared via self‐assembly of melamine, cobalt ions (Co2+) and phytic acid (PA) on the surfaces of α‐zirconium phosphate (α‐ZrP). It was found that both compatibility and dispersion of α‐ZrP sheets in thermoplastic polyurethane (TPU) matrices were improved with the incorporation of organic supramolecular components in TPU/MCP@ZrP nanocomposites. Moreover, their fire‐retardant characteristic was significantly enhanced, along with effective suppression of smoke and toxic gas emission. By adding 5 wt% MCP@ZrP, peak heat release rate, total heat release, total smoke production, and total CO production of such nanocomposites were reduced by 35.66%, 18.01%, 15.52%, and 41.42%, respectively. The generation of a continuous and dense char layer benefited from well‐dispersed MCP@ZrP nanohybrids, which resulted in tortuous effect to impede heat diffusion and prevent the evaporation of volatile gasses. By means of the barrier effect of ZrP, TPU/MCP@ZrP composite films also showed improved anticorrosion performance. Effective interfacial adhesion, achieved by combining MCP supermolecules and α‐ZrP sheets, offers a viable approach to improve protective properties of TPU nanocomposites. Highlights: Supramolecular‐wrapped α‐ZrP was prepared via self‐assembly strategy.MCP@ZrP showed good dispersion and interface adhesion within TPU matrices.MCP@ZrP enhanced the flame retardancy and mechanical performance of TPU.MCP@ZrP preventing smoke and toxic gas evaporation. [ABSTRACT FROM AUTHOR]

In previous studies, the effect of cell structures of polypropylene (PP) foam materials on flammability behavior had been largely overlooked. In this work, ammonium polyphosphate and pentaerythritol were used as intumescent flame retardants (IFR) for PP, and then the PP‐IFR flame retardant foams were prepared by using injection foaming technology with two different weight reduction methods (same mold volume before foaming and after foaming). The results showed that the average cell size of all the PP‐IFR flame retardant foams in the 10% to 30% weight reduction was less than 100 μm. The PP‐IFR flame retardant foams with an average cell diameter of 26.22 μm and cell density of 7.88 × 106 cells/cm3 had the best limiting oxygen index (LOI) of 27.9%. In addition, the PP‐IFR flame retardant foams with better foaming quality had a higher LOI and a denser foam carbon layer whatever the weight reduction methods, resulting in better flame retardant properties. The escape of gases from the foamed and un‐foamed areas not only reduced the concentration of flammable gases but also led to the collapse and rupture of the foam carbon layer during the combustion process. Hence, it provides guidance for preparing PP foam materials with excellent flame retardancy. [ABSTRACT FROM AUTHOR]

This paper aimed to provide technical support for fuel management by exploring different strengths of fuel removal on the physical and chemical properties and flammability of Betula platyphylla forests in the wildland–urban interface. After investigating the northeastern region during the forest fire prevention period in May 2023, a typical WUI area was selected, and three different treatment strengths, combined with a control, were set up to carry out indoor and outdoor experiments for 27 weeks. Compared with previous studies, this study mainly investigated and analyzed the dynamic changes in the physical and chemical properties and fuel flammability after different intensities of treatments on a time scale. By processing and analyzing the data, the following results were obtained. Significant differences existed in the fuel loading of different time-lag fuels over time (p < 0.05). The ash and ignition point of 1 h time-lag fuel after different treatment intensities generally increased first and then decreased, and the higher heat value and ash-free calorific value generally decreased first and then increased. The physical and chemical properties of 10 h and 100 h time-lag fuel fluctuated with time, but the overall change was insignificant. The indicator that had the greatest impact on the combustion comprehensive score for different time-lag fuels was fuel loading. The change in the flammability of dead surface fuel with time varied significantly, and different treatment intensities effectively reduced the fuel's flammability. The reduction effects, presented in descending order, were as follows: medium-strength treatment > low-strength treatment > high-strength treatment > control check. In conclusion, different treatment intensities have significant effects on the flammability of the fuel, and the medium-strength treatment has the best effect. Considering the ecological and economic benefits, adopting the medium-strength treatment for the WUI to regulate the fuel is recommended. [ABSTRACT FROM AUTHOR]

A model of opposed flame spread along thin electric wires is developed to estimate the variation of flame spread rate ( $ {V_\textrm{f}} $ V f ) with oxygen concentrations and oxidiser flow velocity. The length of pyrolysis zone ( $ {L_{\textrm{py}}} $ L py ) and $ {V_\textrm{f}} $ V f are treated as eigenvalues of the problem, and one-dimensional energy balance equations for the wire core and insulation are formulated to derive their solutions. To obtain a set of steady solutions for $ {L_{\textrm{py}}} $ L py and $ {V_\textrm{f}} $ V f , the macroscopic energy balance equation for the entire system is calculated from the one-dimensional energy balance equations with appropriate boundary conditions. Since the equations are nonlinear function of $ {L_{\textrm{py}}} $ L py and $ {V_\textrm{f}} $ V f , multiple solutions appear. The physical meaning of each solution is evaluated based on the deviation of energy from the equilibrium. Comparison of the temperature distribution along the wire with experimental data confirms that the model reproduces well the actual flame spread process. The variation of $ {V_\textrm{f}} $ V f with oxygen concentration shows a C-shaped curve. The upper branch is the stable solution, and the lower branch is the unstable solution and the merging point of two branches correspond to the limit condition for flame spread. Therefore, the model can be used to estimate the limiting oxygen concentration based on the existence of a solution for $ {V_\textrm{f}} $ V f . Furthermore, the variation of $ {V_\textrm{f}} $ V f with oxidiser flow velocity shows O-shaped curve, and it is confirmed that radiative extinction under low flow velocity and blow-off under high flow velocity can also be estimated with the model. Mapping of variations of radiative extinction and blow-off extinction with oxygen concentration reveals the U-shaped flammability diagram. The predicted flame spread limits are in good agreement with the limiting oxygen concentrations measured in both microgravity and normal gravity, demonstrating the validity of using this model to predict flammability characteristics of electric wires under various oxidiser flow velocity. [ABSTRACT FROM AUTHOR]

Potassium‐ion batteries (PIBs) with conventional organic‐based flammable electrolytes suffer from serious safety issues with a high risk of ignition and burning especially under harsh conditions, which significantly limits their widespread applications. Flame‐retardant electrolytes (FREs) are considered as one of the most effective strategies to address these safety issues. Therefore, it's much necessary to summarize the challenges, recent progress, and design principles of flame‐retardant nonaqueous electrolytes for PIBs to guide their development and future applications. In this review, an in‐depth introduction and explanation of the origins of electrolyte flammability are first presented. Particularly, the state‐of‐the‐art design principles of FREs for PIBs are extensively summarized and emphasized, including the electrolyte flame‐retardant solvents/additives, highly concentrated electrolytes (HCEs), localized high‐concentration electrolytes (LHCEs), ionic liquids‐based electrolytes and solid‐state electrolytes. Moreover, the advantages and drawbacks of each approach are systematically presented and discussed, following by proposed perspectives to guide the rational development of next‐generation high‐safety PIBs for practical applications. [ABSTRACT FROM AUTHOR]

In this article, the optimal conditions for synthesizing a new flame retardant based on pentaerythritol, phosphoric acid, and magnesium hydroxide are studied. In this case, the molar ratio of the initial substances was 3.64:1, and the synthesis duration was four hours. After the completion of this process, different (1, 3, and 5%) solutions of magnesium hydroxide were added at a temperature of 90 ºC for 3 hours. The yield of this reaction was 85%. Applying this obtained flame retardant to textile materials increases the fire resistance of textile materials. The composition of synthesized antiperine and antiperine applied textile fabrics was studied by IR spectrum, and the thermal decomposition of antiperine applied fabric was investigated by TGA and DTA analysis, and 100 μm sections of flame retardant treated fabrics were measured by scanning electron microscope. The fire resistance and physical mechanical properties of these materials were studied based on the requirements of GOST 50810-95. The oxygen index of the fabric treated with synthesized flame retardant was 35.6%. [ABSTRACT FROM AUTHOR]

After the period of halogenated compounds, the period of nano-structured systems, and that of phosphorus (and nitrogen)-based additives (still in progress), following the increasingly demanding circular economy concept, about ten years ago the textile flame retardant world started experiencing the design and exploitation of bio-sourced products. Indeed, since the demonstration of the potential of such bio(macro)molecules as whey proteins, milk proteins (i.e., caseins), and nucleic acids as effective flame retardants, both natural and synthetic fibers and fabrics can take advantage of the availability of several low-environmental impact/“green” compounds, often recovered from wastes or by-products, which contain all the elements that typically compose standard flame-retardant recipes. The so-treated textiles often exhibit flame-retardant features that are similar to those provided by conventional fireproof treatments. Further, the possibility of using the same deposition techniques already available in the textile industry makes these products very appealing, considering that the application methods usually do not require hazardous or toxic chemicals. This review aims to present an overview of the development of bio-sourced flame retardants, focusing attention on the latest research outcomes, and finally discussing some current challenging issues related to their efficient application, paving the way toward further future implementations. [ABSTRACT FROM AUTHOR]

The growing requirements regarding the safety of using polymers and their composites are related to the emergence of more effective, sustainable, and hazardous-limited fire retardants (FRs). Significant amounts of FRs are usually required to effectively affect a polymer's burning behavior, while the knowledge of their recycling potential is still insufficient. At the same time, concerns are related not only to the reduced effectiveness of flame retardancy but also, above all, to the potential deterioration of mechanical properties caused by the degradation of temperature-affected additives under processing conditions. This study describes the impact of the four-time reprocessing of bio-based polyamide 11 (PA11) modified with an intumescent flame-retardant (IFR) system composed of ammonium polyphosphate (APP), melamine cyanurate (MC), and pentaerythritol (PER) and its composites containing additional short basalt fibers (BFs). Composites manufactured via twin-screw extrusion were subjected to four reprocessing cycles using injection molding. A comprehensive analysis of their structural, mechanical, and fire behavior changes in each cycle was conducted. The obtained results confirmed the safety of using the proposed fire-retarded polyamide and its composites while reprocessing under the recommended process parameters without the risk of significant changes in the structure. The partial increase in flammability of reprocessed PA-based materials caused mainly by polymer degradation has been described. [ABSTRACT FROM AUTHOR]

Anthropogenic climate change is altering the state of worldwide fire regimes, including by increasing the number of days per year when vegetation is dry enough to burn. Indices representing the percent moisture content of dead fine fuels as derived from meteorological data have been used to assess geographic patterns and temporal trends in vegetation flammability. To date, this approach has assumed a single flammability threshold, typically between 8 and 12%, controlling fire potential regardless of the vegetation type or climate domain. Here we use remotely sensed burnt area products and a common fire weather index calculated from global meteorological reanalysis data to identify and describe geographic variation in fuel moisture as a flammability threshold. This geospatial analysis identified a wide range of flammability thresholds associated with fire activity across 772 ecoregions, often well above or below the commonly used range of values. Many boreal and temperate forests, for example, can ignite and sustain wildfires with higher estimated fuel moisture than previously identified; Mediterranean forests, in contrast, tend to sustain fires with consistently low estimated fuel moisture. Statistical modelling showed that flammability thresholds derived from burnt area are primarily driven by climatological variables, particularly precipitation and temperature. Our analysis also identified complex associations between vegetation structure, fuel types, and climatic conditions highlighting the complexity in vegetation–climate–fire relationships globally. Our study provides a critical, necessary step in understanding and describing global pyrogeography and tracking changes in spatial and temporal fire activity. [ABSTRACT FROM AUTHOR]

Reestablishing appropriate tree species is an important step in converting off‐site monocultures into woodlands. Species conversion is often necessary, as off‐site exotic species rarely function like woodland species. However, when off‐site tree species are native, and functionally redundant to woodland species, conversion may be unnecessary. To explore this possibility in the southeastern United States, we reviewed the literature on trait differences among the primary southern pines and qualitatively assessed the effect of their identity at the species and stand‐levels. In this region, woodland restoration focuses on removing loblolly (Pinus taeda) and slash pine (P. elliottii) to reestablish longleaf (P. palustris) or shortleaf pine (P. echinata). Our review found minimal variation among species in understory flammability, fire resistance at maturity, and Red‐cockaded Woodpecker (Leuconotopicus borealis) habitat at the stand‐level. Longleaf and shortleaf pine were generally more resistant to abiotic and pest disturbance at the tree‐level; however, stand‐level differences in wind, drought, and boring insect resistance among southern pines growing in open forests were considered minimal. Retaining loblolly and slash pine will improve stand‐level productivity in the short term, but creates regeneration problems due to low juvenile fire resistance and resilience. Ice resistance and long‐term carbon sequestration will also likely be reduced by retaining loblolly and slash pine. Collectively, these results suggest that southern pine species are generally interchangeable at the stand‐level in woodlands; although woodlands featuring loblolly and slash pine may be less stable in the face of disturbance than those dominated by shortleaf and longleaf pine. [ABSTRACT FROM AUTHOR]

Cotton fabrics are widely used in clothing, packaging, and medical applications because of their excellent comfort, breathability, and low cost. However, it poses a threat to use them in specific scenarios, where flame retardance and antibacterial activity are highly desired. In this work, we propose the functionalization route by using layer-by-layer assembly of polyethyleneimine (PEI), phytic acid (PA), iron (Fe3+), and aluminum (Al3+) ions on cotton fabrics. Interestingly, the modified cotton fabric showed good biocompatibility in the cell viability (> 70%) and hemolysis (< 3%) test. In addition to biocompatibility, the antibacterial performance was largely improved for the modified cotton fabric with the antibacterial efficacy of > 99% due to the presence of Fe3+ and Al3+ that work in a synergistic manner. In term of flame retardance, the modified cotton fabric exhibited self-extinguishing characteristics in vertical burning experiments, with the Limiting Oxygen Index (LOI) of 35.0%. The excellent flame-retardant property was further supported by the results in cone calorimetry test, thermal gravimetric analysis, and TG-IR test, elucidating the underlying mechanism that rapid formation of dense char layer by the thermal decomposition of PEI/PA/FeAl system is effective to prevent the spreading of flame and thus protect the cotton from burning. This work provides a strategy to achieve multifunctionality on cotton fabrics, which may inspire the design on other types of fabrics or materials for extended applications. [ABSTRACT FROM AUTHOR]

The South Korean government has implemented an acceptance system to promote the high-quality recycling of waste. Industrial waste generators must provide "hazardous characteristics data" to recycling operators. Nonetheless, ~80% of industrial safety accidents in South Korea occur during recycling, most involving fire or explosions. Moreover, a gap in safety management exists during 'Circular Resource' acceptance if the target substance is not regarded as waste. In this study collected data on hazardous waste characteristics. From 62 waste generators, 72 waste samples were collected, accounting for most of the resources accepted for recycling, including waste synthetic polymers, slag, dust, waste sand, and waste foundry sand. Then, the hazardous characteristics, as stated in the Ministry of Environment notifications, were assessed. Leaching toxicity was detected in one slag sample and six dust samples. The Cd, Cu, As, Pb, Zn, Ni, Hg, F, and CN levels dissatisfied the Soil Contamination Warning Standard in 31 samples. Explosivity was not detected in any sample, whereas flammability was detected in one waste synthetic polymer sample. The results revealed 15 cases of potential flammability. Flammability is legally defined as below the criteria if the combustion speed criterion is not met. However, in the case of flame ignition, which could cause large fires and safety accidents, the relevant notification should be revised. In this study, we aimed to improve the gap between the hazardous waste management systems and industrial fields through actual measurements of hazardous characteristics. By doing so, we seek to contribute to the prevention of environmental and safety accidents. By continuously accumulating data and utilizing actual measurements, we aim to revise and enhance relevant regulations, ultimately improving the hazardous characteristics of waste management systems. [ABSTRACT FROM AUTHOR]

Background: Live fuel comprises a significant portion of the fuel consumed in forest and scrub crown fires. However, its flammability remains poorly understood. Although live fuel differs from dead fuel in moisture content, chemical composition, cellular structure and physiological characteristics, its higher moisture content masks the effect of other characteristics on its flammability. Aims: The aim of the study was to delineate and assess the effects of live/dead condition, moisture content and particle size on flammability of gorse (Ulex europaeus L.). Methods: Live and dead gorse material of three size classes (0–3, 3–6, and 6–10 mm in diameter) at six moisture contents (0, 10, 25, 50, 75 and 100%) was tested in a cone calorimeter to evaluate its flammability using new sample preparation and moisture conditioning techniques. Key results: On average, live fuel ignited 21% slower, reached 11% higher peak heat release rate, and had a 12% shorter burn duration than dead fuel of the same moisture content. These differences were most pronounced in coarser material. Conclusions: For gorse, fine dead fuels increase the likelihood of ignition, fine live fuels contribute to high burning intensities, and coarser live and dead fuels prolong combustion. Implications: These findings highlight the need to account for flammability differences between live and dead fuels in fire behaviour models beyond those driven by variations in moisture content. This study compares the flammability of live and dead vegetation at a range of moisture contents and particle sizes. Live fuel took longer to ignite but burned faster and more intensely than dead fuel of the same moisture content, emphasising the importance of live fuel flammability in fire prediction models. [ABSTRACT FROM AUTHOR]

Natural fibre-reinforced polymer composite (NFRPC) has been introduced as one of the solutions to overcome the ecological and environmental problems accompanying the widespread usage of polymeric materials in every facet of life. However, the organic nature of both natural fibres (NFs) and polymers increases their flammability behaviour, and this, in turn, limits their application. In this regard, this work concentrates on studying the effect of adding flame retardants (FR) to jute-reinforced epoxy composites (JRECs), either by treating the jute fabric with diammonium phosphate (DAP) or adding DAP powder to the epoxy resin matrix on the flame retardancy performance as well as the mechanical properties. The results showed that the effect of the incorporation method of DAP either to jute fabric or to resin matrix has a significant difference on the flammability test results at low concentrations; however, at higher concentrations, the flame retardancy performance is not affected by the technique of adding FR to the composite system. On the other hand, the mechanical properties are significantly affected by the method of incorporating FR to JRECs at all concentrations. Moreover, the results obtained from JRECs with FR systems were evaluated and compared with the literature by constructing selection charts that relate the flame retardancy level to mechanical properties.

Highlights Globally, with the advancement of industrialization and globalization, the automotive sector has drastically increased for transportation and commercial purposes. Hence, to maximize efficiency and minimize the weight of automobiles, the automotive and aerospace industries have welcomed synthetic fibre‐reinforced composites, vastly replacing conventional metals. Despite the superior performance, the usage of synthetic fibre composites has led to the massive dumping of automotive waste in landfills, making the land unfit for future purposes. Therefore, natural fibre‐reinforced composites (NFRCs) quickly replace synthetic fibres with their unique features, such as being lightweight, biodegradable, and non‐toxic, en routing a new path towards a sustainable environment. Though NFRCs are finding new applications in various industries, researchers are trying to enhance their thermal, electrical, and mechanical properties to make them synergic composites. However, with the presence of cellulose, lignin, and wax, natural fibres become highly responsive toward flammability, limiting their use in various emerging applications. As the subject of the flammability of NFRCs has a limited amount of literature, the current review article aims to address the current flammability studies and strategies adopted to improve the flame‐retardant characteristics of NFRCs exclusively. Also, this review covers the factors and influence of different types of flame‐retardant fillers adopted to improve the flame retreatant characteristic of NFRCs and their mechanism. Additionally, this review article summarises various official and laboratory flame‐testing techniques such as radial panel test (RPT), cone calorimetry, and limited oxygen index (LOI) adopted to characterize the flammable properties of NFRCs. Natural fiber biocomposites are becoming a potential candidate for structural and interior applications in the automotive and aircraft industries. Flammability becomes a major alarm as it concerns with the safety of passengers. The flammability behavior of natural fiber composites is extensively discussed. Mechanisms, factors, and selection of flame‐retardant materials are reviewed to improve the flame‐retardant characteristics. The influence of surface treatments, fiber content, and flame‐retardant nanofillers are also elaborately discussed. Advanced flame testing techniques were conversed with pictorial representation. [ABSTRACT FROM AUTHOR]