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Your search keyword '"Fadaei, Farzaneh T."' showing total 8 results
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8. Large heterometallic coordination cages with gyrobifastigium-like geometry

Author

Bassam Alameddine, Giacomo Cecot, Euro Solari, Stéphanie Prior, Rosario Scopelliti, Kay Severin, Silvano Geremia, Rita De Zorzi, Farzaneh T. Fadaei, Cecot, Giacomo, Alameddine, Bassam, Prior, Stéphanie, DE ZORZI, Rita, Geremia, Silvano, Scopelliti, Rosario, Fadaei, Farzaneh T., Solari, Euro, and Severin, Kay

Subjects
Steric effects, Materials Chemistry2506 Metals and Alloys, Clathrochelate, Surfaces, Coatings and Film, Ceramics and Composite, Geometry, 010402 general chemistry, 01 natural sciences, Catalysis, Catalysi, Coatings and Films, Materials Chemistry, Electronic, Optical and Magnetic Materials, 010405 organic chemistry, Chemistry, Electronic, Optical and Magnetic Material, Chemistry (all), Metals and Alloys, General Chemistry, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Surfaces, Ceramics and Composites, 2506, Stoichiometry
Abstract

Large (Mw > 10 kDa) heterometallic coordination cages with gyrobifastigium-like geometry are obtained by using metalloligands with sterically demanding FeII clathrochelate cores and four divergent pyridyl groups. Upon reaction with cis-blocked PtII and PdII complexes, MII8L4 cages are formed. The gyrobifastigium geometry of these cages is in contrast to the barrel-like structures which are typically observed for metallasupramolecular assemblies with M8L4 stoichiometry.

Published
2016

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