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The leaf chlorophyll content (LCC) of winter wheat, an important food crop widely grown worldwide, is a key indicator for assessing its growth and health status in response to CO2 stress. However, the remote sensing quantitative estimation of winter wheat LCC under CO2 stress conditions also faces challenges such as an unclear spectral sensitivity range, baseline drift, overlapping spectral peaks, and complex spectral response due to CO2 stress changes. To address these challenges, this study introduced the fractional order derivative (FOD) and continuous wavelet transform (CWT) techniques into the estimation of winter wheat LCC. Combined with the raw hyperspectral data, we deeply analyzed the spectral response characteristics of winter wheat LCC under CO2 stress. We proposed a stacking model including multiple linear regression (MLR), decision tree regression (DTR), random forest (RF), and adaptive boosting (AdaBoost) to filter the optimal combination from a large number of feature variables. We use a dual-band combination and vegetation index strategy to achieve the accurate estimation of LCC in winter wheat under CO2 stress. The results showed that (1) the FOD and CWT methods significantly improved the correlation between the raw spectral reflectance and LCC of winter wheat under CO2 stress. (2) The 1.2-order derivative dual-band index (RVI (R720, R522)) constructed by combining the sensitive spectral bands of the CO2 response of winter wheat leaves achieved a high-precision estimation of the LCC under CO2 stress conditions (R2 = 0.901). Meanwhile, the red-edged vegetation stress index (RVSI) constructed based on the CWT technique at specific scales also demonstrated good performance in LCC estimation (R2 = 0.880), verifying the effectiveness of the multi-scale analysis in revealing the mechanism of the CO2 impact on winter wheat. (3) By stacking the sensitive spectral features extracted by combining the FOD and CWT methods, we further improved the LCC estimation accuracy (R2 = 0.906). This study not only provides a scientific basis and technical support for the accurate estimation of LCC in winter wheat under CO2 stress but also provides new ideas and methods for coping with climate change, optimizing crop-growing conditions, and improving crop yield and quality in agricultural management. The proposed method is also of great reference value for estimating physiological parameters of other crops under similar environmental stresses. [ABSTRACT FROM AUTHOR]

To non-destructively and rapidly monitor the chlorophyll content of winter wheat leaves under CO2 microleakage stress, and to establish the quantitative relationship between chlorophyll content and sensitive bands in the winter wheat growing season from 2023 to 2024, the leakage rate was set to 1 L/min, 3 L/min, 5 L/min, and 0 L/min through field experiments. The dimensional reduction was realized, fractional differential processing of a wheat canopy spectrum was carried out, a multiple linear regression (MLR) and partial least squares regression (PLSR) estimation model was constructed using a SPA selection band, and the model's accuracy was evaluated. The optimal model for hyperspectral estimation of wheat SPAD under CO2 microleakage stress was screened. The results show that the spectral curves of winter wheat leaves under CO2 microleakage stress showed a "red shift" of the green peak and a "blue shift" of the red edge. Compared with 1 L/min and 3 L/min, wheat leaves were more affected by CO2 at 5 L/min. Evaluation of the accuracy of the MLR and PLSR models shows that the MLR model is better, where the MLR estimation model based on 1.1, 1.8, 0.4, and 1.7 differential SPAD is the best for leakage rates of 1 L/min, 3 L/min, 5 L/min, and 0 L/min, with validation set R2 of 0.832, 0.760, 0.928, and 0.773, which are 11.528, 14.2, 17.048, and 37.3% higher than the raw spectra, respectively. This method can be used to estimate the chlorophyll content of winter wheat leaves under CO2 trace-leakage stress and to dynamically monitor CO2 trace-leakage stress in crops. [ABSTRACT FROM AUTHOR]

To solve the problem of long logistics delivery time in supply chain, a Mixed Integer Non-linear Program (MINLP) model is built by using Mixed Integer nonlinear programming theory. Firstly, the General algebraic modeling system (GAMS) is used to build the model to fully integrate each parameter of logistics transportation, the total distribution time of the supply chain network, the coverage radius of the logistics base, the number of users, the total capacity of the logistics base, the mode of railway and road transportation, the nonlinear programming model is built and solved by DICOPT solver in GAMS. The cost of logistics can be decreased, transportation time can be reduced, and the logistics system's operating efficiency can be increased in the long term with the help of this algorithm. The proper operation of the logistics system is critical in encouraging the supply chain circulation of various industries and has a direct impact on the society's economic development. The optimal logistics distribution plan with 5 logistics bases covered users of 18 and railway capacity of 2. With the same railway capacity and the same total budget, the larger the number of covered users, the greater the total distribution time increases, but the larger the total budget, the growth of the total distribution time slows down significantly. Experiments show that MINLP model can solve the problem of logistics-based layout optimization in nonlinear logistics management.

Wheat is the main grain crop in our country, and the traditional wheat yield estimation method is time-consuming and laborious. By estimating wheat yield efficiently, quickly and non-destructively, agricultural producers can quickly obtain information about wheat yield, manage wheat fields more scientifically and accurately, and ensure national food security. Taking the Xinxiang Experimental Base of the Crop Science Research Institute, Chinese Academy of Agricultural Sciences as an example, hyperspectral data for the critical growth stages of wheat were pre-processed. A total of 27 vegetation indices were calculated from the experimental plots. These indices were then subjected to correlation analysis with measured wheat yield. Vegetation indices with Pearson correlation coefficients greater than 0.5 were selected. Five methods, including multiple linear regression, stepwise regression, principal component regression, neural networks and random forests, were used to construct wheat yield estimation models. Among the methods used, multiple linear regression, stepwise regression and the models developed using principal component analysis showed a lower modelling accuracy and validation precision. However, the neural network and random forest methods both achieved a modelling accuracy R2 greater than 0.6, with validation accuracy R2 values of 0.729 and 0.946, respectively. In addition, the random forest method had a lower cross-validation RMSE value, with values of 869.8 kg/hm−2, indicating a higher model accuracy. In summary, the random forest method provided the optimal estimation for wheat yield, enabling the timely and accurate pre-harvest wheat yield prediction, which has significant value for precision agriculture management and decision making. [ABSTRACT FROM AUTHOR]

We fabricated a hollow cage-like layered double hydroxide modified carbon paste electrode (Ni1Co4-LDH/C) as an efficient catalyst for electrochemical water oxidation in neutral media. Reaction kinetics studies indicate that Ni1Co4-LDH/C can provide high water oxidation performance, mainly due to the small charge transfer resistance, and a high number of catalytic active sites. [ABSTRACT FROM AUTHOR]