Search

The results of the combined application of a series of analytical methods (clay mineralogy, vitrinite reflectance, Raman microspectroscopy) placed tight constraints on the thermal evolution of the Karakaya Complex of northern Anatolia, a mostly Permo-Triassic subduction-accretion complex resulting from the progressive closure of the Palaeotethys. The thermal evolution of the Karakaya Complex is the result of Permian-Triassic subduction-accretion processes, and was not significantly affected by later Alpine-age tectonism, as shown by Liassic shallow-water siliciclastic and carbonate deposits overlying unconformably the Karakaya Complex which did not undergo any significant burial. The Lower Karakaya Complex, comprising metabasite and subordinate marble and phyllite, experienced maximum temperatures ranging from 340 to 497° C, in agreement with independently determined thermobarometric reconstructions. The entire Upper Karakaya Complex, previously considered unmetamorphosed or slightly metamorphosed, was affected by zeolite to lower greenschist facies metamorphism (120-376° C). The coherent results of this study show that Raman thermometry has great potential for palaeotemperature determination at low temperature ranges (200-350° C).

The Mondragone 1 well, drilled in 1968 by Agip, for hydrocarbon exploration, cut across siliciclastic fine-to-coarse-grained upper Miocene–Quaternary deposits, for a total depth of 2002 m. Thirteen cores have been recovered from 495 down to 2002 m. This paper deals with both the results of the biostratigraphical analyses performed on a new sampling of the cores and the significance of the well stratigraphy in the context of the late Messinian Lago–Mare episode in central Mediterranean. The Lago–Mare biofacies has been characterised from 675 down to 2002 m by the ostracod assemblages that are made of species belonging to the Loxocorniculina djafarovi Zone, as defined by Carbonnel [Carbonnel, G., 1978. La zone a Loxoconcha djaffarovi Schneider (Ostracoda,Miocène supérieur) ou leMessinien de laVallée du Rhône. Rev.Micropaleontol. 21, 106–118.] (e.g. L. djafarovi, Loxoconcha eichwaldi, Cyprideis anlavauxensis, Amnicythere palimpsesta, Zalanyiella venusta). Thus, the Lago–Mare deposits have a true thickness of about 938 m since the strata show a mean dip value of 45°. Similar thickness (530 m) has been measured in the pre- Pliocene sediments drilled at ODP Site 652, which can be correlated withMondragone 1 by the occurrence of brackish-water forms. In both these areas syn-rift depositional processes have been suggested to explain the unusual thickness of the late Messinian sediments. Data from seismic lines have been used to reconstruct the geometry and the structural setting of the Garigliano Basin during the latest Messinian. Moreover, the analysis of the SP log integrated with the palaeoecological indications from the ostracod assemblages allows us to suggest a possible sequence stratigraphy evolution of the Garigliano Basin during the late Messinian Lago–Mare episode. Different tectonic behaviour with differences in subsidence rates between the northern and the southern Tyrrhenian Basin have been suggested since the uppermost Messinian syn-rift clastic wedges recognized in the onshore of northern Latium and Tuscany show thickness lower than that drilled at the ODP Site 652 and at the Mondragone 1 well.

An integrated array of analytical methods -including clay mineralogy, vitrinite reflectance, Raman spectroscopy on carbonaceous material, and apatite fission-track analysis- was employed to constrain the thermal and thermochronological evolution of selected portions of the Pontides of northern Turkey. (1) A multimethod investigation was applied for the first time to characterise the thermal history of the Karakaya Complex, a Permo-Triassic subduction-accretion complex cropping out throughout the Sakarya Zone. The results indicate two different thermal regimes: the Lower Karakaya Complex (Nilüfer Unit) -mostly made of metabasite and marble- suffered peak temperatures of 300-500°C (greenschist facies); the Upper Karakaya Complex (Hodul and the Orhanlar Units) –mostly made of greywacke and arkose- yielded heterogeneous peak temperatures (125-376°C), possibly the result of different degree of involvement of the units in the complex dynamic processes of the accretionary wedge. Contrary to common belief, the results of this study indicate that the entire Karakaya Complex suffered metamorphic conditions. Moreover, a good degree of correlation among the results of these methods demonstrate that Raman spectroscopy on carbonaceous material can be applied successfully to temperature ranges of 200-330°C, thus extending the application of this method from higher grade metamorphic contexts to lower grade metamorphic conditions. (2) Apatite fission-track analysis was applied to the Sakarya and the İstanbul Zones in order to constrain the exhumation history and timing of amalgamation of these two exotic terranes. AFT ages from the İstanbul and Sakarya terranes recorded three distinct episodes of exhumation related to the complex tectonic evolution of the Pontides. (i) Paleocene - early Eocene ages (62.3-50.3 Ma) reflect the closure of the İzmir-Ankara ocean and the ensuing collision between the Sakarya terrane and the Anatolide-Tauride Block. (ii) Late Eocene - earliest Oligocene (43.5-32.3 Ma) ages reflect renewed tectonic activity along the İzmir-Ankara. (iii) Late Oligocene- Early Miocene ages reflect the onset and development of the northern Aegean extension. The consistency of AFT ages, both north and south of the tectonic contact between the İstanbul and Sakarya terranes, suggest that such terranes were amalgamated in pre-Cenozoic times. (3) Fission-track analysis was also applied to rock samples from the Marmara region, in an attempt to constrain the inception and development of the North Anatolian Fault system in the region. The results agree with those from the central Pontides. The youngest AFT ages (Late Oligocene - early Miocene) were recorded in the western portion of the Marmara Sea region and reflect the onset and development of northern Aegean extension. Fission-track data from the eastern Marmara Sea region indicate rapid Early Eocene exhumation induced by the development of the İzmir-Ankara orogenic wedge. Thermochronological data along the trace of the Ganos Fault –a segment of the North Anatolian Fault system- indicate the presence of a tectonic discontinuity active by Late Oligocene time, i.e. well before the arrival of the North Anatolian Fault system in the area. The integration of thermochronologic data with preexisting structural data point to the existence of a system of major E-W-trending structural discontinuities active at least from the Late Oligocene. In the Early Pliocene, inception of the present-day North Anatolian Fault system in the Marmara region occurred by reactivation of these older tectonic structures.

The pulsed supersonic jet expansion microwave spectra of the parent and all three 13C mono-substituted isotopologues of methyl trifluoroacetate have been measured in the 6.5–18 GHz range. All observed transitions are split into two component lines, due to the internal rotation of the methyl group. The corresponding barrier has been determined to be V 3 = 4.379(3) kJ/mol. Structural information has been obtained from the 12 available rotational constants.