Search

We analyse the exact solutions of a conditionally-solvable Schr\"odinger equation with a rational potential. From the nodes of the exact eigenfunctions we derive a connection between the otherwise isolated exact eigenvalues and the actual eigenvalues of the Hamiltonian operator.

The Workflows Community Summit gathered 111 participants from 18 countries to discuss emerging trends and challenges in scientific workflows, focusing on six key areas: time-sensitive workflows, AI-HPC convergence, multi-facility workflows, heterogeneous HPC environments, user experience, and FAIR computational workflows. The integration of AI and exascale computing has revolutionized scientific workflows, enabling higher-fidelity models and complex, time-sensitive processes, while introducing challenges in managing heterogeneous environments and multi-facility data dependencies. The rise of large language models is driving computational demands to zettaflop scales, necessitating modular, adaptable systems and cloud-service models to optimize resource utilization and ensure reproducibility. Multi-facility workflows present challenges in data movement, curation, and overcoming institutional silos, while diverse hardware architectures require integrating workflow considerations into early system design and developing standardized resource management tools. The summit emphasized improving user experience in workflow systems and ensuring FAIR workflows to enhance collaboration and accelerate scientific discovery. Key recommendations include developing standardized metrics for time-sensitive workflows, creating frameworks for cloud-HPC integration, implementing distributed-by-design workflow modeling, establishing multi-facility authentication protocols, and accelerating AI integration in HPC workflow management. The summit also called for comprehensive workflow benchmarks, workflow-specific UX principles, and a FAIR workflow maturity model, highlighting the need for continued collaboration in addressing the complex challenges posed by the convergence of AI, HPC, and multi-facility research environments.

ALMA-IMF observed 15 massive protoclusters capturing multiple spectral lines and the continuum emission. We focus on the G351.77 protocluster ($\sim$ 2500 M$_{\odot}$, estimated from single-dish continuum observations) located at 2 kpc. We trace the dense gas emission and kinematics with N$_2$H$^+$ (1-0) at $\sim$ 4 kau resolution. We estimate an N$_2$H$^+$ relative abundance $\sim (1.7 \pm 0.5) \times 10^{-10}$. We decompose the N$_2$H$^+$ emission into up to two velocity components, highlighting the kinematic complexity in the dense gas. By examining the position-velocity (PV) diagrams on small scales, we observe clear inflow signatures (V-shapes) associated with dense cores. The most prominent V-shape has a mass inflow rate of $\sim 9.8 \times 10^{-4}$ M$_{\odot}$ yr$^{-1}$ and a short timescale of $\sim$ 15.6 kyr. We also observe V-shapes without associated cores. This suggests both that cores or centers of accretion exist below the 1.3 mm detection limit, and that the V-shapes may be viable tracers of very early accretion and star formation on $\sim$ 4 kau scales. The large-scale PV diagram shows that the protocluster is separated into 2 principal velocity structures. Combined with smaller scale DCN and H$_2$CO emission, we propose a scenario of larger scale slow contraction with rotation in the center based on simple toy models. This scenario leads the suggestion of outside-in evolution of the protocluster as it collapses. The gas depletion times implied by the V-shapes are short ($\sim$ 0.3 Myr), requiring either very fast cluster formation, and/or continuous mass feeding of the protocluster. The latter is possible via the Mother Filament G351.77 is forming out of. The similarities in the properties of G351.77 and the recently published work in G353.41 indicate that many of the physical conditions inferred via the ALMA-IMF N$_2$H$^+$ observations may be generic to protoclusters., Comment: Submitted in A&A, 28 pages, 31 figures, 4 interactive figures, 7 tables

The rising popularity of computational workflows is driven by the need for repetitive and scalable data processing, sharing of processing know-how, and transparent methods. As both combined records of analysis and descriptions of processing steps, workflows should be reproducible, reusable, adaptable, and available. Workflow sharing presents opportunities to reduce unnecessary reinvention, promote reuse, increase access to best practice analyses for non-experts, and increase productivity. In reality, workflows are scattered and difficult to find, in part due to the diversity of available workflow engines and ecosystems, and because workflow sharing is not yet part of research practice. WorkflowHub provides a unified registry for all computational workflows that links to community repositories, and supports both the workflow lifecycle and making workflows findable, accessible, interoperable, and reusable (FAIR). By interoperating with diverse platforms, services, and external registries, WorkflowHub adds value by supporting workflow sharing, explicitly assigning credit, enhancing FAIRness, and promoting workflows as scholarly artefacts. The registry has a global reach, with hundreds of research organisations involved, and more than 700 workflows registered., Comment: 30 pages, 4 figures

Kinetic inductance detectors (KIDs) have been proven as reliable systems for astrophysical observations, especially in the millimetre range. Their compact size enables to optimally fill the focal plane, thus boosting sensitivity. The KISS (KIDs Interferometric Spectral Surveyor) instrument is a millimetre camera that consists of two KID arrays of 316 pixels each coupled to a Martin-Puplett interferometer (MPI). The addition of the MPI grants the KIDs camera the ability to provide spectral information in the 100 and 300 GHz range. In this paper we report the main properties of the KISS instrument and its observations. We also describe the calibration and data analysis procedures used. We present a complete model of the observed data including the sky signal and several identified systematics. We have developed a full photometric and spectroscopic data analysis pipeline that translates our observations into science-ready products. We show examples of the results of this pipeline on selected sources: Moon, Jupiter and Venus. We note the presence of a deficit of response with respect to expectations and laboratory measurements. The detectors noise level is consistent with values obtained during laboratory measurements, pointing to a sub-optimal coupling between the instrument and the telescope as the most probable origin for the problem. This deficit is large enough as to prevent the detection of galaxy clusters, which were KISS main scientific objective. Nevertheless, we have demonstrated the feasibility of this kind of instrument, in the prospect for other KID interferometers (such as the CONCERTO instrument). As this regard, we have developed key instrumental technologies such as optical conception, readout electronics and raw calibration procedures, as well as, adapted data analysis procedures., Comment: 23 pages, 15 figures. Accepted for publication in Publications of the Astronomical Society of the Pacific

We show that a perturbed Coulomb problem discussed recently is conditionally solvable. We obtain the exact eigenvalues and eigenfunctions and compare the former with eigenvalues calculated by means of a numerical method. We discuss the meaning of the numbers that determine the exact solutions which arise from the Frobenius (power-series) method.

This work focuses on the study of the AME, an important emission mechanism between 10 and 60 GHz whose polarization properties are not yet fully understood, and is therefore a potential contaminant for future CMB polarization observations. We use new QUIJOTE-MFI maps 11, 13, 17 and 19 GHz, together with other public ancillary data including WMAP and Planck, to study the polarization properties of the AME in three Galactic regions: rho-Ophiuchi, Perseus and W43. We have obtained the SEDs for those three regions over the frequency range 0.4-3000 GHz, both in intensity and polarization. The intensity SEDs are well described by a combination of free-free emission, thermal dust, AME and CMB anisotropies. In polarization, we extracted the flux densities using all available data between 11 and 353 GHz. We implemented an improved intensity-to-polarization leakage correction that has allowed for the first time to derive reliable polarization constraints well below the 1% level from Planck-LFI data. A frequency stacking of maps in the range 10-60 GHz has allowed us to reduce the statistical noise and to push the upper limits on the AME polarization level. We have obtained upper limits on the AME polarization fraction of order <1% (95% confidence level) for the three regions. In particular we get Pi_AME < 1.1% (at 28.4 GHz), Pi_AME < 1.1% (at 22.8 GHz) and Pi_AME < 0.28% (at 33 GHz) in rho-Ophiuchi, Perseus and W43 respectively. At the QUIJOTE 17 GHz frequency band, we get Pi_AME< 5.1% for rho-Ophiuchi, Pi_AME< 3.5% for Perseus and Pi_AME< 0.85% for W43. Our final upper limits derived using the stacking procedure are Pi_AME < 0.58% for rho-Ophiuchi, Pi_AME < 1.64% for Perseus and Pi_AME < 0.31% for W43. Altogether, these are the most stringent constraints to date on the AME polarization fraction of these three star-forming regions., Comment: 26 pages. 15 figures. Submitted to A&A. Comments welcome

Small satellites such as CubeSats pose demanding requirements on the weight, size, and multifunctionality of their structures due to extreme constraints on the payload mass and volume. To address this challenge, we introduce a concept of multifunctional deployable space structures for CubeSats based on ultrathin, elastically foldable, and self-deployable bistable composite structures integrated with flexible electronics. The multifunctional bistable booms can be stored in a coiled configuration and self-deploy into a long structure upon initiation by releasing the stored strain energy. The boom demonstrates the capabilities of delivering power and transmitting data from the CubeSat to the flexible devices on the boom tip. The boom also shows the ability to monitor the dynamics and vibration during and after the deployment. A payload boom has been installed in a 3U CubeSat as flight hardware for in-space testing and demonstration. This effort combines morphable ultrathin composite structures with flexible electronics.

We revisit the quantum-mechanical two-dimensional harmonic oscillator with an electric field confined to a circular box of impenetrable walls. In order to obtain the energy spectrum we resort to the Rayleigh-Ritz method with polynomial and Gaussian basis sets. We compare present results with those derived recently by other authors. We discuss the limits of large and small box radius and also do some calculations with perturbation theory.

We present a study connecting the physical properties of protostellar envelopes to the morphology of the envelope-scale magnetic field. We use the ALMA polarization observations of 55 young prtostars at 0.87 mm on $\sim400-3000$ au scales from the {\em B}-field Orion Protostellar Survey (BOPS) to infer the envelope-scale magnetic field and both dust and gas emission on comparable scales to measure the envelope properties. We find that the protostellar envelopes with compact polarized dust emission tend to have lower envelope masses, than the sources with more extended envelopes. We also find that protostars showing hourglass-field morphologies tend to have lower velocity dispersions in their envelopes, whereas systems with spiral-field morphologies have higher velocity dispersion. Combining with the disk properties taken from the Orion VLA/ALMA Nascent Disk and Multiplicity (VANDAM) survey, we connect envelope properties to fragmentation. Our results suggest that envelope mass may not correlate with fragmentation, whereas turbulence appears to promote fragmentation. On the other hand, we find that fragmentation is suppressed in systems with pinched magnetic fields, suggesting that the magnetic field play a role on providing additional support against gravitational collapse, and the formation of an hourglass-like field may coincide with enhanced magnetic braking that removes angular momentum and hinders the formation of embedded disks. Nevertheless, significant misalignment between magnetic field and outflow axes tends to reduce magnetic braking, leading to the formation of larger disks., Comment: 18 pages, 6 figures, submitted to ApJ

The stellar initial mass function (IMF) is critical to our understanding of star formation and the effects of young stars on their environment. On large scales, it enables us to use tracers such as UV or Halpha emission to estimate the star formation rate of a system and interpret unresolved star clusters across the universe. So far, there is little firm evidence of large-scale variations of the IMF, which is thus generally considered universal. Stars form from cores and it is now possible to estimate core masses and compare the core mass function (CMF) with the IMF, which it presumably produces. The goal of the ALMA-IMF large program is to measure the core mass function at high linear resolution (2700 au) in 15 typical Milky Way protoclusters spanning a mass range of 2500 to 32700 Msun. In this work, we used two different core extraction algorithms to extract about 680 gravitationally bound cores from these 15 protoclusters. We adopt per core temperature using the temperature estimate from the PPMAP Bayesian method. A power-law fit to the CMF of the sub-sample of cores above the 1.64 Msun completeness limit, 330 cores, through the maximum likelihood estimate technique yields a slope of 1.97 +/- 0.06, significantly flatter than the 2.35 Salpeter slope. Assuming a self-similar mapping between the CMF and the IMF, this result implies that these 15 high-mass protoclusters will generate atypical IMFs. This sample is the largest to date produced and analysed self-consistently, derived at matched physical resolution, with per-core temperature estimates and cores as massive as 150 Msun. We provide the raw source extraction catalogues and the source derived size, temperature, mass, and spectral indices in the 15 protoclusters., Comment: Accepted by A&A

The contribution of the magnetic field to the formation of high-mass stars is poorly understood. We report the high-angular resolution ($\sim0.3^{\prime\prime}$, 870 au) map of the magnetic field projected on the plane of the sky (B$_\mathrm{POS}$) towards the high-mass star forming region G333.46$-$0.16 (G333), obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.2 mm as part of the Magnetic Fields in Massive Star-forming Regions (MagMaR) survey. The B$_\mathrm{POS}$ morphology found in this region is consistent with a canonical ``hourglass'' which suggest a dynamically important field. This region is fragmented into two protostars separated by $\sim1740$ au. Interestingly, by analysing H$^{13}$CO$^{+}$ ($J=3-2$) line emission, we find no velocity gradient over the extend of the continuum which is consistent with a strong field. We model the B$_\mathrm{POS}$, obtaining a marginally supercritical mass-to-flux ratio of 1.43, suggesting an initially strongly magnetized environment. Based on the Davis-Chandrasekhar-Fermi method, the magnetic field strength towards G333 is estimated to be 5.7 mG. The absence of strong rotation and outflows towards the central region of G333 suggests strong magnetic braking, consistent with a highly magnetized environment. Our study shows that despite being a strong regulator, the magnetic energy fails to prevent the process of fragmentation, as revealed by the formation of the two protostars in the central region.

In this short note we resort to the well known Hellmann-Feynman theorem to prove that some non-relativistic Hamiltonian operators support an infinite number of bound states.

A crucial aspect in addressing the challenge of measuring the core mass function, that is pivotal for comprehending the origin of the initial mass function, lies in constraining the temperatures of the cores. We aim to measure the luminosity, mass, column density and dust temperature of star-forming regions imaged by the ALMA-IMF large program. High angular resolution mapping is required to capture the properties of protostellar and pre-stellar cores and to effectively separate them from larger features, such as dusty filaments. We employed the point process mapping (PPMAP) technique, enabling us to perform spectral energy distribution fitting of far-infrared and submillimeter observations across the 15 ALMA-IMF fields, at an unmatched 2.5" angular resolution. By combining the modified blackbody model with near-infrared data, we derived bolometric luminosity maps. We estimated the errors impacting values of each pixel in the temperature, column density, and luminosity maps. Subsequently, we employed the extraction algorithm getsf on the luminosity maps in order to detect luminosity peaks and measure their associated masses. We obtained high-resolution constraints on the luminosity, dust temperature, and mass of protoclusters, that are in agreement with previously reported measurements made at a coarser angular resolution. We find that the luminosity-to-mass ratio correlates with the evolutionary stage of the studied regions, albeit with intra-region variability. We compiled a PPMAP source catalog of 313 luminosity peaks using getsf on the derived bolometric luminosity maps. The PPMAP source catalog provides constraints on the mass and luminosity of protostars and cores, although one source may encompass several objects. Finally, we compare the estimated luminosity-to-mass ratio of PPMAP sources with evolutionary tracks and discuss the limitations imposed by the 2.5" beam., Comment: 35 pages, 19 figures, 5 tables Accepted by A&A

To design semiconductor-based optical devices, the optical properties of the used semiconductor materials must be precisely measured over a large band. Transmission spectroscopy stands out as an inexpensive and widely available method for this measurement but requires model assumptions and reconstruction algorithms to convert the measured transmittance spectra into optical properties of the thin films. Amongst the different reconstruction techniques, inverse synthesis methods generally provide high precision but rely on rigid analytical models of a thin film system. In this paper, we demonstrate a novel flexible inverse synthesis method that uses angular spectrum wave propagation and does not rely on rigid model assumptions. Amongst other evaluated parameters, our algorithm is capable of evaluating the geometrical properties of thin film surfaces, which reduces the variance caused by inverse synthesis optimization routines and significantly improves measurement precision. The proposed method could potentially allow for the characterization of "uncommon" thin film samples that do not fit the current model assumptions, as well as the characterization of samples with higher complexity, e.g., multi-layer systems., Comment: 10 pages, 7 figures, 5 tables

We report on ALMA observations of polarized dust emission at 1.2 mm from NGC6334I, a source known for its significant flux outbursts. Between five months, our data show no substantial change in total intensity and a modest 8\% variation in linear polarization, suggesting a phase of stability or the conclusion of the outburst. The magnetic field, inferred from this polarized emission, displays a predominantly radial pattern from North-West to South-East with intricate disturbances across major cores, hinting at spiral structures. Energy analysis of CS$(J=5 \rightarrow 4)$ emission yields an outflow energy of approximately $3.5\times10^{45}$ ergs, aligning with previous interferometric studies. Utilizing the Davis-Chandrasekhar-Fermi method, we determined magnetic field strengths ranging from 1 to 11 mG, averaging at 1.9 mG. This average increases to 4 $\pm 1$ mG when incorporating Zeeman measurements. Comparative analyses using gravitational, thermal, and kinetic energy maps reveal that magnetic energy is significantly weaker, possibly explaining the observed field morphology. We also find that the energy in the outflows and the expanding cometary {\HII} region is also larger than the magnetic energy, suggesting that protostellar feedback maybe the dominant driver behind the injection of turbulence in NGC6334I at the scales sampled by our data. The gas in NGC6334I predominantly exhibits supersonic and trans-Alfvenic conditions, transitioning towards a super-Alfvenic regime, underscoring a diminished influence of the magnetic field with increasing gas density. These observations are in agreement with prior polarization studies at 220 GHz, enriching our understanding of the dynamic processes in high-mass star-forming regions., Comment: Accepted for Publication at the Astrophysical Journal

In this work, a one-dimensional simulation code was developed for both single-phase and two-phase systems, focusing on time-dependent Euler equations for gas and particles. These equations, non-linear hyperbolic conservation laws, describe the dynamics of compressible materials, where body forces, viscous stresses, and heat flux are neglected. The Euler equations were discretized using the finite volume method, and the code was written in MATLAB. To test the accuracy of the computational fluid code, the Sod shock tube problem, a physical analogue of the Riemann problem, was employed. This problem models a pressure discontinuity where high and low-pressure regions are separated by a diaphragm, which breaks at t=0, creating a discontinuity in density as well. Exact solutions were used for code verification. A key focus was on modeling a curtain of particles impacted by a shock wave, relevant to multiphase heterogeneous cylindrical explosion studies by the PSAAP II project. This initiative, funded by the US Department of Energy (DOE) National Nuclear Security Administration (NNSA) Office of Advanced Simulation and Computing (ASC), involves Sandia National Laboratories and the Center for Compressible Multiphase Turbulence at the University of Florida. The propagation of uncertainties in the maximum density of the particle curtain was studied by varying initial curtain thickness and initial high density. Given the computational expense of multiple code evaluations for uncertainty propagation, a multi-fidelity surrogate model combining low and high-fidelity simulations was implemented. This model facilitated uncertainty propagation using DAKOTA, a flexible and extensible interface between analysis codes and iterative systems analysis methods., Comment: 72 pages, 15 figures, and 8 tables

Industrial accidents, chemical spills, and structural fires can release large amounts of harmful materials that disperse into urban atmospheres and impact populated areas. Computer models are typically used to predict the transport of toxic plumes by solving fluid dynamical equations. However, these models can be computationally expensive due to the need for many grid cells to simulate turbulent flow and resolve individual buildings and streets. In emergency response situations, alternative methods are needed that can run quickly and adequately capture important spatiotemporal features. Here, we present a novel deep learning model called ST-GasNet that was inspired by the mathematical equations that govern the behavior of plumes as they disperse through the atmosphere. ST-GasNet learns the spatiotemporal dependencies from a limited set of temporal sequences of ground-level toxic urban plumes generated by a high-resolution large eddy simulation model. On independent sequences, ST-GasNet accurately predicts the late-time spatiotemporal evolution, given the early-time behavior as an input, even for cases when a building splits a large plume into smaller plumes. By incorporating large-scale wind boundary condition information, ST-GasNet achieves a prediction accuracy of at least 90% on test data for the entire prediction period., Comment: 13 pages, 10 figures

We argue that several potentials proposed recently for the analysis of the vibrational-rotational spectra of diatomic molecules and their thermodynamic properties exhibit a flaw. One can easily show that the parameters $D_e $ and $r_e$ in those potentials are not the dissociation energy and equilibrium bond length, respectively, as the proposers believe. We show how to overcome the mistake in a simple and quite general way.

We present VelCrys, a web-based interactive tool, that allows to perform further post-processing of the elastic tensor in order to compute and plot the group velocity of the acoustic waves for any crystal symmetry. We also implemented the calculation of effective magnetic corrections to the elastic tensor and corresponding fractional change in group velocity under a magnetic field. We apply it to dry sandstone, cubic CoPt and hcp Co to show some of the program features. In the analysis of magnetic corrections, we find complex landscapes of fractional change in group velocity as a function of ray direction, as well as a field dependence consistent with Simon effect.

We overview the main equations of the Rayleigh-Ritz variational method and discuss their connection with the problem of simultaneous diagonalization of two Hermitian matrices.

The ALMA-IMF Large Program provides multi-tracer observations of 15 Galactic massive protoclusters at matched sensitivity and spatial resolution. We focus on the dense gas kinematics of the G353.41 protocluster traced by N$_2$H$^+$ (1$-$0), with an spatial resolution $\sim$0.02 pc. G353.41, at a distance of $\sim$2 kpc, has a mass of $\sim$2500 M$_{\odot}$ within $1.3\times1.3$ pc$^2$. We extract the N$_2$H$^+$ isolated line component and we decompose it by fitting up to 3 Gaussian velocity components. This allows us to identify velocity structures that are impossible to identify in the traditional position-velocity diagram. We identify multiple velocity gradients on large ($\sim$1 pc) and small scales ($\sim$0.2 pc). We find good agreement between the N$_2$H$^+$ velocities and the previously reported DCN core velocities, suggesting that cores are kinematically coupled to the dense gas in which they form. We measure 9 converging ``V-shaped'' velocity gradients ($\sim20$ km/s/pc), located in filaments, which are sometimes associated with cores near their point of convergence. The average inflow timescale is $\sim67$ kyr, or about twice the free-fall time of cores in the same area ($\sim33$ kyr) but substantially shorter than protostar lifetime estimates ($\sim$0.5 Myr). We derive mass accretion rates in the range of $(0.35-8.77)\,\times\,10^{-4}$ M$_{\odot}$/yr. This feeding might lead to further filament collapse and formation of new cores. We suggest that the protocluster is collapsing on large scales, but the velocity signature of collapse is slow compared to pure free-fall. These data are consistent with a comparatively slow global protocluster contraction under gravity, and faster core formation within, suggesting the formation of multiple generations of stars over the protocluster lifetime., Comment: Accepted in A&A, 22 pages, 21 figures, 1 interactive figure, 4 tables

We test the analytical expressions for the first two eigenvalues of the harmonic oscillator with a Gaussian perturbation proposed recently. Our numerical eigenvalues show that those expressions are valid in an interval of the coupling parameter that is greater than the one estimated by the authors. We also calculate critical values of the coupling parameter and several exceptional points in the complex plane.

Sites associated with high-mass star and cluster formation exhibit a so-called hot core phase, characterized by high temperatures and column densities of complex organic molecules. We built a comprehensive census of hot core candidates towards the ALMA-IMF protoclusters based on the detection of two CH3OCHO emission lines at 216.1 GHz. We used the source extraction algorithm GExt2D to identify peaks of methyl formate (CH3OCHO) emission that is a complex species commonly observed towards sites of star formation. We built up a catalog of 76 hot core candidates with masses ranging from about 0.2 to 80 Msun , of which 56 are new detections. A large majority of these objects are compact, rather circular, with deconvolved FWHM sizes of about 2300 au on average. About 30% of our sample of methyl formate sources have core masses above 8 Msun within sizes ranging from about 1000 au to 13400 au, which well correspond to archetypical hot cores. The origin of the CH3OCHO emission toward the lower-mass cores can be explained by a mixture of contribution from shocks, or may correspond to objects in a more evolved state, i.e. beyond the hot core stage. We find that the fraction of hot core candidates increases with the core mass. The large fraction of hot core candidates towards the most massive cores suggests that they rapidly enter the hot core phase and feedback effects from the forming protostar(s) impact their environment on short time-scales.

Heat wave (HW) events are becoming more frequent, and they have important consequences because of the negative effects they can have not only on the human population in health terms, but also on biodiversity and agriculture. This motivated a study of the trends in HW events over Extremadura, a region in the southwest of Spain, with much of its area in summer devoted to the production of irrigated crops such as maize and tomatoes. Heat waves were defined for the study as two consecutive days with temperatures above the 95th percentile of the summer (June-August) maximum temperature (Tmax) time series. Two datasets were used: one consisted of 13 daily temperature records uniformly distributed over the Region, and the other was the SPAIN02 gridded observational dataset, extracting just the points corresponding to Extremadura. The trends studied were in the duration, intensity, and frequency of HW events, and in other parameters such as the mean, low (25th percentile), and high (75th percentile) values. In general terms, the results showed significant positive trends in those parameters over the east, the northwest, and a small area in the south of the Region. In order to study changes in HW characteristics (duration, frequency and intensity) considering different subperiods, a stochastic model was used to generate 1000 time series equivalent to the observed ones. The results showed that there were no significant changes in HW duration in the last 10-year subperiod in comparison with the first. But the results were different for warm events (WE), defined with a lower threshold (the 75th percentile), which are also important for agriculture. For several sites, there were significant changes in WE duration, frequency, and intensity., Comment: 36 pages, 11 figures

In this work the role that charge delocalization plays in the non-linear optical response of ionic liquids is evaluated. The first hyperpolarizability for the non-linear process of second harmonic generation (SHG) and second hyperpolarizability for the non-linear process of electro-optical Kerr-Effect (EOKE) of a large number of ionic liquid forming ions were estimated by means of density functional theory calculations. The results point to that both charge delocalization and molecular geometry are the key features that govern their hyperpolarizabilities. Our findings show that some of the most commonly used anions in ionic liquids are expected to present strong non-linear responses while common cations present a much more limited performance. However, this limitation can be overcome by a proper tailoring of cations to present charge delocalization over large molecular regions. The hypothesis of additivity of hyperpolarizabilities in ionic liquids is tested and exploited to obtain a map of second and third order non-linear susceptibilities of 1496 ion combinations. This map is intended to be a guide for future works on the hyperpolarizability of ILs, Comment: 12 pages, 6 figures, 4 tables, supplementary data associated with this article can be found, in the online version, at https://doi.org/10.1016/j.molliq.2021.118153

We aimed to measure the CMF in the evolved W33-Main star-forming protocluster to compare it with CMF recently obtained in other Galactic star-forming regions, including the ones included in the ALMA-IMF program. We used observations from the ALMA-IMF large program: 2'x2' maps of emission from the continuum and selected lines at 1.3mm and 3mm observed by the ALMA 12m only antennas. Our angular resolution was typically 1'', that is 2400au at a distance of 2.4kpc. The lines we analysed are CO(2-1), SiO(5-4), N2H+(1-0), H41alpha as well as He41alpha blended with C41alpha. We built a census of dense cores in the region, and we measured the associated CMF based on a core-dependent temperature value. We confirmed the 'evolved' status of W33-Main by identifiying three HII regions within the field, and to a lesser extent based on the number and extension of N2H+ filaments. We produced a filtered core catalog of 94 candidates, that we refined to take into account the contamination of the continuum by free-free and line emission, obtaining 80 cores with masses that range from 0.03 to 13.2Msun. We fitted the resulting high-mass end of the CMF with a single power law of the form N(log(M)) ~ M^alpha, obtaining alpha = -1.44(+0.16)(-0.22), slightly steeper but consistent with the Salpeter index. We categorized our cores in pre- and protostellar, mostly based on outlow activity and hot core nature. We found the prestellar CMF to be steeper than a Salpeter-like distribution, and the protostellar CMF to be slightly top heavy. We found a higher proportion of cores within the HII regions and their surroundings than in the rest of the field. We also found that the cores' masses were rather low (maximum mass of 13Msun).

The Large Latin American Millimeter Array (LLAMA for short) is a joint scientific and technological undertaking of Argentina and Brazil whose goal is to install and to operate an observing facility capable of performing observations of the Universe at millimeter and sub-millimeter wavelengths. It will consist of a 12m ALMA-like antenna with the addition of two Nasmyth cabins. LLAMA is located at 4850m above sea level in the Puna Saltenia, in the northwest region of Argentina. When completed, LLAMA will be equipped with six ALMA receivers covering Bands 1, 2+3, 5, 6, 7, and 9, which will populate the two Nasmyth cabins. We summarize here the main ideas related with the Science that LLAMA could accomplish on different astronomical topics, gathered from the experience of a group of international experts on each field., Comment: 11 pages, contributed paper to the workshop "Prospects for low-frequency radio astronomy in South America", held in Buenos Aires, Nov 2022; to appear in the RevMexAA-SC

The Automatic Dependent Surveillance-Broadcast (ADS-B) is a surveillance technology that becomes mandatory in many airspaces. It improves safety, increases efficiency and reduces air traffic congestion by broadcasting aircraft navigation data. Yet, ADS-B is vulnerable to spoofing attacks as it lacks mechanisms to ensure the integrity and authenticity of the data being supplied. None of the existing cryptographic solutions fully meet the backward compatibility and bandwidth preservation requirements of the standard. Hence, we propose the Compatible Authenticated Bandwidth-efficient Broadcast protocol for ADS-B (CABBA), an improved approach that integrates TESLA, phase-overlay modulation techniques and certificate-based PKI. As a result, entity authentication, data origin authentication, and data integrity are the security services that CABBA offers. To assess compliance with the standard, we designed an SDR-based implementation of CABBA and performed backward compatibility tests on commercial and general aviation (GA) ADS-B in receivers. Besides, we calculated the 1090ES band's activity factor and analyzed the channel occupancy rate according to ITU-R SM.2256-1 recommendation. Also, we performed a bit error rate analysis of CABBA messages. The results suggest that CABBA is backward compatible, does not incur significant communication overhead, and has an error rate that is acceptable for Eb/No values above 14 dB., Comment: The paper has been submitted to IEEE Transactions on Aerospace and Electronic Systems

Recording the provenance of scientific computation results is key to the support of traceability, reproducibility and quality assessment of data products. Several data models have been explored to address this need, providing representations of workflow plans and their executions as well as means of packaging the resulting information for archiving and sharing. However, existing approaches tend to lack interoperable adoption across workflow management systems. In this work we present Workflow Run RO-Crate, an extension of RO-Crate (Research Object Crate) and Schema.org to capture the provenance of the execution of computational workflows at different levels of granularity and bundle together all their associated objects (inputs, outputs, code, etc.). The model is supported by a diverse, open community that runs regular meetings, discussing development, maintenance and adoption aspects. Workflow Run RO-Crate is already implemented by several workflow management systems, allowing interoperable comparisons between workflow runs from heterogeneous systems. We describe the model, its alignment to standards such as W3C PROV, and its implementation in six workflow systems. Finally, we illustrate the application of Workflow Run RO-Crate in two use cases of machine learning in the digital image analysis domain. A corresponding RO-Crate for this article is at https://w3id.org/ro/doi/10.5281/zenodo.10368989, Comment: 38 pages, 5 figures, 3 tables. Resubmitted to PLOS ONE following peer review

We present archive Atacama Large Millimeter/Submillimeter Array (ALMA) Band 6 observations of the $^{13}$CO (J=2-1) and $^{12}$CO (J=2-1) molecular line emission of the protostellar system associated with HH 30. The $^{13}$CO molecular line shows the accretion disk while the molecular outflow is traced by the emission of the $^{12}$CO molecular line. We estimated a dynamical mass for the central object of $0.45\pm0.14$ M$_\odot$, and a mass for the molecular outflow of $1.83\pm0.19\times10^{-4}$ M$_\odot$. The molecular outflow presents an internal cavity as well as multiple outflowing shell structures. We distinguish three different shells with constant expansion ($\sim4-6$ km s$^{-1}$) and possible rotation signatures ($\leq0.5$ km s$^{-1}$). We find that the shells can be explained by magnetocentrifugal disk winds with launching radii $R_\mathrm{launch}\lesssim4$ au and a small magnetic lever arm $\lambda\sim1.6-1.9$. The multiple shell structure may be the result of episodic ejections of the material from the accretion disk associated with three different epochs with dynamical ages of $497\pm15$ yr, $310\pm9$ yr, and $262\pm11$ yr for the first, second, and third shells, respectively. The outermost shell was ejected $187\pm17$ yr before the medium shell, while the medium shell was launched $48\pm14$ yr before the innermost shell. Our estimations of the linear and angular momentum rates of the outflow as well as the accretion luminosity are consistent with the expected values if the outflow of HH 30 is produced by a wide-angle disk wind.

We discuss in detail a well known method for obtaining the frequencies of the normal modes of coupled harmonic oscillators that is based on the simultaneous diagonalization of two symmetric matrices. We apply it to some simple illustrative examples recently chosen for the presentation of an alternative approach based on a set of constants of the motion. We show that the traditional method is simpler, even in the case of equal frequencies. We also discuss a problem that commonly appears in elementary courses on quantum mechanics that also requires the diagonalization of two symmetric matrices.

On August 9-10, 2023, a workshop was convened at the Pacific Northwest National Laboratory (PNNL) in Richland, WA that brought together a group of internationally recognized experts in metabolomics, natural products discovery, chemical ecology, chemical and biological threat assessment, cheminformatics, computational chemistry, cloud computing, artificial intelligence, and novel technology development. These experts were invited to assess the value and feasibility of a grand-scale project to create new technologies that would allow the identification and quantification of all small molecules, or to decode the molecular universe. The Decoding the Molecular Universe project would extend and complement the success of the Human Genome Project by developing new capabilities and technologies to measure small molecules (defined as non-protein, non-polymer molecules less than 1500 Daltons) of any origin and generated in biological systems or produced abiotically. Workshop attendees 1) explored what new understanding of biological and environmental systems could be revealed through the lens of small molecules; 2) characterized the similarities in current needs and technical challenges between each science or mission area for unambiguous and comprehensive determination of the composition and quantities of small molecules of any sample; 3) determined the extent to which technologies or methods currently exist for unambiguously and comprehensively determining the small molecule composition of any sample and in a reasonable time; and 4) identified the attributes of the ideal technology or approach for universal small molecule measurement and identification. The workshop concluded with a discussion of how a project of this scale could be undertaken, possible thrusts for the project, early proof-of-principle applications, and similar efforts upon which the project could be modeled.