1. Revealing the microstructure of sodium-montmorillonite aqueous suspensions
- Author
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Shoaib, Mohammad, Khan, Shaihroz, Wani, Omar B, Mata, Jitendra, Krzysko, Anthony J., Kuzmenko, Ivan, Bleuel, Markus, Fiddes, Lindsey K., Roth, Eric W., and Bobicki, Erin R
- Subjects
Condensed Matter - Soft Condensed Matter - Abstract
Aqueous suspensions of geometrically anisometric (2D) sodium-montmorillonite (Na-Mt) particles display a sol-gel transition at very low solids concentrations. The underlying microstructure of the gel has remained a point of contention since the time of Irving Langmuir. An in-situ investigation encompassing length scales much larger than the individual particles is required to provide support for one of the two models proposed in the literature: 1) a percolated network governed by electrostatic attraction between platelets; and 2) a jammed suspension stabilized by repulsive electrostatic forces between particles. We settle this debate by comprehensively probing the microstructure of Na-Mt suspensions using ultra-small angle neutron/X-ray scattering and found that it is ordered and contains entities that are at least an order of magnitude larger than the individual particles. Complementary cryo-electron microscopy showed both the presence of domains having strong particle-particle ordering and regions of particle-particle aggregation. These data indicate 1) the presence of nematic domains, which refutes a purely attractive nature, and 2) assembly of particles, which refutes a purely repulsive nature. Na-Mt gels appear to have a hybrid microstructure with both attractive and repulsive domains.
- Published
- 2022