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Underground Hydrogen Storage (UHS) provides a large-scale and safe solution to balance the fluctuations in energy production from renewable sources and energy consumption but requires a proper and detailed characterization of the candidate reservoirs. The scope of this study was to estimate the hydrogen diffusion coefficient for real caprock samples from two natural gas storage reservoirs that are candidates for underground hydrogen storage. A significant number of adsorption/desorption tests were carried out using a Dynamic Gravimetric Vapor/Gas Sorption System. A total of 15 samples were tested at the reservoir temperature of 45 °C and using both hydrogen and methane. For each sample, two tests were performed with the same gas. Each test included four partial pressure steps of sorption alternated with desorption. After applying overshooting and buoyancy corrections, the data were then interpreted using the early time approximation of the solution to the diffusion equation. Each interpretable partial pressure step provided a value of the diffusion coefficient. In total, more than 90 estimations of the diffusion coefficient out of 120 partial pressure steps were available, allowing a thorough comparison between the diffusion of hydrogen and methane: hydrogen in the range of 1 × 10−10 m2/s to 6 × 10−8 m2/s and methane in the range of 9 × 10−10 m2/s to 2 × 10−8 m2/s. The diffusion coefficients measured on wet samples are 2 times lower compared to those measured on dry samples. Hysteresis in hydrogen adsorption/desorption was also observed.

We map the High Sillaro Valley, in the Northern Apennines of Italy. Here the Ligurian wedge overthrust the foredeep deposits of the Marnoso Arenacea formation – MA. The overthrusting occurred through a shear zone with components derived from the frontal part of the Ligurian wedge and interpreted as a tectonic mélange (Sestola-Vidiciatico Tectonic unit - SVU) here subdivided into two different subunits structurally independent one from the other. In the area, the Visignano chaotic body (VIS) constitutes an intercalation within the Serravallian-Tortonian MA and derives, as the SVU, from the frontal part of the Ligurian wedge. We performed a detailed investigation of the components of the VIS that helps to better define the architecture of the frontal part of the Ligurian wedge and to constrain the timing of the deformation phases affecting this portion of the Northern Apennines during the middle-late Miocene.

The understanding of multiphase flow phenomena occurring in porous media at the pore scale is fundamental in a significant number of fields, from life science to geo and environmental engineering. However, because of the optical opacity and the geometrical complexity of natural porous media, detailed visual characterization is not possible or is limited and requires powerful and expensive imaging techniques. As a consequence, the understanding of micro-scale behavior is based on the interpretation of macro-scale parameters and indirect measurements. Microfluidic devices are transparent and synthetic tools that reproduce the porous network on a 2D plane, enabling the direct visualization of the fluid dynamics. Moreover, microfluidic patterns (also called micromodels) can be specifically designed according to research interests by tuning their geometrical features and surface properties. In this work we design, fabricate and test two different micromodels for the visualization and analysis of the gas-brine fluid flow, occurring during gas injection and withdrawal in underground storage systems. In particular, we compare two different designs: a regular grid and a real rock-like pattern reconstructed from a thin section of a sample of Hostun rock. We characterize the two media in terms of porosity, tortuosity and pore size distribution using the A* algorithm and CFD simulation. We fabricate PDMS-glass devices via soft lithography, and we perform preliminary air-water displacement tests at different capillary numbers to observe the impact of the design on the fluid dynamics. This preliminary work serves as a validation of design and fabrication procedures and opens the way to further investigations.

The Monte Piano — Blsmantova sequence (Middle Eocene — Late Miocene) in the Northern Apenmnes represents a new sedimentary cycle after the tectonic phase of the Early—Middle Eocene. This phase principally affected the structural Units of Ligurian domain. This sedimentary sequence (the postorogenic Ligurian Sequence), shows evidence of the progression of the Apennine orogenesis mainly through the development of unconformities of regional extension. In fact, this new sedimentary cycle began after the definitive closure of the Ligurian ocean (Oceanic stage) and sedimentation continued durIng the subsequent development of a collisional margin (Ensialic stage) between the European and African Adriatic plates. The stratigraphic and structural features of the Apenmne margin between Tresinaro Valley and Lavino Valley are described brteflv in this paper. Moreover, the contact between the Ranzano Formation and the Antognola Formation, parts of the postorogenic Ligurian Sequence, is discussed in terms of the micropaleontologica] data obtained from three stratigraphical sections situated In the lower valley of the Secchia River. The contact coincides with an unconformity that is marked by a biostratigraphical hiatus. In fact, foraminifera] associations indicate that the top of the Ranzano Formation is attributable to Zone PI 8 (Lower Oligocene) and that the base of the Antognola Formation is already attributable to Zone P 21 (Upper Oligocene). There was no evidence of the presence of Zone PI 9/20. The chronological range of the hiatus is estimated as 2.4 to 1 0 Ma, depending upon the chronological scale adopted and the exact position of the "top" of the Ranzano Formation and the base of the Antognola Formation. On the basis of the stratigraphic relations existing among the various units of the postorogenic Ligurian Sequence outcropping in the studied area and on the basis of the data collected on the contact between the Ranzano Formation and Antognola Formation, it is clear that the hiatus is attributable to submarine erosion of a part of the turbiditic deposits of the Ranzano Formation, which are affected by pronounced tectono—sedimentary phenomena. The tectonic movements developed in the Ligurian domain in a per10d preceding the deposition of the Antognola Formation. They are thus contemporary with the beginning of the deposition of the Macigno in the Tuscan paleogeographical domain.