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Jupiters south polar region was observed by JWST Mid Infrared Instrument in December 2022. We used the Medium Resolution Spectrometer mode to provide new information about Jupiters South Polar stratosphere. The southern auroral region was visible and influenced the atmosphere in several ways. 1: In the interior of the southern auroral oval, we retrieved peak temperatures at two distinct pressure levels near 0.01 and 1 mbar, with warmer temperatures with respect to non auroral regions of 12 pm 2 K and 37 pm 4 K respectively. A cold polar vortex is centered at 65S at 10 mbar. 2: We found that the homopause is elevated to 590+25-118 km above the 1-bar pressure level inside the auroral oval compared to 460+60-50 km at neighboring latitudes and with an upper altitude of 350 km in regions not affected by auroral precipitation. 3: The retrieved abundance of C2H2 shows an increase within the auroral oval, and it exhibits high abundances throughout the polar region. The retrieved abundance of C2H6 increases towards the pole, without being localized in the auroral oval, in contrast with previous analysis. We determined that the warming at 0.01 mbar and the elevated homopause might be caused by the flux of charged particles depositing their energy in the South Polar Region. The 1 mbar hotspot may arise from adiabatic heating resulting from auroral driven downwelling. The cold region at 10 mbar may be caused by radiative cooling by stratospheric aerosols. The differences in spatial distribution seem to indicate that the hydrocarbons analyzed are affected differently by auroral precipitation.

The temperature structure of a giant planet was traditionally thought to be an adiabat assuming convective mixing homogenizes entropy. The only in-situ measurement made by the Galileo Probe detected a near-adiabatic temperature structure within one of Jupiter's 5$\mu$m hot spots with small but definite local departures from adiabaticity. We analyze Juno's microwave observations near Jupiter's equator (0 ~ 5$^o$N) and find that the equatorial temperature structure is best characterized by a stable super-adiabatic temperature profile rather than an adiabatic one. Water is the only substance with sufficient abundance to alter the atmosphere's mean molecular weight and prevent dynamic instability if a super-adiabatic temperature gradient exists. Thus, from the super-adiabaticity, our results indicate a water concentration (or the oxygen to hydrogen ratio) of about 4.9 times solar with a possible range of 1.5 ~ 8.3 times solar in Jupiter's equatorial region., Comment: 46 pages, 11 figures, accepted by Icraus

The study of planets and small bodies within our Solar System is fundamental for understanding the formation and evolution the Earth and other planets. Compositional and meteorological studies of the giant planets provide a foundation for understanding the nature of the most commonly observed exoplanets, while spectroscopic observations of the atmospheres of terrestrial planets, moons, and comets provide insights into the past and present-day habitability of planetary environments, and the availability of the chemical ingredients for life. While prior and existing (sub)millimeter observations have led to major advances in these areas, progress is hindered by limitations in the dynamic range, spatial and temporal coverage, as well as sensitivity of existing telescopes and interferometers. Here, we summarize some of the key planetary science use cases that factor into the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m class single dish facility: (1) to more fully characterize planetary wind fields and atmospheric thermal structures, (2) to measure the compositions of icy moon atmospheres and plumes, (3) to obtain detections of new, astrobiologically relevant gases and perform isotopic surveys of comets, and (4) to perform synergistic, temporally-resolved measurements in support of dedicated interplanetary space missions. The improved spatial coverage (several arcminutes), resolution ($\sim1.2''-12''$), bandwidth (several tens of GHz), dynamic range ($\sim10^5$) and sensitivity ($\sim1$ mK km s$^{-1}$) required by these science cases would enable new insights into the chemistry and physics of planetary environments, the origins of prebiotic molecules and the habitability of planetary systems in general., Comment: Submitted to Open Research Europe (AtLAST collection). 19 pages

We use an infrared dataset captured between 1984 and 2017 using several instruments and observatories to report five rare equatorial disturbances that completely altered the appearance of Jupiter's Equatorial Zone (EZ): the clearance of tropospheric clouds revealed a new 5-$\mu$m-bright band encircling the planet at the equator, accompanied by large 5-$\mu$m-bright filaments. Three events were observed in ground-based images in 1973, 1979 and 1992. We report and characterize for the first time the entire evolution of two new episodes of this unusual EZ state that presented their maximum 5-$\mu$m-brightness in December 1999 and February 2007, coinciding with a brown coloration south of the equator and with large bluish filaments and white plumes in the northern EZ at visible wavelengths. We characterize their typical infrared-bright lifetimes of 12-18 months, with possible periodicities of 6-8 or 13-14 years. We predict that a full-scale equatorial disturbance could occur in 2019-21.

Using images at multiple mid-infrared wavelengths, acquired in May 2018 using the VISIR instrument on ESO's Very Large Telescope (VLT), we study Jupiter's pole-to-pole thermal, chemical and aerosol structure in the troposphere and stratosphere. We confirm that the pattern of cool and cloudy anticyclonic zones and warm cloud-free cyclonic belts persists throughout the mid-latitudes, up to the polar boundaries, and evidence a strong correlation with the vertical maximum windshear and the locations of Jupiter's zonal jets. At high latitudes, VISIR images reveal a large region of mid-infrared cooling poleward $\sim$64$^{\circ}$N and $\sim$67$^{\circ}$S extending from the upper troposphere to the stratosphere, co-located with the reflective aerosols observed by JunoCam, and suggesting that aerosols play a key role in the radiative cooling at the poles. Comparison of zonal-mean thermal properties and high-resolution visible imaging from Juno allows us to study the variability of atmospheric properties as a function of altitude and jet boundaries, particularly in the cold southern polar vortex. However, the southern stratospheric polar vortex is partly masked by a warm mid-infrared signature of the aurora. Co-located with the southern main auroral oval, this warming results from the auroral precipitation and/or joule heating which heat the atmosphere and thus cause a significant stratospheric emission. This high emission results from a large enhancement of both ethane and acetylene in the polar region, reinforcing the evidence of enhanced ion-related chemistry in Jupiter's auroral regions.

Spectral observations of Neptune made in 2019 with the MUSE instrument at the Very Large Telescope in Chile have been analysed to determine the spatial variation of aerosol scattering properties and methane abundance in Neptune's atmosphere. The darkening of the South Polar Wave (SPW) at $\sim$ 60$^\circ$S, and dark spots such as the Voyager 2 Great Dark Spot is concluded to be due to a spectrally-dependent darkening ($\lambda < 650$nm) of particles in a deep aerosol layer at $\sim$ 5 bar and presumed to be composed of a mixture of photochemically-generated haze and H$_2$S ice. We also note a regular latitudinal variation of reflectivity at wavelengths of very low methane absorption longer than $\sim$ 650 nm, with bright zones latitudinally separated by $\sim$ 25$^\circ$. This feature, similar to the spectral characteristics of a discrete deep bright spot DBS-2019 found in our data, is found to be consistent with a brightening of the particles in the same $\sim$5-bar aerosol layer at $\lambda > 650 $ nm. We find the properties of an overlying methane/haze aerosol layer at $\sim$ 2 bar are, to first-order, invariant with latitude, while variations in the opacity of an upper tropospheric haze layer reproduce the observed reflectivity at methane-absorbing wavelengths, with higher abundances found at the equator and also in a narrow `zone' at $80^\circ$S. Finally, we find the mean abundance of methane below its condensation level to be 6--7% at the equator reducing to $\sim$3% south of $\sim$25$^\circ$S, although the absolute abundances are model dependent., Comment: 32 pages, 13 figures. Accepted in JGR: Planets

Saturn's northern summertime hemisphere was mapped by JWST/MIRI (4.9-27.9 $\mu$m) in November 2022, tracing the seasonal evolution of temperatures, aerosols, and chemical species in the five years since the end of the Cassini mission. The spectral region between reflected sunlight and thermal emission (5.1-6.8 $\mu$m) is mapped for the first time, enabling retrievals of phosphine, ammonia, and water, alongside a system of two aerosol layers (an upper tropospheric haze $p<0.3$ bars, and a deeper cloud layer at 1-2 bars). Ammonia displays substantial equatorial enrichment, suggesting similar dynamical processes to those found in Jupiter's equatorial zone. Saturn's North Polar Stratospheric Vortex has warmed since 2017, entrained by westward winds at $p<10$ mbar, and exhibits localised enhancements in several hydrocarbons. The strongest latitudinal temperature gradients are co-located with the peaks of the zonal winds, implying wind decay with altitude. Reflectivity contrasts at 5-6 $\mu$m compare favourably with albedo contrasts observed by Hubble, and several discrete vortices are observed. A warm equatorial stratospheric band in 2022 is not consistent with a 15-year repeatability for the equatorial oscillation. A stacked system of windshear zones dominates Saturn's equatorial stratosphere, and implies a westward equatorial jet near 1-5 mbar at this epoch. Lower stratospheric temperatures, and local minima in the distributions of several hydrocarbons, imply low-latitude upwelling and a reversal of Saturn's interhemispheric circulation since equinox. Latitudinal distributions of stratospheric ethylene, benzene, methyl and carbon dioxide are presented for the first time, and we report the first detection of propane bands in the 8-11 $\mu$m region., Comment: 53 pages, 25 figures, accepted for publication in JGR: Planets

Previous observations of dark vortices in Neptune's atmosphere, such as Voyager-2's Great Dark Spot, have been made in only a few, broad-wavelength channels, which has hampered efforts to pinpoint their pressure level and what makes them dark. Here, we present Very Large Telescope (Chile) MUSE spectrometer observations of Hubble Space Telescope's NDS-2018 dark spot, made in 2019. These medium-resolution 475 - 933 nm reflection spectra allow us to show that dark spots are caused by a darkening at short wavelengths (< 700 nm) of a deep ~5-bar aerosol layer, which we suggest is the H$_2$S condensation layer. A deep bright spot, named DBS-2019, is also visible on the edge of NDS-2018, whose spectral signature is consistent with a brightening of the same 5-bar layer at longer wavelengths (> 700 nm). This bright feature is much deeper than previously studied dark spot companion clouds and may be connected with the circulation that generates and sustains such spots., Comment: 1 table. 3 figures. Nature Astronomy (2023)

We present a study of the long term variability of Jupiter's mid-infrared auroral CH4 emissions. 7.7 - 7.9 micron images of Jupiter recorded by Earth-based telescopes over the last three decades were collated in order to quantify the magnitude and timescales over which the northern auroral hotspot's CH4 emissions varies. We find that the ratio of the radiance of the poleward northern auroral emissions to a lower-latitude zonal mean, henceforth 'Relative Poleward Radiance' or RPR, exhibits a 37% variability over a range of timescales. We searched for patterns of variability in order to test whether seasonally-varying solar insolation, the 11-year solar cycle, or short-term solar wind variability at Jupiter's magnetopause could explain the observed evolution. The variability of the RPR exhibits a weak (r < 0.2) correlation with the solar insolation received at Jupiter's high-northern latitudes. This rules out the hypothesis suggested in previous work (e.g. Sinclair et al., 2017a) that shortwave solar heating of aurorally-produced haze particles is the dominant heating mechanism in the lower stratosphere. We also find the variability exhibits negligible (r < 0.18) correlation with the monthly-mean sunspot number, which rules out variability associated with the solar cycle. On shorter timescales, we find moderate correlations of the RPR with solar wind conditions at Jupiter in the preceding days before images were recorded. For example, we find correlations of r = 0.45 and r = 0.51 of the RPR with the mean and standard deviation on the solar wind dynamical pressure in the preceding 7 days. The moderate correlation suggests that either: 1) only a subset of solar wind compressions lead to brighter, poleward, CH4 emissions and/or 2) a subset of CH4 emission brightening events are driven by internal magnetospheric and independent of the solar wind.

In this work we present, for the first time, infrared spectra of Titan from the Spitzer Space Telescope ($2004-2009$). The data are from both the short wavelength-low resolution (SL, $5.13-14.29\mathrm{\mu m}, R\sim60-127$) and short wavelength-high resolution channels (SH, $9.89 - 19.51\mathrm{\mu m}, R\sim600$) showing the emissions of CH$_{4}$, C$_{2}$H$_{2}$, C$_{2}$H$_{4}$, C$_{2}$H$_{6}$, C$_{3}$H$_{4}$, C$_{3}$H$_{6}$, C$_{3}$H$_{8}$, C$_{4}$H$_{2}$, HCN, HC$_{3}$N, and CO$_{2}$. We compare the results obtained for Titan from Spitzer to those of the Cassini Composite Infrared Spectrometer (CIRS) for the same time period, focusing on the $16.35-19.35\mathrm{\mu m}$ wavelength range observed by the SH channel but impacted by higher noise levels in CIRS observations. We use the SH data to provide estimated haze extinction cross-sections for the $16.67-17.54\mathrm{\mu m}$ range that are missing in previous studies. We conclude by identifying spectral features in the $16.35-19.35\mathrm{\mu m}$ wavelength range, including two prominent emission features at 16.39 and $17.35\mathrm{\mu m}$, that could be analyzed further through upcoming James Webb Space Telescope Cycle 1 observations with the Mid-Infrared Instrument ($5.0-28.3\mathrm{\mu m}, R\sim1500-3500$). We also highlight gaps in current spectroscopic knowledge of molecular bands, including candidate trace species such as C$_{60}$ and detected trace species such as C$_{3}$H$_{6}$, that could be addressed by theoretical and laboratory study., Comment: Accepted to Planetary Science Journal April 28, 2023

ESA's Jupiter Icy Moons Explorer (JUICE) will provide a detailed investigation of the Jovian system in the 2030s, combining a suite of state-of-the-art instruments with an orbital tour tailored to maximise observing opportunities. We review the Jupiter science enabled by the JUICE mission, building on the legacy of discoveries from the Galileo, Cassini, and Juno missions, alongside ground- and space-based observatories. We focus on remote sensing of the climate, meteorology, and chemistry of the atmosphere and auroras from the cloud-forming weather layer, through the upper troposphere, into the stratosphere and ionosphere. The Jupiter orbital tour provides a wealth of opportunities for atmospheric and auroral science: global perspectives with its near-equatorial and inclined phases, sampling all phase angles from dayside to nightside, and investigating phenomena evolving on timescales from minutes to months. The remote sensing payload spans far-UV spectroscopy (50-210 nm), visible imaging (340-1080 nm), visible/near-infrared spectroscopy (0.49-5.56 $\mu$m), and sub-millimetre sounding (near 530-625\,GHz and 1067-1275\,GHz). This is coupled to radio, stellar, and solar occultation opportunities to explore the atmosphere at high vertical resolution; and radio and plasma wave measurements of electric discharges in the Jovian atmosphere and auroras. Cross-disciplinary scientific investigations enable JUICE to explore coupling processes in giant planet atmospheres, to show how the atmosphere is connected to (i) the deep circulation and composition of the hydrogen-dominated interior; and (ii) to the currents and charged particle environments of the external magnetosphere. JUICE will provide a comprehensive characterisation of the atmosphere and auroras of this archetypal giant planet., Comment: 83 pages, 24 figures, accepted to Space Science Reviews special issue on ESA's JUICE mission

We present mid-infrared spectroscopy of Jupiter's mid-to-high latitudes using Gemini-North/TEXES (Texas Echelon Cross Echelle Spectrograph) on March 17-19, 2017. These observations capture Jupiter's hydrocarbon auroral emissions before, during and after the arrival of a solar wind compression on March 18th, which highlights the coupling between the polar stratosphere and external space environment. In comparing observations on March 17th and 19th, we observe a brightening of the CH$_4$, C$_2$H$_2$ and C$_2$H$_4$ emissions in regions spatially coincident with the northern, duskside main auroral emission (henceforth, MAE). In inverting the spectra to derive atmospheric information, we determine that the duskside brightening results from an upper stratospheric (p < 0.1 mbar/z > 200 km) heating (e.g. $\Delta T$ = 9.1 $\pm$ 2.1 K at 9 $\mu$bar at 67.5$^\circ$N, 162.5$^\circ$W) with negligible heating at deeper pressures. Our interpretation is that the arrival of the solar wind enhancement drove magnetospheric dynamics through compression and/or viscous interactions on the flank. These dynamics accelerated currents and/or generated higher Poynting fluxes, which ultimately warmed the atmosphere through Joule heating and ion-neutral collisions. Poleward of the southern MAE, temperature retrievals demonstrate that auroral-related heating penetrates as deep as the 10-mbar level, in contrast to poleward of the northern MAE, where heating is only observed as deep as $\sim$3 mbar. We suggest this results from the south having higher Pedersen conductivities, and therefore stronger currents and acceleration of the neutrals, as well as the poleward heating overlapping with the apex of Jupiter's circulation thereby inhibiting efficient horizontal mixing/advection.

Jupiter's weather layer exhibits long-term and quasi-periodic cycles of meteorological activity that can completely change the appearance of its belts and zones. There are cycles with intervals from 4 to 9 years, dependent on the latitude, which were detected in 5$\mu$m radiation, which provides a window into the cloud-forming regions of the troposphere; however, the origin of these cycles has been a mystery. Here we propose that magnetic torsional oscillations/waves arising from the dynamo region could modulate the heat transport and hence be ultimately responsible for the variability of the tropospheric banding. These axisymmetric waves are magnetohydrodynamic waves influenced by the rapid rotation, which have been detected in Earth's core, and have been recently suggested to exist in Jupiter by the observation of magnetic secular variations by Juno. Using the magnetic field model JRM33, together with the density distribution model, we compute the expected speed of these waves. For the waves excited by variations in the zonal jet flows, their wavelength can be estimated from the width of the alternating jets, yielding waves with a half period of 3.2-4.7 years in 14-23$^\circ$N, consistent with the intervals with the cycles of variability of Jupiter's North Equatorial Belt and North Temperate Belt identified in the visible and infrared observations. The nature of these waves, including the wave speed and the wavelength, is revealed by a data-driven technique, dynamic mode decomposition, applied to the spatio-temporal data for 5$\mu$m emission. Our results imply that exploration of these magnetohydrodynamic waves may provide a new window to the origins of quasi-periodic patterns in Jupiter's tropospheric clouds and to the internal dynamics and the dynamo of Jupiter.

We present a retrospective analysis of Earth-based mid-infrared observations of Jupiter capturing the aftermath of the impacts by Comet D/Shoemaker-Levy 9 (henceforth SL9) in July 1994 and the Wesley impactor in July 2009. While the atmospheric effects of both impacts have been reported previously, we were motivated to re-examine both events using consistent methods to enable robust, quantitative comparisons. We analyzed spectrophotometry and spectroscopy capturing both impacts using two independent analyses: 1) a least-squares search over a grid of candidate mineral species to determine the composition of impact residue and 2) a radiative transfer analysis to derive atmospheric information. We observe that the SL9 impact sites are enhanced in stratospheric CH4 emissions at 7.9 um, due to shock heating and adiabatic compression from plume re-entry, and from 8.5 - 11.5 um due to stratospheric NH3 emission and non-gaseous cometary material. We derive NH3 concentrations of 5.7 ppmv at 30 mbar. In new findings, we find that the SL9 impact sites also exhibit a non-gaseous emission feature at 18 - 19 um. The non-gaseous emission at 8.5 - 11.5 and 18 - 19 um emission is best reproduced by predominantly amorphous olivine and obsidian at similar abundances. The Wesley impact site exhibits enhanced emissions from 8.8 - 11.5 and 18 - 19 um. We found this could be reproduced by predominantly amorphous olivine and stratospheric NH3 at concentrations of 150 ppbv at 30 mbar. Stratospheric NH3 abundances are a factor of 40 higher in the SL9 impacts compared to the Wesley impact, which confirms the former reached deeper, NH3-richer altitudes of the atmosphere. The absence of silicas in the Wesley impact would place an upper limit of 10 km/s on the incident velocity and 9 degree on the entry angle of the impactor such that temperatures were insufficient to convert silicates.

A multi-decade record of ground-based mid-infrared (7-25 $\mu$m) images of Saturn is used to explore seasonal and non-seasonal variability in thermal emission over more than a Saturnian year (1984-2022). Thermal emission measured by 3-m and 8-m-class observatories compares favourably with synthetic images based on both Cassini-derived temperature records and the predictions of radiative climate models. 8-m class facilities are capable of resolving thermal contrasts on the scale of Saturn's belts, zones, polar hexagon, and polar cyclones, superimposed onto large-scale seasonal asymmetries. Seasonal changes in brightness temperatures of $\sim30$ K in the stratosphere and $\sim10$ K in the upper troposphere are observed, as the northern and southern polar stratospheric vortices (NPSV and SPSV) form in spring and dissipate in autumn. The timings of the first appearance of the warm polar vortices is successfully reproduced by radiative climate models, confirming them to be radiative phenomena, albeit entrained within sharp boundaries influenced by dynamics. Axisymmetric thermal bands (4-5 per hemisphere) display temperature gradients that are strongly correlated with Saturn's zonal winds, indicating winds that decay in strength with altitude, and implying meridional circulation cells forming the system of cool zones and warm belts. Saturn's thermal structure is largely repeatable from year to year (via comparison of infrared images in 1989 and 2018), with the exception of low-latitudes. Here we find evidence of inter-annual variations because the equatorial banding at 7.9 $\mu$m is inconsistent with a $\sim15$-year period for Saturn's equatorial stratospheric oscillation, i.e., it is not strictly semi-annual. Finally, observations between 2017-2022 extend the legacy of the Cassini mission, revealing the continued warming of the NPSV during northern summer. [Abr.], Comment: 25 pages, 15 figures, accepted for publication in Icarus

During the Grand Finale stage of the Cassini mission, organic-rich ring material was discovered to be flowing into Saturn's equatorial upper atmosphere at a surprisingly large rate. Through a series of photochemical models, we have examined the consequences of this ring material on the chemistry of Saturn's neutral and ionized atmosphere. We find that if a substantial fraction of this material enters the atmosphere as vapor or becomes vaporized as the solid ring particles ablate upon atmospheric entry, then the ring-derived vapor would strongly affect the composition of Saturn's ionosphere and neutral stratosphere. Our surveys of Cassini infrared and ultraviolet remote-sensing data from the final few years of the mission, however, reveal none of these predicted chemical consequences. We therefore conclude that either (1) the inferred ring influx represents an anomalous, transient situation that was triggered by some recent dynamical event in the ring system that occurred a few months to a few tens of years before the 2017 end of the Cassini mission, or (2) a large fraction of the incoming material must have been entering the atmosphere as small dust particles less than ~100 nm in radius, rather than as vapor or as large particles that are likely to ablate. Future observations or upper limits for stratospheric neutral species such as HC$_3$N, HCN, and CO$_2$ at infrared wavelengths could shed light on the origin, timing, magnitude, and nature of a possible vapor-rich ring-inflow event., Comment: accepted in Icarus

This chapter of the Planetary Exploration Horizon 2061 Report reviews the way the six key questions about planetary systems, from their origins to the way they work and their habitability, identified in chapter 1, can be addressed by means of solar system exploration, and how one can find partial answers to these six questions by flying to the different provinces to the solar system: terrestrial planets, giant planets, small bodies, and up to its interface with the local interstellar medium. It derives from this analysis a synthetic description of the most important space observations to be performed at the different solar system objects by future planetary exploration missions. These observation requirements illustrate the diversity of measurement techniques to be used as well as the diversity of destinations where these observations must be made. They constitute the base for the identification of the future planetary missions we need to fly by 2061, which are described in chapter 4. Q1- How well do we understand the diversity of planetary systems objects? Q2- How well do we understand the diversity of planetary system architectures? Q3- What are the origins and formation scenarios for planetary systems? Q4- How do planetary systems work? Q5- Do planetary systems host potential habitats? Q6- Where and how to search for life?, Comment: 107 pages, 37 figures, Horizon 2061 is a science-driven, foresight exercise, for future scientific investigations

An essential component of planetary climatology is knowledge of the tropospheric temperature field and its variability. Previous studies of Jupiter hinted at periodic behavior that was non-seasonal, as well as dynamical relationships between tropospheric and stratospheric temperatures. However, these observations were made over time frames shorter than Jupiter's orbit or they used sparse sampling. We derived upper-tropospheric (300-mbar) temperatures over 40 years, extending those studies to cover several orbits of Jupiter, revealing unexpected results. Periodicities of 4, 7 8-9 and 10-14 years were discovered that involved different latitude bands and seem disconnected from seasonal changes in solar heating. Anti-correlations of variability in opposite hemispheres were particularly striking at 16, 22 and 30 degrees from the equator. Equatorial temperature variations are also anticorrelated with those 60-70 km above. Such behavior suggests a top-down control of equatorial tropospheric temperatures from stratospheric dynamics. Realistic future global climate models must address the origins of these variations in preparation for their extension to a wider array of gas-giant exoplanets., Comment: Primary file: 16 pages, 5 figures. Supplemental File (attached): 12 pages, 3 figures, 1 table

We present maps of Ganymede's surface composition with almost complete longitude coverage, acquired using high spatial resolution near-infrared (0.95 to 1.65$\mu m$) observations from the ground-based VLT/SPHERE instrument. Observed reflectance spectra were modelled using a Markov Chain Monte Carlo method to estimate abundances and associated uncertainties of water ices, acids, salts and a spectrally-flat darkening agent. Results confirm Ganymede's surface is dominated by water ice in young bright terrain (impact craters, sulci), and low-albedo spectrally-flat material in older dark terrain (e.g. Galileo Regio). Ice grain size has strong latitudinal and longitudinal gradients, with larger grains at the equator and on the trailing hemisphere. These trends are consistent with the effects of the latitudinal thermal gradient and global variations in radiation driven sputtering. Sulphuric acid has a low abundance and appears potentially spatially correlated with plasma bombardment, where Ganymede's poles are exposed to the external jovian magnetic field. Best-estimate abundances suggest a mixture of salts could be present, although their low abundances, spectral degeneracies and associated uncertainties mean individual salt species cannot be detected with confidence. If present, sodium magnesium sulphate and magnesium chlorate appear tentatively correlated with exogenic plasma bombardment, while magnesium chloride and sulphate appear tentatively correlated with younger terrain, implying a possible endogenic origin. MCMC modelling was also performed on Galileo/NIMS data, showing comparable distributions. The high spatial resolution of SPHERE allows the precise mapping of small scale (<150km) surface features, which could be used along with higher spectral resolution observations to jointly confirm the presence and distribution of potential species., Comment: To be published in JGR: Planets

The thermal structure of planetary atmospheres is an essential input for predicting and retrieving the distribution of gases and aerosols, as well as the bulk chemical abundances. In the case of Jupiter, the temperature at a reference level - generally taken at 1 bar - serves as the anchor in models used to derive the planet's interior structure and composition. Most models assume the temperature measured by the Galileo probe (Seiff et al. 1998). However, those data correspond to a single location, an unusually clear, dry region, affected by local atmospheric dynamics. On the other hand, the Voyager radio occultation observations cover a wider range of latitudes, longitudes, and times (Lindal et al. 1981). The Voyager retrievals were based on atmospheric composition and radio refractivity data that require updating and were never properly tabulated: the few existing tabulations are incomplete and ambiguous. Here, we present a systematic electronic digitization of all available temperature profiles from Voyager, followed by their reanalysis, employing currently accepted values of the abundances and radio refractivities of atmospheric species. We find the corrected temperature at the 1 bar level to be up to 4 K greater than previously published values, i.e., 170.3{\pm}3.8 K at 12{\deg}S (Voyager 1 ingress) and 167.3{\pm}3.8 K at 0{\deg}N (Voyager 1 egress). This is to be compared with the Galileo probe value of 166.1{\pm}0.8 K at the edge of an unusual feature at 6.57{\deg}N. Altogether, this suggests that Jupiter's tropospheric temperatures may vary spatially by up to 7 K between 7{\deg}N and 12{\deg}S., Comment: 11 pages, 3 figures

Giant planets acquire gas, ices and rocks during the early formation stages of planetary systems and thus inform us on the formation process itself. Proceeding from inside out, examining the connections between the deep interiors and the observable atmospheres, linking detailed measurements on giant planets in the solar system to the wealth of data on brown dwarfs and giant exoplanets, we aim to provide global constraints on interiors structure and composition for models of the formation of these planets. New developments after the Juno and Cassini missions point to both Jupiter and Saturn having strong compositional gradients and stable regions from the atmosphere to the deep interior. This is also the case of Uranus and Neptune, based on available, limited data on these planets. Giant exoplanets and brown dwarfs provide us with new opportunities to link atmospheric abundances to bulk, interior abundances \rev{and to link these abundances and isotopic ratios to formation scenarios. Analysing the wealth of data becoming available} will require new models accounting for the complexity of the planetary interiors and atmospheres, Comment: 40 pages, 16 figures. Review chapter submitted to Protostars and Planets VII, Editors: Shu-ichiro Inutsuka, Yuri Aikawa, Takayuki Muto, Kengo Tomida, and Motohide Tamura

We present maps of surface composition of Europa's anti-jovian hemisphere acquired using high spatial resolution IFU multi-spectral data from the SPHERE instrument on the Very Large Telescope (0.95 to 1.65$\mu$m) and the NIMS instrument on the Galileo orbiter (0.7 to 5.2$\mu$m). Spectral modelling was performed using a Markov Chain Monte Carlo method to estimate endmember abundances and to quantify their associated uncertainties. Modelling results support the leading-trailing hemisphere difference in hydrated sulphuric acid abundances caused by exogenic plasma bombardment. Water ice grains are found to be in the 100$\mu$m to 1mm range, with larger grains present on the trailing hemisphere, consistent with radiation driven sputtering destroying smaller grains. Modelling best estimates suggest a mixture of sulphate and chlorinated salts, although uncertainties derived from the MCMC modelling suggest that it is difficult to confidently detect individual salt abundances with low spectral resolution spectra from SPHERE and NIMS. The high spatial resolution offered by SPHERE allows the small scale spatial distribution (<150km) of potential species to be mapped, including ground-based detection of lineae and impact features. This could be used in combination with other higher spectral resolution observations to confirm the presence of these species.

We present a reanalysis (using the Minnaert limb-darkening approximation) of visible/near-infrared (0.3 - 2.5 micron) observations of Uranus and Neptune made by several instruments. We find a common model of the vertical aerosol distribution that is consistent with the observed reflectivity spectra of both planets, consisting of: 1) a deep aerosol layer with a base pressure > 5-7 bar, assumed to be composed of a mixture of H2S ice and photochemical haze; 2) a layer of photochemical haze/ice, coincident with a layer of high static stability at the methane condensation level at 1-2 bar; and 3) an extended layer of photochemical haze, likely mostly of the same composition as the 1-2-bar layer, extending from this level up through to the stratosphere, where the photochemical haze particles are thought to be produced. For Neptune, we find that we also need to add a thin layer of micron-sized methane ice particles at ~0.2 bar to explain the enhanced reflection at longer methane-absorbing wavelengths. We suggest that methane condensing onto the haze particles at the base of the 1-2-bar aerosol layer forms ice/haze particles that grow very quickly to large size and immediately 'snow out' (as predicted by Carlson et al. 1988), re-evaporating at deeper levels to release their core haze particles to act as condensation nuclei for H2S ice formation. In addition, we find that the spectral characteristics of 'dark spots', such as the Voyager-2/ISS Great Dark Spot and the HST/WFC3 NDS-2018, are well modelled by a darkening or possibly clearing of the deep aerosol layer only., Comment: 58 pages, 23 figures, 4 tables

We present an analysis of all currently available ground-based imaging of Neptune in the mid-infrared. Dating between 2003 and 2020, the images reveal changes in Neptune's mid-infrared ($\sim 8-25\mu$m) emission over time in the years surrounding Neptune's 2005 southern summer solstice. Images sensitive to stratospheric ethane ($\sim12\mu$m), methane ($\sim8\mu$m), and CH$_3$D ($\sim9\mu$m) display significant sub-seasonal temporal variation on regional and global scales. Comparison with H$_2$ S(1) hydrogen-quadrupole ($\sim17.035\mu$m) spectra suggests these changes are primarily related to stratospheric temperature changes. The stratosphere appears to have cooled between 2003 and 2009 across multiple filtered wavelengths, followed by a dramatic warming of the south pole between 2018 and 2020. Conversely, upper-tropospheric temperatures -- inferred from $\sim 17-25$-micron imaging -- appear invariant during this period, except for the south pole, which appeared warmest between 2003 and 2006. We discuss the observed variability in the context of seasonal forcing, tropospheric meteorology, and the solar cycle. Collectively, these data provide the strongest evidence to date that processes produce sub-seasonal variation on both global and regional scales in Neptune's stratosphere., Comment: 52 pages, 29 figures, accepted to AAS journals (PSJ)

Jupiter's atmosphere is dominated by multiple jet streams which are strongly tied to its 3D atmospheric circulation. Lacking a rigid bottom boundary, several models exist for how the meridional circulation extends into the planetary interior. Here we show, collecting evidence from multiple instruments of the Juno mission, the existence of mid-latitudinal meridional circulation cells which are driven by turbulence, similar to the Ferrel cells on Earth. Different than Earth, which contains only one such cell in each hemisphere, the larger, faster rotating Jupiter can incorporate multiple cells. The cells form regions of upwelling and downwelling, which we show are clearly evident in Juno's microwave data between latitude 60S and 60N. The existence of these cells is confirmed by reproducing the ammonia observations using a simplistic model. This study solves a long-standing puzzle regarding the nature of Jupiter's sub-cloud dynamics and provides evidence for 8 cells in each Jovian hemisphere., Comment: 13 pages, 5 figures, Supporting information. Accepted to Geophysical Research Letters

The abundance of deuterium in giant planet atmospheres provides constraints on the reservoirs of ices incorporated into these worlds during their formation and evolution. Motivated by discrepancies in the measured deuterium-hydrogen ratio (D/H) on Jupiter and Saturn, we present a new measurement of the D/H ratio in methane for Saturn from ground-based measurements. We analysed a spectral cube (covering 1151-1160 cm$^{-1}$ from 6 February 2013) from the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA's Infrared Telescope Facility (IRTF) where emission lines from both methane and deuterated methane are well resolved. Our estimate of the D/H ratio in stratospheric methane, $1.65_{-0.21}^{+0.27} \times 10^{-5}$ is in agreement with results derived from Cassini CIRS and ISO/SWS observations, confirming the unexpectedly low CH$_{3}$D abundance. Assuming a fractionation factor of $1.34 \pm 0.19$ we derive a hydrogen D/H of $1.23_{-0.23}^{+0.27} \times 10^{-5}$. This value remains lower than previous tropospheric hydrogen D/H measurements of (i) Saturn $2.10 (\pm 0.13) \times 10^{-5}$, (ii) Jupiter $2.6 (\pm 0.7) \times 10^{-5}$ and (iii) the proto-solar hydrogen D/H of $2.1 (\pm 0.5) \times 10^{-5}$, suggesting that the fractionation factor may not be appropriate for stratospheric methane, or that the D/H ratio in Saturn's stratosphere is not representative of the bulk of the planet., Comment: 9 pages, 6 figures, 1 table

The UVS instrument on the Juno mission records far-ultraviolet reflected sunlight from Jupiter. These spectra are sensitive to the abundances of chemical species in the upper atmosphere and to the distribution of the stratospheric haze layer. We combine observations from the first 30 perijoves of the mission in order to study the meridional distribution of acetylene (C$_2$H$_2$) in Jupiter's stratosphere. We find that the abundance of C$_2$H$_2$ decreases towards the poles by a factor of 2-4, in agreement with previous analyses of mid-infrared spectra. This result is expected from insolation rates: near the equator, the UV solar flux is higher, allowing more C$_2$H$_2$ to be generated from the UV photolysis of CH$_4$. The decrease in abundance towards the poles suggests that horizontal mixing rates are not rapid enough to homogenize the latitudinal distribution., Comment: Accepted in JGR Planets. 19 pages, 3 figures

Uranus provides a unique laboratory to test our understanding of planetary atmospheres under extreme conditions. Multi-spectral observations from Voyager, ground-based observatories, and space telescopes have revealed a delicately banded atmosphere punctuated by storms, waves, and dark vortices, evolving slowly under the seasonal influence of Uranus' extreme axial tilt. Condensables like methane and hydrogen sulphide play a crucial role in shaping circulation, clouds, and storm phenomena via latent heat release through condensation, strong equator-to-pole gradients suggestive of equatorial upwelling and polar subsidence, and through forming stabilising layers that may decouple different circulation and convective regimes as a function of depth. Weak vertical mixing and low atmospheric temperatures associated with Uranus' negligible internal heat means that stratospheric methane photochemistry occurs in a unique high-pressure regime, decoupled from the influx of external oxygen. The low homopause also allows for the formation of an extensive ionosphere. Finally, the atmosphere provides a window on the bulk composition of Uranus - the ice-to-rock ratio, supersolar elemental and isotopic enrichments inferred from remote sensing and future \textit{in situ} measurements - providing key insights into its formation and subsequent migration. This review reveals the state of our knowledge of the time-variable circulation, composition, meteorology, chemistry, and clouds on this enigmatic `Ice Giant,' summarising insights from more than three decades of observations, and highlighting key questions for the next generation of planetary missions. As a hydrogen-dominated, intermediate-sized, and chemically-enriched world, Uranus could be our closest and best example of atmospheric processes on a class of worlds that may dominate the census of planets beyond our own Solar System., Comment: Invited review submitted for publication in the Oxford Research Encyclopedia of Planetary Science. Oxford University Press. Comments welcome

NASA's Spitzer Infrared Spectrometer (IRS) acquired mid-infrared (5-37 microns) disc-averaged spectra of Uranus very near to its equinox in December 2007. A mean spectrum was constructed from observations of multiple central meridian longitudes, spaced equally around the planet, which has provided the opportunity for the most comprehensive globally-averaged characterisation of Uranus' temperature and composition ever obtained (Orton et al., 2014 a [arXiv:1407.2120], b [arXiv:1407.2118]). In this work we analyse the disc-averaged spectra at four separate central meridian longitudes to reveal significant longitudinal variability in thermal emission occurring in Uranus' stratosphere during the 2007 equinox. We detect a variability of up to 15% at wavelengths sensitive to stratospheric methane, ethane and acetylene at the ~0.1-mbar level. The tropospheric hydrogen-helium continuum and deuterated methane absorption exhibit a negligible variation (less than 2%), constraining the phenomenon to the stratosphere. Building on the forward-modelling analysis of the global average study, we present full optimal estimation inversions (using the NEMESIS retrieval algorithm, Irwin et al., 2008 [10.1016/j.jqsrt.2007.11.006]) of the Uranus-2007 spectra at each longitude to distinguish between thermal and compositional variability. We found that the variations can be explained by a temperature change of less than 3 K in the stratosphere. Near-infrared observations from Keck II NIRC2 in December 2007 (Sromovsky et al., 2009 [arXiv:1503.01957], de Pater et al., 2011 [10.1016/j.icarus.2011.06.022]), and mid-infrared observations from VLT/VISIR in 2009 (Roman et al., 2020 [arXiv:1911.12830]), help to localise the potential sources to either large scale uplift or stratospheric wave phenomena., Comment: 26 pages, 21 figures, to be published in Icarus (accepted 2021-04-27)

In its 16 years of scientific measurements, the Spitzer Space Telescope performed a number of ground-breaking infrared measurements of Solar System objects. In this second of two papers, we describe results from Spitzer observations of asteroids, dust rings, and planets that provide new insight into the formation and evolution of our Solar System. The key Spitzer results presented here can be grouped into three broad classes: characterizing the physical properties of asteroids, notably including a large survey of Near Earth Objects; detection and characterization of several dust/debris disks in the Solar System; and comprehensive characterization of ice giant (Uranus, Neptune) atmospheres. Many of these observations provide critical foundations for future infrared space-based observations., Comment: Published in Nature Astronomy, Volume 4, page 940. This arXiv version pre-dates the proofs corrections; the final published version is available at https://rdcu.be/b8fgs [Updated on October 28 to get the right figures in this version]

This white paper, written in support of NASA's 2023-2032 Planetary Decadal Survey, outlines 10 major questions that focus on the origin, evolution, and current processes that shape the atmospheres of Uranus and Neptune. Prioritizing these questions over the next decade will greatly improve our understanding of this unique class of planets, which have remained largely unexplored since the Voyager flybys. Studying the atmospheres of the Ice Giants will greatly inform our understanding of the origin and evolution of the solar system as a whole, in addition to the growing number of exoplanetary systems that contain Neptune-mass planets., Comment: 8 pages, 0 figures, White Paper submitted to the Astrobiology and Planetary Science Decadal Survey

The National Academy Committee on Astrobiology and Planetary Science (CAPS) made a recommendation to study a large/medium-class dedicated space telescope for planetary science, going beyond the Discovery-class dedicated planetary space telescope endorsed in Visions and Voyages. Such a telescope would observe targets across the entire solar system, engaging a broad spectrum of the science community. It would ensure that the high-resolution, high-sensitivity observations of the solar system in visible and UV wavelengths revolutionized by the Hubble Space Telescope (HST) could be extended. A dedicated telescope for solar system science would: (a) transform our understanding of time-dependent phenomena in our solar system that cannot be studied currently under programs to observe and visit new targets and (b) enable a comprehensive survey and spectral characterization of minor bodies across the solar system, which requires a large time allocation not supported by existing facilities. The time-domain phenomena to be explored are critically reliant on high spatial resolution UV-visible observations. This paper presents science themes and key questions that require a long-lasting space telescope dedicated to planetary science that can capture high-quality, consistent data at the required cadences that are free from effects of the terrestrial atmosphere and differences across observing facilities. Such a telescope would have excellent synergy with astrophysical facilities by placing planetary discoveries made by astrophysics assets in temporal context, as well as triggering detailed follow-up observations using larger telescopes. The telescope would support future missions to the Ice Giants, Ocean Worlds, and minor bodies across the solar system by placing the results of such targeted missions in the context of longer records of temporal activities and larger sample populations., Comment: A whitepaper submitted to the Planetary Science Decadal Survey

We advocate for a mission concept study for a space telescope dedicated to solar system science in Earth orbit. Such a study was recommended by the Committee on Astrobiology and Planetary Science (CAPS) report "Getting Ready for the Next Planetary Science Decadal Survey." The Mid-Decadal Review also recommended NASA to assess the role and value of space telescopes for planetary science. The need for high-resolution, UV-Visible capabilities is especially acute for planetary science with the impending end of the Hubble Space Telescope (HST); however, NASA has not funded a planetary telescope concept study, and the need to assess its value remains. Here, we present potential design options that should be explored to inform the decadal survey., Comment: Whitepaper submitted to Planetary Science and Astrobiology Decadal Survey

At wavelengths between 0.15 and 0.19 $\mu$m, the far-ultraviolet spectrum of Jupiter is dominated by the scattered solar spectrum, attenuated by molecular absorptions primarily by acetylene and ethane, and to a lesser extent ammonia and phosphine. We describe the development of our radiative transfer code that enables the retrieval of abundances of these molecular species from ultraviolet reflectance spectra. As a proof-of-concept we present an analysis of Cassini Ultraviolet Imaging Spectrograph (UVIS) observations of the disk of Jupiter during the 2000/2001 flyby. The ultraviolet-retrieved acetylene abundances in the upper stratosphere are lower than those predicted by models based solely on infrared thermal emission from the mid-stratosphere observed by the Composite Infrared Spectrometer (CIRS), requiring an adjustment to the vertical profiles above 1 mbar. We produce a vertical acetylene abundance profile that is compatible with both CIRS and UVIS, with reduced abundances at pressures $<$1 mbar: the 0.1 mbar abundances are $1.21 \pm 0.07$ ppm for acetylene and $20.8 \pm 5.1$ ppm for ethane. Finally, we perform a sensitivity study for the JUICE UVS instrument, which has extended wavelength coverage out to 0.21 $\mu$m, enabling the retrieval of ammonia and phosphine abundances, in addition to acetylene and ethane., Comment: Accepted for publication in The Astronomical Journal 28 pages, 23 figures, 3 tables

The distant ice giants of the Solar System, Uranus and Neptune, have only been visited by one space mission, Voyager 2. The current knowledge on their composition remains very limited despite some recent advances. A better characterization of their composition is however essential to constrain their formation and evolution, as a significant fraction of their mass is made of heavy elements, contrary to the gas giants Jupiter and Saturn. An in situ probe like Galileo would provide us with invaluable direct ground-truth composition measurements. However, some of the condensibles will remain out of the grasp of a shallow probe. While additional constraints could be obtained from a complementary orbiter, thermochemistry and diffusion modeling can further help us to increase the science return of an in situ probe., Comment: Accepted for publication in Space Science Reviews

Recent work by Sromovsky et al. (2017, Icarus 291, 232-244) suggested that all red colour in Jupiter's atmosphere could be explained by a single colour-carrying compound, a so-called 'universal chromophore'. We tested this hypothesis on ground-based spectroscopic observations in the visible and near-infrared (480-930 nm) from the VLT/MUSE instrument between 2014 and 2018, retrieving a chromophore absorption spectrum directly from the North Equatorial Belt, and applying it to model spatial variations in colour, tropospheric cloud and haze structure on Jupiter. We found that we could model both the belts and the Great Red Spot of Jupiter using the same chromophore compound, but that this chromophore must exhibit a steeper blue-absorption gradient than the proposed chromophore of Carlson et al. (2016, Icarus 274, 106-115). We retrieved this chromophore to be located no deeper than 0.2+/-0.1 bars in the Great Red Spot and 0.7+/-0.1 bars elsewhere on Jupiter. However, we also identified some spectral variability between 510 nm and 540 nm that could not be accounted for by a universal chromophore. In addition, we retrieved a thick, global cloud layer at 1.4+/-0.3 bars that was relatively spatially invariant in altitude across Jupiter. We found that this cloud layer was best characterised by a real refractive index close to that of ammonia ice in the belts and the Great Red Spot, and poorly characterised by a real refractive index of 1.6 or greater. This may be the result of ammonia cloud at higher altitude obscuring a deeper cloud layer of unknown composition., Comment: 14 figures + 4 tables, preprint accepted by Icarus on the 29th of November 2019

We present results from mid-infrared imaging of Uranus at wavelengths of 13.0 micron and 18.7 micron, sensing emission from the stratosphere and upper troposphere, acquired using the VISIR instrument at the Very Large Telescope (VLT), September 4-October 20, 2018. Using a combination of inverse and forward modeling, we analyze these northern mid-spring (L_s~46) images and compare them to archival data to assess seasonal changes since the 1986 southern solstice and subsequent equinox. We find the data are consistent with little change (< 0.3 K) in the upper tropospheric temperature structure, extending the previous conclusions of Orton et al (2015) well past equinox, with only a subtle increase in temperature at the emerging north pole. Additionally, spatial-temporal variations in 13 micron stratospheric emission are investigated for the first time, revealing meridional variation and a hemispheric asymmetry not predicted by models. Finally, we investigate the nature of the stratospheric emission and demonstrate that the observed distribution appears related and potentially coupled to the underlying tropospheric emission six scale heights below. The observations are consistent with either mid-latitude heating or an enhanced abundance of acetylene. Considering potential mechanisms and additional observations, we favor a model of acetylene enrichment at mid-latitudes resulting from an extension of the upper-tropospheric circulation, which appears capable of transporting methane from the troposphere, through the cold trap, and into the stratosphere for subsequent photolysis to acetylene., Comment: 22 pages, 17 figures; Accepted for publication in The Astronomical Journal

We obtained the first maps of Jupiter at 1-3 mm wavelength with the Atacama Large Millimeter/Submillimeter Array (ALMA) on 3-5 January 2017, just days after an energetic eruption at 16.5S jovigraphic latitude had been reported by the amateur community, and about 2-3 months after the detection of similarly energetic eruptions in the northern hemisphere, at 22.2-23.0N. Our observations, probing below the ammonia cloud deck, show that the erupting plumes in the SEB bring up ammonia gas from the deep atmosphere. While models of plume eruptions that are triggered at the water condensation level explain data taken at uv-visible and mid-infrared wavelengths, our ALMA observations provide a crucial, hitherto missing, link in the moist convection theory by showing that ammonia gas from the deep atmosphere is indeed brought up in these plumes. Contemporaneous HST data show that the plumes reach altitudes as high as the tropopause. We suggest that the plumes at 22.2-23.0N also rise up well above the ammonia cloud deck, and that descending air may dry the neighboring belts even more than in quiescent times, which would explain our observations in the north., Comment: 28 pages, 12 figures, 4 tables

Atmospheric circulation patterns derived from multi-spectral remote sensing can serve as a guide for choosing a suitable entry site for a future in situ probe mission. Since the Voyager-2 flybys in the 1980s, three decades of observations from ground- and space-based observatories have generated a picture of Ice Giant circulation that is complex, perplexing, and altogether unlike that seen on the Gas Giants. This review seeks to reconcile the various competing circulation patterns from an observational perspective, accounting for spatially-resolved measurements of: zonal albedo contrasts and banded appearances; cloud-tracked zonal winds; temperature and para-H$_2$ measurements above the condensate clouds; and equator-to-pole contrasts in condensable volatiles (methane and hydrogen sulphide) in the deeper troposphere. These observations identify three distinct latitude domains: an equatorial domain of deep upwelling and upper-tropospheric subsidence, potentially bounded by peaks in the retrograde zonal jet and analogous to Jovian cyclonic belts; a mid-latitude transitional domain of upper-tropospheric upwelling, vigorous cloud activity, analogous to Jovian anticyclonic zones; and a polar domain of strong subsidence, volatile depletion, and small-scale (and potentially seasonally-variable) convective activity. Taken together, the multi-wavelength observations suggest a tiered structure of stacked circulation cells (at least two in the troposphere and one in the stratosphere), potentially separated in the vertical by (i) strong molecular weight gradients associated with cloud condensation, and by (ii) transitions from a thermally-direct circulation regime at depth to a wave-driven circulation regime at high altitude. The inferred circulation can be tested in the coming decade by 3D simulations and by observations from future world-class facilities. [Abridged], Comment: 29 pages, 8 figures, review article accepted to SSRv special issue on "In Situ Exploration of the Ice Giants"

Uranus and Neptune, and their diverse satellite and ring systems, represent the least explored environments of our Solar System, and yet may provide the archetype for the most common outcome of planetary formation throughout our galaxy. Ice Giants will be the last remaining class of Solar System planet to have a dedicated orbital explorer, and international efforts are under way to realise such an ambitious mission in the coming decades. In 2019, the European Space Agency released a call for scientific themes for its strategic science planning process for the 2030s and 2040s, known as Voyage 2050. We used this opportunity to review our present-day knowledge of the Uranus and Neptune systems, producing a revised and updated set of scientific questions and motivations for their exploration. This review article describes how such a mission could explore their origins, ice-rich interiors, dynamic atmospheres, unique magnetospheres, and myriad icy satellites, to address questions at the heart of modern planetary science. These two worlds are superb examples of how planets with shared origins can exhibit remarkably different evolutionary paths: Neptune as the archetype for Ice Giants, whereas Uranus may be atypical. Exploring Uranus' natural satellites and Neptune's captured moon Triton could reveal how Ocean Worlds form and remain active, redefining the extent of the habitable zone in our Solar System. For these reasons and more, we advocate that an Ice Giant System explorer should become a strategic cornerstone mission within ESA's Voyage 2050 programme, in partnership with international collaborators, and targeting launch opportunities in the early 2030s., Comment: 34 pages, 9 figures, accepted to Planetary and Space Science

The atmospheres of the four giant planets of our Solar System share a common and well-observed characteristic: they each display patterns of planetary banding, with regions of different temperatures, composition, aerosol properties and dynamics separated by strong meridional and vertical gradients in the zonal (i.e., east-west) winds. On Jupiter, the reflective white bands of low temperatures, elevated aerosol opacities, and enhancements of quasi-conserved chemical tracers are referred to as 'zones.' Conversely, the darker bands of warmer temperatures, depleted aerosols, and reductions of chemical tracers are known as `belts.' On Saturn, we define cyclonic belts and anticyclonic zones via their temperature and wind characteristics, although their relation to Saturn's albedo is not as clear as on Jupiter. On distant Uranus and Neptune, the exact relationships between the banded albedo contrasts and the environmental properties is a topic of active study. This review is an attempt to reconcile the observed properties of belts and zones with (i) the meridional overturning inferred from the convergence of eddy angular momentum into the eastward zonal jets at the cloud level on Jupiter and Saturn and the prevalence of moist convective activity in belts; and (ii) the opposing meridional motions inferred from the upper tropospheric temperature structure, which implies decay and dissipation of the zonal jets with altitude above the clouds. These two scenarios suggest meridional circulations in opposing directions, the former suggesting upwelling in belts, the latter suggesting upwelling in zones. This presents an unresolved paradox for our current understanding of the banded structure of giant planet atmospheres, that could be addressed via a multi-tiered vertical structure of 'stacked circulation cells.' [Abridged], Comment: 25 pages, 6 figures, Space Science Reviews, accepted

Jupiter's banded structure undergoes strong temporal variations, changing the visible and infrared appearance of the belts and zones in a complex and turbulent way due to physical processes that are not yet understood. In this study we use ground-based 5-$\mu$m infrared data captured between 1984 and 2018 by 8 different instruments mounted on the Infrared Telescope Facility in Hawai'i and on the Very Large Telescope in Chile to analyze and characterize the long-term variability of Jupiter's cloud-forming region at the 1-4 bar pressure level. The data show a large temporal variability mainly at the equatorial and tropical latitudes, with a smaller temporal variability at mid-latitudes. We also compare the 5-$\mu$m-bright and -dark regions with the locations of the visible zones and belts and we find that these regions are not always co-located, specially in the southern hemisphere. We also present Lomb-Scargle and Wavelet Transform analyzes in order to look for possible periodicities of the brightness changes that could help us understand their origin and predict future events. We see that some of these variations occur periodically in time intervals of 4-8 years. The reasons of these time intervals are not understood and we explore potential connections to both convective processes in the deeper weather layer and dynamical processes in the upper troposphere and stratosphere. Finally we perform a Principal Component analysis to reveal a clear anticorrelation on the 5-$\mu$m brightness changes between the North Equatorial Belt and the South Equatorial Belt, suggesting a possible connection between the changes in these belts., Comment: Accepted in the Astronomical Journal

The narrow main rings of Uranus are composed of almost exclusively centimeter- to meter-sized particles, with a very small or nonexistent dust component; however, the filling factor, composition, thickness, mass, and detailed particle size distribution of these rings remain poorly constrained. Using millimeter (1.3 - 3.1 mm) imaging from the Atacama Large (sub-)Millimeter Array and mid-infrared (18.7 $\mu$m) imaging from the Very Large Telescope VISIR instrument, we observed the thermal component of the Uranian ring system for the first time. The $\epsilon$ ring is detected strongly and can be seen by eye in the images; the other main rings are visible in a radial (azimuthally-averaged) profile at millimeter wavelengths. A simple thermal model similar to the NEATM model of near-Earth asteroids is applied to the $\epsilon$ ring to determine a ring particle temperature of $77.3 \pm 1.8$ K. The observed temperature is higher than expected for fast-rotating ring particles viewed at our observing geometry, meaning that the data favor a model in which the thermal inertia of the ring particles is low and/or their rotation rate is slow. The $\epsilon$ ring displays a factor of 2-3 brightness difference between periapsis and apoapsis, with $49.1 \pm 2.2$\% of sightlines through the ring striking a particle. These observations are consistent with optical and near-infrared reflected light observations, confirming the hypothesis that micron-sized dust is not present in the ring system., Comment: Accepted to AJ

Observations of Neptune, made in 2018 using the new Narrow Field Adaptive Optics mode of the Multi Unit Spectroscopic Explorer (MUSE) instrument at the Very Large Telescope (VLT) from 0.48 - 0.93 micron, are analysed here to determine the latitudinal and vertical distribution of cloud opacity and methane abundance in Neptune's observable troposphere (0.1 - ~3 bar). Previous observations at these wavelengths in 2003 by HST/STIS (Karkoschka and Tomasko 2011, Icarus 205, 674-694) found that the mole fraction of methane above the cloud tops (at ~2 bar) varied from ~4% at equatorial latitudes to ~2% at southern polar latitudes, by comparing the observed reflectivity at wavelengths near 825 nm controlled primarily by either methane absorption or H2-H2/H2-He collision-induced absorption. We find a similar variation in cloud-top methane abundance in 2018, which suggests that this depletion of methane towards Neptune's pole is potentially a long-lived feature, indicative of long-term upwelling at mid-equatorial latitudes and subsidence near the poles. By analysing these MUSE observations along the central meridian with a retrieval model, we demonstrate that a broad boundary between the nominal and depleted methane abundances occurs at between 20 - 40S. We also find a small depletion of methane near the equator, perhaps indicating subsidence there, and a local enhancement near 60 - 70S, which we suggest may be associated with South Polar Features (SPFs) seen in Neptune's atmosphere at these latitudes. Finally, by the use of both a reflectivity analysis and a principal component analysis, we demonstrate that this depletion of methane towards the pole is apparent at all locations on Neptune's disc, and not just along its central meridian.

We analyse the potential vorticity of Saturn's polar regions, as it is a fundamental dynamical tracer that enables us to improve our understanding of the dynamics of these regions and their seasonal variability. In particular, we present zonally averaged quasi-geostrophic potential vorticity maps between 68{\deg} planetographic latitude and the poles at altitudes between 500 mbar and 1mbar for three different epochs: (i) June 2013 (early northern summer) for the north polar region, (ii) December 2008 (late northern winter) for both polar regions and (iii) October 2006 (southern summer) for the south, computed using temperature profiles retrieved from Cassini Composite Infrared Spectrometer (CIRS) data and wind profiles obtained from Cassini's Imaging Science Subsystem (ISS). The results show that quasi-geostrophic potential vorticity maps are very similar at all the studied epochs, showing positive vorticities at the north and negative at the south, indicative of the dominance of the Coriolis parameter 2${\Omega}sin{\phi}$ at all latitudes, except near the pole. The meridional gradients of the quasi-geostrophic potential vorticity show that dynamical instabilities, mainly due to the barotropic term, could develop at the flanks of the Hexagon at 78{\deg}N, the jet at 73.9{\deg}S and on the equatorward flank of both polar jets. There are no differences in potential vorticity gradients between the two hemispheres that could explain why a hexagon forms in the north and not in the south. No seasonal variability of the potential vorticity and its meridional gradient has been found, despite significant changes in the atmospheric temperatures over time., Comment: 21 pages, 9 figures. Accepted in Journal of Geophysical Research