Search

The oxidation of 10,15‐diaryl‐21‐carba‐23‐selenaporphyrinoids resulted in the creation of dyads. The dimerization process follows a [5+2] cycloaddition path with the formation of an azepine unit. The arrays display two direct bonds between the peripheral carbocyclic carbon atoms of one carbaselenaporphyrinic subunit and the central carbon and nitrogen atoms of the second subunit. This results in a unique canted arrangement of two carbaporphyrinoid planes resembling an open seashell‐like motif. [ABSTRACT FROM AUTHOR]

This article, published in Angewandte Chemie International Edition, discusses the use of an azepine ring as a merging motif in 21-carbaselenaporphyrinoid dyads. The dyads, which are covalently linked, have a unique geometry characterized by a canted arrangement of two carbaselenaporphyrinic planes. The dimerization process occurs through a [5+2] cycloaddition reaction. The authors of the article are Anna Berlicka, Lechosław Latos-Grażyński, and others. [Extracted from the article]

This article, published in Angewandte Chemie, discusses the use of an azepine ring as a merging motif in 21-carbaselenaporphyrinoid dyads. The dyads, which are covalently linked, have a unique geometry characterized by a canted arrangement of two carbaselenaporphyrinic planes. The dimerization process occurs through a [5+2] cycloaddition reaction. The authors of the article are Anna Berlicka, Lechosław Latos-Grażyński, and others. [Extracted from the article]