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Changes in groundwater flow in response to strong earthquakes are widely described in many tectonic environments. For example, a post-seismic discharge variation is often attributed to an increase of bulk permeability due to co-seismic fracturing and/or to a change in the role of faults in acting as conduits/barrier to groundwater flow.We take as an example the fractured aquifer of the Mts. Sibillini carbonate massif, in Central Italy, which were affected by a strong and prolonged extensional seismic sequence in 2016-17. The sequence was characterized by an M=6.5 event (mainshock), an M=6 event, an M=5.9 event, up to 60 M>4 events and several M>5 earthquakes. The strongest events caused rupturing of the topographic surface for a cumulative length in the order of 30 km and an important portion of aftershocks occurred at depths where groundwater is stored.As a response to the seismic sequence, the main NNW-directed groundwater flow was diverted to the west and a discharge deficit was observed at the foot-wall of the activated fault system with a relevant discharge increase, accompanied by geochemical variations, at the fault system hanging-wall.By integrating geo-structural reconstructions, seismological and ground deformation data, artificial tracer tests results and a 4-years discharge and geochemical monitoring campaign data, we show that the observed groundwater variations are due to a combination of permeability increase along the activated fault systems and hydraulic conductivity increase of the hanging-wall block due to fracturing, extension and subsidence, which determined a fast aquifers emptying. Seismicity temporarily triggered a change of the pre-existing predominant along-faults-strike NNW-SSE oriented regional flow to a west-directed flow, perpendicular to faults strike. We discuss the position of the aquifer with respect to the activated faults and how this affected the observed phenomena. REFERENCECambi, C., Mirabella, F., Petitta, M., Banzato, F., Beddini, G., Cardellini, C., ... & Valigi, D. (2022). Reaction of the carbonate Sibillini Mountains Basal aquifer (Central Italy) to the extensional 2016–2017 seismic sequence. Scientific Reports, 12(1), 1-13. DOI: 10.1038/s41598-022-26681-2

Environmental isotopes were used to determine the source and to understand the physical–chemical processes involved in groundwater movement along a flowpath. This study applies groundwater stable isotopes to assess snow-cover influence on the recharge processes of some regional carbonate aquifers of central Italy. Starting with extensively investigated aquifers, 17 springs were selected and sampled (June–October 2016) for isotope analyses. The δ18O–δD results follow the local meteoric water line; the low mismatch between the 2016 sampling surveys suggests that those springs are not influenced by seasonal variability. Nevertheless, the average elevations of recharge areas calculated using the vertical isotope gradient were higher compared to those obtained with hypsographic profiles. This means that the relevant contribution to recharge comes from higher elevation areas; hence, snowpack coverage and snowpack persistence over time on recharge areas were analysed using satellite images. Four different relationships between the snowpack characteristics and the elevation of recharge areas have been identified. These offer relevant information about the different degrees of dependence of the regional aquifers of central Italy on the recharge due to high-elevation subbasins where the snowpack cover is significant. A possible correlation emerges between computed isotope recharge elevation and mean snow cover elevation, revealing how snowmelt is a primary source for aquifer recharge. Consequently, to evaluate the risk of groundwater resource depletion in a climate-change scenario, there is discussion on how a potential snow-cover reduction would affect the recharge rate of mountainous aquifers.

Knowing water quality at larger scales and related ground and surface water interactions impacted by land use and climate is essential to our future protection and restoration investments. Population growth has driven humankind into the Anthropocene where continuous water quality degradation is a global phenomenon as shown by extensive recalcitrant chemical contamination, increased eutrophication, hazardous algal blooms, and faecal contamination connected with microbial hazards antibiotic resistance. In this framework, climate change and related extreme events indeed exacerbate the negative trend in water quality. Notwithstanding the increasing concern in climate change and water security, research linking climate change and groundwater quality remain early. Additional research is required to improve our knowledge of climate and groundwater interactions and integrated groundwater management. Long-term monitoring of groundwater, surface water, vegetation, and land-use patterns must be supported and fortified to quantify baseline properties. Concerning the ways climate change affects water quality, limited literature data are available. This study investigates the link between climate change and groundwater quality aquifers by examining case studies of regional carbonate aquifers located in Central Italy. This study also highlights the need for strategic groundwater management policy and planning to decrease groundwater quality due to aquifer resource shortages and climate change factors. In this scenario, the role of the Society of Environmental Geochemistry is to work together within and across geochemical environments linked with the health of plants, animals, and humans to respond to multiple challenges and opportunities made by global warming.

The dynamic of groundwater systems feeding several springs of the Sibillini Mountains was deeply affected by nine Mw 5.0÷6.5 seismic events occurred in central Italy starting from August 2016. The strongest shock occurred on October 30th 2016 about 5 km NNE of Norcia Town, 9 km below the surface, as a result of upper crust normal faulting on the nearly 30 km-long Mt Vettore - Mt Bove fault system, a NW-SE trending, SW-dipping fault system outcropping on the western slope of Mt Vettore, the highest peak of Sibillini Mountains. Soon after this event, a general increase of springs and rivers discharge and groundwater levels was observed both in the Visso and Norcia areas, west of the Sibillini Mountains. In the Visso area the hydrogeological changes due to the seismic sequence exhausted in the 2019, while nowadays both discharges and groundwater levels are still higher than before in the Norcia area. Discharge data of the main springs located east, south-east of the Sibillini Mountains were analysed to verify whether the general increase observed on the western side was associated to a decrease on the eastern and southern-east area. The results show that the springs located on the eastern side and southern-east side of Mt Vettore experienced a significant long-term discharge decrease. In this preliminary work, the analysis of the historical discharge series of the Pescara di Arquata spring (SE of Mt Vettore), and its relationship with the Standard Precipitation Index (SPI) shows that the very low discharge values recorded during the post-seismic period are not associated with SPI as low as documented in the past for similar discharges. Moreover, the stable isotopic composition of Pescara di Arquata water during the post-earthquake period is slightly different from that measured before the seismic events; this suggests that a lower amount of water having more enriched isotopic δ18O content reaches the spring after the seismic sequence. These aspects seem to indicate that groundwater circulation in the southern-east area of Sibillini Mountains has been affected by the 2016-2017 seismic sequence.

A sustained increase in spring discharges was monitored after the 2016 Central Italy seismic sequence in the fractured carbonate aquifer of Valnerina–Sibillini Mts. The groundwater surplus recorded between August 2016 and November 2017 was determined to be between 400 and 500 × 106 m3. In fractured aquifers, the post-seismic rise in spring discharges is generally attributed to an increase in bulk permeability caused by the fracture cleaning effect, which is induced by pore pressure propagation. In the studied aquifers, the large amount of additional discharge cannot only be attributed to the enhanced permeability, which was evaluated to be less than 20% after each main seismic event. A detailed analysis of the spring discharge hydrographs and of the water level at five gauging stations was carried out to determine the possible causes of this sudden increase in groundwater outflow. Taking into account the geological and structural framework, a conceptual model of a basin-in-series has been adopted to describe the complex hydrogeological setting, where the thrusts and extensional faults have clearly influenced the groundwater flow directions before and after the seismic sequence. The prevalent portion of the total post-seismic discharge surplus not explained by the increase in permeability has been attributed to changes in the hydraulic gradient that caused seismogenic fault rupture and the disruption in the upgradient sector of the aquifer. The additional flow calculated through the breach of the pre-existing hydrostructural barrier corresponds to approximately 470 × 106 m3. This value is consistent with the total discharge increase measured in the whole study area, validating the proposed conceptual model. Consequently, a shift in the piezometric divide of the hydrogeological system has been induced, causing a potentially permanent change that lowers the discharge amount of the eastern springs.

A seismic sequence in central Italy from August 2016 to January 2017 affected groundwater dynamics in fractured carbonate aquifers. Changes in spring discharge, water-table position, and streamflow were recorded for several months following nine Mw 5.0–6.5 seismic events. Data from 22 measurement sites, located within 100 km of the epicentral zones, were analyzed. The intensity of the induced changes were correlated with seismic magnitude and distance to epicenters. The additional post-seismic discharge from rivers and springs was found to be higher than 9 m3/s, totaling more than 0.1 km3 of groundwater release over 6 months. This huge and unexpected contribution increased streamflow in narrow mountainous valleys to previously unmeasured peak values. Analogously to the L’Aquila 2009 post-earthquake phenomenon, these hydrogeological changes might reflect an increase of bulk hydraulic conductivity at the aquifer scale, which would increase hydraulic heads in the discharge zones and lower them in some recharge areas. The observed changes may also be partly due to other mechanisms, such as shaking and/or squeezing effects related to intense subsidence in the core of the affected area, where effects had maximum extent, or breaching of hydraulic barriers.