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Terrestrial mud volcanoes represent surface features of channels for subsurface methane transport and, therefore, constitute an important source of methane emission from natural environments. How microbial processes regulate methane emissions in terrestrial mud volcanoes has yet to be fully addressed. This study demonstrated the geochemical characteristics and microbial communities of four mud volcano and seep sites in two geological settings of Sicily, Italy. At sites within the accretionary wedge that exhibited higher methane and sulfate concentrations, the communities were dominated by members capable of catalyzing methane and sulfate metabolisms and organic degradation. In particular, both anaerobic and aerobic methanotrophs were abundant and their abundance distribution coincided with the geochemical transition. In contrast, the sites near Mount Etna were characterized by high fluid salinity, CO2, and low methane and sulfate concentrations, with communities consisting of halophilic organic degraders and sulfur metabolizers, along with a minor presence of aerobic methanotrophs. Substantial variations in community composition and geochemistry across spatial and vertical redox gradients suggest that physicochemical contexts imposed by the geology, fluid path, and source characteristics play a vital role in shaping community composition and cycling of methane, sulfur and organic carbon in Sicily mud volcanoes.

A previously undocumented shallow water hydrothermal field from Sicily (Southern Tyrrhenian Sea, Italy) is here described, based on a multidisciplinary investigation. The field, covering an area of nearly 8000 m2 and a depth from the surface to -5 m, was explored in June 2021 to characterise the main physico-chemical features of the water column, describe the bottom topography and features, and identify the main megabenthic and nektonic species. Twenty sites were investigated to characterise the carbonate system. Values of pH ranged between 7.84 and 8.04, ΩCa between 3.68 and 5.24 and ΩAr from 2.41 to 3.44. Geochemical analyses of hydrothermal gases revealed a dominance of CO2 (98.1%) together with small amounts of oxygen and reactive gases. Helium isotope ratios (R/Ra = 2.51) and δ13CCO2 suggest an inorganic origin of hydrothermal degassing of CO2 and the ascent of heat and deep-seated magmatic fluids to the surface. Visual census of fishes and megabenthos (mainly sessile organisms) allowed the identification of 64 species, four of which are protected by the SPA/BIO Protocol and two by the International Union for Conservation of Nature. The macroalgae Halopteris scoparia and Jania rubens and the sponge Sarcotragus sp. were the dominant taxa in the area, while among fishes Coris julis and Chromis chromis were the most abundant species. This preliminary investigation of San Giorgio vent field suggests that the site could be of interest and suitable for future experimental studies of ocean acidification.

Volcanic eruptions pose a major natural hazard influencing the environment, climate and human beings at different temporal and spatial scales. Nevertheless, several volcanoes worldwide are poorly monitored and assessing the impact of their eruptions remains, in some cases, challenging. Nowadays, different numerical dispersion models are largely employed in order to evaluate the potential effects of volcanic plume dispersion due to the transport of ash and gases. On 28 August 2019, both Mt. Etna and Stromboli had eruptive activity; Mt. Etna was characterised by mild-Strombolian activity at summit craters, while at Stromboli volcano, a paroxysmal event occurred, which interrupted the ordinary typical-steady Strombolian activity. Here, we explore the spatial dispersion of volcanic sulphur dioxide (SO2) gas plumes in the atmosphere, at both volcanoes, using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) considering the ground-measured SO2 amounts and the plume-height as time-variable eruptive source parameters. The performance of WRF-Chem was assessed by cross-correlating the simulated SO2 dispersion maps with data retrieved by TROPOMI and OMI sensors. The results show a feasible agreement between the modelled dispersion maps and TROPOMI satellite for both volcanoes, with spatial pattern retrievals and a total mass of dispersed SO2 of the same order of magnitude. Predicted total SO2 mass for Stromboli might be underestimated due to the inhibition from ground to resolve the sin-eruptive SO2 emission due to the extreme ash-rich volcanic plume released during the paroxysm. This study demonstrates the feasibility of a WRF-Chem model with time-variable ESPs in simultaneously reproducing two eruptive plumes with different SO2 emission and their dispersion into the atmosphere. The operational implementation of this method could represent effective support for the assessment of local-to-regional air quality and flight security and, in case of particularly intense events, also on a global scale.

Submarine hydrothermal systems along active volcanic ridges and arcs are highly dynamic, responding to both oceanographic (e.g., currents, tides) and deep-seated geological forcing (e.g., magma eruption, seismicity, hydrothermalism, and crustal deformation, etc.). In particular, volcanic and hydrothermal activity may also pose profoundly negative societal impacts (tsunamis, the release of climate-relevant gases and toxic metal(loid)s). These risks are particularly significant in shallow (

In September 2021, the La Fossa crater at Vulcano, in Italy, entered a new phase of unrest. We discuss a set of monitoring parameters included in the INGV surveillance network, which closely tracked the sequence of effects related to the crisis. The low-frequency local seismicity sharply increased, while the GPS and tiltmeter networks recorded the inflation of the cone, as an effect of fluid expansion in the hydrothermal system. Gravity variations were probably the effects of fast processes within shallow sources. The anomalies in soil CO2 flux, fumarole temperature, and in plume SO2 flux marked the strong increase in the vapor output from crater fumaroles. The signs of the impending crisis had been evident in the chemical and isotopic composition of fumarole gases since July 2021. These geochemical anomalies were clearly indicative of the enhanced input of gases from a magmatic source. In October, the massive degassing also influenced the areas at the base of the cone. In some areas, soil CO2 degassing and the thermal aquifer recorded strong anomalies. By early November, the crisis reached its acme. Afterward, the monitored parameters started a slow and discontinuous decreasing trend although remaining, some of them, sensibly above the background for several months. The multidisciplinary approach proved decisive for the interpretation of the underlying processes acting in the different phases of the unrest, thus allowing a consistent evaluation of the multiple hazards.

During the autumn season, Sicily is often affected by severe weather events, such as self-healing storms called V-shaped storms. These phenomena cause significant total rainfall quantities in short time intervals in localized spatial areas. In this framework, this study analyzes the meteorological event recorded on 11–12 November 2019 in Sicily (southern Italy), using the Weather Research and Forecasting (WRF) model with a horizontal spatial grid resolution of 3 km. It is important to note that, in this event, the most significant rainfall accumulations were recorded in eastern Sicily. In particular, the weather station of Linguaglossa North Etna (Catania) recorded a total rainfall of 293.6 mm. The precipitation forecasting provided by the WRF model simulation has been compared with the data recorded by the meteorological stations located in Sicily. In addition, a further simulation was carried out using the Four-Dimensional Data Assimilation (FDDA) technique to improve the model capability in the event reproduction. In this regard, in order to evaluate which approach provides the best performance (with or without FDDA), the Root Mean Square Error (RMSE) and dichotomous indexes (Accuracy, Threat Score, BIAS, Probability of Detection, and False Alarm Rate) were calculated.

Technological advances have impacted almost every facet of modern culture and even in the educational methodologies. As new technologies become available, they are often embraced in educational innovation in an attempt to enhance traditional instruction. To this purpose, the “flipped classroom” is a learning model in which content attainment is shifted forward to outside of class, then followed by teacher-facilitated concept application activities in class. The constructivist approach, realized through an active-learning style of teaching, is more important respect to the order with which the teacher participated in the learning process. In this respect, the goal is to provide an alternative teaching approach on environmental issue. In particular, thanks to active learning (flipped classroom) it is possible to know and to appreciate a new \textit{eco-friendly} material named to “Geopolymers”. One of the most important environmental advantage that can be attributed to this material is represented by the lower energy requirements for its production. Thus, this material could represent a potential tool able to mitigate the environmental pollution. In this regard, the geopolymers could provide a possible solution to wastes reuse as a resource to scale down the demand for extraction of new resources. This paper looks at some positive aspects of technology and waste treatment, and deals with the production of innovative building materials obtained by waste recycling known as geopolymers. Specifically, it is important to highlight the possibility of using wastes characterized by high silica and aluminum amounts as raw materials, particularly suitable to produce geopolymers by chemical activation with alkali. This is a useful method to improve hazardous-waste management and to reduce health and environmental issues due to the strong capability of make inert hazardous waste. This solution confirms the importance of re-manufacturing, reusing and recycling and, moreover, making a waste a new raw material and helps to move toward a more circular economy where wastes become negligible and further natural resources are used in an efficient and sustainable way. The proposed topic is addressed to students and aims to arouse their interest in the fields of the environmental protection and waste management, but overall it gives the perspective of natural resource preservation, and a most efficient way of their use without depleting the planet's resources.

This contribution is intended to answer the question of why in teaching approaches it is important to speak about territory? The answer to the question is driven by the consideration that the territory, including the established human activities, encompasses the history, the events and the culture of the people who populated it. On this regard, it should be noted that the relationship between natural elements and human activities that refer to a given territory has a dynamic character since both influence each other and help to write the history of that place. In this framework, the proposed method is used as an interdisciplinary approach to the theme of clay minerals. These latter are hydrous aluminium phyllosilicates, with variable amounts of iron, magnesium, alkali metals, alkaline earths. They are the main constituents of soils, and have been used by humans since ancient times in agriculture and manufacturing. For this reason, clays played a basic role for the human civilization process since its earliest periods. Clays are recognized amongst the most important rock products, both as raw material and in the form of pottery, bricks, tiles, terra-cotta and many other tools for daily use. This is particular evident in Sicily, where, since ancient times, the availability of local clay sources favoured the diffusion of clay-artefacts and related workshops found over the territory. This paper makes reference to a lecture addressed to university students and includes: i) the description of the main mineralogical features and properties of clay minerals; ii) a brief discussion on the role played by clays in terms of clay-artefacts production in the historical and cultural evolution of the Messina territory; iii) a description of local clay outcrops; iiii) a presentation of the main kilns over the Messina territory, and in particular of unpublished archaeological information on the S. Pier Niceto kilns. The proposed approach aims to increase the interest of students towards the significant aspects that affected the social-economic growth of the Messina’s territory and on the importance that geo-materials had in the technological evolution of its civilization process.

Pollution due to natural radioactivity is still a poorly known topic among young people. This paper describes the contents for an introductive university course or lecture conceived in a multitask program. Along with a so-called “flipped” configuration, where students are able to receive didactic materials prior to face-to-face lessons, multimedia contents should be shown to the students, who are at first faced with known anthropogenic accidents. Moreover, field and laboratory experimental activities can provide further insight regarding the radiological assessment strategies. Here, the most important principles and effects concerning the radioactive decay of naturally occurring radionuclides are described. The greatest part of natural radioactivity derives from terrestrial radionuclides occurring in soil and rocks. The radionuclides are atoms characterized by an excess of nuclear energy, which makes them unstable giving rise to decay. The radionuclides emit gamma rays, as well as alpha and/or beta particles. People are constantly subjected to indoor and outdoor exposure due to natural radioactivity. The possible sources can be considered as external due to natural sources located outside the human body, and internal provoked by ingestion or inhalation of radionuclides. The indoor exposure from natural sources is mainly related to radiation from building materials and to radon entering buildings from soils and rocks though cracks in walls and floor. The outdoor exposure mainly accounts for the terrestrial gamma radiation that crosses the soil-air interface, and for the radon emitted from soils in seismic and volcanic areas. In this regard, there is a strong relationship between health diseases (e.g. cancer, necrosis and DNA and RNA modifications) and high-levels of natural radioactivity. For this reason, the radiological assessment of the most vulnerable areas represents a key point in order to mitigate hazard and risk connected to the human exposure to natural radioactivity.

Abstract The Comoros archipelago is an active geodynamic region of intra‐plate volcanism within which the youngest and oldest islands (Grande Comore and Mayotte respectively) are characterized by recent volcanic activity. The frequent eruptions of the large shield volcano Karthala on Grande Comore (last eruption 2007), and the recent birth of a large submarine volcano since 2018 at the submarine base of Mayotte are associated with permanent fumarolic emissions, bubbling gas seeps, and soil gas emissions, which are studied in detail here for the first time. CO2 fluxes and chemical and isotopic gas compositions acquired during two surveys in 2017 and 2020 are integrated with older data sets collected between 2005 and 2016, permitting the identification of a possible influence of the recent volcanic and magmatic activity at Mayotte. At Karthala, high gas fluxes with high temperature, and a marked magmatic signature are concentrated close to the summit crater area, while only weaker emissions with a stronger biogenic signature are found on the volcano flanks. At Mayotte, lower temperature and higher CH4 content are recorded in two main seep areas of CO2‐rich fluid bubbling, while soil emissions on land record a higher proportion of magmatic fluids compared to Karthala. Our preliminary results reveal two quite separate gas emission patterns for each island that are distinct in composition and isotopic signatures, and well correlated with the present state of volcanic activity. This work may potentially provide support for local observation infrastructures and contribute to the improvement in volcanic and environmental monitoring.

The Black Sea bottom is well known to be earth’s largest anaerobic methane source, hosting a huge amount of cold seeps releasing significant volumes of methane of both thermogenic and biogenic origin. Taking into account the well-known effects of methane concerning global warming, including the warming up of the oceans, an effective monitoring of its output from the Black Sea is nowadays an essential target for interdisciplinary studies. We discuss the results achieved during monitoring campaigns aimed to detect and track methane flares from the seafloor of the Romanian sector of the Black Sea, in order to better constrain the possible mechanisms responsible for its injection from the marine sediments, through the water column, into the atmosphere. In the mainframe of the ENVRI-Plus project, we deployed a multidisciplinary seafloor observatory for short, mid and long time monitoring and collected samples of the water column. The multidisciplinary seafloor observatory was equipped with probes for passive acoustic signals, dissolved CH4 and chemical-physical parameters. The collected data showed a high concentration of dissolved methane up to values of 5.8 micromol/L. Passive acoustics data in the frequencies range 40–2,500 Hz allow us to discriminate different degassing mechanisms and degassing styles. The acoustic energy associated with gas bubbling is interpreted as a consequence of the gas dynamics along the water column while the acoustic range 2–20 Hz reveals vibration mechanisms generated by gas dynamic’s along the cracks and inside the sediments.

Gases present in the Earth crust are important in various branches of human activities. Hydrocarbons are a significant energy resource, helium is applied in many high-tech instruments, and studies of crustal gas dynamics provide insight in the geodynamic processes and help monitor seismic and volcanic hazards. Quantitative analysis of methane and CO2 migration is important for climate change studies. Some of them are toxic (H2S, CO2, CO); radon is responsible for the major part of human radiation dose. The development of analytical techniques in gas geochemistry creates opportunities of applying this science in numerous fields. Noble gases, hydrocarbons, CO2, N2, H2, CO, and Hg vapor are measured by advanced methods in various environments and matrices including fluid inclusions. Following the “Geochemical Applications of Noble Gases”(2009), “Frontiers in Gas Geochemistry” (2013), and “Progress in the Application of Gas Geochemistry to Geothermal, Tectonic and Magmatic Studies” (2017) published as special issues of Chemical Geology and “Gas geochemistry: From conventional to unconventional domains” (2018) published as a special issue of Marine and Petroleum Geology, this volume continues the tradition of publishing papers reflecting the diversity in scope and application of gas geochemistry.

Renewable energies have been the only sources recording a clear increase in total installed capacity, setting a record in new power capacity in 2020, despite the pandemic. The European Union Green Deal represents a strategy towards a sustainable economic model. In this framework, land-based geothermics has seen very limited development; however, offshore geothermics is almost completely absent in the discussion on energy source alternatives, even though it represents a real challenge for energy transition, including the production of green hydrogen. This article discusses an excursus on the activities carried out on offshore geothermal areas worldwide. We focused on the energy potential capacity of the Marsili volcanic seamount located over the bathial plain of the Tyrrhenian Basin, describing the detailed geological, geochemical, and geophysical investigations that have been carried out on that seamount since the 2000s. All the collected data have shown evidence supporting the existence of an exploitable geothermal system in the Marsili seamount consisting of a reservoir of supercritical geothermal fluids of about 100 km3. We discuss and evaluate the actual consistence of the impacts associated with the occurrence of potential risks. We also describe the necessary further steps towards the pilot well. An important breakthrough in the short-medium term that allows for an exit from the predominance of fossil sources may come from the development of energy production derived from offshore high-enthalpy geothermal fields, especially in areas such as the Southern Tyrrhenian Sea. There is a natural clear predisposition for its exploitation combined with a low ecological footprint, which is the target objective of international agreements in the context of a blue economy strategy.

Investigations carried out over the southernmost portion of the Apennine chain (Nebrodi-Peloritani Mountains, Sicily, Italy) reveal a close connection between the tectonic setting and the regional degassing of CO2-dominated volatiles. The geochemical features of the collected gases show that the pristine composition has been modified by gas-water interaction (GWI) and degassing processes. The 3He/4He isotopic ratio in the range of 0.7-2.8 Ra highlights variable contributions of mantle-derived helium, representing an unusual feature for the crustal regime of the study areas characterized by the widespread presence of 4He-producer metamorphic rocks. The degassing of mantle helium is coherent with the tectonics and related to the NW-SE extensional regime of the Calabro-Peloritan Arc (CPA). We propose that the degassing regime as well as the geochemical features of both the dissolved and bubbling gases is closely connected to the strain accumulation rate, inducing almost no temporal changes and insignificant deep-originated fluid contributions to the locked fault volumes. Investigations including discrete and continuous monitoring and degassing-rate estimations are useful tools to gain a better insight into the evolution of seismogenesis, considering the fault rupture as the final stage of a seismic cycle.

Geochemical investigations carried out on submarine hydrothermal fluids vented offshore the Pontine Islands (Tyrrhenian Sea) revealed the existence of gas vents to the W of Zannone Island and SW of Ventotene Island. The geochemical features of the CO2-rich gas samples show a clear mantle-derived signature with 3He/4He of 3.72-3.75 Ra and 1.33 Ra at Zannone and Ventotene, respectively. Gas geochemistry denotes how CO2-rich gases undergo fractionation processes due to CO2 dissolution to a variable extent favoring enrichment in the less soluble gas species, i.e., CH4, N2, and He. The carbon isotope composition of CO2, expressed as δ13C vs. V-PDB, ranges from -0.71 and -6.16‰ at Zannone to 1.93‰ at Ventotene. Preliminary geothermometric and geobarometric estimations indicate equilibrium temperatures in the range of 150-200°C at Zannone and >200°C at Ventotene besides H2O pressures in the range of 5 bar and 20 bar at Zannone and Ventotene, respectively. Although the latest volcanic activity at the Pontine Archipelago is dated Middle Pleistocene, the combination of the new geochemical information along with geothermometric estimations indicates that cooling magmas are likely releasing enough thermal energy to form an efficient hydrothermal system.

Geohazards associated to submarine hydrothermal systems still represent a tricky enigma to face and solve for the scientific community. The poor knowledge of a submarine environment, the rare and scarce monitoring activities, and the expensive and sometimes complicated logistics are the main problems to deal with. The submarine low-energy explosion, which occurred last November 3, 2002, off the volcanic island of Panarea, highlighted the absence of any hazard scenario to be used to manage the volcanic crisis. The “unrest” of the volcanic activity was triggered by a sudden input of deep magmatic fluids, which caused boiling water at the sea surface with a massive CO2 release besides changes in the fluids’ geochemistry. That event dramatically pushed scientists to develop new methods to monitor the seafloor venting activity. Coupling the information from geochemical investigations and data collected during the unrest of volcanic activity, we were able to (a) develop theoretical models to gain a better insight on the submarine hydrothermal system and its relationships with the local volcanic and tectonic structures and (b) to develop a preliminary submarine volcanic hazard assessment connected to the Panarea system (Aeolian Islands). In order to mitigate the potential submarine volcanic hazard, three different scenarios are described here: (1) ordinary hydrothermal venting, (2) gas burst, and (3) volcanic eruption. The experience carried out at Panarea demonstrates that the best way to face any submarine volcanic-hydrothermal hazard is to improve the collection of data in near real-time mode by multidisciplinary seafloor observatories and to combine it with periodical sampling activity.

This study was developed to carry out a comprehensive radiological assessment of natural radioactivity for river sediment samples from Calabria, southern Italy, and to define a baseline background for the area on a radiation map. In the studied area, elevated levels of natural radionuclides are expected, due to the outcropping acidic intrusive and metamorphic rocks from which the radioactive elements derive. To identify and quantify the natural radioisotopes, ninety river sediment samples from nine selected coastal sampling points (ten samples for each point) were collected as representative of the Ionian and the Tyrrhenian coastline of Calabria. The samples were analyzed using a gamma ray spectrometer equipped with a high-purity germanium (HPGe) detector. The values of mean activity concentrations of 226Ra, 232Th and 40K measured for the studied samples are (21.3 ± 6.3) Bq kg−1, (30.3 ± 4.5) Bq kg−1 and (849 ± 79) Bq kg−1, respectively. The calculated radiological hazard indices showed average values of 63 nGy h−1 (absorbed dose rate), 0.078 mSv y−1 (effective dose outdoors), 0.111 mSv y−1 (effective dose indoors), 63 Bq kg−1 (radium equivalent), 0.35 (Hex), 0.41 (Hin), 0.50 (activity concentration index) and 458 µSv y−1 (Annual Gonadal Equivalent Dose, AGED). In order to delineate the spatial distribution of natural radionuclides on the radiological map and to identify the areas with low, medium and high radioactivity values, the Surfer 10 software was employed. Finally, the multivariate statistical analysis was performed to deduce the interdependency and any existing relationships between the radiological indices and the concentrations of the radionuclides. The results of this study, also compared with values of other locations of the Italian Peninsula characterized by similar local geological conditions, can be used as a baseline for future investigations about radioactivity background in the investigated area.

Knowledge of the products originating from the subcontinental lithospheric mantle (SCLM) is crucial for constraining the geochemical features and evolution of the mantle. This study investigated the chemistry and isotope composition (noble gases and CO2) of fluid inclusions (FI) from selected mantle xenoliths originating from Wilcza Góra (Lower Silesia, southwest Poland), with the aim of integrating their petrography and mineral chemistry. Mantle xenoliths are mostly harzburgites and sometimes bear amphiboles, and are brought to the surface by intraplate alkaline basalts that erupted outside the north-easternmost part of the Eger (Ohře) Rift in Lower Silesia. Olivine (Ol) is classified into two groups based on its forsterite content: (1) Fo88.9−91.5, which accounts for a fertile-to-residual mantle, and (2) Fo85.5−88.1, which indicates large interactions with circulating (basic) melts. This dichotomy is also related to orthopyroxene (Opx) and clinopyroxene (Cpx), which show two ranges of Mg# values (87–90 and 91–93, respectively) and clear evidence of recrystallization. CO2 predominates within FI, followed by N2. The δ13C of mantle CO2 varies between −4.7‰ and −3.1‰, which mostly spans the MORB range (−8‰ < δ13C < −4‰). The 3He/4He ratio is 6.7–6.9 Ra in Cpx, 6.3–6.8 Ra in Opx, and 5.9–6.2 Ra in Ol. These values are within the range proposed for European SCLM (6.3 ± 0.3 Ra). The decrease in 3He/4He from Cpx to Ol is decoupled from the He concentration, and excludes any diffusive fractionation from FI. The chemistry of FI entrapped in Ol indicates that the mantle is depleted by variable extents of partial melting, while that of Opx and Cpx suggests the overprinting of at least one metasomatic event. According to Matusiak-Małek et al. (2017), Cpx, Opx, and amphiboles were added to the original harzburgite by carbonated hydrous silicate melt related to Cenozoic volcanism. This process resulted in entrapment of CO2-rich inclusions whose chemical and isotope composition resembles that of metasomatizing fluids. We argue that FI data reflect a mixing between two endmembers: (1) the residual mantle, resulting from partial melting of European SCLM, and (2) the metasomatic agent, which is strongly He-depleted and characterized by MORB-like features.

The geological, biological and geochemical features of a particular field of hydrothermal vents, discovered in the Panarea Volcanic Complex during a research survey carried out in 2015, are described for the first time. The site, located at 70-80 m depth off the South-western coast of the islet of Basiluzzo, was named Smoking Land for the presence of a large number of wide and high active chimneys and was characterized in terms of dissolved benthic fluxes, associated macrofauna and megafauna communities and preliminary mineralogy and geochemistry of chimney structures. On the whole field, a total of 39 chimneys, different in size and shape, were closely observed and described; 14 of them showed emission of low temperature hydrothermal fluids of marine origin characterized by acidified chemical conditions. The CTD and benthic chamber measurements highlighted that the Smoking Land is able to form a sea water bottom layer characterized by variable acidity and high DIC and trace elements concentrations; these characteristics weaken moving away from the chimney mouths. The SEM-EDS analysis of the collected solid samples revealed a chimney structure principally composed by amorphous and low crystalline Fe-oxyhydroxides of hydrothermal origins. The ROV explorations revealed a wide coverage of red algae (Peyssonnelia spp.) colonized by the green algae Flabiella petiolata and by suspension feeders, mainly sponges, but also bryozoans, and tubicolous polychaetes. Although novent-exclusive species were identified, the benthic communities found in association to the chimneys included more taxa than those observed in the surrounding no-vent rocky areas. These first findings evidence a submarine dynamic habitat where geological, chemical and biological processes are intimately connected, making the Smoking Land an important site in terms of marine heritage that should be safeguarded and protected.

Italy has a strong geothermal potential for power generation, although, at present, the only two geothermal fields being exploited are Larderello-Travale/Radicondoli and Mt. Amiata in the Tyrrhenian pre-Apennine volcanic district of Southern Tuscany. A new target for geothermal exploration and exploitation in Italy is represented by the Southern Tyrrhenian submarine volcanic district, a geologically young basin (Upper Pliocene-Pleistocene) characterised by tectonic extension where many seamounts have developed. Heat-flow data from that area show significant anomalies comparable to those of onshore geothermal fields. Fractured basaltic rocks facilitate seawater infiltration and circulation of hot water chemically altered by rock/water interactions, as shown by the widespread presence of hydrothermal deposits. The persistence of active hydrothermal activity is consistently shown by many different sources of evidence, including: heat-flow data, gravity and magnetic anomalies, widespread presence of hydrothermal-derived gases (CO2, CO, CH4), 3He/4He isotopic ratios, as well as broadband OBS/H seismological information, which demonstrates persistence of volcano-tectonic events and High Frequency Tremor (HFT). The Marsili and Tyrrhenian seamounts are thus an important—and likely long-lasting-renewable energy resource. This raises the possibility of future development of the world’s first offshore geothermal power plant.

Increased passenger safety and emission control are two of the main driving forces in the automotive industry for the development of light weight constructions. For increased strength to weight ratio, ultra-high-strength steels (UHSSs) are used in car body structures. Prediction of failure in such sheet metals is of high significance in the simulation of car crashes to avoid additional costs and fatalities. However, a disadvantage of this class of metals is a pronounced scatter in their material properties due to e.g., the manufacturing processes. In this work, a robust numerical model is developed in order to take the scatter into account in the prediction of the failure in manganese boron steel (22MnB5). To this end, the underlying material properties which determine the shapes of forming limit curves (FLCs) are obtained from experiments. A modified Marciniak–Kuczynski model is applied to determine the failure limits. By using a statistical approach, the material scatter is quantified in terms of two limiting hardening relations. Finally, the numerical solution obtained from simulations is verified experimentally. By generation of the so called forming limit bands (FLBs), the dispersion of limit strains is captured within the bounds of forming limits instead of a single FLC. In this way, the FLBs separate the whole region into safe, necking and failed zones.

A periodic sampling of the groundwaters and dissolved and free gases in selected deep wells located in the area affected by the May-June 2012 southern Po Valley seismic sequence has provided insight into seismogenic-induced changes of the local aquifer systems. The results obtained show progressive changes in the fluid geochemistry, allowing it to be established that deep-seated fluids were mobilized during the seismic sequence and reached surface layers along faults and fractures, which generated significant geochemical anomalies. The May-June 2012 seismic swarm (mainshock on May 29, 2012, M 5.8; 7 shocks M >5, about 200 events 3 > M > 5) induced several modifications in the circulating fluids. This study reports the preliminary results obtained for the geochemical features of the waters and gases collected over the epicentral area from boreholes drilled at different depths, thus intercepting water and gases with different origins and circulation. The aim of the investigations was to improve our knowledge of the fluids circulating over the seismic area (e.g. origin, provenance, interactions, mixing of different components, temporal changes). This was achieved by collecting samples from both shallow and deep-drilled boreholes, and then, after the selection of the relevant sites, we looked for temporal changes with mid-to-long-term monitoring activity following a constant sampling rate. This allowed us to gain better insight into the relationships between the fluid circulation and the faulting activity. The sampling sites are listed in Table 1, along with the analytical results of the gas phase. […]