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Microbial corrosion is the deterioration of materials associated with microorganisms in environments, especially in oil- and gas-dominated sectors. It has been widely reported to cause great losses to industrial facilities such as drainage systems, sewage structures, food-processing equipment, and oil and gas facilities. Generally, bacteria, viruses, and other microorganisms are the most important microorganisms associated with microbial corrosion. The destructive nature of these microorganisms differs based on the kind of bacteria involved in the corrosion mechanism. Amongst the microorganisms related to microbial corrosion, sulfate-reducing bacteria (SRB) is reported to be the most common harmful bacteria. The detailed mechanistic explanations relating to the corrosion of pipelines by sulfate-reducing bacteria are discussed. The mechanism of microbial corrosion in pipelines showing the formation of pitting corrosion and cathodic depolarization is also reported. The current review provides theoretical information for the control and protection of pipelines caused by microbial corrosion and how new eco-friendly protection methods could be explored.

Considerable evidence links the "Big Five" personality traits (neuroticism, extroversion, conscientiousness, agreeableness, and openness) with depression. However, potential mediating and moderating factors are less well understood. We utilized data from a cross-sectional survey of 3065 German-speaking adults from the D-A-CH region to estimate multivariable-adjusted odds ratios and 95% confidence intervalsbetween personality traits and lifetime prevalence of depression (overall and stratified by sex and age). We further explored proportions mediated by psychosocial factors optimism, empathy, perspective-taking, work-life balance, and interpersonal trust. High levels of neuroticism were associated with more than two-fold higher odds of depression, whereas higher levels of conscientiousness were associated with approximately 30% lower odds of depression. The association with neuroticism persisted in all investigated subgroups; apparently, stronger associations for females and participants aged ≥60 years did not correspond to statistically significant interactions. Overall and across all strata, the association of neuroticism with depression appeared to be mediated in part by the considered psychosocial factors; optimism explained the largest proportion of the association. Our results provide empirical evidence for the dynamic predisposition model. Further investigations of these relationships are warranted in longitudinal data with more precise outcome assessments.

Interpersonal trust declined worldwide during the COVID-19 pandemic; strategies are needed to restore it. We surveyed 3,065 quota-sampled German-speaking adults residing in the D-A-CH region. Using multinomial logistic regression models and backward elimination for variable selection, we calculated multivariable-adjusted odds ratios (OR) and 95% confidence intervals (95% CIs) to appraise correlates of interpersonal trust using the Interpersonal Trust Short Scale (KUSIV3). Participants with high levels of interpersonal trust (top KUSIV3 tertile (T3)) tended to be older, male, residents of Switzerland, university degree holders, and workers with higher income and work satisfaction (all Pdiff<0.01) compared to those in the lowest KUSIV3 tertile (T1). Optimism was most strongly associated with high interpersonal trust (ORT3vsT1 = 5.75, 95%CI = 4.33-7.64). Also significantly associated with high interpersonal trust were: Having voted in the last national election (for the opposition, OR = 1.39, 95%CI = 1.02-1.89 or the governing party, OR = 1.61, 95%CI = 1.23-2.11) versus non-voters; perspective taking (ORT3vsT1 = 1.46, 95%CI = 1.11-1.91); being more extraverted (ORT3vsT1 = 1.99, 95%CI = 1.53-2.59) and more agreeable (ORT3vsT1 = 1.95, 95% CI = 1.46-2.61); and scoring higher on complexity thinking (ORT3vsT1 = 1.32, 95%CI = 1.01-1.72). Participants scoring significantly lower for interpersonal trust did not regularly participate in religious meetings (OR = 0.61, 95%CI = 0.44-0.84, versus participation at least monthly); were more conscientious (ORT3vsT1 = 0.68, 95%CI = 0.51-0.91) or current smokers (OR = 0.68; 95%CI = 0.53-0.87, versus never smoking); had sleep problems >5 times a week (OR = 0.48; 95%CI = 0.36-0.66, versus none); and scored high on conspiracy belief (ORT3vsT1 = 0.53; 95%CI = 0.41-0.69). Results differed minimally by gender and country. These findings may be helpful in devising targeted strategies to strengthen interpersonal trust and social engagement in European societies, especially during times of crises., Competing Interests: The authors have declared that no competing interests exist., (Copyright: © 2023 Schernhammer et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.)

Microbially influenced concrete corrosion (MICC) causes substantial financial losses to modern societies. Concrete corrosion with various environmental factors has been studied extensively over several decades. With the enhancement of public awareness on the environmental and economic impacts of microbial corrosion, MICC draws increasingly public attention. In this review, the roles of various microbial communities on MICC and corresponding protective measures against MICC are described. Also, the current status and research methodology of MICC are discussed. Thus, this review aims at providing insight into MICC and its mechanisms as well as the development of protection possibilities.

Mitigating the effects of environmental deterioration requires a focus on not just CO 2 emissions from energy consumption, but also environmental pollution from industry sectors. To reach this goal, recent studies have extended ecological footprint (EF) analysis to identify the ecological drivers of various key industry sectors. The role of the phosphorus (P) industry on the EF within the environmental Kuznets curve (EKC) framework for China is the emphasis of this study. Autoregressive distributive lag (ARDL) as well as the impulse response function and robustness analysis were used to consider a time from 1985 to 2018. The study verifies the EKC hypothesis for China in both the long and the short run, and indispensable determinants are proposed to be included to assure the model's fitness and robustness when conducting EF analysis of industry sectors. Energy consumption-based carbon emissions have been verified as the dominant contributor to EF, but P use and urbanization have a significant lagged positive influence on EF in the short run. P exports, in particular, have been highlighted as a critical driver of the EF of China's P industry. The conducted frequency domain causality test reinforced the above findings and demonstrated bidirectional causality at different frequencies. This work suggests that formulating plausible P export policies to alleviate the conflict between the output of China's P industry and the environmental sustainability of this industry are necessary. In this context, "multidisciplinary, multidimensional, and practical solutions" are most desirable for sustainable P management., (© 2022. The Author(s).)

Microplastics are an obstinate pollutant in terrestrial environments, posing a risk to the subsurface soil matrix and potentially to groundwater. In this study, the transport and retention behaviour of two major plastic polymers, 125-300 μm Polyvinyl chloride (PVC) plastic fragments and 300 μm Low-density polyethylene (LDPE) spherical particles, were explored in saturated quartz sand (1.6-2.0 mm) columns. The PVC used in this study represented secondary microplastics, while the LDPE represented primary microplastics. Retention profiles at different ultrapure water flow rates (2.0-3.5 ml/min) were compared and analysed. At the beginning and end of each column test, the microplastic particles were scrutinized, identified, and quantified by light microscopy. The results showed that the transport distance of microplastic particles increased with their decreasing diameter. Small-sized PVC microplastic particles, whose morphology was more 1-dimensional, were more susceptible to fragmentation within the column, promoting migration. Spherical LDPE remained at their initial position without fragmenting. Microplastic degradation into fragments appeared to play an important role in improving the movement of particles. This study offers initial indications of infiltration depths and shape-dependent fragmentation of secondary microplastics in coarse sand based on the lab experiments., Competing Interests: Declaration of competing interest The authors declare that they have no competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Background: Emergence of new coronavirus variants and waning immunity may necessitate regular COVID-19 vaccine boosters, but empirical data on population willingness for regular vaccination are limited., Methods: In August 2021, we surveyed 3,067 quota-sampled German-speaking adults residing in the D-A-CH region (Germany, Austria, Switzerland). Using multivariable adjusted ordered logistic regression models we calculated odds ratios (OR) and 95% confidence intervals (95% CIs) to assess factors associated with willingness to vaccinate annually against COVID-19., Findings: Among 2,480 participants vaccinated or planning to get vaccinated, 82·4% indicated willingness to receive annual COVID-19 boosters. This willingness was higher in Austria (OR=1·47, 95% CI, 1·19-1·82; p < 0·001) and Germany (OR=1·98, 95% CI, 1·60-2·45; p  < 0·001) versus Switzerland and increased with age. Having voted in the last national election (OR opposition party voters =1·51, 95% CI=1·18-1·92; p  = 0·001 and OR governing party voters =1·57, 95% CI=1·28-1·93; p  < 0·001, versus non-voters) and not regularly participating in religious meetings (OR=1·37, 95% CI=1·08-1·73; p  = 0·009, versus participation at least monthly) were significantly associated with willingness to vaccinate, as was partial (OR=1·97, 95% CI=1·43-2·72; p  < 0·001) or total (OR=5·20, 95% CI=3·76-7·19; p  < 0·001) approval of COVID-19 mitigation measures (versus non-approval). By country, Austrians showed the strongest association of voting behavior and mitigation measure approval with willingness to vaccinate., Interpretation: Targeted promotion programs informed by political and religious engagement and mitigation measure approval are needed to increase willingness to receive regular COVID-19 boosters., Funding: Medical University of Vienna, Department of Epidemiology, Danube University Krems, Department for Knowledge and Communication Management; Austrian Society of Epidemiology., Competing Interests: JW received funding from the Austrian Society of Epidemiology. BMB reports that her institution (Brigham and Women's Hospital, Boston, MA, USA) received research grant funding from the US National Institutes of Health and from the American Institute for Cancer Research (AICR) to support research projects that she leads and that are unrelated to this manuscript (cancer etiology studies). She is also has been an unpaid member of the Scientific Advisory Panel of the Oliver Foundation (Key Biscayne, FL) since 2015 to help guide their work on pediatric cancer prevention. IS reports royalties from book publications and Honoraria (about 2-3 times per year) for invited lectures not exceeding on the average € 1000 per year. MB reports to have received funding from the German Federal Ministry of Science and Education, German Federal Ministry of Economic affairs, Saxonian Ministry of Science and the Arts, EU H-2020 and honoraria for reviews from European public funding organizations. MB also reports patents DE102021115850.8; DE102020134133.4; DE102020107138.8; DE102018105449.1; and he is Member of the Executive committee of the Saxonian Academy of Sciences, Secretary General for the technical sciences in the Saxonian Academy of Sciences, Head of DECHEMA expert group “Raw Materials”, as well as Director of Recycling unit at Fraunhofer Institute for Ceramic Technologies and Systems IKTS; Fraunhofer Technology Center for High-Performance Materials THM, Am St.-Niclas-Schacht 13, 09599 Freiberg, Germany. LZ reports small shares in a stock portfolio < 500 EUR. MDL reports funding from the NSF (USA), small amounts of royalties for several published books, and he is Advisory boards (KLI; Complexity Science Hub, Vienna, TU Graz; TISE). ESS reports funding from the National Institute of Health, FFG, FWF, H-2020, and received honoraria (about 2-3 times per year, each never >1000 Euro) for invited lectures. She is member on the Advisory board of trustees of the FWF (Austrian Science Fund), and the Scientific Advisory Board for the Annual Houska Award; honorary board member of the Austrian Cancer Help; scientific advisory board member for Cochrane Austria; advisory board member of the Austrian Scientific Community and member of Board of Trustees “Sparkling Science” Funding, Ministry of Health Austria; as well as ad hoc NIH study section member and Horizon Europe Scientific Review Panel member., (© 2022 The Author(s).)

To study the abnormal failure of magnesium anodes for buried pipelines in marine engineering in the unique environment of mudflats, a strain of a sulfate-reducing prokaryote (SRP) was isolated from pipe-laying soil, and identified as Desulfovibrio sp. HQM3. Weight-loss test, electrochemical measurements, SEM, EDS, XRD, and CLSM techniques were used to study the effect of corrosion on the AZ31B magnesium alloy. Under the influence of SRP, the magnesium alloy corroded severely at rates up to 1.31 mm/year in the mudflat environment. SRP accelerated corrosion by 0.3mm/year. Pitting occurred on the samples in both abiotic and biotic systems. The pitting depth reached 163.47 μm in the biotic system after 14 days. The main composition of a petal-like corrosion product was Mg(OH) 2 . The results show that a mudflat environment can lead to an accelerated corrosion of magnesium alloys.

Renewable biowaste-derived carbon dots have garnered immense interest owing to their exceptional optical, fluorescence, chemical, and environmentally friendly attributes, which have been exploited for the detection of metals, non-metals, and organics in the environment. In the present study, water-soluble fluorescent carbon dots (CDs) were synthesized via facile green microwave pyrolysis of pine-cone biomass as precursors, without any chemical additives. The synthesized fluorescent pine-cone carbon dots (PC-CDs) were spherical in shape with a bimodal particle-size distribution (average diameters of 15.2 nm and 42.1 nm) and a broad absorption band of between 280 and 350 nm, attributed to a π-π* and n-π* transition. The synthesized PC-CDs exhibited the highest fluorescent (FL) intensity at an excitation wavelength of 360 nm, with maximum emission of 430 nm. The synthesized PC-CDs were an excellent fluorescent probe for the selective detection of Cu 2+ in aqueous solution, amidst the presence of other metal ions. The FL intensity of PC-CDs was exceptionally quenched in the presence of Cu 2+ ions, with a low detection limit of 0.005 μg/mL; this was largely ascribed to Cu 2+ ion binding interactions with the enriched surface functional groups on the PC-CDs. As-synthesized PC-CDs are an excellent, cost effective, and sensitive probe for detecting and monitoring Cu 2+ metal ions in wastewater.

This study presents the first known exploration of Congo red dye (CR) adsorption by a polycationic Fe/Al Di-metal nanostructured composite (PDFe/Al) synthesised using Fe(III) and Al(III) recovered from authentic acid mine drainage (AMD). The PDFe/Al successfully removed CR from the aqueous solution. The mineralogical, microstructural, and chemical properties of the synthesised PDFe/Al adsorbent (before and after adsorption) were studied using state-of-the-art analytical instruments. The optimum conditions were observed to be 100 mg·L -1 CR, 1 g of the PDFe/Al in 500 mL adsorbate solution, 20 min of shaking, pH = 3-8, and a temperature of 35 °C. At optimised conditions, the PDFe/Al showed ≥99% removal efficacy for CR dye and an exceptionally high Langmuir adsorption capacity of 411 mg·g -1 . Furthermore, a diffusion-limited adsorption mechanism was observed, with two distinct surfaces involved in the adsorption of CR from an aqueous solution. It was determined that the adsorption of CR induced internal strain and deformation within the matrices and interlayers of the PDFe/Al which resulted in a marked increase in the adsorbent pore surface area and pore volume. The remarkably high adsorption capacity could be attributed to the high surface area. A regeneration study showed that the adsorbent could be reused more than four times for the adsorption of CR. The findings from this study demonstrated the feasibility of recovering valuable minerals from toxic and hazardous AMD and demonstrated their potential for the treatment of industrial wastewaters.

One of the main mechanisms of bacterial decolorization and degradation of azo dyes is the use of biological enzymes to catalyze the breaking of azo bonds. This paper shows the expression and properties of a novel azo reductase (hybrid-cluster NAD(P)-dependent oxidoreductase, accession no. A0A1S1BVU5, named BVU5) from the bacterial flora DDMZ1 for degradation of azo dyes. The molecular weight of BVU5 is about 40.1 kDa, and it contains the prosthetic group flavin mononucleotide (FMN). It has the decolorization ability of 80.1 ± 2.5% within 3 min for a dye concentration of 20 mg L -1 , and 53.5 ± 1.8% even for a dye concentration of 200 mg L -1 after 30 min. The optimum temperature of enzyme BVU5 is 30 °C and the optimum pH is 6. It is insensitive to salt concentration up to a salinity level of 10%. Furthermore, enzyme BVU5 has good tolerance toward some metal ions (2 mM) such as Mn 2+ , Ca 2+ , Mg 2+ and Cu 2+ and some organic solvents (20%) such as DMSO, methanol, isopentyl, ethylene glycol and N -hexane. However, the enzyme BVU5 has a low tolerance to high concentrations of denaturants. In particular, it is sensitive to the denaturants guanidine hydrochloride (GdmCl) (2 M) and urea (2 M). Analysis of the dye substrate specificity shows that enzyme BVU5 decolorizes most azo dyes, which is indicating that the enzyme is not strictly substrate specific, it is a functional enzyme for breaking the azo structure. Liquid chromatography/time-of-flight/mass spectrometry (LC-TOF-MS) revealed after the action of enzyme BVU5 that some intermediate products with relatively large molecular weights were produced; this illustrates a symmetric or an asymmetric rapid cleavage of the azo bonds by this enzyme. The potential degradation pathways and the enzyme-catalyzed degradation mechanism are deduced in the end of this paper. The results give insight into the potential of a rapid bio-pretreatment by enzyme BVU5 for processing azo dye wastewater., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Geoenergy and geoengineering applications usually involve fluid injection into and production from fractured media. Accounting for fractures is important because of the strong poromechanical coupling that ties pore pressure changes and deformation. A possible approach to the problem uses equivalent porous media to reduce the computational cost and model complexity instead of explicitly including fractures in the models. We investigate the validity of this simplification by comparing these two approaches. Simulation results show that pore pressure distribution significantly differs between the two approaches even when both are calibrated to predict identical values at the injection and production wells. Additionally, changes in fracture stability are not well captured with the equivalent porous medium. We conclude that explicitly accounting for fractures in numerical models may be necessary under some circumstances to perform reliable coupled thermohydromechanical simulations, which could be used in conjunction with other tools for induced seismicity forecasting., (© 2021. The Authors.)

Advanced nanotechnologies for efficient arsenic decontamination remain largely underdeveloped. The most abundant inorganic arsenic species are neutrally-charged arsenate, As(III), and negatively-charged arsenite, As(V). Compared with As(V), As(III) is 60 times more toxic and more difficult to remove due to high mobility. Herein, an electrochemical filtration system was rationally designed for one-step As(III) decontamination. The key to this technology is a functional electroactive carbon nanotube (CNT) filter functionalized with sea urchin-like FeOOH. With the assistance of electric field, CNT-FeOOH anodic filter can in situ transform As(III) to less toxic As(V) while passing through. Then, as-produced As(V) could be effectively sequestrated by FeOOH. The sufficient exposed sorption sites, flow-through design, and filter's electrochemical reactivity synergistically guaranteed a rapid arsenic removal kinetic. The underlying working mechanism was unveiled based on systematic experimental investigations and theoretical calculations. The system efficacy can be adapted across a wide pH range and environmental matrixes. Exhausted CNT-FeOOH filters could be effectively regenerated by chemical washing with diluted NaOH solution. Outcomes of the present study are dedicated to provide a straightforward and effective strategy by integrating electrochemistry, nanotechnology, and membrane separation for the removal of arsenic and other similar heavy metals from water bodies., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Common Machine-Learning (ML) approaches for scene classification require a large amount of training data. However, for classification of depth sensor data, in contrast to image data, relatively few databases are publicly available and manual generation of semantically labeled 3D point clouds is an even more time-consuming task. To simplify the training data generation process for a wide range of domains, we have developed the BLAINDER add-on package for the open-source 3D modeling software Blender, which enables a largely automated generation of semantically annotated point-cloud data in virtual 3D environments. In this paper, we focus on classical depth-sensing techniques Light Detection and Ranging (LiDAR) and Sound Navigation and Ranging (Sonar). Within the BLAINDER add-on, different depth sensors can be loaded from presets, customized sensors can be implemented and different environmental conditions (e.g., influence of rain, dust) can be simulated. The semantically labeled data can be exported to various 2D and 3D formats and are thus optimized for different ML applications and visualizations. In addition, semantically labeled images can be exported using the rendering functionalities of Blender.

We would like to extend on the article by Alley et al [...].

The microstructural and optical reflectivity response of photonic SiO 2 /TiO 2 nanomultilayers have been investigated as a function of temperature and up to the material system's melting point. The nanomultilayers exhibit high, broadband reflectivities up to 1350 °C with values that exceed 75% for a 1 μm broad wavelength range (600-1600 nm). The optimized nanometer sized, dielectric multilayers undergo phase transformations from anatase TiO 2 and amorphous SiO 2 to the thermodynamically stable phases, rutile and cristobalite, respectively, that alter their structural morphology from the initial multilayers to that of a scatterer. Nonetheless, they retain their photonic characteristics, when characterized on top of selected substrate foils. The thermal behavior of the nanometer sized multilayers has been investigated by differential thermal analysis (DTA) and compared to that of commercially available, mm-sized, annealed powders. The same melting reactions were observed, but the temperatures were lower for the nm-sized samples. The samples were characterized using X-ray powder diffraction before DTA and after annealing at temperatures of 1350 and 1700 °C. The microstructural evolution and phase compositions were investigated by scanning electron microscopy and energy-dispersive X-ray spectroscopy measurements. The limited mutual solubility of one material to another, in combination with the preservation of their optical reflectivity response even after annealing, makes them an interesting material system for high-temperature, photonic coatings, such as photovoltaics, aerospace re-entry and gas turbines, where ultra-high temperatures and intense thermal radiation are present., Supplementary Information: The online version contains supplementary material available at 10.1007/s10853-021-06557-y., Competing Interests: Conflict of interestAll authors declare that they have no competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© The Author(s) 2021.)

Although the first coronavirus disease 2019 (COVID-19) wave has peaked with the second wave underway, the world is still struggling to manage potential systemic risks and unpredictability of the pandemic. A particular challenge is the "superspreading" of the virus, which starts abruptly, is difficult to predict, and can quickly escalate into medical and socio-economic emergencies that contribute to long-lasting crises challenging our current ways of life. In these uncertain times, organizations and societies worldwide are faced with the need to develop appropriate strategies and intervention portfolios that require fast understanding of the complex interdependencies in our world and rapid, flexible action to contain the spread of the virus as quickly as possible, thus preventing further disastrous consequences of the pandemic. We integrate perspectives from systems sciences, epidemiology, biology, social networks, and organizational research in the context of the superspreading phenomenon to understand the complex system of COVID-19 pandemic and develop suggestions for interventions aimed at rapid responses.

Gold (Au) has been considered catalytically inert for decades, but recent reports have described the ability of Au nanoparticles to catalyze H 2 O 2 decomposition in the Haber-Weiss cycle. Herein, the design and demonstration of a flow-through electro-Fenton system based on an electrochemical carbon nanotube (CNT) filter functionalized with atomically precise Au nanoclusters (AuNCs) is described. The functionality of the device was then tested for its ability to catalyze antibiotic tetracycline degradation. In the functional filters, the Au core of AuNCs served as a high-performance Fenton catalyst; while the AuNCs ligand shells enabled CNT dispersion in aqueous solution for easy processing. The hybrid filter enabled in situ H 2 O 2 production and catalyzed the subsequent H 2 O 2 decomposition to HO·. The catalytic function of AuNCs lies in their ability to undergo redox cycling of Au + /Au 0 under an electric field. The atomically precise AuNCs catalysts demonstrated superior catalytic activity to larger nanoparticles; while the flow-through design provided convection-enhanced mass transport, which yielded a superior performance compared to a conventional batch reactor. The adsorption behavior and decomposition pathway of H 2 O 2 on the filter surfaces were simulated by density functional theory calculations. The research outcomes provided atomic-level mechanistic insights into the Au-mediated Fenton reaction.

Developing advanced technologies to achieve decontamination of emerging contaminants such as antimony (Sb) is highly demanded. Herein, we successfully designed a dual-functional photoelectrochemical filter system for "one-step" detoxification and sequestration of highly toxic Sb(III). The key to this technology is a photoelectrical-responsive CNT filter functionalized with nanoscale MIL-88B(Fe) photocatalysts. At 2.5 V and under illumination, a 97.7 ± 1.5 % Sb(III) transformation and a 92.9 ± 2.3 % Sb total removal efficiency can be obtained using an optimal hybrid filter (e.g. CM(50:3)) over 2 h continuous filtration. This can be explained by the synergistic effects of the filter's flow-through design, photoelectrochemical reactivity, fine pore size, and plentiful exposed sorption sites. Various advanced characterization techniques validated the system efficacy. Improved Sb(III) removal kinetics were observed when compared with conventional batch system (97.5 % vs 75.8 %). A synergistic effect between photocatalytic (PC) and electrochemical (EC) process were identified (k PEC =0.99 h -1 >k PC =0.21 h -1 + k EC =0.30 h -1 ). EPR and photochemical characterizations suggested that hydroxyl radicals dominated the Sb(III) conversion. The proposed technology works effectively across a wide range of pH values and water matrixes. The outcomes of this study can facilitate mechanistic insights into photoelectrocatalysis and provide a promising nanotechnology for efficient Sb(III) decontamination., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Environmental pollution caused by antimony (Sb) has attracted worldwide attention recently. Here, we employed a flow-through electro-Fenton system for the rapid and efficient detoxification of highly toxic Sb(III). A FeOCl modified carbon nanotube (CNT) filter served as functional cathode, where FeOCl as nanocatalyst promoted the generation of HO by facilitating effective Fe 3+ /Fe 2+ cycling. Upon application of a proper potential, an ultra-rapid conversion of Sb(III) to less toxic Sb(V) can be achieved in situ just by a single-pass filtration (>99% within 2 s). Compared with the conventional batch reactor, the proposed system demonstrated ultra-rapid Sb(III) detoxification kinetics due to the convection-enhanced mass transport. The proposed flow-through E-Fenton system works effectively across a wide pH range (e.g., 3-9). EPR technique and radical quenching experiments indicate that HO and HO 2 were the dominant radical species responsible for Sb(III) detoxification. At -0.4 V vs. Ag/AgCl, a >96.4% Sb(III) conversion efficiency still can be achieved when challenged with 500 μg L -1 Sb(III)-spiked tap water. The as-produced Sb(V) can be removed effectively by another Sb(V)-specific CNT filter functionalized with nanoscale iron oxides. The outcome of this research provides a promising strategy by integrating state-of-the-art electro-Fenton, membrane separation, carboncatalysis and nanotechnology for detoxification of Sb(III) and other similar heavy metal ions in polluted water., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

In this study, electrooxidation of the tetracycline hydrolysis products was investigated using a carbon nanotube (CNT) electrochemical filter and 4-epianhydrochlortetracycline (EACTC) as a model compound. Electrochemical filtration of 10 μmol L -1 EACTC at a voltage of 2.5 V and a flow rate of 1.5 mL min -1 (hydraulic residence time <3 s) provided an oxidation flux of 1251 ± 28 μmol h -1 m -2 . Replacement of the Ti cathode with a CNT filter cathode increased the EACTC oxidative flux by 1.3 fold at a voltage of 2.5 V. The electrochemical filtration process is effective for the degradation of EACTC and the reduction of the antimicrobial activity based on liquid chromatography time-of-flight mass spectrometry (LC-TOF-MS) analysis and luminescent bacteria test. The high oxidation flux within 300 min (1212-1263 μmol h -1 m -2 ) and affordable cost (0.25 kWh m -3 ) at a voltage of 2.5 V show the potential application of the electrochemical filtration system as a promising unit for EACTC degradation. These findings provided new insights into the rational design principles of novel continuous-flow filtration system aimed to efficiently remove hydrolysis products of the antibiotic tetracycline., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Compared with phosphate (+5 valence), phosphite (HPO 3 2 - , +3 valence) possesses higher solubility, and is more resistant to biotransformation. Herein, we designed a one-step electroactive filter technology for rapid and efficient phosphite removal. The filter consists of carbon nanotubes (CNT) and functionalized with nanoscale TiCe binary oxides. The phosphite removal kinetics and capacity increased with electric field (e.g., from 54.5% at 0 V to 75.6% at 2 V) and flow rate (e.g., from 63.1% at 1.5 mL/min to 81.2% at 6 mL/min). This can be attributed to synergistic effects of the filter's electrochemical reactivity, limited pore size, more exposed active sites and flow-through design. Meanwhile, phosphite can be converted to phosphate once adsorbed under electric field. The TiO 2 PO 3 -CNT filter could work effectively across a wide pH range, and the presence of various coexisting anions posed negligible impact on phosphite removal. Electrochemical characterizations verified the essential role of CeO - and applied electric field, which synergistically accelerated electron transfer rate and increased charge capacity. The TiO 2 /CeO x -CNT filter can be regenerated effectively by chemical washing. The system efficacy was further supported by a comparable phosphite removal efficiency of 72.8% in actual lake water conditions. Therefore, this TiO x and applied electric field, which synergistically accelerated electron transfer rate and increased charge capacity. The TiO 2 -CNT filter technology is promising for mitigating the challenging issue of phosphite contamination from water bodies.x -CNT filter can be regenerated effectively by chemical washing. The system efficacy was further supported by a comparable phosphite removal efficiency of 72.8% in actual lake water conditions. Therefore, this TiO 2 /CeO x -CNT filter technology is promising for mitigating the challenging issue of phosphite contamination from water bodies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Background: Underground miners can experience occupational health diseases due to exposure to particulate matter hazards., Objectives: The aim of the present study was to examine occupational exposures of underground miners to dust and diesel particulate matter and to identify exposure groups with high potential to develop associated health effects due to the presence of dust and diesel particulate matter (DPM) hazards in an underground gold mine in Ghana., Methods: Purposive sampling was employed using gravimetric air samplers over an 8-hour time weighted average period. The National Institute for Occupational Safety and Health (NIOSH) analytical Chapter Q and 5040 were used in determining crystalline silica dust and diesel particulate matter fractions, respectively. Structured questionnaires were administered to gather data on workers' level of awareness to dust and DPM exposures., Results: It was found that 41% of the sampled groups were exposed to higher crystalline silica levels above the (NIOSH) permissible exposure limit (PEL) level of 0.05 mg/m 3 . For DPM, 49% of these groups had exposures above the Mine Safety and Health Administration (MSHA) PEL level of 160 μg/m 3 . Among the 94 mine workers who responded to this study, 62% were found to be aware of the presence and hazardous nature of silica dust, 28% had minimal knowledge and the remaining were found to be unaware., Conclusions: There are varying levels of dust and DPM due to the presence of silica-bearing rocks, the production of diesel fumes and inefficiencies of available mitigation measures. Research carried out over the past decades has found confirmed cases of silicosis and lung cancer due to high dust exposure levels. Rock drillers, blast men and shotcrete operators were found to be exposed to higher levels of dust and diesel particulate matter and are at greater risk of silicosis., Participant Consent: Obtained., Ethics Approval: This study was approved by the Ethics Committee of the Kwame Nkrumah University of Science and Technology, Ghana and carried out under full consent of the mining company under study., Competing Interests: The authors declare no competing financial interests., (© Pure Earth 2020.)

Membrane fouling is the bottleneck limiting the wide application of membrane processes. Herein, we adopted an electroactive polyether sulfone (PES) membrane capable of mitigating fouling by various negatively charged foulants. To evaluate anti-fouling performance and the underlying mechanism of this electroactive PES membrane, three types of model foulants were selected rationally (e.g., bovine serum albumin (BSA) and sodium alginate (SA) as non-migratory foulants, yeast as a proliferative foulant and emulsified oil as a spreadable foulant). Water flux and total organic carbon (TOC) removal efficiency in the filtering process of various foulants were tested under an electric field. Results suggest that under electrochemical assistance, the electroactive PES membrane has an enhanced anti-fouling efficacy. Furthermore, a low electrical field was also effective in mitigating the membrane fouling caused by a mixture of various foulants (containing BSA, SA, yeast and emulsified oil). This result can be attributed to the presence of electrostatic repulsion, which keeps foulants away from the membrane surface. Thereby it hinders the formation of a cake layer and mitigates membrane pore blocking. This work implies that an electrochemical control might provide a promising way to mitigate membrane fouling.

In this study, we have developed a continuous-flow electrochemical system towards the rapid and selective conversion of ammonia to N 2 , based on a tubular substoichiometric titanium dioxide (Ti 4 O 7 ) anode and a Pd-Cu co-modified Ni foam (Pd-Cu/NF) cathode, both of which are indispensable. Under the action of a suitable anode potential, the Ti 4 O 7 anode enables the conversion of Cl - to chloride radicals (Cl˙), which could selectively react with ammonia to produce N 2 . The anodic byproducts, e.g. NO 3 - at the Pd-Cu/NF cathode. EPR and scavenger experiments confirmed the dominant role of Cl˙ in ammonia conversion. Complete transformation of 30 mg L 2 ammonia could be obtained over 40 min of continuous operation under optimal conditions. The proposed electrochemical system also exhibits enhanced oxidation kinetics compared to conventional batch systems. This study provides new insights into the rational design of a high-performance electrochemical system to address the challenging issue of ammonia pollution.-1 ammonia could be obtained over 40 min of continuous operation under optimal conditions. The proposed electrochemical system also exhibits enhanced oxidation kinetics compared to conventional batch systems. This study provides new insights into the rational design of a high-performance electrochemical system to address the challenging issue of ammonia pollution., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Fructose was utilized as an additional co-substrate to systematically investigate the molecular mechanism of its boosting effect for the degradation of refractory dye reactive black 5 (RB5) by a natural bacterial flora DDMZ1. A decolorizing rate of 98% was measured for sample YE + FRU(200) (with 3 g/L fructose additionally to yeast extract medium, 10% (v/v) inoculation size of flora DDMZ1, 200 mg/L RB5) after 48 h. This result was 21% and 77%, respectively, higher than those of samples with only yeast extract or only fructose. Fructose was found to significantly stimulated both intracellular and extracellular azoreductase secretion causing enhanced activity. Metagenomic sequencing technology was used to analyze the functional potential of genes. A label-free quantitative proteomic approach further confirmed the encoding of functional proteins by the candidate genes. Subsequently, the molecular mechanism of RB5 degradation by candidate genes and functional proteins of the dominant species were proposed. This study provides important perspectives to the molecular mechanism of co-metabolic degradation of refractory pollutants by a natural bacterial flora., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Being able to simultaneously reduce and adsorb highly toxic Cr(VI) from bodies of water would provide a significant advance in the treatment of water pollution. Herein, we report on the design of an electroactive filter consisting of nanoscale polyaniline modified carbon nanotubes (PANI-CNT). In an electric field, both Cr(VI) reduction kinetics and Cr(III) sorption capacity were enhanced as the flow rate and voltage increased. At pH 7, Cr(VI) removal efficiency increased from 29.3% at 0 V to 70.2% at 2.5 V. This can be ascribed to superior electrical conductivity, more available active sites and limited pore size of the PANI-CNT filter, further boosted by the flow-through operation. Due to convection-enhanced mass transport, the proposed continuous-flow PANI-CNT filter demonstrated an evidently enhanced kinetic process when compared to conventional batch system. Various advanced assessments and density functional theory calculations verified the essential role of the electric field during Cr(VI) removal. Scanning transmission electron microscopy (STEM) examinations showed that the Cr was mainly sequestered by the PANI. It was also confirmed that an exhausted PANI-CNT filter can be regenerated by chemical washing with an HCl solution. Experiments with actual Cr(VI)-contaminated electroplating wastewater further verified the effectiveness of the system, with complete Cr(VI) transformation and a 50% Cr total removal efficiency at 2.5 V with a flow rate of 3 mL/min. This study provides new insights into practical continuous-flow solutions to the effective removal of highly toxic Cr(VI)., (Copyright © 2019 Elsevier B.V. All rights reserved.)

We have designed a facile method to synthesize a dual-functional electrochemical filter consisting of two 1-D materials: titanate nanowires and carbon nanotubes. The hybrid titanate-CNT filter was prepared by a sonication coupled with a post-filtration route. Due to the synergistic effects of the increased number of exposed sorption sites, electrochemical reactivity, small pore size of the titanate-CNT network coupled with a flow-through design, simultaneous Sb(III) oxidation and sequestration can be readily achieved. Atomic fluorescence spectrometer technology demonstrated that the applied electrical field accelerates the Sb(III) conversion rate and the as-obtained Sb(V) were adsorbed effectively by the titanate nanowires due to their Sb specificity. This protocol provides a practical solution for the removal of highly toxic Sb(III) and other similar heavy metal ions.

Four sugar sources were used as co-substrates to promote the degradation of a selected refractory dye reactive black 5 (RB5) by the natural bacterial flora DDMZ1. The boosting performance of the four sugar sources on RB5 decolorization ranked as: fructose > sucrose > glucose > glucose + fructose. Kinetic results of these four co-metabolism systems agreed well with a first-order kinetic model. Four sugar sources stimulated the extracellular azoreductase secretion causing enhanced enzyme activity. An increased formation of low molecular weight intermediates was caused by the addition of sugar sources. The toxicity of RB5 degradation products was significantly reduced in the presence of sugar sources. The bacterial community structure differed remarkably as a result of sugar sources addition. For a fructose addition, a considerably enriched population of the functional species Burkholderia-Paraburkholderia and Klebsiella was noted. The results enlarge our knowledge of the microkinetic and microbiological mechanisms of co-metabolic degradation of refractory pollutants., (Copyright © 2019 Elsevier Inc. All rights reserved.)

Water contamination from ammonia has recently became a global concern. Herein, a chloride-radical-mediated electrochemical filtration system has been developed towards effective and rapid conversion of ammonia to nitrogen (N 2 ). This continuous-flow system consists of a nanoscale tin oxide modified carbon nanotube (SnO 2 -CNT) anode and a Pd-Cu co-modified Ni foam (Pd-Cu/NF) cathode. The SnO 2 -CNT anode enables the Cl - oxidation to a chloride radical (Cl) at a proper anode potential (e.g., 2.5 V vs. Ag/AgCl) without severe self-oxidation. The macro-porous Pd-Cu/NF cathode further reduces anodic by-products (e.g., NO 3 and NO - and NO 2 . EPR and scavenging tests indicate that Cl was the dominant radical specie responsible for ammonia conversion. Anode potentials, chloride concentration, flow rate and solution pH were identified as key parameters affecting the overall conversion performance. The proposed continuous-flow system showed enhanced conversion kinetics as compared to the conventional batch reactor due to the convectively enhanced mass transport. This study provides new insight for the rational design of advanced continuous-flow systems towards ammonia decontamination from water bodies.- ) to N 2 . EPR and scavenging tests indicate that Cl was the dominant radical specie responsible for ammonia conversion. Anode potentials, chloride concentration, flow rate and solution pH were identified as key parameters affecting the overall conversion performance. The proposed continuous-flow system showed enhanced conversion kinetics as compared to the conventional batch reactor due to the convectively enhanced mass transport. This study provides new insight for the rational design of advanced continuous-flow systems towards ammonia decontamination from water bodies., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Methanogenic degradation of n -alkanes is prevalent in n -alkane-impacted anoxic oil reservoirs and oil-polluted sites. However, little is known about the initial activation mechanism of the substrate, especially n -alkanes with a chain length above C 16 Here, a methanogenic C 16 to C 20 -alkane-degrading enrichment culture was established from production water of a low-temperature oil reservoir. At the end of the incubation (364 days), C n -alkane-degrading enrichment culture was established from production water of a low-temperature oil reservoir. At the end of the incubation (364 days), C 16 to C 20 -alkane-amended enrichment culture, suggesting that fumarate addition had occurred in the degradation process. This evidence is supported further by the positive amplification of the n gene encoding the alpha subunit of alkylsuccinate synthase. A phylogenetic analysis shows these assA gene encoding the alpha subunit of alkylsuccinate synthase. A phylogenetic analysis shows these assA and Smithella clades. Together with the high abundance of these clades in the bacterial community, these two species are postulated to be the key players in the degradation of C Desulfatibacillum clades. Together with the high abundance of these clades in the bacterial community, these two species are postulated to be the key players in the degradation of C 16 to C 20 n Methanogenic hydrocarbon degradation is the major process for oil degradation in subsurface oil reservoirs and is blamed for the formation of heavy oil and oil sands. Addition of n -alkanes to fumarate yielding alkyl-substituted succinates is a well-characterized anaerobic activation mechanism for hydrocarbons and is the most common activation mechanism in the anaerobic biodegradation of IMPORTANCE Methanogenic hydrocarbon degradation is the major process for oil degradation in subsurface oil reservoirs and is blamed for the formation of heavy oil and oil sands. Addition of n However, the activation mechanism involved in the methanogenic biodegradation of n -alkanes with chain lengths less than C 16 is still uncertain. In this study, we analyzed a methanogenic enrichment culture amended with a mixture of C n -alkanes longer than C 16 is still uncertain. In this study, we analyzed a methanogenic enrichment culture amended with a mixture of C 16 to C 20 and n species under methanogenic conditions. These observations provide a fundamental understanding of long- n -alkane metabolism under methanogenic conditions and have important applications for the remediation of oil-contaminated sites and for energy recovery from oil reservoirs.Smithella and Desulfatibacillum species under methanogenic conditions. These observations provide a fundamental understanding of long- n -alkane metabolism under methanogenic conditions and have important applications for the remediation of oil-contaminated sites and for energy recovery from oil reservoirs., (Copyright © 2019 American Society for Microbiology.)

Herein, nanoscale iron (oxyhydr)oxide-coated carbon nanotube (CNT) filters were rationally designed for rapid and effective removal of Sb(iii) from water. These iron (oxyhydr)oxide particles (<5 nm) were uniformly coated onto the CNT sidewalls. The as-fabricated hybrid filter demonstrated improved sorption kinetics and capacity compared with the conventional batch system. At a flow rate of 6 mL min -1 , a Sb(iii) pseudo-first-order adsorption rate constant of 0.051 and a removal efficiency of >99% was obtained when operated in the recirculation mode. The improved Sb(iii) sorption performance can be ascribed to the synergistic effects of convection-enhanced mass transport, limited pore size, and more exposed active sorption sites of the filters. The presence of 1-10 mmol L -1 of carbonate, sulfate, and chloride inhibits Sb(iii) removal negligibly. Exhausted hybrid filters can be effectively regenerated by an electrical field-assisted chemical washing method. STEM characterization confirmed that Sb was mainly sequestered by iron (oxyhydr)oxides. XPS, AFS and XAFS results suggest that a certain amount of Sb(iii) was converted to Sb(v) during filtration. DFT calculations further indicate that the bonding energy for Sb(iii) onto the iron (oxyhydr)oxides was 2.27-2.30 eV, and the adsorbed Sb(iii) tends to be oxidized., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Environmental pollution and energy crisis have become recent worldwide concerns. Huge amounts of organic wastes are discharged into water bodies, causing serious environmental pollution. Meanwhile, these organic compounds are important carbon and energy sources that could be utilized instead of being discarded. A smart design of a photocatalytic fuel cell (PFC) can achieve double benefits: it can degrade organic pollutants and at the same time generate energy. In this review article, we discuss recent progress in the development of PFC systems, and summarize the principles for constructing advanced PFC systems. We particularly focus on the rational design of electrode materials in terms of surface, morphology, facet, and interfacial reaction engineering. The impact of important operational parameters on PFC performance is further discussed in detail. We then discuss the major limitations and opportunities for future PFCs research. The development of smart and advanced PFC systems depends on highly interdisciplinary collaborations, which require concerted efforts from the communities of materials science, chemistry, engineering, and environmental science., (Copyright © 2019 Elsevier B.V. All rights reserved.)

The malodor attached to textiles not only causes indoor environmental pollution but also endangers people's health even at low concentrations. Existing technologies cannot effectively eliminate the odor. Herein, an effective and environmentally friendly technology was proposed to address this challenging issue. This technology utilizes electrospraying process to produce Engineered Water Nanostructures (EWNS) in a controllable manner. Upon application of a high voltage to the Taylor cone, EWNS can be generated from the condensed vapor water through a Peltier element. Smoking, cooking and perspiration, considered the typical indoor malodorous gases emitted from human activities, were studied in this paper. A headspace SPME method in conjunction with GC-MS was employed for the extraction, detection and quantification of any odor residues. Results indicated that EWNS played a significant role in the deodorization process with removal efficiencies for the three odors were 95.3 ± 0.1%, 100.0 ± 0.0% and 43.7 ± 2.3%, respectively. The Reactive Oxygen Species (ROS) contained in the EWNS, mainly hydroxyl (OH˙) and superoxide radicals are the possible mechanisms for the odor removal. These ROS are strong oxidative and highly reactive and have the ability to convert odorous compounds to non-odorous compounds through various chemical reaction mechanisms. This study showed clearly the potential of the proposed method in the field of odor removal and can be applied in the battle against indoor air pollution., Competing Interests: There are no conflicts of interest to declare., (This journal is © The Royal Society of Chemistry.)

In this work, the performance and mechanism for the boosting effects of fructose as an additional co-metabolite towards the biological treatment of reactive black 5 were systematically investigated. A decolorization efficiency of 98% was obtained in sample FRU200 (with 3 g/L fructose added based on 3 g/L yeast extract), which was 21% higher than that without fructose. Several intermediates with low molecular weight generated in sample FRU200 and different metabolic pathways were deduced. The bacterial community structure significantly changed due to fructose addition. Label-free quantitative proteomic approach suggested that several up-regulated proteins in sample FRU200 might play essential roles during the degradation. Furthermore, the mechanisms of RB5 degradation by proteins/enzymes of the dominant species in flora DDMZ1 were proposed. This work deepens our understanding of the molecular and ecological mechanism of fructose as co-metabolite enhancing the biodegradation of refractory organic pollutants by a natural bacterial flora., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Herein, we rationally designed a dual-functional electroactive filter system for simultaneous detoxification and sequestration of Sb(III). Binder-free and nanoscale TiO 2 -modified carbon nanotube (CNT) filters were fabricated. Upon application of an external electrical field, in situ transformation of Sb(III) to less toxic Sb(V) can be achieved, which is further sequestered by TiO 2 . Sb(III) removal kinetics and capacity increase with applied voltage and flow rate. This can be explained by the synergistic effects of the filter's flow-through design, electrochemical reactivity, small pore size, and increased number of exposed sorption sites. STEM characterization confirms that Sb were mainly sequestered by TiO 2 . XPS, AFS, and XAFS results verify that the Sb(III) conversion process was accelerated by the electrical field. The proposed electroactive filter technology works effectively across a wide pH range. The presence of sulfate, chloride, and carbonate ions negligibly inhibited Sb(III) removal. Exhausted TiO 2 -CNT filters can be effectively regenerated using NaOH solution. At 2 V, 100 μg/L Sb(III)-spiked tap water generated ∼1600 bed volumes of effluent with >90% efficiency. Density functional theory calculations suggest that the adsorption energy of Sb(III) onto TiO 2 increases (from -3.81 eV to -4.18 eV) and Sb(III) becomes more positively charged upon application of an electrical field.

Herein, a strengthened circulation anaerobic (SCA) reactor was employed for the treatment of actual alkali-decrement wastewater. The degradation mechanism of polyester oligomers and the relationship between the treatment performance and microbial community structure were systematically investigated using various advanced techniques. Results suggest that the accumulation of volatile fatty acids has an inhibitory effect on methanogenic activity. Molecular weight distributions suggest that only incomplete degradation of oligomers was achieved, due to acetogenic inhibition in the lower part of the SCA reactor. Meta-proteomic approach analysis revealed that the methanogens containing heterodisulfide reductase were the primary species involved in methane metabolism. Based on these findings, a possible degradation mechanism for alkali-decrement wastewater in the SCA reactor is proposed. This high-performance anaerobic reactor could be further scaled-up and optimized to serve as a promising and effective unit for the treatment of other refractory industrial wastewaters., (Copyright © 2018 Elsevier Ltd. All rights reserved.)