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Abstract. The early Eocene (56 to 48 million years ago) is inferred to havebeen the most recent time that Earth's atmospheric CO2 concentrationsexceeded 1000 ppm. Global mean temperatures were also substantially warmerthan those of the present day. As such, the study of early Eocene climate provides insightinto how a super-warm Earth system behaves and offers an opportunity toevaluate climate models under conditions of high greenhouse gas forcing. TheDeep Time Model Intercomparison Project (DeepMIP) is a systematicmodel–model and model–data intercomparison of three early Paleogene timeslices: latest Paleocene, Paleocene–Eocene thermal maximum (PETM) and earlyEocene climatic optimum (EECO). A previous article outlined the modelexperimental design for climate model simulations. In this article, weoutline the methodologies to be used for the compilation and analysis ofclimate proxy data, primarily proxies for temperature and CO2. Thispaper establishes the protocols for a concerted and coordinated effort tocompile the climate proxy records across a wide geographic range. Theresulting climate “atlas” will be used to constrain and evaluate climatemodels for the three selected time intervals and provide insights into themechanisms that control these warm climate states. We provide version 0.1 ofthis database, in anticipation that this will be expanded in subsequentpublications.

Climate variability is typically amplified towards polar regions. The underlying causes, notably albedo and humidity changes, are challenging to accurately quantify with observations or models, thus hampering projections of future polar amplification. Polar amplification reconstructions from the ice-free early Eocene (∼56 –48 Ma) can exclude ice albedo effects, but the required tropical temperature records for resolving timescales shorter than multi-million years are lacking. Here, we reconstruct early Eocene tropical sea surface temperature variability by presenting an up to ∼4 kyr resolution biomarker-based temperature record from Ocean Drilling Program (ODP) Site 959, located in the tropical Atlantic Ocean. This record shows warming across multiple orbitally paced carbon cycle perturbations, coeval with high-latitude-derived deep-ocean bottom waters, showing that these events represent transient global warming events (hyperthermals). This implies that orbital forcing caused global temperature variability through carbon cycle feedbacks. Importantly, deep-ocean temperature variability was amplified by a factor of 1.7–2.3 compared to the tropical surface ocean, corroborating available long-term estimates. This implies that fast atmospheric feedback processes controlled meridional temperature gradients on multi-million year, as well as orbital, timescales during the early Eocene. Our combined records have several other implications. First, our amplification factor is somewhat larger than the same metric in fully coupled simulations of the early Eocene (1.1–1.3), suggesting that models slightly underestimate the non-ice-related – notably hydrological – feedbacks that cause polar amplification of climate change. Second, even outside the hyperthermals, we find synchronous eccentricity-forced temperature variability in the tropics and deep ocean that represent global mean sea surface temperature variability of up to 0.7 °C, which requires significant variability in atmospheric p CO 2. We hypothesize that the responsible carbon cycle feedbacks that are independent of ice, snow, and frost-related processes might play an important role in Phanerozoic orbital-scale climate variability throughout geological time, including Pleistocene glacial–interglacial climate variability. [ABSTRACT FROM AUTHOR]

The element mercury (Hg) is a key pollutant, and much insight has been gained by studying the present-day Hg cycle. However, many important processes within this cycle operate on timescales responsive to centennial- to millennial-scale environmental variability, highlighting the importance of also investigating the longer-term Hg records in sedimentary archives. To this end, we here explore the timing, magnitude, and expression of Hg signals retained in sediments over the past ∼ 90 kyr from two lakes, linked by a subterranean karst system: Lake Prespa (Greece, North Macedonia, and Albania) and Lake Ohrid (North Macedonia and Albania). Results suggest that Hg fluctuations are largely independent of variability in common host phases in each lake, and the recorded sedimentary Hg signals show distinct differences first during the Late Pleistocene (Marine Isotope Stages 2–5). The Hg signals in Lake Prespa sediments highlight an abrupt, short-lived peak in Hg accumulation coinciding with local deglaciation. In contrast, Lake Ohrid shows a broader interval with enhanced Hg accumulation and, superimposed, a series of low-amplitude oscillations in Hg concentration peaking during the Last Glacial Maximum, which may result from elevated clastic inputs. Divergent Hg signals are also recorded during the Early and Middle Holocene (Marine Isotope Stage 1). Here, Lake Prespa sediments show a series of large Hg peaks, while Lake Ohrid sediments show a progression to lower Hg values. Since ∼ 3 ka , anthropogenic influences overwhelm local fluxes in both lakes. The lack of coherence in Hg accumulation between the two lakes suggests that, in the absence of an exceptional perturbation, local differences in sediment composition, lake structure, Hg sources, and water balance all influence the local Hg cycle and determine the extent to which Hg signals reflect local- or global-scale environmental changes. [ABSTRACT FROM AUTHOR]

The International Ocean Discovery Program (IODP) Expedition 396 to the mid-Norwegian margin recovered > 1300 m of pristinely preserved, volcanic-ash-rich sediments deposited during the late Paleocene and early Eocene from close to the centre of the North Atlantic Igneous Province (NAIP). Remarkably, many of these cores contain glendonites, pseudomorphs after the purported cold-water mineral ikaite, from sediments dated to the late Paleocene and early Eocene. These time intervals span some of the hottest climates of the Cenozoic, including the Paleocene–Eocene Thermal Maximum (PETM). Global deep-ocean temperatures are not thought to have dropped below 10 ∘ C at any point during this time, making the occurrence of supposedly cold-water (near-freezing temperature) glendonite pseudomorphs seemingly paradoxical. This study presents a detailed sedimentological, geochemical, and microscopic study of the IODP Exp. 396 glendonites and presents an updated model for the ikaite-to-calcite transformation for these glendonites. Specifically, we show that early diagenesis of basaltic ashes of the NAIP appear to have chemically promoted ikaite growth in the sediments in this region. Together with existing knowledge of late Paleocene and early Eocene glendonites from Svalbard to the north and early Eocene glendonites from Denmark to the south, these new glendonite finds possibly imply episodic, short-duration, and likely localized cooling in the Nordic Seas region, which may have been directly or indirectly linked to the emplacement of the NAIP. [ABSTRACT FROM AUTHOR]

Sedimentary bulk organic matter and various molecular organic components exhibit strong CO 2 -dependent carbon isotope fractionation relative to dissolved inorganic carbon sources. This fractionation (εp) has been employed as a proxy for paleo- p CO 2. Yet, culture experiments indicate that CO 2 -dependent εp is highly specific at genus and even species level, potentially hampering the use of bulk organic matter and non-species-specific organic compounds. In recent years, significant progress has been made towards a CO 2 proxy using controlled growth experiments with dinoflagellate species, also showing highly species-specific εp values. These values were, however, based on motile specimens, and it remains unknown whether these relations also hold for the organic-walled resting cysts (dinocysts) produced by these dinoflagellate species in their natural environment. We here analyze dinocysts isolated from core tops from the Atlantic Ocean and Mediterranean Sea, representing several species (Spiniferites elongatus, S. (cf.) ramosus, S. mirabilis, Operculodinium centrocarpum sensu Wall and Dale (1966) (hereafter referred to as O. centrocarpum) and Impagidinium aculeatum) using laser ablation–nano-combustion–gas-chromatography–isotope ratio mass spectrometry (LA/nC/GC-IRMS). We find that the dinocysts produced in the natural environment are all appreciably more 13 C-depleted compared to the cultured motile dinoflagellate cells, implying higher overall εp values, and, moreover, exhibit large isotope variability. Where several species could be analyzed from a single location, we often record significant differences in isotopic variance and offsets in mean δ13 C values between species, highlighting the importance of single-species carbon isotope analyses. The most geographically expanded dataset, based on O. centrocarpum, shows that εp correlates significantly with various environmental parameters. Importantly, O. centrocarpum shows a CO 2 -dependent εp above ∼ 240 µ atm p CO 2. Similar to other marine autotrophs, relative insensitivity at low p CO 2 is in line with active carbon-concentrating mechanisms at low p CO 2 , although we here cannot fully exclude that we partly underestimated εp sensitivity at low p CO 2 values due to the relatively sparse sampling in that range. Finally, we use the relation between εp and p CO 2 in O. centrocarpum to propose a first p CO 2 proxy based on a single dinocyst species. [ABSTRACT FROM AUTHOR]

Palaeoclimate reconstructions of periods with warm climates and high atmospheric CO.sub.2 concentrations are crucial for developing better projections of future climate change. Deep-ocean.sup.1,2 and high-latitude.sup.3 palaeotemperature proxies demonstrate that the Eocene epoch (56 to 34 million years ago) encompasses the warmest interval of the past 66 million years, followed by cooling towards the eventual establishment of ice caps on Antarctica. Eocene polar warmth is well established, so the main obstacle in quantifying the evolution of key climate parameters, such as global average temperature change and its polar amplification, is the lack of continuous high-quality tropical temperature reconstructions. Here we present a continuous Eocene equatorial sea surface temperature record, based on biomarker palaeothermometry applied on Atlantic Ocean sediments. We combine this record with the sparse existing data.sup.4-6 to construct a 26-million-year multi-proxy, multi-site stack of Eocene tropical climate evolution. We find that tropical and deep-ocean temperatures changed in parallel, under the influence of both long-term climate trends and short-lived events. This is consistent with the hypothesis that greenhouse gas forcing.sup.7,8, rather than changes in ocean circulation.sup.9,10, was the main driver of Eocene climate. Moreover, we observe a strong linear relationship between tropical and deep-ocean temperatures, which implies a constant polar amplification factor throughout the generally ice-free Eocene. Quantitative comparison with fully coupled climate model simulations indicates that global average temperatures were about 29, 26, 23 and 19 degrees Celsius in the early, early middle, late middle and late Eocene, respectively, compared to the preindustrial temperature of 14.4 degrees Celsius. Finally, combining proxy- and model-based temperature estimates with available CO.sub.2 reconstructions.sup.8 yields estimates of an Eocene Earth system sensitivity of 0.9 to 2.3 kelvin per watt per square metre at 68 per cent probability, consistent with the high end of previous estimates.sup.11.A 26-million-year record of equatorial sea surface temperatures reveals synchronous changes of tropical and polar temperatures during the Eocene epoch forced by variations in concentrations of atmospheric carbon dioxide, with a constant degree of polar amplification., Author(s): Margot J. Cramwinckel [sup.1] , Matthew Huber [sup.2] , Ilja J. Kocken [sup.1] , Claudia Agnini [sup.3] , Peter K. Bijl [sup.1] , Steven M. Bohaty [sup.4] , Joost [...]

Climate variability is typically amplified towards polar regions. The underlying causes, notably albedo and humidity changes, are challenging to accurately quantify with observations or models, hampering projections of future polar amplification. Polar amplification reconstructions from the ice-free early Eocene (~56-48 million years ago) can exclude ice albedo effects, but the required tropical temperature records for resolving timescales shorter than multi-million years are lacking. Here, we reconstruct early Eocene tropical sea surface temperature variability by presenting an up to ~4 kyr-resolution biomarker-based temperature record from Ocean Drilling Program Site 959, located in the tropical Atlantic Ocean. This record shows warming across multiple orbitally paced carbon cycle perturbations, coeval with high-latitude-derived deep-ocean bottom waters, showing that these events represent transient global warming events (hyperthermals). This implies that orbital forcing caused global temperature variability through carbon cycle feedbacks. Importantly, deep-ocean temperature variability was amplified by a factor 1.7-2.3 compared to the tropical surface ocean, corroborating available long-term estimates. This implies that fast atmospheric feedback processes controlled meridional temperature gradients on multi-million year, as well as orbital timescales during the early Eocene. Our combined records have several other implications. First, our amplification factor is somewhat larger than the same metric in fully-coupled simulations of the early Eocene (1.1-1.3), suggesting that models slightly underestimate the non-ice related -- notably hydrological -- feedbacks that cause polar amplification of climate change. Second, even outside the hyperthermals, we find synchronous eccentricity-forced temperature variability in the tropics and deep ocean that represent global mean sea surface temperature variability of up to 0.7 °C, and requires significant variability in atmospheric pCO2. We hypothesize that the responsible carbon cycle feedbacks that are independent of ice, snow and frost-related processes might play an important role in Phanerozoic orbital-scale climate variability throughout geological time, including Pleistocene glacial-interglacial climate variability. [ABSTRACT FROM AUTHOR]

The International Ocean Discovery Program (IODP) Expedition 396 to the mid-Norwegian margin recovered >1300 m of pristinely preserved, volcanic ash-rich sediments deposited during the late Paleocene and early Eocene, from close to the centre of the North Atlantic Igneous Province (NAIP). Remarkably, many of these cores contain glendonites, pseudomorphs after the purported cold-water mineral ikaite, from sediments dated to the late Paleocene, Paleocene – Eocene boundary and early Eocene. These time intervals span some of the hottest climates of the Cenozoic, including the Paleocene-Eocene Thermal Maximum (PETM). Global deep ocean temperatures are not thought to have dropped below 10 °C at any point during this time, making the occurrence of supposedly cold-water (near-freezing temperature) glendonite pseudomorphs seemingly paradoxical. This study presents a detailed sedimentological, geochemical, and microscopic study of the Exp. 396 glendonites, and presents an updated model for the ikaite-to-calcite transformation for these glendonites. Specifically, we show that early diagenesis of basaltic ashes of the NAIP appear to have chemically promoted ikaite growth in the sediments in this region. Together with existing knowledge of late Paleocene and early Eocene glendonites from Svalbard to the north, and early Eocene glendonites from Denmark to the south, these new glendonite finds possibly imply episodic, short-duration, and likely localised cooling in the Nordic Seas region, which may have been directly or indirectly linked to the emplacement of the NAIP. [ABSTRACT FROM AUTHOR]

There is a temporal correlation between the peak activity of the North Atlantic Igneous Province (NAIP) and the Paleocene–Eocene Thermal Maximum (PETM), suggesting that the NAIP may have initiated and/or prolonged this extreme warming event. However, corroborating a causal relationship is hampered by a scarcity of expanded sedimentary records that contain both climatic and volcanic proxies. One locality hosting such a record is the island of Fur in Denmark, where an expanded pre- to post-PETM succession containing hundreds of NAIP ash layers is exceptionally well preserved. We compiled a range of environmental proxies, including mercury (Hg) anomalies, paleotemperature proxies, and lithium (Li) and osmium (Os) isotopes, to trace NAIP activity, hydrological changes, weathering, and seawater connectivity across this interval. Volcanic proxies suggest that NAIP activity was elevated before the PETM and appears to have peaked during the body of the δ13 C excursion but decreased considerably during the PETM recovery. This suggests that the acme in NAIP activity, dominated by flood basalt volcanism and thermogenic degassing from contact metamorphism, was likely confined to just ∼ 200 kyr (ca. 56.0–55.8 Ma). The hundreds of thick (> 1 cm) basaltic ashes in the post-PETM strata likely represent a change from effusive to explosive activity, rather than an increase in NAIP activity. Detrital δ7 Li values and clay abundances suggest that volcanic ash production increased the basaltic reactive surface area, likely enhancing silicate weathering and atmospheric carbon sequestration in the early Eocene. Signals in lipid biomarkers and Os isotopes, traditionally used to trace paleotemperature and weathering changes, are used here to track seaway connectivity. These proxies indicate that the North Sea was rapidly cut off from the North Atlantic in under 12 kyr during the PETM recovery due to NAIP thermal uplift. Our findings reinforce the hypothesis that the emplacement of the NAIP had a profound and complex impact on Paleocene–Eocene climate, both directly through volcanic and thermogenic degassing and indirectly by driving regional uplift and changing seaway connectivity. [ABSTRACT FROM AUTHOR]