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Deep Eutectic Solvents (DESs) are "green" competitors for some conventional plating baths and electrolytes used for surface modification. Their use allows a material to be obtained with a structure different from that observed in conventional plating or finishing technologies. In this work the titanium anodizing process was investigated in a bath based on a choline dihydrogencitrate salt and oxalic acid (1 : 1 molar ratio) green solvent. Titanium anodized at the lowest voltage applied (10 V) was a deep yellow color, which turned to deep blue at 30 V. The surface morphology and topography of titanium, both anodized and untreated, were monitored by optical, scanning electron (SEM and HR-SEM) and atomic force (AFM) microscopy. Anodizing at 10 V produced a fine granular morphology of the oxide layer, while anodizing at 30 V led to the formation of a probably thicker and quite uneven oxide layer, characterized by a distinct and coarse granular morphology. The average size of the micro-nodules was higher than those at 10 V and porous structures have been also identified. According to X-ray photoelectron spectroscopy (XPS) the stoichiometric TiO 2 , regardless of the applied voltage during anodizing, was practically the only component of the oxide layer produced on titanium in the DES bath. At 10 V, the oxide layer was thicker (>10 nm) than the natural Ti passive layer (approx. 2.2 nm), which, apart from TiO 2 , also contained oxides of titanium at lower oxidation states, i.e. +2 and +3. Moreover, the XPS technique was supported by electrochemical impedance spectroscopy (EIS), especially in the context of the structure of the oxide layer and its interaction with a corrosive environment. The corrosion resistance of anodized titanium was assessed in 0.05 mol dm -3 solution of NaCl by the linear polarization resistance (LPR) technique and polarization curves. During interpretation of the impedance spectra, the layers produced by the anodizing process were described using the two-layer model. It was assumed that the inner layer formed directly on the surface of metallic titanium was responsible for the barrier properties (resistance of 2.8 MΩ cm 2 ). The porous outer layer formed on it has a much lower corrosion resistance, i.e. 800-1300 Ω cm 2 ., Competing Interests: Authors declare no conflict of interest., (This journal is © The Royal Society of Chemistry.)

Climate change, increasing inequality in freshwater supply and consumption, as well as human land use activities are remarkable drivers of the alteration of the water cycle on the Earth. The aim of our research was to determine if socio-economic and climatic changes affected the ecosystem of a deep dam reservoir which is used for drinking water. A 30-years data series showed that suburbanization did not negatively affect the quality of the water. Moreover, 30 years of socio-economic and political changes resulted in land use changes (increase of forest from 45 to 50% and decrease of agricultural land from 53 to 43%) and better management of the catchment, as well as the modernization and introduction of new technologies. Furthermore, simultaneous climatic changes affected various physical and chemical features of the studied reservoir, and the most important finding is that the thermal stratification period is extended as an effect of global warming (begins earlier and lasts longer). The complexity of the processes contributing to the functioning of the ecosystem is large, so some processes might be a result of synergistic effects of global warming and socio-economic changes. Our 30-year monitoring study explicitly shows how the ecosystem of a deep dam reservoir reflected these changes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Objectives: Mechanical thrombectomy (MT) is not reimbursed by the Polish public health system. We present a description of 5 years of experience with MT in acute stroke in Comprehensive Stroke Centers (CSCs) in Poland., Methods and Results: We retrospectively analyzed the results of a structured questionnaire from 23 out of 25 identified CSCs and 22 data sets that include 61 clinical, radiological and outcome measures., Results: Most of the CSCs (74%) were founded at University Hospitals and most (65.2%) work round the clock. In 78.3% of them, the working teams are composed of neurologists and neuro-radiologists. All CSCs perform CT and angio-CT before MT. In total 586 patients were subjected to MT and data from 531 of them were analyzed. Mean time laps from stroke onset to groin puncture was 250±99min. 90.3% of the studied patients had MT within 6h from stroke onset; 59.3% of them were treated with IV rt-PA prior to MT; 15.1% had IA rt-PA during MT and 4.7% - emergent stenting of a large vessel. M1 of MCA was occluded in 47.8% of cases. The Solitaire device was used in 53% of cases. Successful recanalization (TICI2b-TICI3) was achieved in 64.6% of cases and 53.4% of patients did not experience hemorrhagic transformation. Clinical improvement on discharge was noticed in 53.7% of cases, futile recanalization - in 30.7%, mRS of 0-2 - in 31.4% and mRS of 6 in 22% of cases., Conclusion: Our results can help harmonize standards for MT in Poland according to international guidelines., (Copyright © 2017 Polish Neurological Society. Published by Elsevier Urban & Partner Sp. z o.o. All rights reserved.)

Since the last decade, the use of external pacing systems became very popular and this means more frequent need for lead extraction or exchange. The extraction of "old", indwelling pacemaker or defibrillator leads is a standard procedure, done in many electrophysiology labs using many modern techniques. However, when a lead is torn off, and stays intravenous --its extraction is difficult. First, it must be caught endovascular, withdrawn out of a body and then extracted. Below, we present the case of successful extraction of torn off lead in a 25-year-old male by means of interventional radiology endovascular techniques.