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The von Neumann entropy is a key quantity in quantum information theory and, roughly speaking, quantifies the amount of quantum information contained in a state when many identical and independent i.i.d. copies of the state are available, in a regime that is often referred to as being asymptotic. In this work, we provide a new operational characterization of the von Neumann entropy which neither requires an i.i.d. limit nor any explicit randomness. We do so by showing that the von Neumann entropy fully characterizes single-shot state transitions in unitary quantum mechanics, as long as one has access to a catalyst - an ancillary system that can be re-used after the transition - and an environment which has the effect of dephasing in a preferred basis. Building upon these insights, we formulate and provide evidence for the catalytic entropy conjecture, which states that the above result holds true even in the absence of decoherence. If true, this would prove an intimate connection between single-shot state transitions in unitary quantum mechanics and the von Neumann entropy. Our results add significant support to recent insights that, contrary to common wisdom, the standard von Neumann entropy also characterizes single-shot situations and opens up the possibility for operational single-shot interpretations of other standard entropic quantities. We discuss implications of these insights to readings of the third law of quantum thermodynamics and hint at potentially profound implications to holography., Comment: 4+5 pages, 1 figure

Randomness is a defining element of mixing processes in nature and an essential ingredient to many protocols in quantum information. In this work, we investigate how much randomness is required to transform a given quantum state into another one. Specifically, we ask whether there is a gap between the power of a classical source of randomness compared to that of a quantum one. We provide a complete answer to these questions, by identifying provably optimal protocols for both classical and quantum sources of randomness, based on a dephasing construction. We find that in order to implement any noisy transition on a $d$-dimensional quantum system it is necessary and sufficient to have a quantum source of randomness of dimension $\sqrt{d}$ or a classical one of dimension $d$. Interestingly, coherences provided by quantum states in a source of randomness offer a quadratic advantage. The process we construct has the additional features to be robust and catalytic, i.e., the source of randomness can be re-used. Building upon this formal framework, we illustrate that this dephasing construction can serve as a useful primitive in both equilibration and quantum information theory: We discuss applications describing the smallest measurement device, capturing the smallest equilibrating environment allowed by quantum mechanics, or forming the basis for a cryptographic private quantum channel. We complement the exact analysis with a discussion of approximate protocols based on quantum expanders deriving from discrete Weyl systems. This gives rise to equilibrating environments of remarkably small dimension. Our results highlight the curious feature of randomness that residual correlations and dimension can be traded against each other., Comment: 18 pages, 6 figures; Fixed typo in expander theorem

Numerous works have shown that under mild assumptions unitary dynamics inevitably leads to equilibration of physical expectation values if many energy eigenstates contribute to the initial state. Here, we consider systems driven by arbitrary time-dependent Hamiltonians as a protocol to prepare systems that do not equilibrate. We introduce a measure of the resilience against equilibration of such states and show, under natural assumptions, that in order to increase the resilience against equilibration of a given system, one needs to possess a resource system which itself has a large resilience. In this way, we establish a new link between the theory of equilibration and resource theories by quantifying the resilience against equilibration and the resources that are needed to produce it. We connect these findings with insights into local quantum quenches and investigate the (im-)possibility of formulating a second law of equilibration, by studying how resilience can be either only redistributed among subsystems, if these remain completely uncorrelated, or in turn created in a catalytic process if subsystems are allowed to build up some correlations., Comment: 6 pages + 4 pages of Supplemental Material

Quantum systems strongly coupled to many-body systems equilibrate to the reduced state of a global thermal state, deviating from the local thermal state of the system as it occurs in the weak-coupling limit. Taking this insight as a starting point, we study the thermodynamics of systems strongly coupled to thermal baths. First, we provide strong-coupling corrections to the second law applicable to general systems in three of its different readings: As a statement of maximal extractable work, on heat dissipation, and bound to the Carnot efficiency. These corrections become relevant for small quantum systems and always vanish in first order in the interaction strength. We then move to the question of power of heat engines, obtaining a bound on the power enhancement due to strong coupling. Our results are exemplified on the paradigmatic situation of non-Markovian quantum Brownian motion., Comment: 20 pages, 3 figures, version two is substantially revised and contains new results

We investigate the limitations that emerge in thermodynamic tasks as a result of having local control only over the components of a thermal machine. These limitations are particularly relevant for devices composed of interacting many-body systems. Specifically, we study protocols of work extraction that employ a many-body system as a working medium whose evolution can be driven by tuning the on-site Hamiltonian terms. This provides a restricted set of thermodynamic operations, giving rise to novel bounds for the performance of engines. Our findings show that those limitations in control render it in general impossible to reach Carnot efficiency; in its extreme ramification it can even forbid to reach a finite efficiency of work per particle. We focus on the 1D Ising model in the thermodynamic limit as a case study. We show that in the limit of strong interactions the ferromagnetic case becomes useless for work extraction, while the anti-ferromagnetic improves its performance with the strength of the couplings, reaching Carnot in the limit of arbitrary strong interactions. Our results provide a promising connection between the study of quantum control and thermodynamics and introduce a more realistic set of physical operations well suited to capture current experimental scenarios., Comment: 10 pages, 5 figures

Recent years have seen an enormously revived interest in the study of thermodynamic notions in the quantum regime. This applies both to the study of notions of work extraction in thermal machines in the quantum regime, as well as to questions of equilibration and thermalisation of interacting quantum many-body systems as such. In this work we bring together these two lines of research by studying work extraction in a closed system that undergoes a sequence of quenches and equilibration steps concomitant with free evolutions. In this way, we incorporate an important insight from the study of the dynamics of quantum many body systems: the evolution of closed systems is expected to be well described, for relevant observables and most times, by a suitable equilibrium state. We will consider three kinds of equilibration, namely to (i) the time averaged state, (ii) the Gibbs ensemble and (iii) the generalised Gibbs ensemble (GGE), reflecting further constants of motion in integrable models. For each effective description, we investigate notions of entropy production, the validity of the minimal work principle and properties of optimal work extraction protocols. While we keep the discussion general, much room is dedicated to the discussion of paradigmatic non-interacting fermionic quantum many-body systems, for which we identify significant differences with respect to the role of the minimal work principle. Our work not only has implications for experiments with cold atoms, but also can be viewed as suggesting a mindset for quantum thermodynamics where the role of the external heat baths is instead played by the system itself, with its internal degrees of freedom bringing coarse-grained observables to equilibrium., Comment: 22 pages, 4 figures, improvements in presentation

The deterministic KPZ equation has been recently formulated as a gradient flow, in a nonequilibrium potential (NEP) \[\Phi[h(\mathbf{x},t)]=\int\mathrm{d}\mathbf{x}\left[\frac{\nu}{2}(\nabla h)^2-\frac{\lambda}{2}\int_{h_0(\mathbf{x},0)}^{h(\mathbf{x},t)}\mathrm{d}\psi(\nabla\psi)^2\right].\] This NEP---which provides at time $t$ the landscape where the stochastic dynamics of $h(\mathbf{x},t)$ takes place---is however unbounded, and its exact evaluation involves all the detailed histories leading to $h(\mathbf{x},t)$ from some initial configuration $h_0(\mathbf{x},0)$. After pinpointing some consequences of these facts, we study the time behavior of the NEP's first few moments and analyze its signatures when an external driving force $F$ is included. We finally show that the asymptotic form of the NEP's time derivative $\dot\Phi[h]$ turns out to be valid for any substrate dimensionality $d$, thus providing a valuable tool for studies in $d>1$., Comment: 15 pages, 6 figures, submitted to JSTAT

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines, in an analogous way to the role played, for macroscopic machines, by the energy stored in the idealisation of a lifted weight. Despite of several attempts to resolve this issue by putting forward specific models, these are far from capturing realistically the transitions that a quantum machine is expected to perform. In this work, we adopt a novel strategy by considering arbitrary kinds of systems that one can attach to a quantum thermal machine and seeking for work quantifiers. These are functions that measure the value of a transition and generalise the concept of work beyond the model of a lifted weight. We do so by imposing simple operational axioms that any reasonable work quantifier must fulfil and by deriving from them stringent mathematical condition with a clear physical interpretation. Our approach allows us to derive much of the structure of the theory of thermodynamics without taking as a primitive the definition of work. We can derive, for any work quantifier, a quantitative second law in the sense of bounding the work that can be performed using some non-equilibrium resource by the work that is needed to create it. We also discuss in detail the role of reversibility and correlations in connection with the second law. Furthermore, we recover the usual identification of work with energy in degrees of freedom with vanishing entropy as a particular case of our formalism. Our mathematical results can be formulated abstractly and are general enough to carry over to other resource theories than quantum thermodynamics., Comment: 22 pages, 4 figures, axioms significantly simplified, more comprehensive discussion of relationship to previous approaches

The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small systems are often disregarded when deriving such bounds, which is specifically important in the context of quantum thermodynamics. Here, we study the maximum extractable work with limited control over the working system and its interaction with the heat bath. We derive a general second law when the set of accessible Hamiltonians of the working-system is arbitrarily restricted. We then apply our bound to particular scenarios that are important in realistic implementations: limitations on the maximum energy gap and local control over many-body systems. We hence demonstrate in what precise way the lack of control affects the second law. In particular, contrary to the unrestricted case, we show that the optimal work extraction is not achieved by simple thermal contacts. Our results do not only generalize the second law to scenarios of practical relevance, but also take first steps in the direction of local thermodynamics., Comment: 10 pages, 2 figures, changes in presentation

How much work can be extracted from a heat bath using a thermal machine? The study of this question has a very long tradition in statistical physics in the weak-coupling limit, applied to macroscopic systems. However, the assumption that thermal heat baths remain uncorrelated with physical systems at hand is less reasonable on the nano-scale and in the quantum setting. In this work, we establish a framework of work extraction in the presence of quantum correlations. We show in a mathematically rigorous and quantitative fashion that quantum correlations and entanglement emerge as a limitation to work extraction compared to what would be allowed by the second law of thermodynamics. At the heart of the approach are operations that capture naturally non-equilibrium dynamics encountered when putting physical systems into contact with each other. We discuss various limits that relate to known results and put our work into context of approaches to finite-time quantum thermodynamics., Comment: 28 pages, 1 figure

The Busse-Heikes dynamical model is described in terms of relaxational and nonrelaxational dynamics. Within this dynamical picture a diverging alternating period is calculated in a reduced dynamics given by a time-dependent Hamiltonian with decreasing energy. A mean period is calculated which results from noise stabilization of a mean energy. The consideration of spatial-dependent amplitudes leads to vertex formation. The competition of front motion around the vertices and the Kuppers-Lortz instability in determining an alternating period is discussed., Comment: 28 pages, 11 figures

We study domain growth in a nonlinear optical system useful to explore different scenarios that might occur in systems which do not relax to thermodynamic equilibrium. Domains correspond to equivalent states of different circular polarization of light. We describe three dynamical regimes: a coarsening regime in which dynamical scaling holds with a growth law dictated by curvature effects, a regime in which localized structures form, and a regime in which polarization domain walls are modulationally unstable and the system freezes in a labyrinthine pattern., Comment: 13 pages, 6 figures

We present a study of dynamical scaling and front motion in a one dimensional system that describes Rayleigh-Benard convection in a rotating cell. We use a model of three competing modes proposed by Busse and Heikes to which spatial dependent terms have been added. As long as the angular velocity is different from zero, there is no known Lyapunov potential for the dynamics of the system. As a consequence the system follows a non-relaxational dynamics and the asymptotic state can not be associated with a final equilibrium state. When the rotation angular velocity is greater than some critical value, the system undergoes the Kuppers-Lortz instability leading to a time dependent chaotic dynamics and there is no coarsening beyond this instability. We have focused on the transient dynamics below this instability, where the dynamics is still non-relaxational. In this regime the dynamics is governed by a non-relaxational motion of fronts separating dynamically equivalent homogeneous states. We classify the families of fronts that occur in the dynamics, and calculate their shape and velocity. We have found that a scaling description of the coarsening process is still valid as in the potential case. The growth law is nearly logarithmic with time for short times and becomes linear after a crossover, whose width is determined by the strength of the non-potential terms., Comment: 15 pages, 10 figures

We present a study of dynamical scaling and domain growth in a non potential system that models Rayleigh-Benard convection in a rotating cell. In d=1, dynamical scaling holds, but the non potential terms modify the characteristic growth law with a crossover from logarithmic to linear in time. In d=2 the non potential terms prevent coarsening for any value of the angular rotation speed., Comment: 8 pages, 2 figures