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By inducing gamma radiation at a dose of 25 kGy, vinylpyrrolidone (VP) was combined with dioctyl sodium sulfosuccinate, an anionic surfactant, to create PVP@DSSS. The sorption and recovery of Ce(III) and Co(II) from aqueous solutions were evaluated using PVP@DSSS. The physical and chemical characterisation of prepared sorbent was investigated by X-ray diffraction spectroscopy (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and thermal analysis (TGA-DTA). The characterisations show that sorbents prepared using these techniques outperform conventional preparation methods. The PVP@DSSS was implanted for batch processing with the goal of studying the effect of different parameters on the sorption of the investigated metal ions, such as pH, contact time, metal ion concentration, and reaction temperatures. The results show that the maximum adsorption capacity of the PVP@DSSS adsorbent for Ce(III) and Co(III) were 9.8 and 0.9 mg/g, respectively. The adsorption of Ce(III) and Co(II) from aqueous suspension using PVP@DSSS was fit to Langmuir and pseudo second order equations well. The changes in the free energy (ΔG) and enthalpy (ΔH) values of Ce(III) confirm the endothermic nature of the adsorption reaction, whereas Co(II) adsorption was exothermic and spontaneous. The desorption efficiency was 95% for Co(II) and less than 10% for Ce(III) with HCl as good desorbing agent.The results show that PVP@DSSS is a promising adsorbent for the the recovery and separation process of Ce(III) ions from aqueous solution. [ABSTRACT FROM AUTHOR]

The measurement of patients' dosages of radiation caused by medical diagnostics continues to be challenging. A Cantor sequence photonic crystal structure using porous silicon doped with a polymer of polyvinyl alcohol, carbol fuchsin and crystal violet (DPV) is proposed. The influence rules of geometrical and optical parameters such as the radiation doses, number of periods, porosity of porous layers, incident angle and thickness of layers are investigated using MATLAB based on the transfer matrix method. The transmittance of the Cantor sequence of a defective photonic crystal sensor under different conditions is investigated to select the optimum conditions. The proposed system recorded the accepted sensitivity of 0.265 nm/Gy, FoM of 6.5 Gy − 1 , Q of 12,701, RS of 6 × 1 0 − 3 and LoD of 8 × 1 0 − 3 for gamma radiation. The suggested detector has simple design, accurate monitoring efficiency and immense potential for gamma radiation sensing. [ABSTRACT FROM AUTHOR]

Perovskite nanocrystals (NCs) are emerging as a next generation display technology. In this regard, exploring the structural and optical stability when subjected to radiation is crucial for expanding their application in aerospace and radiation detection technologies. In this study, we investigated the effects of gamma radiation on CsPbBr 3 heterojunction thin films through a comprehensive analysis of their structural and optical characteristics. The thin films of CsPbBr 3 were subjected to varying doses of gamma radiation, ranging from 100 krad to 1 Mrad, followed by thorough examination using X-ray diffraction (XRD) and optical spectroscopy techniques. Our findings unveil significant changes in the crystal structure of CsPbBr 3 thin films when exposed to gamma radiation, including shifts in diffraction peak positions from cubic to monoclinic phases, broadening of peaks, and variations in peak intensities due to induced surface defects. The optical properties, such electroluminescence (EL) and photoluminescence (PL) intensity slightly drops at the moderate irradiation dose of 300 krad, while at an irradiation dose of 1 Mrad deteriorated severely. Notably, 300 krad is equivalent to the radiation dose accumulated by satellites in low-Earth orbit over 10 years. The findings in this work suggest the fabricated CsPbBr 3 thin film has the potential to be used in space applications. [ABSTRACT FROM AUTHOR]

The present study is about the effect of gamma radiations on the degradation of Acid Violet 49 (AV49) in the presence of H2O2 (γ/H2O2). The Cs-137 radiation source was calibrated to irradiate the aqueous solution of AV49 within the 1 kGy, 5 kGy & 10 kGy dose range. The results showed that 50–150 mg/L of AV49 was effectively degraded by γ radiation (85 %), however, the concentration of H2O2 in the range of 0.2–0.6 mL promoted degradation to 90 % and 98 %, respectively. It was observed that all absorption bands declined with rising irradiation dose and disappeared completely after 10 kGy applied dose. pH conditions (3, 5,7, and 9) were used in the radio-lytic degradation of AV49, the results showed that the best degradation efficiency has been found for pH 9. The optimum degradation rate is higher (98 %) with a 50 mg/L concentration of AV49, 0.6 mL H2O2, and pH 9 at a 10 kGy absorbed dose. In addition, the influence of various parameters on the rate of degradation such as the effect of irradiation dose, pH, H2O2, and dye (AV49) concentration was also studied. Furthermore, the removal of total organic carbon TOC was not as effective as that of the AV 49. Total nitrogen TN was not completely removed even at high dosage. Radio-lytic degradation of AV49 was analyzed by using Fourier transform infrared spectroscopy (FTIR) and liquid chromatography coupled to mass spectrometry (LC-MS) as an analytical technique. Results revealed that the proposed methodology for degradation of dyes is effective and probably could be applied for the removal of other toxic pollutants. [ABSTRACT FROM AUTHOR]

Dental caries is a common disease widely known to be the main cause of tooth decay. This study evaluated the antibacterial properties of zinc oxide nanoparticles (ZnO NPs) against four Streptococcus mutans isolated from dental caries. ZnO NPs were biosynthesized from a mixture of zinc chloride (ZnCl2) solution with various pomegranate peel extracts under different doses of gamma radiation. The antibacterial activity was evaluated using the agar-well diffusion method. The structure and elemental content of these artificial ZnO NPs were studied using X-ray diffraction (XRD), ultraviolet–visible absorption spectroscopy (UV–Vis), transmission electron microscope (TEM), and Fourier-transform infrared spectroscopy (FTIR). UV analysis revealed that the pomegranate/ZnO nanoparticles prepared at 60 kGy gamma irradiation dose had the highest intensity at absorption peaks between 395 and 445 nm compared to the other gamma doses. The biosynthesized ZnO NPs demonstrated a strong sensitivity toward Streptococcus mutans. FTIR analysis indicated the presence of specific peaks associated with the functional groups found in pomegranate, which play a role in the production, capping, and stabilization of the biosynthesized ZnO NPs. The presence of Zn–O bonds at 437, 505, 610, 1412, and 1623 cm−1 confirmed the presence of ZnO NPs. TEM analyses revealed that the biosynthesized ZnO NPs were well dispersed and existed in three different shapes: spherical, rod-shaped, and triangular nanoparticles, with sizes of 17.95 nm, 10.29 nm, and 76.98 nm, respectively. XRD analysis gave a sharp peak at 31.68° related to the formed ZnO NPs. To ensure the safety of ZnO NPs, a sulforodamine B (SRB) assay was conducted. Ninety-nine percent of human oral epithelial cells (OEC) treated with different concentrations of ZnO NPs (0.01, 0.1, 1, 10, and 100 μg/ml) remained viable. The IC50 value was more significant than 100 μg/ml. ZnO NPs with a percentage of 0.1% incorporated with composite resin were the minimal concentration to inhibit S. mutans. These findings suggest that ZnO NPs from pomegranate peel extracts could be a novel antibacterial and eco-friendly agent for preventing dental caries. Biosynthesized Zinc Oxide nanoparticles (ZnO NPs) using Pomegranate peel extract (PPE) and gamma radiation. [ABSTRACT FROM AUTHOR]

High‐energy nonthermal processes (irradiation) are an interesting technique for depolymerization. Gum tragacanth (GT) is a heteropolysaccharide composed of various sugars that are beneficial in the food and pharmaceutical industries. This study investigated the effects of different gamma irradiation doses (2.5, 5, 10, 20, 100, 500, 1,000, and 2000 kGy) on GT properties, considering both structural and physicochemical changes. The results confirmed that gamma irradiation influenced depolymerization with increases in monosaccharides (L‐arabinose, D‐galactose, D‐glucose, D‐xylose, L‐fucose, L‐rhamnose) and the percentage of degradation. Fourier transform infrared (FTIR) spectroscopy analysis indicated that structural changes occurred, with more free O‐H and C‐O bonding, including the carboxylic group (COOH) in the degraded molecules after irradiation. The changes in physicochemical properties were lower viscosity and a color change under gamma irradiation. The property changes in the GT were clearly related to an increased dose of gamma rays. In summary, there was comprehensive GT degradation following exposure using different increasing doses of gamma radiation, with some concomitant property changes in the GT. [ABSTRACT FROM AUTHOR]

Highlights With the increasing complexity of radiation environments, the development of effective shielding materials against 222Rn and gamma radiation is critical for ensuring human health and safety. This study utilized a two‐step hydrothermal method to synthesize Gd₂O(CO₃)₂@bismuth‐based metal–organic frameworks (Bi‐MOFs)/graphene nanoplatelets (GBG) composite fillers, followed by melt blending and hot‐press molding to develop GBG/polymethyl methacrylate (PMMA) composites aimed at shielding against 222Rn and gamma radiation. The successful synthesis and structural integrity of the composites were confirmed using various characterization techniques, including x‐ray diffraction, Fourier‐transform infrared spectroscopy, scanning electron microscopy, and energy‐dispersive x‐ray spectroscopy. The experimental results indicate that the GBG composite filler exhibits superior enhancement in 222Rn shielding capabilities, with the 222Rn diffusion coefficient of GBG/PMMA‐20 composites reduced to 1.41 × 10−13 m2/s, a 98.6% decrease compared to pure PMMA (1.04 × 10−11 m2/s). Furthermore, the GBG demonstrates outstanding improvements in gamma‐ray shielding performance, with the mass attenuation coefficient of GBG/PMMA‐50 reaching 2.70 cm2/g for 59.5 keV gamma rays, nearly 16 times higher than that of pure PMMA (0.16 cm2/g). Additionally, thermogravimetric analysis revealed that the introduction of GBG fillers significantly improves the thermal stability of the PMMA composites. This work could offer an innovative approach to the design of 222Rn and gamma radiation shielding materials. Developed a novel composite for enhanced 222Rn and gamma radiation shielding. Introduced Gd‐based fillers to enhance gamma radiation attenuation in PMMA composites. Achieved superior thermal stability in PMMA composites compared to pure PMMA. Materials designed for application in high‐radiation environments, including mining. [ABSTRACT FROM AUTHOR]

• Proof of the effectiveness of gamma radiation processing for conservation purposes of biodeteriorated cultural heritage artefacts. • Gamma radiation treatment at absorbed doses common for cultural heritage conservation (up to 8 kGy). • Tests were performed at different dose and dose rate values on old books and new paper samples. • Effects of gamma irradiation parameters (absorbed dose and dose rate) on papers of different composition and conservation state. • Secondary effects evaluation by different experimental techniques (Micro-Raman, infrared spectroscopy, viscosimetric and colorimetric analysis). Ionizing radiations, commonly applied as diagnostic tools in Cultural Heritage (CH) field, are also proving effective for eliminating biodeteriogens (insects, fungi, bacteria and molds) responsible for the degradation of CH artifacts and often harmful for restorers, archivists and librarians. The use of ionizing radiations, such as gamma rays, for CH treatments is spreading in many countries. However, some CH operators remain resistant due to insufficient knowledge about the potential physico-chemical modifications (secondary effects) induced by radiation. This work aims to investigate and compare the effects of irradiation parameters (such as absorbed dose and dose rate) on old paper samples and new pure-cellulose paper, chosen as a reference model material. Absorbed doses up to 8 kGy have been used, as these values are commonly agreed upon for the preservation treatment of CH artifacts and are generally effective for biodeteriogen s removal. Optimizing irradiation conditions helps to minimize secondary effects (such as oxidation, depolymerization or color changes), thereby increasing the reliability of the process and boosting confidence among CH operators. The secondary effects were analyzed using various physico-chemical characterizations (Fourier Transform Infrared spectroscopy, Raman microscopy, viscosimetric and colorimetric analysis) on old and new paper samples. The results indicate varying behaviors, correlated with paper composition, sample age and irradiation parameters, towards gamma radiation. This groundbreaking study not only confirms the efficacy of gamma irradiation treatments but also provides essential data that will aid in the development of optimized best practice protocols and guidelines for non-destructive and minimally destructive methods applied to real case studies and treatments. [Display omitted] [ABSTRACT FROM AUTHOR]

The Cu-2 wt% Sb alloy was prepared and exposed to various heat treatments at temperatures ranging from 573 to 973 K to get distinct grain diameters. Different samples of various grain diameters were individually sputtered in an argon glow discharge for various times (0.5, 1, 2 h) using a DC magnetron sputtering device. The surface topography and microstructural features of a Cu-2 wt% Sb alloy were examined utilizing an optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). The C u 3 S b IMC phase was found to segregate at the grain boundaries. Results showed that the topographical features of sputtered samples (grain boundaries, tiny cones, cratered cones, and etch pits) were mainly affected by grain size and sputtering time. Moreover, the mechanical properties of a Cu-2 wt% Sb alloy were examined. The parameters of the stress–strain curves (Young modulus Y, 0.2% offset stress σy0.2, fracture stress σf, parabolic work-hardening coefficient χ p , and ductility ε f \% ) were measured under different testing conditions. Generally, these stress parameters decrease as the grain diameter increases. These parameters, with the exception of ε f \% , increase as the strain rate increases, while ε f \% decreases as the strain rate increases. Additionally, selective samples of the present alloy were irradiated using γ-radiation with different doses 0.5, 1, 1.5, and 2 MGy. The Vickers microhardness of annealed and irradiated samples lowered as the grain size augmented, while it increased as the irradiation dose increased. Based on the obtained activation energy Q value of 20.65 kJ/mol., it is indicated that the predominant deformation mechanism in the Cu-2 wt% Sb alloy is the motion of dislocation through the Cu-matrix. [ABSTRACT FROM AUTHOR]

Gamma irradiation-based mutant creation is one of the most important methods for rice plant mutagenesis breeding and molecular biology research. Although median lethal dose irradiation severely damages rice seedlings, applying brassinolide (BR) can increase the survival rate of irradiated seedlings. In this study, we investigated the effects of soaking seeds in solutions containing different BR concentrations (0.001, 0.01, 0.1, 1.0, and 5.0 μmol/L) and then spraying the resulting seedlings twice with 0.1 μmol/L BR. The combined BR treatments markedly decreased the superoxide anion (O2•−), hydrogen peroxide (H2O2), and malondialdehyde contents but increased the chlorophyll content. An appropriate BR treatment of gamma-irradiated samples substantially increased the activities of the antioxidant enzymes superoxide dismutase, peroxidase, and ascorbate peroxidase as well as the proline, ascorbic acid, and glutathione contents in rice seedling shoots. The BR treatment also promoted the growth of seedlings derived from irradiated seeds and increased the shoot and root fresh and dry weights. Most notably, soaking seeds in 0.01 or 0.1 μmol/L BR solutions and then spraying seedlings twice with 0.1 μmol/L BR significantly increased the final seedling survival rate and decreased mutant loss. The study results suggest that exogenous BR treatments can protect rice seedlings from gamma irradiation stress by enhancing antioxidant metabolism. [ABSTRACT FROM AUTHOR]

In the present study, 366 locations were selected from the Faridabad district of Haryana, India, for seasonal gamma radiation measurements in indoor/outdoor environments. It was measured by a radiation monitor PM 1405 (Polimaster instrument/Republic of Belarus). The measured gamma was statistically analysed using the Wilcoxon signed-ranks test, Shapiro–Wilk test, Mann–Whitney test, and ANOVA test. The significance value of the outdoor gamma dose rate in winter (OGDRW) is found to be less than the significance level (0.05), indicating that the geology has a significant impact on OGDRW. The estimated annual effective dose was related to the values stated by UNSCEAR and ICRP. [ABSTRACT FROM AUTHOR]

Polylactic acid (PLA) is a widely used biopolymer and is currently produced on a global scale. However, PLA has low melt strength, which limits its application. Poly(butylene adipate-co-terephthalate) (PBAT) is a fully biodegradable polymer and one of the most attractive polymers for hardening PLA. As PLA and PBAT are immiscible, they need to be compatibilized to improve the properties of the blend. In this context, the compatibilization of PLA/PBAT blends was investigated through an irradiation process. PLA was previously irradiated, at different absorbed doses, in a cobalt-60 source to assess the compatibility of its blends with PBAT. Differential scanning calorimetry showed a reduction in the glass transition, cold crystallization and melting temperatures, and a second melting peak was observed after polymer irradiation. Also, X-ray diffraction analyses revealed a slight increase in the crystalline fraction. Thermogravimetric analysis showed that as the absorbed dose increased, the thermal stability of PLA decreased. Fourier-transform infrared spectroscopy shows bands attributed to oxidized terminations of polymer chains with carbonyls attributed to the effect of irradiation exposure. For samples irradiated above 100 kGy, an increase in tensile strength and tensile modulus can be observed as the dose increases. Rheological measurements showed a decrease in the complex viscosity of irradiated PLA with increasing absorbed dose. The surface of the polymer blend with PLA irradiated with gamma rays at 150 kGy appears to be more homogeneous according to scanning electron analysis. The polymer blend with 150 kGy irradiated PLA showed improved interaction between the components. [ABSTRACT FROM AUTHOR]

The Philodendron billietiae is a popular ornamental plant, with mutated varieties in high demand and commanding premium prices. This research aims to identify the optimal medium for propagating Philodendron billietiae and to use gamma radiation to induce mutations. Shoot tips of Philodendron billietiae were cultured on Murashige and Skoog (MS) medium supplemented with various concentrations of 6-benzyladenine (BA), both alone and in combination with naphthalene acetic acid (NAA), to induce shoot formation. Different concentrations of NAA were then tested for root induction. Additionally, mutation induction was investigated using gamma radiation from cesium-137 as the primary radioactive source, with doses of 0, 10, 20, 30, 40, and 50 Gray. MS medium supplemented with 1.5 mg L−1 BA achieved the highest shoot induction, resulting in more shoots and leaves per shoot. The optimal medium for root induction was MS medium supplemented with 0.5 mg L−1 NAA. In the mutation induction experiment, increasing radiation doses resulted in decreased survival rates, fewer new shoots, and reduced leaf width and length. Gamma radiation at doses between 20 and 40 Gray induced morphological changes in the leaves of Philodendron billietiae. These findings provide valuable guidelines for the genetic improvement of Philodendron billietiae to enhance its commercial value. [ABSTRACT FROM AUTHOR]

The environment exposed to radionuclide faces detrimental effects of ionizing radiations and these radiations can damage DNA by inducing genotoxicity in living organisms. The gamma radiation induced genotoxicity was evaluated by employing Single cell gel electrophoresis (comet) assay in the foragers of Apis mellifera ligustica by exposing to different doses (1 to 60 Gy) of gamma radiation. DNA damage was measured as the percentage of comet tail DNA. The results showed a dose dependent increase and post irradiation time (1-24 h) dependent decrease in % tail DNA level in bee foragers. A significant increase in DNA damage was observed in all the samples and the extent of damage was proportional to the dose of gamma radiation received by the bees except in those treated with the lower doses (1, 5 and 10 Gy) of gamma radiation. The highest amount of DNA damage was recorded at 1 h post-irradiation which decreased gradually with time, that is, at 3 h and 6 h post-irradiation. However, there were no significant differences in the % tail DNA of bees of 12 h and 24 h post irradiation. The present study shows gamma radiation induced DNA damage in foragers of A. m. ligustica and also the comet assay is a suitable technique for detection of gamma radiation induced DNA damage. [ABSTRACT FROM AUTHOR]

Natural fiber composites are a renewable and environmentally friendly alternative to conventional synthetic materials that combine the biodegradability and essential durability of natural fibers with adaptability. Improved adhesion between fibers and matrix can be accomplished by comparing surface treatments applied to sugarcane, water hyacinth, and banana plant wastes. This will allow us to produce composite materials that are more durable and sustainable. To study the mechanical and morphological characteristics of the composites, two surface treatments were applied: gamma radiation at a dose of 1, 2, 3, 4 and 5 kGy and alkali treatment at a concentration of 5, 10, and 15%. The study revealed that with the increasing treatment of alkali solution, improvements in the composite's mechanical characteristics whereas gamma irradiation treatment enhanced the mechanical properties to a certain extent (2 kGy) after that the mechanical traits dwindled significantly. SEM, XRD, and FTIR analysis of the developed composite samples also revealed the reasons for the improvements in mechanical properties after alkali and gamma radiation treatments. As an ecofriendly and lightweight substitute for conventional materials, bio epoxy composites reinforced with natural fibers can be used for car interior panels, eco‐friendly furniture and as a replacement for any plasticware offering eco‐sustainability for contemporary living space. Highlights: Natural fiber composites offer a renewable and eco‐friendly alternative to synthetic materials, combining biodegradability with durability.Surface treatments like gamma radiation and alkali treatment enhance composite's mechanical properties.Higher concentrations of alkali treatment improve mechanical characteristics, while gamma irradiation peaks at 2 kGy.Surface treatments offer promising avenues for advancing environmentally friendly materials, contributing to sustainable innovations in material science. [ABSTRACT FROM AUTHOR]

The radiation-induced telomerization of tetrafluoroethylene in pentafluorochlorobenzene, pentafluorobromobenzene, and hexafluorobenzene has been studied. It has been shown that the process efficiency and the chain length of the resulting telomers depends on the binding energy of the substituent in the fluorinated benzene rings. An analysis of the IR spectra showed that changes in the molecular structure of telomers occurred under the influence of gamma radiation; these changes were expressed in the detachment of terminal benzene rings and the formation of terminal carboxyl groups. In addition, polymer chain degradation leading to the formation of telomers with a shorter chain length was observed. The hydrophobic properties of the samples of all irradiated telomers were preserved. [ABSTRACT FROM AUTHOR]

Four chromatographic supports were functionalized with bis-(2-ethylhexyl) phosphoric acid (HDEHP) and examined for radiation stability when used for f-element separations after exposure to high levels of ionizing gamma radiation. Changes in Eu(III) partitioning were evaluated and compared to an analogous solvent extraction system using HDEHP in n-dodecane. The solvent extraction system showed an increase in Eu(III) uptake with increasing γ irradiation dose to the solvent in the presence of nitric acid. The Eu(III) distribution profiles indicate that the functionalized chromatographic support materials are less affected by γ irradiation, when exposed in a radiation environment of up to 2.5 MGy in the presence of nitric acid. [ABSTRACT FROM AUTHOR]

Purpose: Nowadays people are exposed to radiation due to various reasons, including natural, diagnostic, occupational or accidental exposure. High level of exposure to ionizing radiation can be fatal to human body. Synthetic drugs used to prevent radiation-induced damage are toxic in nature. Recently, Herbal drugs are being screened as an alternative due to their mechanism of action. Garcinia indica (G. indica) is one of the traditional medicinal plant which contains phytochemicals having several medicinal properties. Materials and methods: In this study, G. indica extract was observed for its modulatory effect against 3 Gray (Gy) gamma radiation-induced damages in human peripheral blood lymphocytes. Various concentrations of G. indica extract ranging from 1 to 25 µg/mL was added to the blood post irradiation at 0 hr. Chromosomal aberration (CA) and Cytochalasin B blocked Micronuclei Cytome (CBMN) Assay were performed as per standard procedure. Results: Radiomodulatory effect of Garcinia indica fruit rind extract (GIFRE) on CA and MN formation was observed in this study. Treatment of GIFRE did not affect the mitotic index. Positive inhibition percentages for dicentrics, total chromosomal aberrations and micronuclei were observed except for one instance. Conclusion: Owing to the various properties of Garcinia extracts, it makes it a potential candidate to be tested for its radiomodulatory effect. Based on the results observed in this preliminary study, it could act as a radiomodulatory agent. Radiomodulatory effect of GIFRE could possibly serve it as a potential herbal medicinal alternative to current drugs. However, results of this study need to be validated on larger sample size. [ABSTRACT FROM AUTHOR]

Aim: The present study aimed to evaluate the antibacterial effectiveness of newly formulated root canal irrigants derived from natural sources. In particular, this study investigated how these irrigants' antimicrobial properties were affected by gamma radiation activation. Methods: Fifty-three single-rooted extracted human teeth with straight canals were selected, fully prepared, and sterilized. The roots were then infected with Escherichia coli , Enterococcus faecalis , and Candida albicans for 21 days at 37°C. Based on the irrigating solution utilized, the roots were divided into seven groups: Group I: chitosan irrigant, Group II: chitosan irrigant gamma irradiated, Group III: curcumin irrigant, Group IV: curcumin irrigant gamma irradiated, Group V: sodium hypochlorite (NaOCl) 5% irrigant, Group VI: positive control (infected roots without treatment), and Group VII: negative control (uncontaminated roots). After cleaning and shaping, microbiological sampling was performed. The samples were then transferred to sterile centrifuge tubes containing 1 mL of saline to determine the microbial growth. Colony-forming unit counts were employed for assessing the antimicrobial action. Statistical analysis was conducted to compare the percentage reduction in the microbial count from the initial count. Results: Group V and Group IV showed significantly higher values in microbial reduction than Group III and Group I. In addition, the results showed that Group II and Group III have significantly higher values than Group I. Conclusion: Natural irrigating solutions exposed to gamma radiation exhibited promising antimicrobial activity that is comparable to that of NaOCl and may be used as effective antimicrobial agents in endodontic treatment. [ABSTRACT FROM AUTHOR]

This study presents the implementation of an internet of things (IoT)-based device for the accurate and continuous measurement of gamma and ultraviolet (UV) radiation in a rural area of Sincelejo, Colombia. The device, calibrated with an error margin below 5%, allowed for the reliable collection of data during the year 2022. An average effective dose rate of gamma radiation of (0.998±0.037) mSv/year was recorded, a value that approaches the recommended limit. Additionally, the inverse square law of radiation was confirmed, observing a decrease in radiation with an increase in altitude. Concurrently, a constant risk of high to extremely high UV radiation exposure was detected throughout the year. These findings emphasize the need for constant monitoring and the implementation of UV protection measures in the region. The integration of IoT in environmental dosimetry has proven to be an invaluable tool for detailed tracking of radiation levels, significantly contributing to the understanding of radiation in rural areas. The exploration of more advanced sensors and data analysis tools in future research is recommended to further improve the accuracy and utility of these devices. [ABSTRACT FROM AUTHOR]

Clay is a native building material in Sudan and is utilized by most low-income people. The radiation shielding characteristics of clay and cement were tested with a specific thickness to explore the behavior of gamma radiation through these materials. The results were compared and estimated by the Phy-X, XCOM, and Py-MLBUF software packages. Mass Attenuation Coefficient (MAC), Linear Attenuation Coefficient (LAC), Half-Value Layer (HVL), Tenth-Value Layer (TVL), Mean Free Path (MFP), and equivalent atomic number (Zeq), which describe the shielding properties of the examined materials, were all determined and compared. The comparison of calculations by software and experimental data of all selected samples showed a high degree of agreement, with discrepancies ranging between 0.01 and 5%. The experiments were carried out in a chamber close to 137Cs and 60Co sources at energies of 662, 1173, and 1332 keV. [ABSTRACT FROM AUTHOR]

Since 1988, the Philippines lacked local access to a nuclear facility, creating a significant void in this field of study for Filipinos. However, after a hiatus of 34 years, this gap was addressed with the recent authorization granted to Philippine Research Reactor 1 (PRR-1) Subcritical Assembly for Training, Education, and Research (SATER), allowing it to resume operations. In this work, a PHITS-based computational model was developed for the recently commissioned PRR-1 SATER. The model utilized a simplified model of the Training, Research, Isotope, General Atomics (TRIGA) fuel that releases photons with 0.6617 MeV energy from the Cs-137 fission product in the fuel. Compared to previous works on photon transport mapping, which utilized average source definition, this study employed individually defined fuel intensities and compared them with the averaged source definition for the fuel. The two fuel source definitions showed noticeable differences inside the reactor tank which is relevant for mixed-field irradiation applications of a research reactor. However, defining the fuel rods by their average strength is sufficient for radiation protection purposes. Simulations were also performed for fuel source definitions based on the average and ±1 standard deviation of the gamma intensity. Gamma doses received by cylindrical phantoms positioned at 0.5 m from the surface of the reactor tank for 500 h were found to be 1 % of the radiation dose limits per year and 4 % of the average dose limit for 5 years as stipulated by the Code of Philippine Nuclear Research Institute (PNRI) Regulations. Loss of water accident was also analyzed based on a conservative exposure time of 500 h. This resulted in a dose value that is only 45.5 % of the dose identified as the emergency turnback guidance of the IAEA. Lastly, PHITS calculated values of gamma doses were found to agree well, with 0.98 ratio, when compared with gamma doses measured at specified locations in the reactor. Results of this study confirm the inherent safety of the PRR-1 SATER in terms of radiological shielding for Cs-137 photons.

Abstract A laser-plasma source emitting photons with energies in the water window spectral range has been used to reveal the radiation chemical yields of single-strand breaks in plasmid DNA as a function of ·OH radical scavenger concentration. Direct and indirect effects were investigated separately using DNA samples with various levels of hydration. We experimentally determined the value of the efficiency factor for strand cleavage in DNA caused by the reaction with ·OH radicals at 0.11, which was previously found in the theoretical studies. Additionally, the radiation chemical yield of ·OH radicals specific to the water window radiation emission of the source was determined by comparison with the gamma radiation-induced strand break yields. The ·OH radical yield determined using the plasmid DNA samples as a model was similar to the yield found using sensitive fluorescent dosimeters in previous experiments.

A model of occupational exposure to gamma flaw detector operators working with portable flaw detectors in the field has been developed. The initial data for the development and verification of the model were the results of measurements of the characteristics of the gamma radiation field at the workplaces of flaw detectors and data from individual dosimetric monitoring. The relationships between the measured (H*(10), Hp(10)) and protection (effective dose) quantities (conversion coefficients) were determined using calculations and phantom experiments simulating three main operations of the full production cycle: transportation of the flaw detector to the place of X-raying of the product, installation of a flaw detector to perform x-raying and X-raying of the product. As a result of the study, it was found that more than 90% of the dose contribution to the readings of an individual dosimeter is due to the installation of the flaw detector in the working position and X-raying of the product. The values of the conversion coefficients for these operations in the form of the ratio of the effective dose values and the readings of dosimeters (Hp(10)) located on the worker's body at chest level (standard place) and abdominal level differ little for both positions of individual dosimeters. The use of maximum conversion coefficient value of 0.8 Sv/Sv corresponding to the operation of X-raying of the product will ensure conservatism in the assessment of the effective dose for the entire production cycle by no more than 15% and 25% for dosimeters located at the chest level and abdominal level, respectively.

Azurin, a secondary metabolite from Pseudomonas aeruginosa, has attracted much attention owing to its valuable therapeutic and biological applications. This work aimed to study and chartly maximize the azurin production process using different doses of gamma irradiation (5–400 Gy) in P. aeruginosa isolates. Seventy-six P. aeruginosa isolates were sourced from 135 environmental samples and 35 clinical bacterial isolates with the following descending order: 35 isolates (46%) from clinical samples, 26 isolates (34%) from water samples, and 15 isolates (20%) from soil samples. The disc diffusion technique was used for antimicrobial susceptibility testing, revealing that the multidrug-resistant (MDR) rate among all collected isolates according to the criteria determined by Clinical and Laboratory Standards Institute (CLSI) was 54 (71%). The genomic experimental results revealed that only 37 MDR isolates tested positive for the azurin gene, as detected by the PCR product at 446 bp. These findings were further supported by FTIR analysis, which revealed peaks around 1636.96 cm− 1, indicating a prominent α-helix secondary structure of azurin in these isolates. Related to their pathogenicity and antibiotic resistance, isolates from clinical origin exhibited the higher azurin gene expression level. Besides, this study confirmed the potency of gamma radiation exposure at 50 and 100 Gy significantly increased the azurin expression levels in three tested clinical isolates (P ≤ 0.05), with a maximum fold expression level of 63.55 compared to the non-irradiated samples. In conclusion, low doses of gamma irradiation effectively enhanced expression level of a secondary metabolite azurin, providing a considerable benefit for subsequent purification processes in both biological and medical applications. [ABSTRACT FROM AUTHOR]

Effects of cobalt-60 gamma irradiation on seed germination and seedling survival of 7 cultivars of Viola cornuta L. were investigated. The results revealed that low doses of gamma radiation at 100 Gray (Gy) significantly stimulated germination in 'Deep Blue Blotch' and 'Clear Purple' and slightly enhanced germination in 'Clear Yellow' and 'Victoriana'. In contrast, higher doses (> 400 Gy) significantly decreased germination across all cultivars. No germination was observed at 1,000 Gy in the 'Deep Blue Blotch' cultivar. Analysis of mean germination time (MGT) and coefficient of velocity of germination (CVG) showed delays in germination and decreased germination velocity with increasing irradiation dose. The seedling survival percentage also decreased with higher radiation doses, indicating sublethal effects on seedling establishment. The lethal dose for 50 % mortality (LD50) values ranged from 320 to 495 Gy for the Bel Viso series and from 430 to 640 Gy for the Grandissimo series. Our findings highlight the dose-dependent effects of gamma irradiation on seed germination and seedling survival and provide insights into irradiation tolerance and susceptibility among cultivars. Understanding these responses is crucial for optimizing irradiation-induced mutagenesis strategies and developing plant selection plans for crop improvement. [ABSTRACT FROM AUTHOR]

Abstract This study aims to create a novel, distinct form of elastomer with superior ability to resist fire, high resistance to radiation, and resistance to environmental conditions such as temperature and solvents. This type of natural-based elastomer was prepared using carboxymethyl cellulose CMC, polyacrylic acid PAA, crosslinked with tannic acid TA. Most techniques in elastomer manufacture technologies are unfriendly and participate in increasing carbon emissions. Gamma radiation was used as a clean tool for copolymerization and crosslinking the elastomer. The irradiation dose of 5 kGy with a rate of 3.32 kGy/h was enough to produce CMC/PAA/TA elastomer. The properties of the produced elastomer were investigated by Fourier-transformed infrared spectroscopy (FT-IR), X-ray diffraction, thermal gravimetric analysis (TGA), and limiting oxygen index (LOI). CMC/PAA/TA has high resistance to solvents such as acetone, benzene, HCl, and HNO3. The tensile strength is 3.376 MPa, the elongation percent is 501.689%, and the LOI value is 30%. The produced elastomer possessed excellent gamma radiation resistance. The elastomer was exposed later to 1864 kGy of gamma radiation without showing degradation and retained its properties, as confirmed by FTIR, TGA, and mechanical properties. After investigation, it can be inferred that the produced CMC/PAA/TA elastomer exhibited outstanding properties.

Abstract This study involves the preparation of polymer composites using untreated and treated chicken feather, leather, and cow hair fiber in combination with unsaturated polyester resin (UPR) and analyzing the effect of gamma radiation on tensile properties. These fibers were incorporated into the resin matrix at various weight percentages (2%, 5%, 7%, 10%, 12%, and 15%). Additionally, the nanoparticle ZnO was added in the composites as filler to improve the mechanical properties. The composites that utilized treated chicken feather fibers yielded superior results in comparison to those that relied on untreated fibers. Prepared composites outperformed neat composites when inorganic components were added as filler to UPR. Composite materials’ mechanical properties, particularly their tensile strength and modulus, can be improved by combining cow hair feather and chicken feather mixed fibers with ZnO filler and gamma radiation modification, according to this study. The morphological and spectroscopic analysis provides supporting evidence for the mechanical strength between the fibers and the resin. Ionizing gamma radiation modification of the fiber resulted in superior tensile characteristics. The optimized composites of animal fibers were then subjected to gamma radiation of variable dose of 0, 2.5, 5 and 7.5 kGy. The tensile properties were found to be the maximum at 5 kGy. Scanning electron microscopy was used to investigate the structural changes caused by the incorporation of animal fibers (chicken feather and cow hair) and ZnO. Composite material and UPR functional group identification were achieved by means of Fourier Transform Infrared Spectroscopy (FTIR).

Abstract Conductive polymer nanocomposites for electromagnetic interference (EMI) shielding are important materials that can be combat the increasingly dangerous radiation pollution arising from electronic equipment and our surrounding environment. In this work, we have synthesized polyaniline-copper nanoparticles (PANI-Cu NPs) by the copper salt based oxidative polymerization method at room temperature and then added with different concentration (0, 1, 3 and 5 wt%) in polystyrene polymer forming PS/ PANI-Cu nanocomposites films by means of the traditional solution casting technique. The formed PANI-Cu NPs were investigated by UV/Vis spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM) and SEM/EDX elemental mapping techniques. On the other hand, the prepared PS/PANI-Cu nanocomposites films were evaluated by UV and SEM, the mechanical properties of the nanocomposites films were evaluated and showed an improvement by added PANI-Cu NPs up to 3 wt% and 50 kGy gamma exposure dose. The PS/PANI-Cu nanocomposites films were examined as electromagnetic interference shielding material. Electromagnetic shielding effectiveness of the produced nanocomposites were tested in the X-band of the radio frequency range namely from 8 to 12 GHz using the vector network analyzer (VNA) and a proper wave guide. All samples were studied before and after 50 kGy gamma-ray irradiation under the same condition of pressure and temperature. The results showed that the nanocomposites have improved shielding properties.

Abstract Radiation enteritis is a frequently encountered issue for patients receiving radiotherapy and has a significant impact on cancer patients' quality of life. The gut microbiota plays a pivotal role in intestinal function, yet the impact of irradiation on gut microorganisms is not fully understood. This study explores the gastroprotective effect and gut microbiome-modulating potential of ubiquinol (Ubq), the reduced form of the powerful antioxidant CoQ-10. For this purpose, male albino rats were randomly assigned to four groups: Control, IRR (acute 7 Gy γ-radiation), Ubq_Post (Ubq for 7 days post-irradiation), and Ubq_Pre/Post (Ubq for 7 days pre and 7 days post-irradiation). The fecal microbiomes of all groups were profiled by 16S rRNA amplicon sequencing followed by bioinformatics and statistical analysis. Histopathological examination of intestinal tissue indicated severe damage in the irradiated group, which was mitigated by ubiquinol with enhanced regeneration, goblet cells, and intestinal alkaline phosphatase expression. Compared to the irradiated group, the Ubq-treated groups had a significant recovery of intestinal interleukin-1β, caspase-3, nitric oxide metabolites, and thio-barbituric reactive substances to near-healthy levels. Ubq_Pre/Post group displayed elevated peroxisome proliferator-activated receptor (PPAR-γ) level, suggesting heightened benefits. Serum insulin reduction in irradiated rats improved post-Ubq treatment, with a possible anti-inflammatory effect on the pancreatic tissue. Fecal microbiota profiling revealed a dysbiosis state with a reduction of bacterial diversity post-irradiation, which was re-modulated in the Ubq treated groups to profiles that are indistinguishable from the control group. These findings underscore Ubq's gastroprotective effects against radiation-induced enteritis and its potential in restoring the gut microbiota’s diversity and balance.

Cassava (Manihot esculentaCrantz) production and productivity in Africa is affected by two viral diseases; cassava mosaic disease (CMD) and cassava brown streak disease (CBSD). Inducedmutagenesis of totipotent/embryogenic tissues or in vitro plantmaterial can lead to the generation of CMD and/or CBSD tolerantmutants. To massively producenon-chimeric plants timely andwithless labor, totipotent cells or tissues are a pre-requisite. This study aimed to determine the effect of gamma radiation on the proliferation and growth of friable embryogenic callus (FEC) and in vitro nodal cuttings respectively. To obtain FEC, 2-6 mm sized leaf lobes of nine cassava genotypes were plated on Murashige and Skoog (MS) basal media supplemented with varying levels (37, 50, 70, 100) mM of picloram for production of organized embryogenic structures (OES). The OES of five cassava genotypes (Alado, CV-60444, NASE 3, NASE 13 and TME 204) were crushed and plated in Gresshoff and Doy (GD) basal media in combination with the amino acid tyrosine in varying concentrations for FEC production. FEC from five cassava genotypes and in vitro nodal cuttings of nine genotypes were irradiated using five different gamma doses (0, 5,10, 15, 20and25Gy) at adose rateof81Gy/hr. The lethaldose (LD)50was determined using the number of roots produced and flow cytometry was done to determine the ploidy status of plants. The highest production of OES was noted in Alado across varying picloramconcentrations, while TME 204 obtained the highest amount of FEC. The irradiated FEC gradually died and by 28 days post irradiation, FEC from all five cassava genotypes were lost. Conversely, the irradiated in vitro nodal cuttings survived and some produced roots, while others produced callus. The LD50 based on number of roots varied from genotype to genotype, but plants remained diploid post-irradiation. Accordingly, the effect of gamma irradiation on Ugandan cassava genotypes (UCGs) was genotype-dependent. This information is foundational for the use of in vitro tissues as target material for cassava mutation breeding. [ABSTRACT FROM AUTHOR]

Regulating chemical drug's responsiveness to gamma radiation is crucial for achieving better therapeutic effects in cancer treatment. Most research focused on thermodynamic chemical structure design, while little attention was paid to kinetic regulate strategy, which possesses greater universality and security. In this study, we achieved a kinetic‐based regulate strategy of gamma radiation reaction, through the construction of microphase environment during polymerization of polytelluoxane (PTeO). We designed hydrophobic segments forming large compound micelles (LCMs) assembly to create kinetically favorable higher concentration for radiation‐induced reaction. It exhibited a > ten times higher responsiveness and, as far as we know, merely required a minimum dosage of 5 Gy for polymerization to occur. What's more, by taking advantages of the assembly change with Te−O hydrophilic segments and gamma radiation, polymerization became milder with lower polydispersity than previous methods. Such kinetic‐based regulate strategy could offer a novel perspective on the design of radiation‐responsive chemoradiotherapy and other radiation‐induced chemical process. [ABSTRACT FROM AUTHOR]

In this work, effect of gamma irradiation on chemical vapor deposition grown ReS2 thin films vis‐a‐vis change in its structure, morphology, chemical composition, and memristive behaviour is reported to assess its radiation hardness for space applications. High‐resolution transmission electron micrographs and selected area electron diffraction pattern infer polycrystalline to amorphous phase transition and increase in the number of grain boundaries (GBs) after exposure to 25 kGy of gamma radiation. X‐ray photoelectron spectroscopy and low‐temperature photoluminescence measurements reveal the formation of sulfur vacancies (SV) accompanied with partial oxidation of film. Memristors are then fabricated on the as‐grown film using different metal electrodes, which are Ag, Pt, and Ti in lateral geometry, and their resistive switching (RS) mechanism is studied along with the impact of gamma irradiation. RS is attributed to the formation of conducting filaments due to GB‐mediated migration of metal ions, SV, and oxygen ions from the partially oxidized film. Furthermore, irradiation is found to increase current in the high resistance state of the device, which subsequently reduces the memory window. This impact is observed to be consistent across all the devices which validates the effect of irradiation irrespective of the nature of the metal electrode used. [ABSTRACT FROM AUTHOR]

Cosmic radiation experienced during space travel may increase the risk of cognitive impairment. While simulated galactic cosmic radiation (GCRsim) has led to memory deficits in wildtype (WT) mice, it has not been investigated whether GCRsim in combination with genetic risk factors for Alzheimer's disease (AD) worsens memory further in aging mice. Here, we investigated the central nervous system (CNS) effects of 0 Gy (sham) or 0.75 Gy five-ion GCRsim or 2 Gy gamma radiation (IRR) in 14-month-old female and male APPNL-F/NL-F knock-in (KI) mice bearing humanized ApoE3 or ApoE4 (APP;E3F and APP;E4F). As travel to a specialized facility was required for irradiation, both traveled sham-irradiated C57BL/6J WT and KI mice and non-traveled (NT) KI mice acted as controls for potential effects of travel. Mice underwent four behavioral tests at 20 months of age and were euthanized for pathological and biochemical analyses 1 month later. Fecal samples were collected pre- and post-irradiation at four different time points. GCRsim seemed to impair memory in male APP;E3F mice compared to their sham counterparts. Travel tended to improve cognition in male APP;E3F mice and lowered total Aβ in female and male APP;E3F mice compared to their non-traveled counterparts. Sham-irradiated male APP;E4F mice accumulated more fibrillar amyloid than their APP;E3F counterparts. Radiation exposure had only modest effects on behavior and brain changes, but travel-, sex-, and genotype-specific effects were seen. Irradiated mice had immediate and long-term differences in their gut bacterial composition that correlated to Alzheimer's disease phenotypes. [ABSTRACT FROM AUTHOR]

Bentonite is an integral part of the engineered barrier system (EBS) in deep geological repositories (DGR) for nuclear waste, but its indigenous microorganisms may jeopardize long-term EBS integrity. To predict microbial activity in DGRs, it is essential to understand microbial reactions to the early hot phase of DGR evolution. Two bentonites (BCV and MX-80) with varied bentonite/water ratios and saturation levels (compacted to 1600 kg.m− 3 dry density/powder/suspension), were subjected to heat (90–150 °C) and irradiation (0.4 Gy.h− 1) in the long-term experiments (up to 18 months). Molecular-genetic, microscopic, and cultivation-based techniques assessed microbial survivability. Exposure to 90 °C and 150 °C notably diminished microbial viability, irrespective of bentonite form, with negligible impacts from irradiation or sample type compared to temperature. Bentonite powder samples exhibited microbial recovery after 90 °C heating for up to 6 months but not 12 months in most cases; exposure to 150 °C had an even stronger effect. Further long-term experiments at additional temperatures combined with the mathematical prediction of temperature evolution in DGR are recommended to validate the possible evolution and spatial distribution of microbially depleted zones in bentonite buffer around the waste canisters and refine predictions of microbial effects over time in the DGR. [ABSTRACT FROM AUTHOR]

The aim of the present study is to develop a pH-sensing biopolymer film based on the immobilization of red cabbage extract (RCE) within bacterial cellulose (BC) to detect contamination and gamma radiation exposure in cucumbers. The results obtained show a sensitivity to pH changes for RCE in its aqueous form and that incorporated within BC films (RCE-BC), both showed color change correlated to bacterial growth (R2 = 0.91), this was supported with increase in pH values from 2 to 12 (R2 = 0.98). RCE and RCE-BC exposure to gamma radiation (0, 2.5, 5, 10, 15, 20, 25 kGy) resulted in gradual decrease in color that was more evident in RCE aqueous samples. To sense bacterial contamination of cucumbers, the total count was followed at 0, 5, 10 and 15 days in cold storage conditions and was found to reach 9.13 and 5.47 log cfu/mL for non-irradiated and 2 kGy irradiated samples, respectively. The main isolates detected throughout this storage period were identified as Pseudomonas fluorescens, Erwinia sp. Pantoea agglomerans using matrix assisted laser desorption ionization–time of flight-ms (MALDI–TOF–MS). Bacterial growth in stored irradiated cucumbers was detected by color change within 5 and 10 days of storage, after which there was no evident change. This is very useful since contamination within the early days of storage cannot be sensed with the naked eye. This study is the first to highlight utilizing RCE and RCE-BC as eco-friendly pH-sensing indicator films for intelligent food packaging to detect both food contamination and gamma preservation for refrigerator stored cucumbers. [ABSTRACT FROM AUTHOR]

Phosphorus in wastewater influents is a global issue. Controlling eutrophic water is crucial. Biological phosphorus removal is an economically and environmentally sustainable method for removing phosphorus from wastewater. This study aims to isolate and improve the capacity of aerobic phosphorus-removing bacteria to reduce excessive phosphate concentrations in the environment. Only three out of fourteen bacterial isolates demonstrated the highest phosphate removal efficiency using Toluidine blue-O. Klebsiella pneumoniae 6A, Klebsiella quasipneumoniae 6R, and Enterobacter mori 8R were isolated from activated sludge and identified by 16srRNA. In a single-factor experiment, the effect of incubation periods, phosphate concentrations, carbon sources, sodium acetate concentrations, temperature, pH, and irradiation dosages were studied. Seventy-two hours of incubation, 55 mg/L PO4, sodium acetate as the carbon source, 30°C and pH 7 resulted in maximum phosphorus removal. After optimising the parameters, the removal efficiency of Klebsiella pneumoniae 6A, Klebsiella quasipneumoniae 6R, and Enterobacter mori 8R increased from 73.5% to 85.1%, 79.1% to 98.1%, and 80.6% to 91.9%, respectively. Gamma irradiation showed significant results only in Klebsiella pneumoniae 6A where 100 Gy increased the phosphorous removal efficiency from 85.1% to 100%. Immobilised mixed culture of the three strains adapted better to 100 mg/L Phosphorus than pure cells. Therefore, this technique holds great new promise for phosphorus-contaminated sites bioremediation. [ABSTRACT FROM AUTHOR]

The present work investigates the potential role of metformin nanoparticles (MTF-NPs) as a radio-protector against cardiac fibrosis and inflammation induced by gamma radiation via CXCL1/TGF-β pathway. Lethal dose fifty of nano-metformin was determined in mice, then 21 rats (male albino) were equally divided into three groups: normal control (G1), irradiated control (G2), and MTF-NPs + IRR (G3). The possible protective effect of MTF-NPs is illustrated via decreasing cardiac contents of troponin, C-X-C motif Ligand 1 (CXCL1), tumor growth factor β (TGF-β), protein kinase B (AKT), and nuclear factor-κB (NF-κB). Also, the positive effect of MTF-NPs on insulin-like growth factor (IGF) and platelet-derived growth factor (PDGF) in heart tissues using immunohistochemical technique is illustrated in the present study. Histopathological examination emphasizes the biochemical findings. The current investigation suggests that MTF-NPs might be considered as a potent novel treatment for the management of cardiac fibrosis and inflammation in patients who receive radiotherapy or workers who may be exposed to gamma radiation. [ABSTRACT FROM AUTHOR]

The effects of Nano propolis (NP-Pro) alone or combined with radiation in human liver cancer cell line (HepG2) in vitro were evaluated. NP-Pro is made up of natural propolis particles that are between 1 and 100 nm in diameter that have been linked together to increase its effectiveness without altering its original characteristics. Numerous benefits of propolis include its anti-inflammatory, antioxidant, anti-cancer, and antifungal properties. Propolis nanoparticles were characterized using dynamic light scattering (DLS), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Cell viability was examined using MTT (3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyl tetrazolium bromide) assay, and apoptosis was assessed using flow cytometry. HepG2 was treated with both different concentrations of NP-Pro and irradiated 10 Gy using a 137Cs gamma source. The cytotoxic effect of the studied NP-Pro increased with an increase in concentrations. The IC50 of NP-Pro in the cytotoxicity test with the HepG2 cells in combination with a radiation dose of 10 Gy was 7.58 ± 0.39 µg/mL, while for free NP-Pro, it was 29.58 ± 1.27 µg/mL. The effects of the combined use of NP-Pro and irradiated 10 Gy on cytotoxicity, generation of reactive oxygen species, and activity of apoptosis-mediated signaling pathways were studied on the HepG2 cell line. Cell apoptosis tests have shown that HepG2 cells that are exposed to nano propolis + 10 Gy undergo apoptosis, and their population is dramatically decreased (p < 0.005). All these studies concluded that propolis nanoparticles could be a good alternative to existing anticancer materials in combination with gamma radiation. [ABSTRACT FROM AUTHOR]

This study involves the preparation of polymer composites using untreated and treated chicken feather, leather, and cow hair fiber in combination with unsaturated polyester resin (UPR) and analyzing the effect of gamma radiation on tensile properties. These fibers were incorporated into the resin matrix at various weight percentages (2%, 5%, 7%, 10%, 12%, and 15%). Additionally, the nanoparticle ZnO was added in the composites as filler to improve the mechanical properties. The composites that utilized treated chicken feather fibers yielded superior results in comparison to those that relied on untreated fibers. Prepared composites outperformed neat composites when inorganic components were added as filler to UPR. Composite materials' mechanical properties, particularly their tensile strength and modulus, can be improved by combining cow hair feather and chicken feather mixed fibers with ZnO filler and gamma radiation modification, according to this study. The morphological and spectroscopic analysis provides supporting evidence for the mechanical strength between the fibers and the resin. Ionizing gamma radiation modification of the fiber resulted in superior tensile characteristics. The optimized composites of animal fibers were then subjected to gamma radiation of variable dose of 0, 2.5, 5 and 7.5 kGy. The tensile properties were found to be the maximum at 5 kGy. Scanning electron microscopy was used to investigate the structural changes caused by the incorporation of animal fibers (chicken feather and cow hair) and ZnO. Composite material and UPR functional group identification were achieved by means of Fourier Transform Infrared Spectroscopy (FTIR). [ABSTRACT FROM AUTHOR]

Maize (Zea mays L.) sprouts growth and activity dynamics of DMDH (decarboxylating malate-dehydrogenase, Malic enzyme EC:1.1.1.40) enzyme have undergone studies under combined stress conditions developed by gamma rays, salt solution, and nanoparticles. Three different factors comprising various doses of gamma radiation (250, 500, and 750 Gy), NaCl solution (100 mM), and iron oxide nanoparticles (maghemite, γ- Fe2O3) have been in use by the study to develop artificial stress conditions. These combined stress conditions have significantly affected and delayed the plant growth compared with the control variant. The higher doses of radiation (500 and 750 Gy) have slowed down the plant growth and caused destruction. The effect of gamma radiation (250 Gy) delayed the growth of plants. However, during the combined influence of nanoparticles (Fe2O3) with a dose of 250 Gy, plant development was better than with an individual dose of 250 Gy. This difference was not evident in the medium with high doses (500 and 750 Gy) of gamma radiation combined with nanoparticles (Fe2O3) and with salt stress (NaCl 100 mM). During the first 10 days of the experiment, DMDH enzyme activity, induced in the root and leaf cells in all variants, included the control, and inhibition occurred on the 15th day. This reaction product can be due to enzyme inhibition. However, the enzyme activity was higher during the combined stress conditions. [ABSTRACT FROM AUTHOR]

Thrombosis is a dangerous condition that can result in major damage. Fibrinolytic enzymes are significant therapeutic agents for thrombosis. This study focused on MsFE, a fibrinolytic protease from M. subtilissimus UCP1262, exploring its physicochemical traits and the impact of gamma radiation on its activity. Investigations included: fibrinogenolytic activity, effects of solvents and ions, gamma rays, enzyme shelf life, FTIR, CD, clotted times determination, and enzymatic kinetics. Notably, the major results obtained show the protease retained 90 % activity in organic solvents, FTIR indicated carbonyl functional groups and Circular dichroism spectroscopic studies indicated that the secondary structure (β-sheet) of enzyme remains mostly unaffected over pH 2.0–9.0, whereas considerable changes were observed in the tertiary structure. Kinetic analysis revealed altered parameters post-irradiation. Gamma radiation initially enhanced enzyme activity (10 kGy) but progressively decreased beyond 20 kGy. Metallic ions, especially magnesium, augmented irradiated enzyme activity. This study highlights gamma radiation's potential as a modulator for enhanced fibrinolytic activity, suggesting future biomedical applications. [Display omitted] • Mucor subtilissimus proves its significance as a producer of fibrinolytic proteases. • The protease degrades the α, β and γ chains of fibrinogen. • The 10 kGy radiation increased the activity of the enzyme by approximately 10 %. • Fe2+, Cu2+ and Mg2+ were able to increase the activity of the irradiated enzyme. • Produced enzymes can be a highly productive fibrinolytic for medical applications. [ABSTRACT FROM AUTHOR]

Gamma radiation can cause structural defects in metal oxide thin films, affecting their conversion efficiency. This study focuses on synthesizing and characterizing Tungsten oxide (WO3) films for photo-electrochemical (PEC) water-splitting applications. The pristine WO3 film was irradiated with a Co-60 gamma source to improve its photocatalytic activity and was named G-WO3. The resulting G-WO3 thin films showed a decrease in the optical direct band gap and showed higher photocurrent density and lower charge transfer resistance for PEC applications. The carrier charge density (Nd) values were found to be increased after γ-radiation. The synthesized G-WO3 thin films possess good stability and reusability for photo-electrochemical water-splitting applications. [ABSTRACT FROM AUTHOR]

This work presents an in-depth analysis of the linear attenuation coefficient (LAC), effective atomic number (Zeff) and half value layer (HVL) for borosilicate glasses doped with ZnO. Utilizing Akima splines and piecewise cubic Hermite interpolating polynomials (PCHIP), we predicted the LAC, Zeff and HVL for the investigated glasses in a wide energy range of 0.015–15 MeV. The results showed that the LAC values for the four prepared glasses predicted by Akima splines and PCHIP closely match the theoretical data at all the selected energy levels. This suggested that both Akima splines and PCHIP are a reliable technique for evaluating the LAC of the prepared borosilicate glasses in the energy range of 0.015–15 MeV. The same agreement between the theoretical and predicted data was also reported for the Zeff and HVL. Also, we examined the accuracy in the Akima splines and PCHIP methods in predicting the radiation shielding properties for the selected glasses at certain energy values emitted by Eu-152. The results demonstrated excellent agreement between Akima splines and PCHIP with the theoretical data, which confirms the usefulness of these two interpolation methods in predicting the radiation shielding parameters in the energy range of 0.0395–1.46 MeV. [ABSTRACT FROM AUTHOR]

A Raman spectroscopic study of radiation-synthesized tetrafluoroethylene telomers with different terminal groups was carried out for the first time. The influence of gamma radiation on the molecular structure of telomers and hydrophobic coatings of aluminoborosilicate glass fabric based on them has been studied. Changes induced by gamma radiation in the molecular and morphological structures of the telomers have been observed. [ABSTRACT FROM AUTHOR]

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Background: The exploration of bacterial endospores as potential antitumor agents has garnered increased attention in recent years. This study investigates the impact of Clostridium sporogenes endospores as modifiers of immune regulation on tumor growth, to refine therapeutic protocols for hepatocellular carcinoma. Methods: Hepatocellular carcinoma was induced in adult male albino rats using diethylnitrosamine (DEN) (20mg/kg b.wt/day) orally injected five times a week for 6 consecutive weeks) and subsequently treated with endospores (intravenous injection of endospores once at a dose of 60 million spores/rat), and samples were taken from rats after one month of endospore injection. Multiple parameters, including interferon-gamma (IFN-γ), nuclear factor-κB (NF-κB), tumor necrosis factor-alpha (TNF-α), antioxidant enzymes, malondialdehyde (MDA), and liver function enzymes were assessed. Results: Results demonstrated a remarkable suppression of tumor proliferation and the induction of enduring immunity through IFN-γ stimulation. The levels of inflammatory markers associated with tumor promotion (NF-κB and TNF-α) witnessed significant improvement. This was paralleled by enhancements in antioxidant status and a reduction in lipid peroxidation in liver tissues of the endospore-treated rats compared to the untreated rats. Histopathological examinations, along with elevated liver function enzymes, provided additional support for these observed improvements. Conclusion: this study offers compelling evidence for the potential of safe concentrations of endospores in modulating immune responses and targeting tumor cells, suggesting their plausible roles as adjuvants to augment cancer therapeutic protocols. [ABSTRACT FROM AUTHOR]

New YAG:Yb:Mg and YAG:Yb:Ca:Mg crystals with a short decay time are grown for the first time using the Czochralski method. The pulsed cathodoluminescence spectra of the new scintillators, their light output, and decay time are studied. The light output of the YAG:Yb:Mg and YAG:Yb:Ca:Mg crystals are found to be 460 and 770 photons/MeV, respectively. It is shown that the decay time spectra of the new crystals are described by two components: 1.57/8.5 ns for YAG:Yb:Mg and 1.52/7.79 ns for YAG:Yb:Ca:Mg. [ABSTRACT FROM AUTHOR]

We report a study of optical and scintillation properties of modules of a prototype electromagnetic calorimeter based on barium fluoride crystals (BaF2) measuring 25 × 25 × 160 mm3. The length of the crystal radiator of the calorimeter is optimized using the Monte Carlo method in order to improve its energy resolution. Homogeneity of the light output from different sections of the module using gamma quanta from a 137Cs source is demonstrated. The scintillation time of the crystal module under gamma excitation is measured. [ABSTRACT FROM AUTHOR]

Conductive polymer nanocomposites for electromagnetic interference (EMI) shielding are important materials that can be combat the increasingly dangerous radiation pollution arising from electronic equipment and our surrounding environment. In this work, we have synthesized polyaniline-copper nanoparticles (PANI-Cu NPs) by the copper salt based oxidative polymerization method at room temperature and then added with different concentration (0, 1, 3 and 5 wt%) in polystyrene polymer forming PS/ PANI-Cu nanocomposites films by means of the traditional solution casting technique. The formed PANI-Cu NPs were investigated by UV/Vis spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM) and SEM/EDX elemental mapping techniques. On the other hand, the prepared PS/PANI-Cu nanocomposites films were evaluated by UV and SEM, the mechanical properties of the nanocomposites films were evaluated and showed an improvement by added PANI-Cu NPs up to 3 wt% and 50 kGy gamma exposure dose. The PS/PANI-Cu nanocomposites films were examined as electromagnetic interference shielding material. Electromagnetic shielding effectiveness of the produced nanocomposites were tested in the X-band of the radio frequency range namely from 8 to 12 GHz using the vector network analyzer (VNA) and a proper wave guide. All samples were studied before and after 50 kGy gamma-ray irradiation under the same condition of pressure and temperature. The results showed that the nanocomposites have improved shielding properties. [ABSTRACT FROM AUTHOR]