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In this chapter, we try to connect the urban design features with energy consumption and consequent pollution parameters. After a review of a selected set of approaches to Urban Energy Systems study with a special focus on electrical power systems, urban energy systems are proposed as networks of multi-source hybrid energy hubs, where different energy flows are collected at the same bus and can be stored, delivered or transformed as needed. Resources at the hub and infrastructures interact with each other; therefore, both definition and boundaries of such energy systems at urban level are difficult to be clearly outlined. Similarly, the possibility to generate new operational models based on existing critical urban infrastructures is also challenging. This contribution proposes a preliminary study of urban energy hubs. Operations of thermal, electrical and mobility infrastructures are considered as qualifying features of the hub, but still the interconnected operation is not taken into account. The application part shows, indeed, the analysis and optimized design of the energy system serving two different urban districts. The related optimized parametric design of power generation infrastructures is considered as a function of urban features. The results about emissions and costs provide some interesting conclusions about the linkage between energy planning and urban features at district level, thus allowing, as possible application of this work, an energy-based territorial planning for urban contexts.