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In this study, 42 urban soil samples were collected from the city centre of Uşak to determine heavy metals concentrations, cation exchange capacity (CEC), N, P, pH, SOM (soil organic matter), and texture. The goals were to evaluate and map the concentrations of As, Cr, Cu, Hg, Ni, Pb, Cd, and Zn, assess heavy metals contamination, and identify the potential ecological risks and their sources. Various assessment methods were used to evaluate potential ecological risk of heavy metals, including geoaccumulation index (Igeo), enrichment factor (EF), degree of contamination (Cdeg), potential ecological risk (RI), and pollution load index (PLI). Spatial distribution maps were created for each heavy metal concentration and assessment method. The concentrations of the selected heavy metals in Uşak ranged from 11.60 to 90.50 mg/kg for As; 31.90 to 1,455.20 mg/kg for Cr; 7.67 to 45.62 mg/kg for Cu; 0.01 to 0.22 mg/kg for Hg; 83.10 to 484.90 mg/kg for Ni; 6.72 to 97.63 mg/kg for Pb; 0.06 to 0.34 mg/kg for Cd; and 19.90 to 89.30 mg/kg for Zn. The CEC values range from 2 to 15% with an average of 7%. N values vary between 0.01 to 0.05%. The soil pH values range from 7.0 to 8.5, with a mean of 7.9. SOM concentrations in the studied soils ranged from 1.8 to 2.7%, with an average of 2.2%. When compared to soil averages of the world, the results indicate that the As, Cr, and Ni concentrations were much greater. Igeo values of Ni and As indicate moderate to heavy contamination in the eastern part of the Uşak. EF values of As show a very high enrichment in the eastern, and northern parts of Uşak. Cdeg calculations show a moderate degree of contamination in the southeastern part of the city. The RI values reveal a moderate ecological risk in the eastern parts of the cıty. The PLI calculations indicate unpolluted to moderately polluted soils in most parts of Uşak. The presence of industrial sites in the east, and a leather tanning industrial site in the southeast validate that the source of the heavy metals contamination is anthropogenic. [ABSTRACT FROM AUTHOR]

Excessive levels of heavy metals in soil can significantly impact human health and ecological safety. Evaluating heavy metal pollution and identifying its sources are crucial for environmental management. This study investigates the status of heavy metal pollution in a southeastern region of China and aims to identify its sources using data from the first national soil pollution survey, which includes 282 sampling points. Indicators such as the geoaccumulation index (Igeo), the potential ecological risk index (RI), the hazard index (HI), and the total lifetime cancer risk (TLCR) were utilized to assess contamination levels. Geographic information systems (GIS), positive matrix factorization (PMF) receptor modeling, cluster analysis (ClusA) and human health risk assessments were integrated to analyze the sources of heavy metals. The results indicate that agricultural pollution sources have a minor impact on overall heavy metal contamination, with low ecological risk levels in the eastern and western regions. In contrast, the central region exhibited moderate risk, with areas of extremely high risk distributed across the central-west and central-south regions. PMF analysis identified pollution sources including natural origins, coal combustion, industrial emissions, and traffic, with contributions of 17.62%, 18.50%, 28.35%, and 35.56%, respectively. Overall, the carcinogenic risk in the study area is not high. Targeted recommendations were made in response to the pollution situation in the study area. This research enhances our understanding of heavy metal pollution in the soil of the study area and provides a reference for pollution source delineation in other regions. [ABSTRACT FROM AUTHOR]

Due to various activities, heavy metals can be released in the environment and endanger the health of people in the society. Considering the importance of the subject, the present research has investigated the contamination of Araghi catchment basin sediments with heavy elements. For this purpose, 24 sediment samples were collected and the concentration of 11 heavy elements, including arsenic(As), cadmium(Cd), cobalt(Co), chromium(Cr), copper (Cu), iron (Fe), Molibden(Mo), nickel (Ni), lead(Pb), vanadium (V)and aluminium(Al), were studied and pollution indicators were used to measure pollution. Based on the calculation of the enrichment index and according to the classification of Chen (2007), Mo (with an average of 0.91), Cu (with an average of 0.92) and Fe (with an average of 0.96) are among the elements without enrichment (less than 1) and the elements of Pb, Cr, As, Ni, Co and V are in the slightly enriched range in the region. Based on this index and the Anthropogenic Percent, the origin of all the studied elements is in the lithogenic area, which is caused by the weathering and erosion of the rock units of the area. The results of examining the Contamination factor, Modify Contamination Degree, Pollution Load Index and Geoaccumulation Index showed that the sediment samples in the study basin did not show any specific pollution and were classified as non-polluted. The average Ecological Risk index and Modified ecological risk index were obtained as 50.38 and 114.07, respectively, which according to Hakanson's classification, the state of Ecological Risk index and Modified ecological risk index of sediments in the studied area are low for heavy elements. [ABSTRACT FROM AUTHOR]

The rapid development of industry and economy has led to the entry of environmental pollutants, particularly heavy metals, into the soil, raising concerns among the global community regarding public health and food security. Consequently, the awareness and assessment of these elements have become significant in predicting hazards and related diseases, as well as establishing soil quality standards. This study aimed to quantify lead (Pb) contamination using various environmental indices in a part of Shahr-e-Ray, Tehran Province. To achieve this, 44 composite soil samples were collected from the 0-20 cm soil depth. After sample preparation, some physical and chemical properties were measured using standard methods, and the total concentration of lead in the soil was determined using the Aqua Regia method. Three environmental indices, including the Enrichment Factor, Geoaccumulation Index, and Contamination Factor, were employed to assess the potential risk of lead contamination. The results indicated that all examined samples exceeded the standard and recommended limit for lead concentration in Iran, with an average of 135.99 mg/kg. In term of the Geoaccumulation Index, the samples exhibited a range of (2.46-2.90), categorizing them in the moderately to heavily polluted class. For the Enrichment Factor, all samples fell into the high enrichment class, with a range of (6.48-9.31). The Contamination Factor also classified the samples as highly contaminated, with a range of (8.25-11.24) which is mainly influenced by human activities. Continuous monitoring and surveillance of lead concentration variations in the studied soils are essential for preserving production resources and achieving food security. [ABSTRACT FROM AUTHOR]

This study aims to assess the extent of the anthropogenic pollution of Area A at the Umm el-Surab archaeological site, Jordan. It examines the concentrations of 21 metals from four Roman, Byzantine, and early and late Ayyubid-Mamluk layers. The site, located near Bosra and Umm el-Jimal, was continuously settled from the Roman till the Islamic periods. The chemical analysis and pollution indices (enrichment and contamination factors (EF, CF), and geo-accumulation index Igeo) show low enrichment in Zn, K, Sr, Na, Pb, Ba, Li, Mn, Mg, Mo, and Cu, and moderate enrichment in Cd, Ag, Ca, As, and Ni. Co is significantly enriched in one sample and moderately enriched in the other ones. The results show pollutant metals more enriched in the Byzantine layer than the rest of the layers. A likely primary source of the limited pollution is organic fuels and their firing product of ash, while a likely secondary source might be the pottery fragments spread in the layers. The results agree with the fact that the site was rural with limited industrial activities, especially metal production, like iron and copper, that would have increased the concentration of the analyzed metals. [ABSTRACT FROM AUTHOR]

Heavy metals pose significant threats to human health, particularly children. This study aimed to assess heavy metal pollution in children's playgrounds using surface dust as an indicator and to ascertain the associated exposure levels and health risks. A total of one hundred twenty dust samples were collected from the surface of playground toys in areas surrounding the cement factory in Bursa, Türkiye, on precipitation-free days. The heavy metal content of the samples was analyzed using ICP-MS. The average total concentration of heavy metals ranged from 2401 to 6832 mg/kg across the sampling sites, with the highest values observed at PG4, PG3, PG2, and PG1, respectively. The most commonly detected heavy metals in the samples included Cr, Mn, Fe, Co, Cu, Zn, Pb, Cd, As, and Ni. Statistical analysis revealed significant positive correlations (p < 0.01) among Cr, Mn, Fe, Co, Cu, Pb, As, and Ni, with Cu and Pb also showing correlation (p < 0.05). PCA analysis identified three principal components explaining 79.905% of the total variance. The Hazard Quotient (HQ) and Hazard Index values for heavy metals were found to be below the safe threshold (HQ < 1). Quantitative techniques such as the geoaccumulation index and enrichment factor are used to determine pollution levels at the sampling sites. Overall, the results indicate that cement factories significantly contribute to heavy metal pollution, with observed values varying based on proximity to the emission source. [ABSTRACT FROM AUTHOR]

The aim of this work was to determine the concentrations, distribution, and fate of potentially toxic elements [lead (Pb), zinc (Zn), nickel (Ni), copper (Cu), mercury (Hg), arsenic (As), and cadmium (Cd)] in sediments of a hydropower plant water reservoir located in the Brazilian Cerrado biome (used as system model). The purpose of this study was achieved with an analysis of the level of contamination based on the geoaccumulation index (Igeo) and factor contamination (FC) and comparisons with values established by environmental legislation. The physical–chemical–biological properties of sediment samples, the distribution, and the fate of potentially toxic elements (PTEs) in the basin of the stream studied were also investigated using Pearson's correlation coefficient (r) and principal component analysis (PCA). Cu, Hg, and Cd concentrations in the sediment samples from most of the points analyzed were above level II of the categorization stipulated in environmental legislation, characterizing sediments of poor quality. Moreover, Igeo and FC values indicated potential pollution of the water reservoir sediment by Cd. Concentrations of Cd exceeding 0.34 mg kg−1 surpassed the reference values for water quality established by Conama Resolution No. 454/2012, highlighting the urgent need for ongoing sediment quality monitoring strategies. Hence, the study water reservoir was classified as being moderately to extremely polluted due to the fate of potentially toxic metals in the sediment samples. Frequent monitoring of the sediment quality in watersheds with hydropower plants is indispensable for the assessment of water resources, considering the importance of the water supply and power generation for the population. Moreover, water contaminated by PTEs poses potential risks to river basins, as well as to human and animal health. The results of this work can assist in the investigation of other water reservoirs around the world. [ABSTRACT FROM AUTHOR]

Abstract This paper studied the spatial distribution and influencing factors of heavy metals (HMs) such as Cu, Pb, Zn, Cr, Ni, Cd and As in the soil of Linzhou County in the Lhasa River basin. By collecting 504 surface soil samples, using descriptive statistics, Kriging interpolation and geoaccumulation index methods, combined with the geographic detector model, the spatial distribution characteristics of soil HMs content and its interaction with 19 environmental factors were systematically analyzed.The results showed that the content of heavy metals in the soil in this area was generally higher than the background value of soil in Lhasa, especially Cd and As, which showed strong spatial heterogeneity, suggesting the existence of specific pollution sources.Although the average HMs content was lower than the soil pollution risk screening value, the As, Cd, Pb and Zn contents at some sampling points exceeded the standard, indicating a high pollution risk in some local areas.The spatial distribution of HMs was uneven, with high-value areas of Pb, Zn and Cd mainly concentrated in the west, Cu concentrated in the northwest, while high-value areas of Cr and Ni were similar, mainly concentrated in the west and central regions. Correlation analysis and geodetector models revealed that traffic pollution and soil texture characteristics were the main environmental factors affecting the spatial variation of soil HMs content, and the distance from national highways and urban roads had a particularly significant relationship with Sc and TK.The study provided a scientific basis for the prevention and control of HMs pollution in soil in high-altitude and cold areas, and recommends targeted environmental management and restoration measures.

Perpetually intensifying soil contamination is an anthropogenic phenomena, which is a global environmental concern. An important tool for the evaluation of contamination levels and ecosystem health is the assessment of soil quality, which can be used to evaluate prospective ecological threats to both organisms and the environment. The aim of this study was to quantify the soil heavy metal pollution levels to assess the site quality of three wildlife parks in different climatic zones of Punjab, Pakistan, where several wild animals were housed for the purpose of conservation. A robust method for calculation, absolute deviation from median (median ± (2 × MAD)), was used to compute geochemical background value of each heavy metal. Single (geoaccumulation index – Igeo and enrichment factor – EF) and complex (pollution load index (PLI)) indices were used to recognize whether the detected heavy metals Pb, Cr, Zn, Cd, Co, Mn and Ni levels in the soil are consequences of anthropogenic or natural sources. In comparison between sites, the heavy metal enrichment for Pb, Cr, Cd and Zn was recorded high at Jallo Forest and Wildlife Park succeeded by Murree Wildlife Park and Bahawalnagar Wildlife Park. Pb, Zn, Cd and Cr showed high EF values at Jallo Forest and Wildlife Park while Igeo values of Pb, Cr, Cd, Mn and Zn were greater at Murree Wildlife Park indicating high heavy metal geoaccumulation. The highest heavy metal contamination site with reference to soil quality was Murree Wildlife Park (PLI = 1.12), which was followed by Jallo Forest and Wildlife Park and Bahawalnagar Wildlife Park with PLI values 1.05 and 0.80, respectively. Analysis by hierarchical clustering (HCA) showed high degree of variation between heavy metal concentrations at all sites with the exception of Pb and Zn. As documented from the present study, significant levels of enrichment and contamination with heavy metals were recorded for soils of selected sites. Further assessment is mandatory because the chosen study sites were situated in climatically diverse areas with reference to environmental factors, topography, climatic condition and their impact on the accumulation patterns in soil as well as in animals. [ABSTRACT FROM AUTHOR]

Heavy metal pollution of the bottom sediments in the Northern Caspian Sea region was assessed for the period from 2012 to 2021. The concentrations and pollution levels of heavy metals were determined using the standard indices as part of the industrial environmental monitoring at the license site in the northern part of the Caspian Sea. Based on the concentrations of all identified metals (zinc, copper, lead, cadmium, nickel, iron, and manganese), significant spatial and temporal variations were observed. The values obtained did not exceed those of international sediment quality standards, thus suggesting that the studied bottom sediments were only slightly polluted by heavy metals. However, certain areas showed high levels of pollution, such as the northwestern area with the elevated iron levels and the central area with the maximum lead and cadmium concentrations. The statistical analysis of geochemical parameters of the bottom sediments revealed distinct patterns in the distribution of heavy metals.

To understand the source, distribution and degree of pollution of heavy metals in the soil around a plateau municipal solid waste incineration plant, a municipal solid waste incineration plant in Lhasa was taken as the research object in this study. The soil surrounding the facility was sampled, and the contents of heavy metals, including Cu, Pb, Zn, Cr, Ni, Cd, As, and Hg, in the soil were analyzed. Then, heavy metal pollution and risk assessments were conducted using the geoaccumulation index method, Nemerow index method, and potential ecological risk index method. Additionally, correlation and principal component analysis were used to determine the correlation between heavy metals in the soil and their sources of pollution. The results showed that based on the Nemerow comprehensive pollution index, the soil surrounding the incineration plant generally had a low level of pollution. Through the analysis of individual potential ecological risk indices, it was found that only the heavy metal Cd presented moderate potential risks, while the other seven heavy metals had mild potential risks. The average value of the total potential risk coefficient was 107.31, which was less than 150, indicating that there was a slight potential risk associated with the soil around the incineration plant. There was significant correlation between six heavy metals, namely, Cu, Pb, Zn, Cr, Ni, and Cd, in the soil around the incineration plant. Their pollution sources were similar, and their levels tended to be affected by the incineration plant. However, there was no significant correlation between the heavy metals As and Hg and the other six heavy metals. These two heavy metals had independent sources of pollution but were also influenced by human activities. [ABSTRACT FROM AUTHOR]

This study investigated the distribution of heavy metals in agricultural soils in the vicinity of three large mining landfills of the Kizhnica mine in the Republic of Kosovo. The mining sector is one of the most important sectors of Kosovo's economic development, and the Kizhnica mine is one of the most important ore producers in Kosovo. Besides the positive aspects, the development of production also has some negative side effects, such as the generation of industrial waste and the possible contamination of surrounding areas, including agricultural land. Therefore, ten sampling sites were selected in the vicinity of the Kizhnica mine. These sites were characterized and assessed as the most important due to the anthropogenic impact of mineral processing and open-tailing waste deposits in Kizhnica. The concentration of Pb, Zn, Cu, As, Cd, Ni, Mn and Sb in the selected samples was determined using inductively coupled plasma–optical emission spectrometry. The data obtained were used to create geochemical maps and calculate the contamination factor, pollution load index and geoaccumulation index. Cluster analysis, Pearson correlation coefficient and air spatial distribution patterns using the air dispersion model were used to evaluate within the area. The results showed that heavy metal levels are influenced by the anthropogenic nature of pollution, confirming a current ecological threat from mining activities in the region. In order to improve waste management, reduce the hazardous impacts of mining and contribute to the sustainable development of the region, the potential reuse of the deposited waste material in the construction industry is proposed. [ABSTRACT FROM AUTHOR]

Legacy tailings from decommissioned mines are known to negatively impact human health and environmental quality. In this study, potentially toxic elements (PTEs) including Cr, Cu, Ni, Pb, and Zn concentrations in tailings from a Selebi-Phikwe mine, Botswana, were assessed for contamination and health risk via multiple exposure pathways in adults and children. Tailings samples from the defunct mine were analyzed for total elemental composition using inductively coupled plasma‒optical emission spectrometry. The results show a decreasing order of mean content of Co (2106 mg/kg) > Ni (1805 mg/kg) > Cr (139 mg/kg) > Co (97 mg/kg) > Zn (53 mg/kg) > Pb (14 mg/kg). The I-geo values show varying degrees of Cr, Cu, Ni, and Zn contamination. Dermal contact (54.5%) was the primary exposure pathway of noncarcinogenic risk for adults, and oral ingestion (95.7%) was the primary exposure route for children. The PTEs posed very low to no noncarcinogenic risks. As a single element, the mean hazard index (HI) for adults and children followed a similar trend: Cr > Cu > Ni > Pb > Zn. However, the carcinogenic risk of Cr, Cu, Ni, and Pb exposure in children was high and unacceptable. For adults, the carcinogenic risks of Cr, Cu, and Ni were high and unacceptable. Overall, children were generally more vulnerable to the adverse effects of PTE exposure. A study of this nature is essential for routine environmental monitoring and assessment and fundamental for planning and reinforcing existing pollution control measures. [ABSTRACT FROM AUTHOR]

Topsoil stripping and storage are primarily carried out before mining, yet the main problem of returning this stockpile post-mining is the decline in soil quality. This study investigated the impact of varying storage durations on soil biogeochemical properties and the presence of heavy metals in stockpiled topsoils of four different ages (3, 8, 13, and 18 years) compared to a native forest at the Newmont Ghana Gold Limited, Ghana. Soil samples were collected on the various stockpiles to evaluate soil pH, total nitrogen, organic carbon, nitrate and ammonium nitrogen, exchangeable cations, bacterial population, and microbial biomass carbon (MBC), Fe, Pb, Cd, Cu, and Zn. Our findings revealed that prolonged storage duration considerably diminishes soil quality relative to the natural forest. Notably, MBC significantly decreased from 49.00 mg C kg-1 soil in the 3-year-old stockpile to 39.00 mg C kg-1 soil in the 8-year-old stockpile. However, MBC increased dramatically from 12.82% to 49.49% in the 13- and 18-year-old stockpiles respectively. The bacteria population decreased by 15.01%, 40.00%, and 40.90% when the storage age increased from 3- to 8-, 13-, and 18-year-old stockpiles. All the stockpiles recorded higher contamination factors, pollution load indexes, and Igeo indexes for measured heavy metals except Cd. The increase in stockpile ages beyond 3 years resulted in an increased deterioration index compared with the natural forest. The principal component analysis revealed that MBC, bacteria, NO3- -N, fungi, and earthworm populations were the most sensitive soil indicators affected by stockpiling. The decline in stockpile quality may significantly hamper reclamation efforts, necessitating that land managers and mining firms consider stockpile age, nutrient content and biological indicators for effective restoration. Additionally, amendment applications to 8 years and above stockpiles could optimize nutrient availability, facilitating ecosystem restoration.

Low ecological risk from these parameters. However, cadmium (Cd), mercury (Hg), and zinc (Zn) exhibited relatively high enrichment factors and geo-accumulation indices, suggesting potential contamination from anthropogenic sources. Potential ecological risk analysis indicated a very high ecological risk associated with heavy metal concentrations in the sediments of Dali River and Wuding River. Statistical analysis revealed strong correlations between metal (Ni, Cd, Cu, and Cr) concentrations and TOC, suggesting that nutrients and those heavy metals might have common pollution sources and similar transport behavior. Principal component analysis identified elevated Cd, Cu, and Ni concentrations as potentially originating from OM, while As may be derived from municipal sewage. Hg and Zn could be probably attributed to industrial effluents. The findings of this study highlight the need for effective pollution control measures to mitigate the ecological risks posed by heavy metal contamination in the sediments of Dali River and Wuding River. [ABSTRACT FROM AUTHOR]

The rupture of an iron mining tailing dam in Brumadinho, Brazil, released around 10 million cubic meters of tailings, of which 1.6 Mm3 reached the Paraopeba River. In this work, a total of 30 samples from three bottom sediment cores were collected in the lower course of the Paraopeba River basin and analyzed for major, trace and rare earth elements by ICP-OES and ICP-MS. The sediments presented a range of compositions with different weathering histories, overall marked by depleted Ca2+, Na+ and K+ compared with the average UCC, PAAS and NASC and some advanced weathering trends. The samples presented a fractionation pattern characterized by a continuous depletion of light REEs from La to Sm and a regular decreased distribution of heavy REEs from Gd to Yb, and the Co/Th vs. La/Sc diagram indicates a predominant intermediate source. The upper samples presented the highest contents of REEs, probably due to the higher presence of iron and aluminum oxides and hydroxides, which can be related to more advanced weathering. The Al, Cu, Ni, V, Zn, Co, Mn, Ti, Fe and Si concentrations and the CF, EF and Igeo index values varied across the sediment core samples, demonstrating that there were long periods of geogenic or anthropogenic contributions. [ABSTRACT FROM AUTHOR]

To identify the source and analyze the enrichment degree of soil cd in the limestone distribution areas of Guizhou Province, the geochemical baseline values of soil cd formed in different geological ages are obtained by standardized method, and the geoaccumulation index is used for evaluation. The results show that the baseline values of cd in the soil formed from the Permian and carboniferous limestone are obviously higher than those of the soil formed from limestone of other geological ages. The comparison between the baseline values of cd in soil and average content of cd in rocks shows that the naturally weathered rocks are the main source of soil cd in limestone areas. According to the evaluation results of geoaccumulation index, the pollution of soil cd in limestone areas of Guizhou is generally at a low level. [ABSTRACT FROM AUTHOR]

Heavy-metal contamination in river and ocean is a critical environmental issue that endangers marine ecosystems and human health. Therefore, conducting extensive research to devise effective mitigation measures is imperative. Sediment samples were taken randomly throughout the study area. Analysis was done to determine the presence of differentmetals, including arsenic, cadmium, chromium, nickel, copper, zinc, lead, andmanganese. The assessment of different pollution levels was done by using various pollution indicators including "geo-accumulation index (Igeo), contamination factor (CF), enrichment factor (EF)" for accuracy. The Igeo measurement for Cd indicated varying pollution, ranging from moderate to significantly polluted, while Mn revealed no contamination. Elements such as Ni, Cr, Cu, andZn showedamoderatelevel of contamination. The contamination factor values exhibited a range of 0.436 (Pb) to 7.637 (Cd), with average values spanning from 0.9176 (Mn) to 4.9714 (Cd), suggesting significant regional variation. EF exhibits a pattern of contamination comparable to that of Igeo. The noncarcinogenic risk associated with exposure to Cd and As exceeded the higher limit (HI > 1) for children and adults. Furthermore, the carcinogenic risk presented by pollutants such as copper (Cu), arsenic (As), nickel (Ni), cadmium(Cd), and chromium (Cr) was found to exceed the limits in children. In adults, only arsenic (As) and copper (Cu) were shown to represent a higher risk of cancer than the limit of 10-4. The PCA analysis revealed that two (PCs) accounted for more than 65% of the total variance in the River Ravi, as determined by eigenvalues greater than 1. This study underscores the importance of the ongoing monitoring and management of heavy-metal pollution to ensure sustainable marine ecosystem development and public health protection. [ABSTRACT FROM AUTHOR]

Soil pollution by heavy metals is a frequently encountered issue at many hazardous waste sites. Mining operations generate a significant volume of inert materials and waste, which are then deposited on the surface. The abandoned mine of Sidi Kambar could pose a major problem due to the potentially high concentrations of potentially toxic elements present in its discharges. To assess the level of soil contamination near the abandoned Pb-Zn mine in Sidi Kambar, heavy metal concentrations were determined in soil samples taken from the Essouk River. The results of the monitoring of the spatial evolution of metal trace elements (Zn, Pb, and Fe) during the month of February 2023 in the soil of this watercourse show that metal content is growing in the order: Pb > Zn > Fe. They also exhibit variations across the ten (10) study stations, ranging from 102.7 to 141.2 for Zn, 1918.8 to 3150.4 for Fe, and 115.5 to 134.5 for Pb. The degree and sources of contamination were determined by calculating metal contamination indices: the geoaccumulation index, the contamination factor, the degree of contamination, and the pollution load index. High levels of contamination have been observed around spills of mining waste, resulting in high levels of contamination. However, no cases of extremely high or ultra-high contamination were found in the mining fields of the studied area. Therefore, human activities could be the main factor in abandoned Pb/Zn mining areas. [ABSTRACT FROM AUTHOR]

The exploitation of iron ore could cause heavy metals pollution in the soils, which threatens the ecosystem and human health. In this study, soil, stream sediment, tailings, rock, and atmospheric deposition samples were collected from an iron mine in Baotou City. The concentrations of As, Cd, Cr, Cu, Hg, Ni, Pb, Zn, Al2O3, CaO, K2O, MgO, Na2O, SiO2, and Fe2O3, as well as the mineral composition and heavy metal speciation of the samples, were analyzed for pollution assessment and source identification of heavy metals. The results reveal that the concentration of Cu in the soils was significantly higher than the background value, and an unpolluted to moderately polluted state was the main pollution level. By analyzing the relationship between Cu/Al2O3 and CaO in different samples, as well as the characteristics of the chemical index of alteration (CIA), mineral composition, and the chemical speciation of Cu in soils and profiles, the results suggest that tailings were the source of Cu pollution in soils. The distribution characteristics of Cu and CaO in stream sediments indicated that hydraulic transport may be one of the main migration pathways. In addition, wind transport may also be a pathway of migration. [ABSTRACT FROM AUTHOR]

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Copyright of Geology & Resources is the property of Geology & Resources Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Potentially toxic element (PTE) contamination of soils and their sources remains one of key global environmental concerns. Agricultural soil in Kalinovac, Podravina region, Croatia is the subject of this study. The main aims include determining the concentration and distribution of PTEs in the soil, differentiation between possible geogenic and anthropogenic sources, and determining the correlation between the analysed PTEs and soil parameters. To achieve these objectives, geochemical analyses of the soil in the study area were carried out. Spatial distribution of the individual PTE contents, enrichment factors (EF), contamination factors (CF), and geoaccumulation index (Igeo) were created using GIS tools. In addition, statistical data processing was carried out, including the calculation of the correlation matrix, hierarchical cluster analysis (HCA), and factor analysis. The obtained results show that certain elements such as lead, chromium, copper, and cadmium were predominantly of anthropogenic origin in the study area, while others tended to have more geogenic origin. By applying different methods used in this study, it is possible to distinguish between geogenic and anthropogenic sources of PTEs in soils of this type. [ABSTRACT FROM AUTHOR]

The continuous use of fertilizers and fungicides has triggered copper (Cu) contamination in cacao soils in Ghana, which is a critical issue for the ecological risk and health safety of cacao products. In this study, we investigated Cu pollution, bioavailability, and ecological risk in soil and determined the Cu levels in the cacao nib, shell, and pod husk. Soils were collected at two soil depths (0–15 ​cm and 15–30 ​cm) from 20 cacao farms, under conventional (CCM: chemical-based fertilizers) and organic (OCM: organic-based fertilizers) management practices together with pods. The total Cu concentration ranged from 67.6 to 96.8 ​mg ​kg−1 in OCM and 28.5–33.9 ​mg ​kg−1 in CCM soil, which decreased with soil depth. The enrichment factor revealed minimal Cu enrichment, which was attributed to anthropogenic activity (fungicide and fertilizer applications). The contamination factor and geoaccumulation index values were low for the CCM soils, and moderate for the OCM soils. Both management systems pose a low potential ecological risk to soil biota activity. Bioavailable Cu extracted with CaCl2, NH4OAc, and DTPA was dominant in CCM soil and decreased with soil depth. The Cu concentration in cacao plants decreased in the order of shell > pod husk > nib, with nib-Cu being below the threshold (50.0 ​mg ​kg−1) of contamination. The results from the pairwise correlation analysis show that CaCl2-available Cu is better for evaluating the Cu content in cacao plants. This study reveals the pollution levels associated with cacao management practices, thus providing valuable insights for developing appropriate mitigation strategies.

Excessive levels of heavy metals in soil can significantly impact human health and ecological safety. Evaluating heavy metal pollution and identifying its sources are crucial for environmental management. This study investigates the status of heavy metal pollution in a southeastern region of China and aims to identify its sources using data from the first national soil pollution survey, which includes 282 sampling points. Indicators such as the geoaccumulation index (Igeo), the potential ecological risk index (RI), the hazard index (HI), and the total lifetime cancer risk (TLCR) were utilized to assess contamination levels. Geographic information systems (GIS), positive matrix factorization (PMF) receptor modeling, cluster analysis (ClusA) and human health risk assessments were integrated to analyze the sources of heavy metals. The results indicate that agricultural pollution sources have a minor impact on overall heavy metal contamination, with low ecological risk levels in the eastern and western regions. In contrast, the central region exhibited moderate risk, with areas of extremely high risk distributed across the central-west and central-south regions. PMF analysis identified pollution sources including natural origins, coal combustion, industrial emissions, and traffic, with contributions of 17.62%, 18.50%, 28.35%, and 35.56%, respectively. Overall, the carcinogenic risk in the study area is not high. Targeted recommendations were made in response to the pollution situation in the study area. This research enhances our understanding of heavy metal pollution in the soil of the study area and provides a reference for pollution source delineation in other regions.

In northern Chile, economic activities related to mining and thermoelectric energy have existed in the city of Tocopilla since the early 1900s and metal concentrations in soils have likely been altered by historic anthropogenic activities. To assess the concentrations of Cu, Zn, Pb, Ni, Co, and Cr in urban soils of Tocopilla, a total of 70 superficial (2 cm) and 70 deep (20 cm) soil samples were collected in 2014. Furthermore, to analyze concentration changes in soils over time, 18 superficial (5 cm) samples were collected in 2020–2021. A numerical evaluation (geoaccumulation index, and enrichment factor), principal component analysis, and spatial distribution approach were applied to infer geogenic and anthropogenic influence on the concentrations of these elements. The main conclusions of this research indicate that urban soils of Tocopilla contain geogenic Cu, Zn, Pb, Ni, Co and Cr. However, elevated concentrations of Cu, Zn, and Pb cannot be attributed to a geogenic origin alone, as a proportion of their enrichment is considered to be anthropogenically sourced. The contamination of anthropogenic elements has been found to be related to historic copper mining and thermoelectric energy production. Furthermore, when compared to other sites globally, median concentrations of Cu (945 mg/kg in 2014 and 823 mg/kg in 2020) and Zn (305 mg/kg in 2014 and 196 mg/kg in 2020) in superficial urban soils are among the highest worldwide. Regarding 2020–2021 sampling, Zn and Pb concentrations have increased, while Cu, Cr, Co, and Ni have remained similar to the 2014 samples. [ABSTRACT FROM AUTHOR]

This research aimed to determine and evaluate the concentrations of As, Cu, Hg, Ni, and Pb, and the physicochemical properties of 48 agricultural soil samples, to identify potential ecological risks and their sources associated with heavy metals contamination in Usak, western Türkiye. Various methods were used to assess ecological risks, including geoaccumulation index (Igeo), enrichment factor (EF), degree of contamination (Cdeg), potential ecological risk (RI), and pollution load index (PLI). The heavy metals concentrations ranged from 4 to 61 mg/kg for As, 8–48 mg/kg for Cu, 0.01–0.06 mg/kg for Hg, 30–813 mg/kg for Ni, and 4–30 mg/kg for Pb. The mean As and Ni concentrations were much greater than Earth’s crustal average, the world’s mean values, and mean values from many other emerging countries. Igeo and EF values for As, Ni, and Pb indicate various degrees of contamination. Cdeg values show that 96% of the study area is affected to some degree by contamination. For RI values, 38% indicate ecological risks ranging from moderate to considerable degrees. PLI values show that 75% of the agricultural soils are moderately polluted. Spatial distribution maps of Cdeg, RI, and PLI show that the northeastern and southwestern parts of the study area have been polluted to different levels by As, Ni, and Pb. Industrial activities and excessive use of fertilizers, pesticides, fungicides, and herbicides were identified as major sources of heavy metals contamination in the agricultural soils of Uşak. [ABSTRACT FROM AUTHOR]

The coast of Espírito Santo state (Southeast Brazil) is recognized for its environmental arsenic (As) enrichment and, over the years, mining operations have potentialized it. We aimed to evaluate the effect of Rio Doce discharge on As inputs and the role of iron ore tailings from the Fundão dam disaster in enhancing As contamination in the marine sediment. Two scenarios were evaluated: Predisaster and Postdisaster; dry and wet conditions were considered in each period. High As concentrations were found in the Predisaster (28.44 ± 13.53 µg g−1), but a significant increase in As was remarkable during the Postdisaster in the wet season, one year after the disaster (maximum of 58.39 µg g−1; geoaccumulation index (Igeo) Class 3, moderately severe pollution). On that occasion, iron (Fe) oxy‐hydroxides from tailings were remobilized from the Rio Doce channel and deposited on the continental shelf bottom. Therefore, chemical interactions among Fe, As, and carbonates were enhanced, resulting in As and Fe coprecipitation and the trapping by carbonate adsorption. Rio Doce discharge seems to be the main factor in As inputs to the inner continental shelf when flooding do not occur previously in samplings, which allows further dispersion of contaminants, although this hypothesis should be tested further. Integr Environ Assess Manag 2024;20:159–168. © 2023 SETAC Key Point: Arsenic contamination of marine sediments was studied before and after the rupture of a mining tailings dam (Fundão dam disaster).Arsenic concentrations increased from moderate (Predisaster) to moderately severe pollution levels (Postdisaster) one year after the disaster.Iron oxy‐hydroxide inputs from iron ore tailings probably explain the accumulation of As in sediments by coprecipitation of As and Fe and deposition by carbonate adsorption.River discharges did not increase As concentrations in sediment during the initial stages after the disaster (twenty days and two months after). [ABSTRACT FROM AUTHOR]

The Klagison River in Sorong City is used by the sand mining industry to dispose of liquid waste. Consequently, turbidity and sedimentation occurred. This study aimed to analyze the water quality, heavy metal concentrations in sediments, and the relationship between the two. The sampling points were determined using the purposive sampling method. Data analysis included the pollution load index (PLI), geoaccumulation index (Igeo), and correlation analysis. The TDS value of the Klagison River ranged from 126 to 168 mg/L and turbidity range of 19.98 to 724 NTU. The analysis results pollution load index showed that the sediment with a PLI value of 0.557 was neither polluted nor lightly polluted. Index geoaccumulation showed Cr and Cu values of 100% (Igeo < 0), while Mn and Fe were 80% unpolluted (Igeo < 0) and 20% unpolluted or mildly polluted (0 < Igeo < 2). The concentrations of Cr, Mn, and Fe had a negative correlation with the water quality parameters of TDS and turbidity. The concentration of Cu has a positive correlation with the water quality parameters, TDS, and turbidity. [ABSTRACT FROM AUTHOR]

The present study focuses on the assessment of Hg distribution in both soil and water samples from the small-scale gold mining region of Karang Jaya Sub-district, Musi Rawas Utara Regency, South Sumatra Province. For over 30 years, this region has witnessed persistent utilization of mercury as an amalgam for gold extraction. The investigation encompasses an analysis of total mercury levels in soil samples obtained from Sukamenang, Muara Batang Empu, and Terusan Villages. As a comparative reference point devoid of gold mining activities, the neighboring Muara Lakitan Village was selected. The obtained results indicate a moderate to strong contamination level across the 30 sampled locations based on the Geoaccumulation Index (Igeo), with an average Igeo value of 2.6. Furthermore, Pollution Load Index (PLI) and Contamination Factor (CF) values demonstrate high contamination. Conversely, analysis of river water samples from 30 stations along the Rupit River reveals that most of the samples comply with quality standards (<0.0005 mg/L), with an average value at 0.000322 mg/L; only four stations exhibit total Hg concentrations surpassing regulatory thresholds. All soil and river water samples from the control area (10 stations) exhibited no signs of pollution. Appropriate investments in technology, finance, and technical skills are needed to reduce mercury pollution due to small-scale gold mining activities. [ABSTRACT FROM AUTHOR]

Municipal sewage sludge is the major by-product generated in the wastewater treatment process with reuse potential, but the presence of heavy metals (HMs) can be a limiting factor, which is why more detailed studies on their potential risks to the environment are necessary. In this research, the concentrations of eight HMs in sewage sludge for agricultural purposes from 11 municipal wastewater treatment plants of the Metropolitan Area of Lima-Callao were evaluated, during the years 2015, 2017 and 2020. In order to determine pollution levels, ecological risk, risk to human health and identify the main sources of contamination, the geoaccumulation index, the potential ecological risk index, the carcinogenic and non-carcinogenic risk index, and multivariate statistical techniques (correlation analysis, principal component analysis (PCA) and hierarchical cluster analysis (HCA)) were applied. The results showed high levels of pollution by Cu and Zn, and low levels of As. Likewise, a moderate to very high ecological risk was recorded, with Cd and Cu being the ones with the highest potential of ecological risk, restraining the use of sewage sludge for agriculture. Considering the economic activities present in the study area, the PCA and the HCA revealed that contamination by HMs derived mainly from industrial, commercial, and domestic activities; however, service activities also contributed to the concentrations of HMs. Finally, the study identified Cd and Cu as the metals of greatest concern. [ABSTRACT FROM AUTHOR]

Heavy-metal contamination in river and ocean is a critical environmental issue that endangers marine ecosystems and human health. Therefore, conducting extensive research to devise effective mitigation measures is imperative. Sediment samples were taken randomly throughout the study area. Analysis was done to determine the presence of different metals, including arsenic, cadmium, chromium, nickel, copper, zinc, lead, and manganese. The assessment of different pollution levels was done by using various pollution indicators including “geo-accumulation index (Igeo), contamination factor (CF), enrichment factor (EF)” for accuracy. The Igeo measurement for Cd indicated varying pollution, ranging from moderate to significantly polluted, while Mn revealed no contamination. Elements such as Ni, Cr, Cu, and Zn showed a moderate level of contamination. The contamination factor values exhibited a range of 0.436 (Pb) to 7.637 (Cd), with average values spanning from 0.9176 (Mn) to 4.9714 (Cd), suggesting significant regional variation. EF exhibits a pattern of contamination comparable to that of Igeo. The noncarcinogenic risk associated with exposure to Cd and As exceeded the higher limit (HI > 1) for children and adults. Furthermore, the carcinogenic risk presented by pollutants such as copper (Cu), arsenic (As), nickel (Ni), cadmium (Cd), and chromium (Cr) was found to exceed the limits in children. In adults, only arsenic (As) and copper (Cu) were shown to represent a higher risk of cancer than the limit of 10−4. The PCA analysis revealed that two (PCs) accounted for more than 65% of the total variance in the River Ravi, as determined by eigenvalues greater than 1. This study underscores the importance of the ongoing monitoring and management of heavy-metal pollution to ensure sustainable marine ecosystem development and public health protection.

Introduction: Rivers are considered as a vital resource for mankind from the past to the present day.Considering the ever-increasing population, industrial developments and the expansion of modern urban societies, it is expected that the rivers located near densely populated urban and rural areas to be in danger of destruction due to a large part of urban, rural, domestic, industrial and agricultural pollutants to the sources of surface and groundwater in the riparian and riverside more than any other water ecosystems. On the other hand, regarding Iran's arid and semi-arid climate, the use of sediment qualitative indicators in research and investigation is crucial in order to predict, evaluate and provide a sustainable solution for controlling the amount of pollutants and also improving the quality of river water. The Karaj River is one of the main freshwater and energy production resources in the region, which plays a vital part in creating an ecological balance in parameters affecting the quality of this water ecosystem. The purpose of this research is to measure the concentration of heavy metals in the sediments of the river bed and to evaluate and analyze it using Geoaccumulation index and Enrichment Factor, which led to the suggested solutions in order to avert and control the further spreading of pollution.Material and Methods: In this research, nine stations were selected based on the land use of the area. The sediments of the river bed in each station were sampled. Sediment samples were prepared and later transferred to the laboratory and the total concentration of heavy metals was measured by Inductively Coupled Plasma Mass Spectroscopy (ICP) device.Results and Discussion: The results obtained from the measurements using the mentioned indices assessed that the level of heavy element pollution is relatively low in the Karaj River. Nevertheless, part of this slight pollution is related to human activities such as road construction, tourism and the leakage of local runoff and sewage into the river and its riparian zone, which led to the increase of the Geoaccumulation of elements including copper and chromium to the numbers of 1.01 and 1.96 in downstream stations P8 and P9, respectively. Also, the highest average amount of Geoaccumulation for copper in 9 sampling stations was 0.23. On the other hand, these anthropogenic activities have significantly increased the arsenic Enrichment up to 17.81 in station P4 and the average Enrichment Factor of Arsenic in 9 sampling stations up to 13.12. But since each heavy element has its own unique nature, part of the quantity of the pollution present in the sedimentary environment of the river is related to natural factors, geology, soil erosion and weathering of riverbed rocks.Conclusion: The process of changes in the amount and distribution of elements in the sediments were compared and the factors affecting their alignment or mismatch were discussed and researched. Generally, the results of this research show that the Karaj River, taking into account the Geoaccumulation index and Enrichment Factor, has negligible contamination of heavy metals in the riverbed sediment. However, the trend of index changes along the river route shows the direct effects of destructive human activities in the region.

Estuaries are excellent environments for identifying pollution episodes that have affected river basins, as their sediments are the final destination of some of the pollutants. This paper studies the geochemical evolution of five elements (As, Co, Cu, Pb, Zn) in a core extracted from the middle estuary of the Tinto River (SW Spain). The results are based on facies interpretation, ICP atomic emission spectrometry analysis, the application of a regional background to obtain the geoaccumulation index and dating. The main objective of this communication is the detection of natural or anthropogenic pollution episodes in the middle estuary of the Tinto River (SW Spain). Four pollution episodes have been detected: (1) ~5.8 cal. kyr BP, probably caused by natural acid rock drainage processes derived from the oxidation of the Iberian Pyritic Belt deposits found in its drainage basin; (2) 4.7–4.5 kyr BP, coming from the first mining activities and characterized by a significant increase in the concentrations of the five elements analyzed; (3) 1850–1960 interval, coinciding with intensive mining and characterized by increasing values of As and, to a lesser extent, Pb (intensive mining); and (4) the second half of the 20th century, with high element concentrations from mining and industrial effluents. All episodes show an increase in their geochemical classes deduced from the geoaccumulation index. This communication can serve as an example for assessing the impact of different types of pollution in estuarine environments. [ABSTRACT FROM AUTHOR]

The works of literature evaluating the eco-environmental risks posed by metals in agricultural areas in developing countries remains limited. This study sought to evaluate the environmental and ecological risks posed by metals in the intensively cultivated areas of the Amik Plain as well as to determine the origins of the metals. For this purpose, 137 soil samples were taken from agricultural production areas of the Amik Plain, and 11 metals (Al, Fe, Ni, Pb, Co, Cr, Cu, Mn, Zn, Cd and As) were examined in the samples. As Ni had the highest average enrichment factor (EF) value (8.04) when compared with the other metals, the soils were found to be significantly enriched with Ni. The Pearson correlation analysis and principal component analysis showed that the Zn concentration was controlled by lithogenic sources, while the Ni, Pb, Cd, Cr and Cu concentrations were controlled by both anthropogenic and lithogenic sources. [ABSTRACT FROM AUTHOR]

Introduction: Rivers are considered as a vital resource for mankind from the past to the present day. Considering the ever-increasing population, industrial developments and the expansion of modern urban societies, it is expected that the rivers located near densely populated urban and rural areas to be in danger of destruction due to a large part of urban, rural, domestic, industrial and agricultural pollutants to the sources of surface and groundwater in the riparian and riverside more than any other water ecosystems. On the other hand, regarding Iran's arid and semi-arid climate, the use of sediment qualitative indicators in research and investigation is crucial in order to predict, evaluate and provide a sustainable solution for controlling the amount of pollutants and also improving the quality of river water. The Karaj River is one of the main freshwater and energy production resources in the region, which plays a vital part in creating an ecological balance in parameters affecting the quality of this water ecosystem. The purpose of this research is to measure the concentration of heavy metals in the sediments of the river bed and to evaluate and analyze it using Geoaccumulation index and Enrichment Factor, which led to the suggested solutions in order to avert and control the further spreading of pollution. Material and Methods: In this research, nine stations were selected based on the land use of the area. The sediments of the river bed in each station were sampled. Sediment samples were prepared and later transferred to the laboratory and the total concentration of heavy metals was measured by Inductively Coupled Plasma Mass Spectroscopy (ICP) device. Results and Discussion: The results obtained from the measurements using the mentioned indices assessed that the level of heavy element pollution is relatively low in the Karaj River. Nevertheless, part of this slight pollution is related to human activities such as road construction, tourism and the leakage of local runoff and sewage into the river and its riparian zone, which led to the increase of the Geoaccumulation of elements including copper and chromium to the numbers of 1.01 and 1.96 in downstream stations P8 and P9, respectively. Also, the highest average amount of Geoaccumulation for copper in 9 sampling stations was 0.23. On the other hand, these anthropogenic activities have significantly increased the arsenic Enrichment up to 17.81 in station P4 and the average Enrichment Factor of Arsenic in 9 sampling stations up to 13.12. But since each heavy element has its own unique nature, part of the quantity of the pollution present in the sedimentary environment of the river is related to natural factors, geology, soil erosion and weathering of riverbed rocks. Conclusion: The process of changes in the amount and distribution of elements in the sediments were compared and the factors affecting their alignment or mismatch were discussed and researched. Generally, the results of this research show that the Karaj River, taking into account the Geoaccumulation index and Enrichment Factor, has negligible contamination of heavy metals in the riverbed sediment. However, the trend of index changes along the river route shows the direct effects of destructive human activities in the region. [ABSTRACT FROM AUTHOR]

Human populations are being exposed to a wide spectrum of radiation from soils as a result of the availability of radiation sources. Assessing the ecological and health effects of radionuclides in soils is crucial to support the optimal soil management practices but large-scale studies are limited. This study compiled data on radionuclides (226Ra, 232Th, 40K, 238U, and 137Cs) in soils located across the world (44 countries and 159 places) between 2008 and 2022 and applied radiological hazards indices and several multivariate statistical approaches. The average activity concentration (Bq/kg) of 226Ra, 232Th, 40K, 238U, and 137Cs were 408.56, 144.80, 508.78, 532.78, and 83.12, respectively, whereas 226Ra, 232Th, 40K, and 238U exceeded the standard limits. The principal component analysis explained more than 91% of variation in soils. Based on the geoaccumulation index, 40K posed moderately to heavy contamination whereas 238U and 226Ra posed moderate contamination in soils. Moreover, the mean values of radiological hazards evaluation such as radium equivalent activity (487.17 Bq/kg), external radiation hazard indices (1.32), internal hazard indices (2.15), absorbed dose rate (247.86 nGyh−1), annual effective dose rate (1.82 mSvy−1), activity utilization index (4.54) and excess lifetime cancer risk (63.84 × 10–4) were higher than recommended limit suggesting significant radiological risks in study region soils. The findings indicated that the study area soils were contaminated by radionuclides and unsafe for hazards in terms of the health risks linked with studied radioactive contents. The study is valuable for mapping radioactivity across the globe to determine the level of radioactivity hazards. [ABSTRACT FROM AUTHOR]

Soil contamination by anthropogenic heavy metals has become a global issue. This study aimed to investigate cadmium (Cd) concentration, mobility, and contamination indices of Cd in soils in the Hamadan province, west of Iran. To investigate the concentration of Cd in soil, one hundred soil samples from wheat farms and five samples from control lands were collected. Pollution indexes, including Cd mobility, enrichment factor, geoaccumulation index, contamination index, and availability ratio, were investigated. The structural equation model was also used to evaluate effective parameters on cadmium durability in soil. Results showed that mean values of available phosphorus (P) were 83.65, 129, and 65 (mg kg−1) in three land-use types rainfed, irrigated, and controlled, respectively. The mean values of Cd in different land-use types of rainfed, irrigated, and controlled were 0.15, 0.18, and 0.08 (mg kg−1), respectively. The results indicated that the amount of Cd in both forms (available and total) in ones that received fertilizer, especially P fertilizers, was higher than in the controlled one. Other pollution indexes revealed that the study area had been slightly contaminated due to anthropogenic activities. Lime, clay, lead, and OM were identified as affective parameters on cadmium durability. Finally, the results demonstrated that the mobility rate was high. Cd had a higher potential mobility in soil samples in the rain-fed and irrigated land than in the controlled land, and Cd had a low retention time. [ABSTRACT FROM AUTHOR]

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This study was conducted to investigate the effects of anaerobically stabilized sewage sludge (SS) converted into 90% dryness granules at different doses of control, 3% SS, 6% SS, and 9% SS on elemental composition of Festuca arundinacea Schreb. and physicochemical properties of soil. Color measurements were made with the CIE L* a* b* method unit; the highest color (4.10) and the highest coating score (5.7) were calculated for the 6% SS treatment. The highest biomass (9.11 g) was obtained from the 3% SS and the lowest (7.67 g) from the 9% SS dose. Plant height measurements were listed as follows: 3% SS (9.5 cm) > 6% SS (8.8 cm) > control (8.7 cm) > 9% SS (8.1 cm). Average bioaccumulation factor for the present heavy metals were ordered as: Cd (0.542) > Hg (0.452) > Cr (0.448) > Ni (0.246) > Pb (0.076). The lowest geoaccumulation index (Igeo) was obtained in Cr (-1.35) and the highest value in Cd (1.69). Available P, K, Ca, Mg were analyzed with ammonium acetate extraction method, and Fe, Zn, Cu, and Mn in the soil extracted with DTPA were determined. In the soil samples, total N (0.180%) and available elements (mg kg-1) P (101.393), Ca (6502.570), Mg (609.433), Na (259.44), Fe (13.61), Cu (4.05), Zn (17.76), and B (1.00) were determined at high values in the 9% SS application. Heavy metals (mg kg-1) were extracted with aqua regia. Nickel (48.87), Pb (26.83), Cd (0.97), and Hg (153.12 µg kg-1) were determined at high values in the 9% SS application. Plant nutrients in the plant samples were extracted from acid digestion, and N (3.93%), P (0.51%), Mg (0.59%), Ca (1.77%), Zn (127 mg kg-1), and B (15 mg kg-1) were determined at high values in the 9% SS application. Heavy metals' (Ni, Cd, Cr, Pb, and Hg) content toxic effects were not observed in the plants. [ABSTRACT FROM AUTHOR]

The goal of this study is to examine the impact of coal power plants on the distribution of natural radionuclides in the environment and its effects on air particulate matter and solid fallout. To this end, spatial distributions and correlations are used to group radionuclides and trace elements. The study also identifies sources of elevated concentrations, such as geogenic, anthropogenic, or agricultural, and provides dose assessments, ecological risk assessments, pollution load indices, and geoaccumulation indices. These findings will inform future research and decision making in managing and regulating natural radionuclides near coal power plants. [ABSTRACT FROM AUTHOR]

This study examined the accumulation of potentially toxic elements (PTE) in oil palm (Elaeis guineensis) biomass, fruits, and soils. About 40 soil samples to a depth of 40 cm and 90 palm biomass samples from roots, leaves/stems, and fruits were collected from reclaimed tailings dam and control sites at two mining areas in southwestern Ghana. PTE concentrations and pollution indices were analyzed via various inferential statistics. The PTE (As, Fe, Zn, Mn, and Cu) concentrations in the palm roots were significantly higher (p < 0.001) than in the soil at Ghana Manganese Company (GMC) Ltd, Nsuta except for As which was significantly higher (p < 0.0001) in the fruits than the soil. Soil PTE concentration was however significantly higher (p < 0.0001) than that of the roots, leaves, and fruits at the Bogoso tailings dam. The contamination factors, enrichment factors, geoaccumulation indices, and pollution load index (PLI) of soils at the tailings dam and reclaimed sites were significantly higher than the control sites. The PLI of the reclaimed tailings and control sites at Bogoso were 17.98 ± 0.56 and 6.06 ± 0.58, respectively, implying the soils at Bogoso are severely polluted with As, Fe, Zn, and Mn while those of the GMC are unpolluted. Bioaccumulation factors were significantly higher in roots than in the leaves and fruits (p < 0.0001) and were greater than 2 at GMC. The translocation of Cu and As to the fruits was significantly high on both study locations with TF of As = 9 at GMC. PTE accumulation in the palm biomass reduced soil PTE concentrations, but the soils on these mined spoils were severely polluted. These high As contents, in the fruits, may contaminate the food chain and increase PTE-related health risks among human populations. Therefore, phytoremediation of mine spoils with oil palm should be done with caution. Experimental studies to examine soil amendment effects on PTE accumulation capacity or removal efficacy by the palm plants at various ages are recommended. [ABSTRACT FROM AUTHOR]

Driven by Thailand's Bio-Circular Green Economy strategy, this study explores industrial waste utilization as a solution to mitigate the impacts of climate change and economic insecurity. This study involved interviews with farmers and field sampling across 131 sugarcane plantations, primarily in four districts in Kanchanaburi, western Thailand. The investigation aimed to assess heavy metal levels (As, Fe, Mn, Zn, Cu, Cr, Pb, Cd, Hg) in the plantation soils and their accumulations in soils and biomass under various agricultural practices, including the uses of filter cake and vinasse (industrial wastes from sugar–ethanol industries). Spatial analysis showed that As often exceeded national soil-quality standards for agriculture (25 mg kg−1). The Cd, As, and Zn tended to accumulate at a high level in most soils, whereas Pb accumulated locally. Factors such as clay content, soil alkalinity (for As and Mn), soil organic matters (As, Mn, and Hg), and no/minimum tillage (Zn and Cd) promoted the metal accumulation. Factor analysis showed that natural geochemical processes govern the spatial variations of the metals. The application of filter cake led to soils with elevated Cr, Fe, As, Cd, and Mn content and a clayey organic-rich composition, while the vinasse resulted in soils with higher levels of Zn, Cu, Fe, and clayey saline. The bioconcentration factors (BCF) revealed that sugarcane generally accumulated Hg (BCF ~2.32−35.72), whereas Cu (2.67) and As (1.04) tended to accumulate in sandy-soil farmlands. The waste utilization, however, neither contributed significantly to the concern levels of soil metals nor enhanced the bioconcentration of the soil metals into the sugarcane biomass. Utilizing the waste as fertilizer could benefit cane yield, but further studies should focus on proper fertilization rates and food safety. [ABSTRACT FROM AUTHOR]

This study aimed at investigating pollution sources and indicators in three study sites, namely, an industrial town (It), landfill (Lf), and wastewater treatment plant (WTP) in the vicinity of Ilam city, west of Iran. To achieve this objective, the sampling was performed from the topsoil (0–10 cm) of three sites (It, Lf, and WTP) with pollution potential. Some soil physico-chemical properties and total concentration of HMs including Cd, Pb, Ni, Cr, and Co, pollution indicators and sources of pollution were evaluated by statistical analysis. The results of the geoaccumulation index (Igeo), enrichment factor (EF), contamination factor (CF), and pollution load index (PLI) showed that the studied areas were contaminated with HMs. The highest average of Cd and Pb were 1.45 and 440.19 mg kg–1, respectively, in the Lf. Whereas, the highest average of Ni and Cr were 106.53 and 43.50 mg kg–1, respectively, in the IT, while the highest average of Co was 81.69 mg kg–1 in the WTP. According to the results of the principal components analysis (PCA) and clustering, a small part of the Pb, Ni, and Co amounts in the soils had the natural origin, while the results confirmed that a significant proportion of Pb, Cd, and Cr concentrations associated with human-caused hazards. Moreover, all areas (especially Lf and WTP sites) were highly contaminated with Cd. Due to the higher mobility of Cd and its human health hazards, this metal should be given more attention in the study sites of Ilam city. In general, based on our results, more paying attention needs to be considered by decision-makers and stakeholders to manage and control pollution production sources in the soils of the study sites. [ABSTRACT FROM AUTHOR]

This study focuses on the riverbed sediments in the Changsha-Zhuzhou-Xiangtan (CS-ZZ-XT) section of the lower reaches of the Xiangjiang River. Principal element analysis, ecological risk analysis, and early warning methods were used to explore the distribution pattern and risk assessment of various chemical elements in the sediments. The results indicated that the vertical distributions of Sc, Co, Th, and U were more homogeneous, while Cr, V, Cu, and Ni distributed heterogeneously with significant changes. Risk assessment of heavy metals was explored by using the Geoaccumulation index, potential ecological risk index, and ecological risk index, suggesting that the contamination levels followed: ZZ > XT > CS. ZU and ZX points in the ZZ section exhibited the higher ecological risk. The ecological risk of heavy metals followed the order of: Pb > Cu > Zn > Ni > Co > Mn > V > Cr, and the contamination of Cd and Mn was located at the severe warning condition. Additionally, it was suggested that Th, U, Pb, Zn, Cu, and Mn mostly originated from both anthropogenic activities and natural processes, while Ni, Cr, Co, V, Sc, and Ba were derived from natural processes. Therefore, the contamination of Cd, Th, U, Pb, Zn, Cu, and Mn, especially Cd and Mn, should be considered by the environmental protection strategies in the studied watershed. [ABSTRACT FROM AUTHOR]

Background: Heavy metal pollutants in rivers are one of the serious environmental concerns in aquatic ecosystems. Sediments, as an environmental indicator, have an acceptable ability to express the degree of environmental pollution with heavy metals. Therefore, with the aim of evaluating the health of the water ecosystem of Zayandeh Rood, we investigated pollution using sediment indicators. Methods: In this study, the sediments of Zayandeh Rood River were sampled at 17 stations. Metals lead, zinc, iron, cadmium, cobalt, nickel, copper and chromium were measured by acid digestion method with atomic absorption device. Also, land accumulation indices, Nemerow pollution index and ecological risk potential were calculated. Results: The average concentration of metals in sediments is 1762.92 iron, 201.52 nickel, 44.07 zinc, 23.36 cobalt, 28.67 copper, 11.51 lead, 10.09 chromium, and 0.87 cadmium mg/kg. According to the Igeo index, the average concentration of chromium, iron, copper, zinc and lead elements in all stations was lower than the average of the earth's crust, and the concentration of nickel and cadmium in all stations was higher than the background value. In all stations, the ecological risk potential index of cadmium was higher than other elements. Conclusion: Considering the condition of river sediments in terms of cadmium and nickel pollution and their very high ecological risk, it is necessary to comprehensively monitor the river and its living organisms. Also, in order to evaluate its health and ecological risk with the approach of examining the trend of spatial and temporal changes, heavy metal pollution in water and river sediments should be taken into consideration.

One of the most important effluents in Guadiana Valley, Durango is El Tunal River, mostly used for agricultural and livestock supply. This river has been polluted by agricultural activity and wastewater discharges. Thus, this study aimed to evaluate the current quality of water and agricultural soil near the river, to estimate the environmental situation of the agricultural sector and its main pollution sources. Hence, a total of 24 soil and five water samples were taken, analysing parameters of organic matter, pH, nutrients, and heavy metals(loid)s (As, Cd, Pb, Zn) in five agricultural areas. The randomised experimental design showed significant variations in soil (p < 0.05) of organic matter, nitrogen, As, and Pb between sampling points, confirming suitable conditions for agriculture. Although contamination by heavy metal(loid)s exists, it is below permitted levels. In contrast, the physicochemical quality of the water indicated high levels of phosphates, total dissolved solids, and total coliforms, mainly in the nearest site of a wastewater treatment plant, thus the quality of the water is not suitable for consumption and irrigation for sensitive crops. Nevertheless, rainfall contributes to improve the quality of the river by diluting pollutants. Moreover, constant use of this water might represent a risk to human health and agriculture as it could transport elements to crops or soil, becoming a severe environmental problem. [ABSTRACT FROM AUTHOR]