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Springs located at the historical sites of Wadi Araba (Eastern Desert of Egypt) and emerging from the escarpments of the Northern and Southern Galala Plateaus were investigated. A combination of methods, including hydrochemistry, stable and radioisotope composition, and structural analyses based on satellite data, provided information about the structure of the subsurface and the derived groundwater flow paths. Satellite images reveal karst features within the northern plateau, e.g. conical landforms. Karstic caves were documented along both escarpments. Chemical analysis of floodwater from Wadi Araba indicates higher concentrations of terrestrial salts compared to floodwaters from central and southern parts of the desert. δ18O and δ2H signatures in spring waters resemble those of floodwater and fall on the global meteoric water line, confirming their fast infiltration with minor influence of evaporation. The aquifer feeding the springs of the Northern Galala Plateau has low retention and the springs dry out quickly, even after heavy rainfall. Contrastingly,3H activities in springs emerging from the Southern Galala Plateau refer to much slower subsurface passage. With respect to3H content (3.8 TU) in recent flood waters, the spring water at Southern Galala Plateau contains about 40% recently recharged groundwater. However, its largest spring—the St. Antony spring—discharges water with a radiocarbon age of about 15,000 years. In combination with this spring’s constant and high discharge over a period of several months, that age estimate suggests a large reservoir with moderate to high retention.

The city of Essaouira is located along the north-west coast of Morocco, where groundwater is the main source of drinking, domestic and agricultural water. In recent decades, the salinity of groundwater has increased, which is why geochemical techniques and environmental isotopes have been used to determine the main sources of groundwater recharge and salinization. The hydrochemical study shows that for the years 1995, 2007, 2016 and 2019, the chemical composition of groundwater in the study area consists of HCO3–Ca–Mg, Cl–Ca–Mg, SO4–Ca and Cl–Na chemical facies. The results show that from 1995 to 2019, electrical conductivity increased and that could be explained by a decrease in annual rainfall in relation to climate change and water–rock interaction processes. Geochemical and environmental isotope data show that the main geochemical mechanisms controlling the hydrochemical evolution of groundwater in the Cenomanian–Turonian aquifer are the water–rock interaction and the cation exchange process. The diagram of δ2H = 8 * δ18O + 10 shows that the isotopic contents are close or above to the Global Meteoric Water Line, which suggests that the aquifer is recharged by precipitation of Atlantic origin. In conclusion, groundwater withdrawal should be well controlled to prevent groundwater salinization and further intrusion of seawater due to the lack of annual groundwater recharge in the Essaouira region.

This hydrochemical study of the surface and groundwater in Khan AL-Baghdadi area, western Iraq, included the interpretation of physical, chemical, and biological properties. Water samples were collected from wells (14 samples) and surface water of Euphrates River (6 samples) for the dry and wet periods of October 2018 and April 2019, respectively. The stable isotopes analysis was performed for the dry period only. The surface water samples were characterized by slightly alkaline, fresh, excessively mineralized, Ca-chloride type, and hard to very hard water class. While the groundwater samples were characterized by slightly alkaline, brackish, excessively mineralized, Ca-chloride and Na-Chloride type, and hard to very hard water class. The stable isotopic analysis was used in studying the interaction between water resources of Euphrates River and groundwater. Stable isotopes (δD and δ18O) were used to study the hydrological aspects of water resources in the study area. The results showed that surface and groundwater samples have similar source with a correlation relationship between them, in addition to the clear effect of river recharge on groundwater. The variation in δ2H and δ18O signature of groundwater in the study area is caused mainly by variation in isotopic composition of recharge water zone and mixing water. Using the δ 2H and δ 18O diagram, all surface and groundwater samples were plotted below the global meteoric water line (GMWL) and Local Meteoric Water line (LMWL), indicating the influences of the evaporation processes and seasonal variation.

Hydrogen and oxygen stable isotopes (δ2H and δ18O) in precipitation were analysed from June 2018 to May 2020 in Ningbo and were influenced by the subtropical monsoon climate in East China. The δ2H and δ18O values of precipitation in Ningbo varied from −90.0 to 6.0‰ and from −13.5 to −1.6‰, respectively. The local meteoric water line (LMWL) in Ningbo was obtained as δ2H = 9.27 δ18O + 35.95 and had a larger slope and intercept compared to the global meteoric water line (GMWL) because its water vapour sources were oceans. The more negative δ18O values and lower deuterium excess (D-excess) of precipitation in summer were due to water vapour sources from the East China Sea, the South Sea and the Western Pacific, which are controlled by the southeasterly monsoon. In contrast, the less negative δ18O and higher D-excess of precipitation in winter were influenced by water vapour sources from the North Asian continent and North China transported by the northwesterly monsoon. The precipitation amount effect was significant in Ningbo, especially in summer. The inverse temperature effect was appeared in Ningbo, except winter. These two effects may be caused mainly by the monsoon climate rather than by the secondary evaporation effect.

Heavy precipitation events are increasingly concerned because their significant contribution to annual precipitation in the Northwestern China, which might be related to invasion of summer monsoon moisture. It is interest whether or not the same is Jade Pass as being outside the control of the Asian summer monsoon. In this work, six heavy precipitation events were selected based on the 95 percentiles of the daily precipitation at the 12 weather stations around the Jade Pass from 1970–2000, with consideration of the influences of elevation. The event on June 19th, 2013 was chosen for a detailed examination due to the fact that the day has a large-scale precipitation as revealed by a gridded precipitation dataset over a large region. Using a Weather Research and Forecasting Model (WRF) simulation with high spatiotemporal resolution and in situ isotopic tracing (δ18O, δD), under a large-scale heavy precipitation event, this study provides ambitious view at the synoptic scale. A dramatic decrease in the δ18O, δD and deuterium (d)-excess of precipitation, very high relative humidity (98%), and reduced air temperature indicate that the precipitation was a result of long-distance-transported monsoon vapor. In addition, the slope of the local water meteoric line (LWML) of the precipitation for this event was very close to that of the global meteoric water line (GWML), indicating the source of moisture was from the ocean. Meanwhile, the WRF simulation confirms that the precipitation at the Jade Pass was not caused by local convection, but by summer monsoon. Both WRF simulation and isotopic tracing support the view that the monsoon moisture could invade Jade Pass at the synoptic scale and impact on precipitation, which need be further investigated.

A speleothem fluid inclusion extraction and isotope analysis system was established based on a vacuum extraction device and a Picarro L2140-i wavelength scanned cavity ring-down spectroscopy (WS-CRDS) water isotope analyzer. WS-CRDS allows to measure the stable oxygen and hydrogen isotope composition ( δ 18O and δ D) of small water samples simultaneously, which is faster, simpler, and requires less maintenance compared to currently used continuous-flow isotope ratio mass spectrometry (CF-IRMS). The precision of water isotopic analysis utilizing the WS-CRDS is often superior to that of CF-IRMS. Therefore, the use of Picarro for isotope analysis has rapidly gained popularity. The oxygen isotopic composition of speleothem calcite ( δ 18Oc) is one of the main proxies of speleothem-based paleoclimate reconstructions, but the interpretation of δ 18Oc remains complex as it can be influenced by many factors. Speleothem fluid inclusions contain the characteristics of cave drip water. The δ 18O and δ D values of fluid inclusion water provide direct information about paleoprecipitation, and can be further used to reconstruct paleotemperature when combined with δ 18Oc. The present paper contains a detailed description of the system as we have designed it, and provides an introduction to the system’s performance. The vacuum extraction device, connected to the Picarro analyzer, is designed to release the water trapped in speleothem fluid inclusions by pneumatically-operated crushing of discrete speleothem calcite chips. The whole device is kept at a temperature of 120°C to ensure the total and instantaneous vaporization of the water without isotopic fractionation. The vaporized water is carried by a flow of high-purity nitrogen to a 40 mL volume for homogenization, and is then introduced into the Picarro analyzer for δ 18O and δ D analysis. A syringe injection unit was added to the vacuum extraction device to be able to measure standard water, with δ 18O and δ D values similar to the speleothem samples, before and during measurements. To verify the precision and accuracy of the system, the same standard water samples were measured with an automated Picarro L2140-i set-up that includes an autosampler and a Picarro evaporation unit. The δ 18O and δ D values of standard waters as measured by both systems are comparable. Using the crushing device, speleothem samples from the East Asian Monsoon region yield paired δ 18O/ δ D values within ±0.5‰ of the Global Meteoric Water Line (GMWL), indicating no isotopic fractionation during the measurements. The precision is a function of the water amount released and of the isotopic composition of the sample. The reproducibility of crushed speleothem samples, whose water vapor concentration is between 2500 and 50000 ppm, is 0.5‰ for δ 18O and 2‰ for δ D (1 SD), similar to results obtained from other published measuring systems.

Evaluation of geogenic carbon fluxes between solid Earth and its atmosphere is essential to understand the global geological carbon cycle. Some of the key geogenic CO2 suppliers are the magmatic mantle and metamorphic degassing from active and quiescent volcanoes, fault zones, geothermal systems and CO2 rich groundwater. Indian Himalayan geothermal field hosts about 340 geothermal springs in natural as well as artesian condition that eject hot waters and volatiles with varied temperature and chemical composition. These sites provide an opportunity to analyse tectonically driven gas emissions and their impact on regional and global climate. Here we adopt a method for direct measurement of Dissolved Inorganic Carbon (DIC ≈ HCO3) concentration in the geothermal springs to estimate geogenic CO2 flux from an active region based on water discharge and area of geothermal system between the tectonic boundaries of the Main Central Thrust (MCT) and Main Boundary Thrust (MBT) of the Garhwal (Northwest) Himalaya. In the study area, geothermal spring water contain high δ13CDIC ratio (− 8.5‰ to + 4.0‰ VPDB), and among the major ions, bicarbonate (HCO3−) varies by an order of magnitude from 1697 to 21,553 μEq/L; chloride and sodium vary from 90 to 19,171 μEq/L and 436 to 23181 μEq/L. The elevated concentration of Cl− and Na+ in geothermal spring waters suggests affinity towards their deeper origin. These geothermal springs cover a large area of nearly 10,000 km2 of the Garhwal region showing a significant discharge of CO2 rich water with an estimated carbon dioxide degassing flux of ~7.2 × 106 mol/year to the atmosphere. Considering widespread occurrences of geothermal springs in tectonically active areas worldwide, the proposed direct measurement of DIC may be used as a reliable tool to estimate CO2 fluxes in different active orogenic settings within the Earth system. Results of stable isotopes of δ18O (VSMOW) and δD (VSMOW) in these geothermal spring waters follow the Global Meteoric Water Line (GMWL), suggesting affinity of their recharge through the meteoric origin.

Triple oxygen isotope compositions have become one of critical proxies in characterizing a wide range of geochemical and hydroclimate processes. However, Δ17O (carbonate 17O anomaly) has only been barely used in the last decade because it is difficult to measure δ17O of natural samples to a sufficient precision in order to resolve small natural variability. In this study, we present triple oxygen isotope data from speleothems obtained by an O2-CO2 Pt-catalyzed oxygen-isotope equilibration method. The high precision (9 per meg or better, 1σ SD) of our new speleothem Δ17O data is sufficient to resolve subtle hydroclimatic signals. Based on this method, we established triple-oxygen-isotope records of TON cave in westerly region since the last 135ka, providing the evolution history of water vapor source and water vapor cycle in the orbit-millennium scale atmospheric precipitation in the Central Asia. In addition, the triple-oxygen-isotope records of speleothem from Asian and South American monsoonal regions were established in the key periods, such as glacial and interglacial periods. Our speleothem Δ17O data indicate a 20 per meg difference between Marine Isotope Stage 5d and 5e in samples from Central Asia, suggesting a shift in moisture source and/or fractionation history. Unexpectedly, there were no measurable Δ17O differences between glacial and interglacial samples from both the South American (western Amazon) and Asian (southern China) monsoon domains, implying consistent moisture-source conditions across glacial and interglacial cycles, at least in terms of relative humidity. Speleothem Δ17O data may thus provide new and important constraints for understanding regional and global hydroclimate dynamics.

Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast, and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98 °C, pH from 1.96 to 11.98, while Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: (1) thermal; (2) cold; (3) acidic (pH 11). On statistical basis, thermal waters were subdivided into subgroups according to both their temperature [warm ( 75 °C)] and TDS [low salinity ( 30 g/L)]. Cold waters were subdivided based on their pCO2 [low ( 0.85 atm)]. δ18O–H2O ranges from − 12.7 to + 2.7‰ versus SMOW, while δ2H–H2O from − 91 to + 12‰ versus SMOW being generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Positive δ18O shifts with respect to the former are mostly related to mixing with seawater, while only for a few samples these shifts point to high-temperature water–rock interaction processes. Only a few thermal waters gave reliable geothermometric estimates, suggesting reservoir temperatures between 80 and 260 °C.

Study region: Robit-Bata watershed, Upper Blue Nile basin, Ethiopia. Study focus: Stable isotopes of water (Oxygen-18 and Deuterium) were used as tracers to estimate the contribution of groundwater in shallow hillslope aquifers to streamflow in the Robit-Bata watershed. To assess the spatiotemporal variability of shallow groundwater and develop a hydrograph separation technique, we collected rainfall, shallow groundwater, and streamflow samples and analyzed their δ18O and δ2H isotopic compositions. The local meteoric water line (LMWL) and local evaporative line (LEL) of the study area were determined and compared with the global meteoric water line (GMWL). A standard unweighted two-component isotope-based hydrograph separation model was used to determine the percentage contribution of shallow groundwater to streamflow. New hydrological insights for the region: The LMWL (δ2H = 8.63·δ18O + 18.2) mostly showed heavy isotopic enrichment relative to GMWL, and the LEL (δ2H = 5.45·δ18O + 6.96) indicated isotopic enrichment compared to Ethiopian lakes. Shallow groundwater responded rapidly to rainfall, with good spatial correlation depending on topographic positions of wells. Pre-event water contributed 90% when the watershed reached maximum storage. This finding gives insight towards the predominant runoff generation process and has significant implications for sustainable dry season irrigation expansion in the area as the sub-surface flow drains out of the watershed from October onwards reducing water tables in the shallow wells.

The first systematic research of the geo-hydrogeological and hydrogeochemical characteristics and isotopic signatures was carried out in the transboundary karstic aquifer in northeast of Iran, in order to investigate the groundwater origin, flow directions and karst development. The karstic springs of the area are characterized by discharge rate of 50–500 L/s, EC values of 370–1050 μS/cm and the Ca–Mg–HCO3 water type. Stable isotope values of the precipitations resulted in a LMWL (δ2H = 7.2 × δ18O+8.6, R2 = 0.96, n = 96) with a lower slope and a lower intercept than the global meteoric water line (GMWL) due to isotope kinetic fractionation effects during precipitation. The δ18O precipitation gradient is −0.32‰ per 100 m of altitude. Isotopes data reveals that recent Mediterranean meteoric water (rain and/or snow) is the main origin of groundwater in the study area. The depleted isotope composition of some of the springs can be attributed to their higher catchment area and more recharge by snow. Groundwater budget analysis reveals that a large amount of water migrates toward the neighboring country. Fold and fault zones can be important variables on groundwater local and regional flows in the karstic aquifer. In terms of karst development, the Sarani spring in transboundary karstic aquifer with lower δ18O, δ37Cl and EC values and higher δ13CDIC has conduit flow regime and more karst development in its catchment area. In comparison, the isotopic values as well as physic-chemical characteristics of the springs confirm larger residence times (>30 years) and lower karst development in the other karstic springs. Consequently, the geo-hydrogeological and tectonic settings as well as isotopic approaches enhances knowledge in both groundwater flow direction and karst development and, ultimately, to better evaluate and manage water resources in the study area, and also in other transboundary karstic regions.

The local meteoric water lines (LMWLs) reflect water sources and the degree of sub-cloud evaporation at a specific location. Lanzhou is a semi-arid city located at the margin of the Asian monsoon, and the isotope composition in precipitation around this region has aroused attention in hydrological and paleoclimate studies. Based on an observation network of stable isotopes in precipitation in Lanzhou, LMWLs at four stations (Anning, Yuzhong, Gaolan and Yongdeng) are calculated using the event-based/monthly data and six regression methods (i.e., ordinary least squares, reduced major axis, major axis regressions, and their counterparts weighted using precipitation amount). Compared with the global meteoric water line, the slope and intercept of LMWL in Lanzhou are smaller. The slopes and intercepts calculated using different methods are slightly different. Among these methods, precipitation-weighted least squares regression (PWLSR) usually had the minimum average value of root mean sum of squared error (rmSSEav), indicating that the result of the precipitation weighted method is relatively stable. Higher precipitation amount and lower air temperature result in larger slopes and intercepts on an annual scale, which is out of accordance with the summertime.

Ciseeng area of the Bogor Regency is geologically composed by the Quarter Volcano Deposition and Tertiary rocks. The phenomenon of hot springs in the Ciseeng area comes out through cracks in Tertiary-aged limestone. The purpose of this study was to determine the characteristics of formation water based on its chemical parameters. Research methods include the preparation stage; collection and compilation of groundwater data, and water samples; processing phase of groundwater chemical data, and stable isotope content of Oxygen-18 and Deuterium (δ18O and δ2H); and data analysis. Based on the analysis of water quality, formation water that comes out as a Ciseeng hot spring contains a high chloride element (Cl) 23,680.6 mgr/l as a result of reacting with rock minerals derived from the Tertiary rocks below which with water at high temperatures, based on its chemical facies the Ciseeng hot springs, have magnesium type chloride. The results of plotting δ18O and δD and deviations from the global meteoric water line show that the Ciseeng hot spring has the heaviest isotope content.

The north-east of Iran is a semi-arid region and faces a water shortage crisis. Therefore, monitoring water resources using accurate methods such as stable isotopes technique is vitally important. In this study, precipitation events were sampled in 10 stations in the Mashhad basin and the Bojnourd region in 2008, 2009, 2011, and 2015, additional surface and groundwater. These samples were analysed at the Ottawa University for both oxygen and hydrogen isotopes. In addition, the moisture sources were determined using the backward trajectories of the HYSPLIT model. The backward trajectories showed that both high- and low-latitude water bodies provide moisture for the north-east of Iran. However, the role of high-latitude water bodies including the Caspian, the Black, and the Mediterranean Seas is stronger. On the other hand, the stable isotopes showed large variations and the developed meteoric water lines deviated in both slope and intercept from the global meteoric water line. This showed that the precipitation events of the north-east of Iran were provided by various air masses and moisture sources. Finally, plotting the isotope values of the surface water resources on high- and low-latitude meteoric water lines demonstrated that these water resources were dominantly recharged by precipitation events originating from high-latitude water bodies.

Shalaii Cave is a closed system cave that contains old and active speleothems. It is located on the northeast limb of the Ashdagh anticline in Sangaw district in northeastern Iraq. The study presents new data on cave monitoring and the geochemistry of stalagmite archives relevant for the palaeoclimate of Iraq. An extensive cave monitoring program was conducted from June 2014 to March 2015, which included analyses of cave air temperature, relative humidity, cave air, dripwater, and modern calcite precipitates on glass slides. Physical parameters were measured monthly and continuously using data loggers and meteorological data; rainwater and dripwater samples were acquired for stable isotope analyses and hydrochemistry analysis. Stable isotopes of oxygen and carbon and absolute dating of U/Th series dating was used to determine palaeoclimate conditions. The microclimate of Shalaii Cave during the studied period (June-2014 to March-2015), the average temperature at the entrance point and inside the monitored cave was 17.05 °C and 20.18 °C respectively. The relative humidity at the entrance point and inside the cave was 66.6% and 100% respectively. Eleven samples of dripwater and five samples of rainwater were acquired for isotope analyses and thirteen samples of dripwater for hydrochemical analysis. From the environmental isotopes analysis (2H and 18O), all water samples fall between the global meteoric water line (GMWL) and Sangaw meteoric water line (SMWL). The precipitation samples plot well above the GMWL. The mechanism of recharge is direct recharge. Two stalagmites (SHC-01 and SHC-02) were sampled from the cave. The first sample (SHC-01) is dated from 1012 ± 42 to 494 ± 29 yr B.P. and the second sample (SHC-02) dates between 8025 ± 38 to 6977 ± 219 yr B.P. Oxygen and carbon isotope results show that there are two climate conditions for palaeoclimate reconstruction in the Sangaw district. Conditions were generally wetter and colder during 8025 ± 38 to 6977 ± 219 yr B.P. than current conditions; from 1012 ± 42 to 494 ± 29 yr B.P., drier and warmer conditions prevail, more similar to today.

Iran faces a water shortage crisis due to its long and frequent droughts and rapid population growth. In this study, moisture sources have been determined in 161 precipitation events from 12 stations using a Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model. Ten main moisture sources have been identified among which the Persian Gulf and the Persian Gulf with terrestrial sources are dominant. Backward trajectory outputs demonstrate that the precipitation events in the stations in the north of Iran originate mostly from the Caspian Sea and terrestrial sources. These precipitation events are mostly plotted on the Global Meteoric Water Line (GMWL) or between GMWL and Eastern Mediterranean Meteoric Water Line (EMMWL). Precipitation events in the middle and south of Iran stations receive moisture mostly from the Persian Gulf and terrestrial sources and they are mostly plotted on EMMWL. Linking backward trajectory models with precipitation events (δ 18O and δ 2H) determines the general isotope characteristics of each moisture source. Most of the precipitation events originate from high sea surface temperature (SST) water bodies and are plotted on EMMWL. However, precipitation events originating from lower SST water bodies are mostly plotted on GMWL and between GMWL and EMMWL. Plotting the average (δ 18O and δ 2H) in the studied stations on the meteoric water lines of the regions located on the dominant air masses trajectories toward Iran confirms the dominant moisture sources for the studied stations and also other obtained results by stable isotope technique and HYSPLIT model in this study.

We present speleothem fluid inclusion δ18Of and δ2Hf values from Larga Cave, Puerto Rico, that covers the interval between 46.2 to 15.3 ka before present on millennial scale, including the Last Glacial Maximum (LGM) and several stadial and interstadial cycles. The dataset can be divided in two main clusters of stable isotope compositions of the fluid inclusion water with respect to the global meteoric water line which coincide with strong variations in the water content of the stalagmite. In particular, this clustering is found to be climate related, where the first cluster comprises samples from cold and dry periods, such as Heinrich and Greenland stadials, as well as parts of the LGM, which exhibit very high δ18Of and δ2Hf values. We interpret this enrichment as caused by evaporation inside the cave due to enhanced cave ventilation during these colder and drier times. In contrast, in most samples corresponding to warmer and wetter Greenland interstadials, but also for some from Heinrich Stadial 2 and 3, the δ18Of and δ2Hf values plot on the meteoric water line and modification of fluid inclusion water due to “in-cave” evaporation is found negligible. Consequently, variations of last glacial hydro-climate and temperature in the western tropical Atlantic can be constrained. In general, δ18Of values from fluid inclusions are up to 3 ‰ higher than those of modern drip water, which is interpreted as a weaker atmospheric convective activity during the last glacial period. In addition, reconstructed temperatures suggest an average cooling of c. 3 °C during the LGM compared to modern cave temperature. During Heinrich Stadials 2 and 3, reconstructed cave temperatures yield an additional cooling of 2.9 ± 2.6 °C and 4.4 ± 0.6 °C, respectively. Higher δ18Of values of these samples further suggest that the drip water was dominated by orographic rainfall and/or cold fronts, along with weak or even absent convective activity. In contrast, during interstadial phases, reconstructed temperatures reached nearly modern values, and convective activity was comparable or only slightly weaker than today.

With the resurgence of water-isotope tracing applications for Integrated Water Resource Management in developing countries, establishing a stable isotopic baseline is necessary. Developing countries, including Malawi, continue to struggle with the generation of consistent and long-term isotopic datasets due to non-existent or inadequate in-country water-isotope capacity. Malawi has made significant advances in its quest to establish a stable isotopic baseline through the establishment of the Malawi Network of Isotope in Precipitation. This study provides the first results for the isotopic characterization of precipitation in Malawi with a view to reinforcing understanding of the country’s hydrological cycle. Error-in-variables regression defined a Local Meteoric Water Line as δ2H = 8.0 (±0.3) δ18O + 13.0 (±2.0) using stable isotopic records of 37 monthly samples from 5 stations between 2014 and 2019. Local precipitation (isotopic composition) is consistent with global precipitation expectations, its condensation-forming process occurring under equilibrium conditions and a higher intercept (d-excess) above the 10‰ for Global Meteoric Water Line, implying that air moisture recycling significantly influences local precipitation. Wider variations observed in local precipitation isotopic signatures are largely attributed to different moisture-bearing systems and diverse geographic factors across the country. Additional stations are recommended to improve spatial coverage that, together with longer temporal records, may help understanding and resolving uncertainties such as the altitude effect. This pioneering study is expected to facilitate Malawi’s ambition to achieve integrated use and improved protection of its surface water and groundwater resources in response to mounting climate change, growing population and land-development concerns.

The triple oxygen isotopes (16O, 17O, and 18O) are very useful in hydrological and climatological studies because of their sensitivity to environmental conditions. This review presents an overview of the published literature on the potential applications of 17O in hydrological studies. Dual-inlet isotope ratio mass spectrometry and laser absorption spectroscopy have been used to measure 17O, which provides information on atmospheric conditions at the moisture source and isotopic fractionations during transport and deposition processes. The variations of δ17O from the developed global meteoric water line, with a slope of 0.528, indicate the importance of regional or local effects on the 17O distribution. In polar regions, factors such as the supersaturation effect, intrusion of stratospheric vapor, post-depositional processes (local moisture recycling through sublimation), regional circulation patterns, sea ice concentration and local meteorological conditions determine the distribution of 17O-excess. Numerous studies have used these isotopes to detect the changes in the moisture source, mixing of different water vapor, evaporative loss in dry regions, re-evaporation of rain drops during warm precipitation and convective storms in low and mid-latitude waters. Owing to the large variation of the spatial scale of hydrological processes with their extent (i.e., whether the processes are local or regional), more studies based on isotopic composition of surface and subsurface water, convective precipitation, and water vapor, are required. In particular, in situ measurements are important for accurate simulations of atmospheric hydrological cycles by isotope-enabled general circulation models.

The stable hydrogen and oxygen isotopes as well as their correlation in precipitation have been widely investigated for the understanding of various hydrological processes. Monthly precipitation data were usually recommended in order to establish a linear relationship between the stable hydrogen and oxygen isotope ratios (also known as local meteoric water lines or LMWL for a specific location); however, the LMWL based on daily (or event-based) precipitation data is usually different from that using monthly data. Based on 83 sampling stations across the world from 2000 to 2017, local meteoric water lines were calculated using daily (or event-based) precipitation data (n=9354) and corresponding monthly data (n=1895), respectively; multiple regression methods were used, including ordinary least squares, reduced major axis and major axis regressions as well as their precipitation-weighted counterparts. The global meteoric water line from daily data is δ2H = (7.72 ± 0.02) δ18O + (6.84 ± 0.15) (n=9354, r2=0.96) and from monthly data is δ2H = (7.81 ± 0.04) δ18O+(7.61 ± 0.32) (n=1895, r2=0.96). The stations used in this study were grouped into five climate types, according to the Köppen Climate classification. The precipitation-weighted regression may increase the long-term receptiveness of LMWL using daily-based (or event-based) samples, not only for arid regions, but also for cold regions. When only relatively short-term isotopic records in event-based precipitation samples are available, which is usual in modern hydrological studies, the weighted regression (especially precipitation weighted ordinary least squares regression, PWLSR) is helpful to create a respective local meteoric water line.

The Cenomanian–Turonian aquifer of the Ouazzi basin is the source of drinking water for the local population, as well as irrigation water for agricultural needs. The aim of the present work was to understand the origin, geochemical evolution of deep groundwater by using a group of years of piezometric, hydrochemistry and isotopic data. The deterioration in groundwater quality of the study area is explained by the decrease in the precipitation due to climate change and overexploitation. The hydrochemical study shows that the chemical composition of groundwater in the study area consists of Cl-Ca-Mg, HCO3-CaMg, Cl-Na, and SO4Ca chemical facies for the years 1995, 2007, 2012, and 2019. Results show that electrical conductivity increased from 1995 to 2019, and this could be explained by a decrease in annual precipitation, in relation to climate change and the characteristics of water–rock interaction. Geochemical and environmental isotopic data show that the water–rock interaction and cation-exchange process are the major geochemical mechanisms controlling hydrochemical evolution of groundwater in the Cenomanian–Turonian aquifer. The diagram of δ2H = f (δ18O) shows that the isotopic contents are close or above to the Global Meteoric Water Line, which suggests that the aquifer is recharged by precipitation of Atlantic origin.

By surveying and evaluating the δD and δ18O values of the water in the source region of the Yangtze River and the Lancang River, the characteristics of the hydrogen and oxygen stable isotope composition have been analyzed. The results showed that the ranges of δD and δ18O values varied from −126.28‰ to −47.96‰ and −16.77‰ to −7.13‰. The standard deviation of δD and δ18O value are 18.58‰ and 2.34‰. The stability of δ18O value is better than δD. Atmospheric precipitation is the principal source of river water supply in the region. The Local Meteoric Water Line equation is δD = 7.73 δ18O + 4.81 (R2 = 0.96, n = 19). Due to strong evapotranspiration, its slope and intercept are smaller than the Global Meteoric Water Line. The strong evapotranspiration in the source regions causes most of the d-excess to be negative, and the ice-snow melt water replenishment feature causes some d-excess to be positive. δD and δ18O values in the source regions exhibited certain latitude effect and continental effect.

The δ2H and δ18O composition of 77 precipitation samples collected between January 2014 and April 2019 from two sites across the Guadalquivir Basin, SW Spain, were analyzed. Sampling was performed within intervals of at least 14 days basis if rain occurred but frequently intervals were longer according to the rainfall incidence. Precipitation weighted averages and local meteoric water lines are presented for use in hydrological applications. δ2H and δ18O values show a remarkably high variability attributed to the influence of Atlantic and Mediterranean vapor sources. Precipitation weighted average d-excess values of 12.5-13 ‰ confirm the Western Mediterranean influence. Temperature and amount effects were found to be weak but significant influence of secondary evaporation for single rainfall events during summer was identified by reduced d-excess values and enriched isotopic signatures plotting close or below the Global Meteoric Water line (GMWL). Isotopic signatures of both sites are very similar in general and any temperature related urban effects of Seville city compared to the rural site Donana could not be identified with the present data

As a species for ecological restoration in northern China, Tamarix ramosissima plays an important role in river protection, flood control, regional climate regulation, and landscape construction with vegetation. Two sampling sites were selected in the hillside and floodplain habitats along the Lanzhou City, and the xylems of T. ramosissima and potential water sources were collected, respectively. The Bayesian mixture model (MixSIAR) and soil water excess (SW-excess) were applied to analyze the relationship on different water pools and the utilization ratios of T. ramosissima to potential water sources in two habitats. The results showed that the slope and intercept of local meteoric water line (LMWL) in two habitats were smaller compared with the global meteoric water line (GMWL), which indicated the existence of drier climate and strong evaporation in the study area, especially in the hillside habitat. Except for the three months in hillside, the SW-excess of T. ramosissima were negative, which indicated that xylems of T. ramosissima are more depleted in &delta, 2H than the soil water line. In growing seasons, the main water source in hillside habitat was deep soil water (80~150 cm) and the utilization ratio was 63 &plusmn, 17% for T. ramosissima, while the main water source in floodplain habitat was shallow soil water (0~30 cm), with a utilization ratio of 42.6 &plusmn, 19.2%, and the water sources were different in diverse months. T. ramosissima has a certain adaptation mechanism and water-use strategies in two habitats, and also an altered water uptake pattern in acquiring the more stable water. This study will provide a theoretical basis for plant water management in ecological environment protection in the Loess Plateau.

The water sources of the Sokoto Basin are mainly of interrelated origin. The groundwater is composed of old water recharged in different climate regimes and of recent meteoric water. The recharge source is influenced by both local and regional moisture circulation given the lower slope and intercept of the local meteoric water line (LMWL) relative to those of the global meteoric water line (GMWL) and distribution of the deuterium excess d from –20 to +14 ‰. The identified interrelated water sources were confirmed by variations in tritium measured between 4.9 and

This review concerns the knowledge of the isotopic composition of current precipitation and its association with climate, geography and orography, in the Central Andes (14–28°S and 75–63°W). This knowledge is required for the evaluation of other hydrological values, especially aquifer recharge and water resources, in environments varying from rainy to hyper-arid. Since the 1960s, oxygen (δ18O) and deuterium (δ2H) isotope composition of natural water have been used as tracers of the global hydrological cycle. In the present article, the goal is to identify the origin and trajectory of air masses that produce rainfall in the Central Andes and the isotopic composition of the precipitation, as a first step to evaluate recharge and groundwater resources. The isotopic composition of rainfall varies spatially and temporarily, depending on the climatic phenomena that originate the movement of air masses, their moisture content and the isotope fractionation processes that occur until precipitation falls. Most of the significant and recent literature on the mechanisms of δ18O and δ2H transport and fractionation in precipitation along the Central Andes has been collected and summarized in this review. Precipitation in the eastern and central Andes comes mainly from the humidity generated in the Atlantic Ocean. Although the processes involved in isotope content variability of precipitation are well known, the processes involved in isotopic variability in the Western Cordillera remain poorly understood. This is mostly due to mixing of different moisture sources: from the Atlantic Ocean in summer and from the Pacific Ocean in winter. In general, winter rainfall is more enriched in δ18O and δ2H than summer rainfall. Looking at existing data, their distribution is far from being homogeneous and well-distributed, so spatial accuracy is poor in some areas, especially in the Altiplano. Hydrological and hydrogeological research and water resources evaluation in the Central Andes would greatly benefit from initiatives to obtain broader spatial coverage of rainfall collection to get isotope data for more accurate and continuous assessment of the local weather patterns. Groundwater isotope composition is a future tool to help in increasing the coverage in data scarce areas., The authors acknowledge SQM (Chile) for their support and for sharing isotopes data of the Salar de Atacama, as well as Southern Copper (Peru) for providing isotopic information. We thank two anonymous reviewers for their valuable comments. Further to this, numerous researchers, professors and practitioners from Argentina and Chile (Daniel E. Martinez, Cristina Dapeña and Christian Herrera) have contributed published and unpublished information and their personal experience.

Increasingly, modern hydrological technologies are dynamically altering river water flow and drastically affecting river hydrogeochemical cycle regimes globally. The present study focused on the reservoir discharges of artificial floodwaters that influence spatiotemporal variations in the physicochemical and stable isotope compositions in the lower Yellow River (LYR) of China. The surface water samples were collected at the nine sites along the LYR during the pre-, inter-and post-flood periods. Then, the collected samples were analysed with the following standard method. The δD and δ18O slopes of the waterline clearly indicated that the prolonged reservoir water and different water flows impacted the hydrological cycle in the LYR regions compared to GMWL (global meteoric water line) and LMWL (local meteoric water line). The thermal stratification processes of the water in the largest reservoir slightly enriched the heavy isotopes, and physicochemical alteration was neglected. Statistical analysis of two-way ANOVA revealed that the p-values (p

We compared five regression approaches, namely, ordinary least squares, major axis, reduced major axis, robust, and Prais–Winsten to estimate δ18O–δ2H relationships in four water types (precipitation, surface water, groundwater collected in wells from lowlands, and groundwater from low-yield springs) from the northern Italian Apennines. Differences in terms of slopes and intercepts of the different regressions were quantified and investigated by means of univariate, bivariate, and multivariate statistical analyses. We found that magnitudes of such differences were significant for water types surface water and groundwater (both in the case of wells and springs), and were related to robustness of regressions (i.e., standard deviations of the estimates and sensitiveness to outliers). With reference to surface water, we found the young water fraction was significant in inducing changes of slopes and intercepts, leading us to suppose a certain role of kinetic fractionation processes as well (i.e., modification of former water isotopes from both snow cover in the upper part of the catchments and precipitation linked to pre-infiltrative evaporation and evapotranspiration processes). As final remarks, due to the usefulness of δ18O–δ2H relationships in hydrological and hydrogeological studies, we provide some recommendations that should be followed when assessing the abovementioned water types from the northern Italian Apennines.

To better understand the process of precipitation and water cycle, the composition of stable isotope in precipitation and its influences by different vapor sources in the eastern of Qilian Mountains were conducted from June 2013 to May 2014. The total of 100 precipitation samples were collected in Wushaoling national meteorological station located in the eastern of Qilian Mountains. The analysis indicates that the slope of Local Meteoric Water Line is lower than that of Global Meteoric Water Line. The average values of δ18O and δD in precipitation are higher in summer but lower in winter. Except for negative correlation with relative humidity, the stable isotope values in precipitation are positive correlations with temperature, precipitation and water vapor pressure. Influenced by water vapor source, the values of d-excess are lower for the Westerly wind and the South Asia Monsoon on July and the Westerly wind and the East Asia Monsoon on August, but they are higher for the Westerly wind on other months, that they are also influenced by the weather conditions in rainfall process. The variation of stable isotope in precipitation exhibited significant temperature effect, and there is also some precipitation amount effect in spring and summer.

This paper deals with the results of a hydrochemical and geothermal study of thermal waters in northeastern Algeria. Eleven samples were collected during the period between November 2013 and April 2015. To identify the origin of the thermal groundwater and for the evaluation of the reservoir temperature in the geothermal systems, the following data were used: concentrations of major chemical constituents, stable isotope ratios (δD and δ18O), saturation indices and chemical geothermometer temperatures. The physicochemical parameters (temperature, pH, and electric conductivity) were measured in-situ; the temperature of the thermal water samples varied from 38 to 96 °C, the pH value of these springs is slightly acid to neutral, with high electrical conductivities up to 4500 μS/Cm. Piper diagrams highlighted two major hydrochemical facies namely sodium chloride (Na-Cl) and sodium sulfate (Na-SO4). The mineral composition of the thermal waters reflects the geological formations found in the deep origin reservoir and chemical changes in the fluids were highly influenced by water-rock interaction. The thermal waters from the study area are depleted in 18O and D and plot on the global meteoric water line (GMWL), their deep-circulating meteoric origin shows that most thermal waters plot on or near the meteoric water line, with some exceptions due to Mediterranean precipitation, probable water-rock isotope exchange or mixing takes place between the ascending geothermal water and shallow colder groundwater. The subsurface reservoir temperatures were calculated using different solute geothermometers and computation of saturation indices for different solid phases. The highest estimated reservoir temperatures are indicated by the cation composition geothermometer (CCG) and the Na–K–Ca geothermometer, while slightly lower estimates are obtained using silica geothermometers, with local geothermal gradients ranging from 25 to 45 °C/km.

We assessed environmental tracers in groundwater in two contrasting basins in Namibia; the Kuiseb Basin, which is a predominantly dry area and the Cuvelai-Etosha Basin, which is prone to alternating floods and droughts. We aimed to determine why the quality of groundwater was different in these two basins which occur in an arid environment. We analysed groundwater and surface water for the stable isotope ratios of hydrogen (δ2H) and oxygen (δ18O) by cavity ring-down spectroscopy and metals by inductively coupled plasma mass spectrometry. The δ2H and δ18O of surface water in the Cuvelai-Etosha Basin plot on an evaporation trend below the global meteoric water line (GMWL) and the local meteoric water line (LMWL). The δ2H and δ18O of some groundwater samples in the Cuvelai-Etosha Basin also plot on the evaporation trend, indicating recharge by evaporated rain or evaporated surface water. In contrast, the δ2H and δ18O of groundwater samples in the Kuiseb Basin plot mostly along the GMWL and the LMWL, indicating direct recharge from unevaporated rain or unevaporated surface water. Fifty percent of groundwater samples in the Cuvelai-Etosha Basin was potable (salinity  K > Ca > Mg vs. Na > Mg > Ca > K for the Cuvelai-Etosha Basin. For metals in the Kuiseb Basin the order of abundance is Fe > Al > V > As > Zn vs. Al > Fe > V> As > Zn for the Cuvelai-Etosha Basin. The relative abundance of cations and metals are attributed to the differences in geology of the basins and the extent of water-rock interaction. Our results show that the quality of groundwater in Cuvelai-Etosha Basin and Kuiseb Basin which vary in the extent of aridity, is controlled by the extent of water-rock interaction at the surface and in the groundwater aquifer.