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In this viewpoint contribution, we argue that the emerging landscape of indoor photovoltaics poses unique challenges that transcend the capabilities of a singular standard, unlike what the community has become accustomed with the success of the AM1.x standard for outdoor application. We aim at illustrating the pitfalls associated with a one-size-fits-all approach to standardisation, emphasising the necessity for a concerted and nuanced methodology tailored to the complexities of indoor energy utilisation, and particularly in the context of the various needs of the Internet of Things. Acknowledging the inherent variability in indoor illumination conditions, and using simple numerical modelling and real-life examples to illustrate how it influences the output of indoor cells, we advocate for a shift from conventional standards to comprehensive guidelines that will better accommodate and evaluate the diverse interplays between photovoltaic device, internet of things sensors, and illumination sources. Our proposed methodology is not merely a set of rules but a strategic framework for the community to build upon, inviting researchers and industry stakeholders to collaborate and establish a unified foundation for assessing the performance of photovoltaic devices indoors. By fostering a collective approach and steering clear of rigid standards, this viewpoint lays the groundwork for future studies to better assess the performance and usability of indoor photovoltaics, thus ensuring innovation, adaptability, and reliable analyses in this very fast evolving and increasingly relevant field., Comment: References are currently missing

Phase evolution during the selenization is crucial for high-quality kesterite Cu2ZnSn(S, Se)4 (CZTSSe) absorbers and efficient solar cells. Herein, we regulate kinetic process of phase evolution from Cu+-Sn4+-MOE (MOE: 2-methoxyethanol) system by precisely controlling positive chamber pressure. We found that, at the heating-up stage, Se vapor concentration is intentionally suppressed in low-temperature region, which effectively reduces collision probability between the CZTS and Se atoms, thus remarkably inhibiting formation of secondary phases on the surface and multiple-step phase evolution processes. This strategy enables the phase evolution to start at relatively higher temperature and thereby leading to high crystalline quality CZTSSe absorber with fewer defects, and corresponding CZTSSe solar cell can present 14.1% efficiency (total area), which is the highest result so far. This work provides important insights into selenization mechanism of CZTSSe absorbers and explores a new way of kinetic regulation strategy to simplify the phase evolution path to efficient CZTSSe solar cells.

The limiting factor preventing kesterite (CZTSSe) thin film solar cell performance further improvement is the large open-circuit voltage deficit (Voc,def) issue, which is 0.345V for the current world record device with an efficiency of 12.6%. In this work, SnCl4 and SnCl2_2H2O are respectively used as tin precursor to investigate the Voc,def issue of dimethyl sulfoxide (DMSO) solution processed CZTSSe solar cells. Different complexations of tin compounds with thiourea and DMSO lead to different reaction pathways from solution to absorber material and thus dramatic difference in photovoltaic performance. The coordination of Sn2+ with Tu leads to the formation of SnS and ZnS and Cu2S in the precursor film, which converted to selenides first and then fused to CZTSSe, resulting in poor film quality and device performance. The highest efficiency obtained from this film is 8.84% with a Voc,def of 0.391V. The coordination of Sn4+ with DMSO facilitates direct formation ofkesterite CZTS phase in the precursor film which directed converted to CZTSSe during selenization, resulting in compositional uniform absorber and high device performance. A device with active area efficiency 12.2% and a Voc,def of 0.344 V was achieved from Sn4+ solution processed absorber. Furthermore, CZTSSe/CdS heterojunction heat treatment (JHT) significantly improved Sn4+ device performance but had slightly negative effect on Sn2+ device. A champion CZTSSe solar cell with a total area efficiency of 12.4% (active are efficiency 13.6%) and low Voc,def of 0.297 V was achieved from Sn4+ solution. Our results demonstrate the preformed uniform kesterite phase enabled by Sn4+ precursor is the key in achieving highly efficient kesterite absorber material. The lowest Voc-def and high efficiency achieved here shines new light on the future of kesterite solar cell., Comment: 10 pages,3 figures