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The Variscan Central-Sudetic Ophiolites (CSO) are located in the Sudetes, the NE segment of the Bohemian Massif. The Devonian CSO display highly depleted, harzburgite mantle sections containing gabbroic dykes and local occurrences of mostly isotropic, large gabbroic bodies as well as volcanic rocks. The ultramafic rocks locally show melt percolation-derived clinopyroxene-olivine aggregates and chromitites. The low REE composition and depletion in LREE relative to HREE of the clinopyroxene as well as the chromite Cr# and Mg# values are typical for phases formed from refractory melts occurring in the supra-subduction zone environment. The gabbroic bodies consist of differently evolved, mostly cumulate rocks, while the volcanic rocks form a relatively monotonous basalt sequence. The trace element compositions of both the plutonic and volcanic rocks display depleted N-MORB affinities, their derivation from a refractory mantle source is further reflected by previously published depleted mantle-like Sr-Nd isotopic compositions. The ultramafic and mafic members of the CSO show greenschist- to lower amphibolite-facies metamorphic overprints. The occurrence of depleted harzburgites and isotropic gabbros forming the mantle and the crustal sections of the CSO, respectively, indicate intermediate- to slow-spreading conditions and a heterogeneous structure of the oceanic lithosphere, untypical for layered ophiolites. The geochemical characteristics of the melt-percolation phases of the ultramafic rocks, the bulk-rock compositions of the mafic rocks and the homogeneous volcanic sequences suggest a formation of the CSO in a mature back-arc basin setting, lacking subduction-derived contamination. Spreading rate conditions and geochemical affinities of the CSO are similar to those of other Devonian ophiolites localized along the Variscan Belt, for instance the Upper Ophiolitic Units in the NW Iberian Massif (Spain), thereby confirming the general absence of N-MORB type lithosphere in the European Variscan Orogen.

Pervasive alteration of basaltic oceanic crust by heated seawater at greenschist facies conditions produces two contrasting hydrothermal rocks. ���Spilites���, consisting of chlorite + albite + quartz �� actinolite �� epidote, occur typically with regional extents. Locally spilites are metasomatically transformed to ���epidosites��� consisting of epidote + quartz + titanite + hematite or magnetite. Both alteration types have been proposed as markers of deep hydrothermal upflow in sub-seafloor convection cells, and as sources of the ore metals in basalt-hosted seafloor massive sulfide deposits. Little direct evidence is available for the chemical compositions of these fluids in their states deep in the upflow zones prior to their discharge at the seafloor. To better characterize them we have conducted a field, petrographic and fluid inclusion study of the lavas, sheeted dikes and plagiogranites in the Semail ophiolite, with supporting samples from the Troodos ophiolite. Our results show that both the spilite- and epidosite-forming fluids were single-phase aqueous liquids during the hydrothermal alteration. At some sites their salinity is 3.1���3.2 wt.% NaCleq, which we take to represent the chlorinity of Cenomanian seawater in the Semail realm. At other sites salinities are as low as 2.4 wt.% NaCleq or as high as 5.7 wt.% NaCleq, attributable to liquid���vapor separation and partial remixing deep in the crust along the dew curve of seawater, prior to ascent of the fluids to the sites of fluid inclusion trapping. Hypersaline brines, often accompanied by vapor, are restricted to plagiogranites in both the Semail and Troodos ophiolites and they represent magmatic���hydrothermal fluids that pre-date and are genetically unrelated to the spilite and epidosite alteration. The volcanostratigraphic locations of the samples constrain their maximum depths to 1470���3600 m below seafloor during alteration. The range of possible fluid trapping pressures for all samples is 31���68 MPa. Trapping temperatures vary between sites from 145 to 440 ��C for spilite fluids and 255 to 435 ��C for epidosite fluids. Quantitative analyses of 12 elements in individual fluid inclusions by LA-ICP-MS define the chemical characters of the two alteration fluids. The Br/Cl ratio in the spilite fluid is the same as in modern seawater and the other elements fit expectations from seawater���basalt experiments at elevated temperature. Accordingly, concentrations of Li, B, Na, Cl, K, Br and Sr in the spilite fluid match those in modern black-smoker vent fluids in basaltic crust. Exceptions are Ca and Fe, which are enriched in the spilite fluid. As these elements may precipitate below or at the seafloor prior to vent sampling, we conclude that the spilite fluids are plausible feeders of basalt-hosted black-smoker vents. The epidosite fluid has broadly similar elemental concentrations to the spilite fluid, but vastly lower Fe, reflecting the highly oxidized state of epidosites. This suggests that epidosite fluids are incapabable of forming basalt-hosted seafloor massive sulfide deposits.

It is controversial about the tempo–spatial distribution and tectonic attributes of the Paleoproterozoic orogenic belts in the North China Craton (NCC). The Hongqiyingzi Complex in the northern margin of the NCC, comprising orthogneiss, supracrustal sequence and an ophiolitic melange, was investigated to have experienced multiple tectonic evolution from Paleoproterozoic to Mesozoic. However, the depositional age and metamorphic P–T path of the supracrustal sequence have not been well addressed. Garnet mica schists are investigated on the basis of petrography, mineral chemistry, phase equilibria modelling and zircon and monazite dating, which record an extreme case with four phases of metamorphism. The first-phase is characterized by high pressure (HP) granulite facies with the peak conditions of 10–11 kbar/>780 °C, which occurred at ~1.95 Ga. It is considered to correspond to a collisional orogeny with crust thickening widespread in the Paleoproterozoic orogenic belts of the NCC, followed by an exhumation with heating at ~1.92 Ga. The second-phase is marked by the overprinting of staurolite-bearing assemblages with the peak conditions of 6–7 kbar/610–630 °C, which occurred at ~1.85 Ga. It may correlate a separate orogeny occurred along the northern margin of the NCC, following a ~1.90 Ga oceanic subduction. Phase modelling suggests this overprinting over the first-phase HP granulites is mainly controlled by water infiltration. The third-phase andalusite-type and the fourth-phase greenschist facies metamorphism are confined to local equilibrium domains and their ages have not been well constrained. With a comparison of regional geology, the third-phase metamorphism is inferred to be related with the 320–290 Ma extension in the northern part of the NCC during Late Paleozoic, and the fourth-phase metamorphism is correlated with the 250–230 Ma collision occurred along the Solonker Suture Zone in the Central Asia Orogenic Belt during Early Mesozoic. Moreover, detrital magmatic zircons yield ages of 2.0–2.1 Ga, providing a definite upper limit on the deposition of the Hongqiyingzi supracrustal sequence.

Lode gold deposits are among the most economically important types of gold deposits in the world. Globally, they formed mainly in three time intervals, 2.8 to 2.5 Ga, 2.1 to 1.8 Ga, and 700 Ma to the present. Sources of ore-forming fluids and other components are of critical importance in a better understanding of the genesis and the geodynamic controls of these deposits. Although ore-forming fluids were mostly derived from devolatization of sedimentary and/or volcanic sequences during greenschist to amphibolite facies metamorphism associated with orogenic deformation, magmatic hydrothermal fluids have been increasingly shown to be important in many gold deposits in various regions. In this review paper, we summarize the major features of lode gold deposits, possible sources of ore-forming fluids, and mechanisms of gold mineralization. While we acknowledge the critical role of metamorphically derived fluids in the genesis of such deposits worldwide, we emphasize that mantle- or basaltic magma-derived fluids may have been much more important than commonly thought. We use the Liaodong peninsula of the North China Craton as an example to demonstrate the significance of mantle-derived fluids. Integrating earlier studies and new data, we show that some of the late Mesozoic lode gold deposits in the North China Craton may have formed from magmatic hydrothermal fluids due to the extension and partial melting of the hydrated, metasomatized subcontinental lithosphere mantle, as best exemplified by the Wulong gold deposit.

International audience; the Alpine belt that exhibits peridotite massifs associated with high-grade crustal metamorphic units. The timing and mechanisms of exhumation of these crust–mantle associations are still debated in the Rif in Morocco as well as in the Betic Cordilleras in Spain. A structural, petrographic, and geochronological study (40Ar–39Ar method) is performed in the Beni Bousera region (Internal Rif) on the Upper Sebtides units that consist of Paleozoic basement and Permo-Triassic metasedimentary rocks. We point out that, in the metagreywackes, an early assemblage of K-feldspar, plagioclase, quartz, muscovite, biotite, and garnet, which is diagnostic of amphibolite facies metamorphism. By dating white mica porphyroclasts from this metamorphic assemblage, we provide the first evidence of internal Rif metamorphism of Triassic age. We assume that these crustal units belong to the ancient continental margin of the Western Tethys, and thus, we interpret this metamorphic event in the framework of a hyperextended margin that is coeval with the exhumation of the subcontinental mantle during the Upper Triassic. Afterward, these units underwent greenschist facies metamorphism during the Lower Miocene due to a thermal event related to the back-arc opening of the Alboran Basin.

The origin of sediment-hosted copper-cobalt deposits (SCDs) within metamorphic terranes remains contentious, particularly in regard to the timing of mineralization relative to basin evolution. Here, we link the timing of Cu-Co mineralization in the Zhongtiao Mountains district, central China, to basin closure during development of the Trans-North China Orogen. Metamorphic apatite from meta-evaporite has a U-Pb age (1844 ± 25 Ma) within error of a Re-Os age for molybdenite from Cu- and Co-bearing veins (1819 ± 10 Ma), implying that mineralization and metamorphism were coincident. In situ trace element and Fe-S isotope analyses of deformed sedimentary pyrite (Py I) and younger euhedral metamorphic pyrite (Py II) in pyritic graphite schist indicate that Co was mobilized from Py I via fluid-mediated dissolution and reprecipitation. In the graphite schist, representing a sulfidic shale metamorphosed at upper greenschist facies conditions, relic Py I has high δ34S values (22.9 ± 0.4‰, n = 10) and δ56Fe values (0.90 ± 0.16‰, n = 8). These values are consistent with bacterial sulfate reduction and pyrite formation in a Paleoproterozoic sulfidic sea (i.e., after the first great oxygenation event). In addition, Py I has unusually high Co contents (0.8–3.0 wt.%), suggesting that transition metals, including Co and Ni, were originally concentrated in sedimentary pyrite in an evaporative setting. The evaporitic setting is supported by the presence of sylvite in sulfidic schists and adjacent scapolitic calc-silicates. Younger Co-poor Py II has slightly lower δ34S values (21.4 ± 0.2‰, n = 19) and higher δ56Fe values (1.61 ± 0.15‰, n = 9), supporting the hypothesis that Co was released from sedimentary sulfide during dissolution and reprecipitation. The great variability of δ34S (14.8 to 22.9‰) and δ56Fe (0.13 to 2.30‰) in hydrothermal pyrite (Py III) associated with Cu-Co mineralization suggests that an external Cu-rich oxidizing fluid was involved in the ore-forming process. Copper and Co in this type of deposit are typically both considered to be derived from fertile basement rocks. This study, however, highlights another potential source for the Co, with its enrichment in a sulfidic sea along an evaporative margin and its upgrading through mobilization during orogenesis that leads to formation of a relatively high-temperature group of SCDs. Tectonometamorphic processes causing such Co enrichments took place during the Paleoproterozoic and Neoproterozoic oxygenation events, implying that the most prospective targets for Co resources are concentrated in ca. 2.2–2.0 Ga and 0.9–0.7 Ga deformed passive margin marine sequences.

The source of the mineralizing fluid in Archean greenstone-hosted orogenic gold deposits is widely debated, with the available geochemical and isotope data interpreted as reflecting the involvement of metamorphogenic fluid produced by devolatilization of greenstone belt metaigneous/metasedimentary rocks or granite-derived magmatic-hydrothermal fluids or both. Orogenic gold deposits form in complex geologic environment involving multiple fluid sources, reflected in the large variation in the B-isotope composition of tourmaline (δ11B = −24.8‰ to +19.8‰). The δ11B distribution of tourmaline from world-wide orogenic gold deposits define two peaks, one at ca. −15‰, and the other between −5 and 0‰. In this study, we modelled the release of boron and associated B-isotope fractionation during prograde metamorphic dehydration of representative mafic and pelitic greenstone rocks using a mass balance approach and compared the results with the B-isotope composition of tourmalines measured globally from orogenic gold deposits. The results indicate that the boron content of greenstone belt metabasalts decreases from ∼26 ppm to ∼2.7 ppm by 530 °C while those in metapelites decrease from ∼60 ppm at 300 °C to ∼40 ppm by the terminal chlorite breakdown temperature of about 570 °C. In both mafic and pelitic assemblages, terminal chlorite breakdown reactions occurring during the greenschist to amphibolite facies transition (530–570 °C) release large amounts of 10B-rich fluids, which rapidly lower the δ11B of the metamorphic fluid. The δ11B of the fluids released from metabasalts and metapelites at these conditions are estimated to be about −14.2 to −10.8‰ and −5.7 to 0.0‰, respectively. Tourmalines precipitating from such metabasalt-derived fluid are expected to have δ11B between −18.0‰ and −12.4‰ while those crystallizing from metapelite-derived fluid will have δ11B between −9.5‰ and −1.6‰ for the temperature range of ore formation (300–550 °C) in orogenic gold deposits. Our calculated range of δ11B for the metabasalt- and metapelite-derived metamorphic fluids matches closely with the two peaks in the δ11B distribution of tourmaline from orogenic gold deposits. The δ11B of metabasalt-derived fluid is highly variable (+2‰ to −15‰ between 450 °C and 610 °C) and strongly dependent on the metamorphic grade attained by the greenstone belt lithologies. The majority of measured tourmaline δ11B values from orogenic gold deposits of all ages can potentially be explained by different peak metamorphic temperatures with a single fluid source from metabasalts, or by mixing between basalt-derived and pelite-derived metamorphic fluids, or both. Prior characterization of the metamorphic grade of the rocks and the temperature of mineralization are desirable before using the B-isotope composition of tourmaline for evaluating fluid source. The δ11B (−14.0‰ to −3.3‰) of tourmalines measured by us from the Hutti and Kolar gold deposits as a case study can be explained by our modelled results with the isotopic variations attributed to mixing between metapelite- and metabasalt-derived fluids. Low Li concentrations in the tourmalines of Hutti and Kolar (avg. 21.7 and 28.0 ppm in Hutti and Kolar, respectively) further support a metamorphic origin for the hydrothermal fluid. The relatively higher V contents of the Hutti tourmalines (avg. 962 ppm) vis-a-vis the Kolar tourmalines (avg. 615 ppm) is suggestive of greater pelitic input in Hutti.

The paper presents data acquired on epigenetic processes in rocks of the Meso- to Neoarchean greenstone complex of the Bundelkhand Craton of the Indian Shield. The study was focused on felsic and mafic metavolcanic and mafic–ultramafic rocks of the Central Bundelkhand Greenstone Complex (CBGC). The rocks contain metamorphic mineral assemblages produced during an earlier high-temperature [Grt–Prg–Pl; Cpx–Prg–Pl; Cpx–Grt–Pl; Cpx–Prg (± Ksp, Qz, Mag)] and later retrograde [Grt–Pl–Hbl; Grt–Chl–(Hbl–Act); Grt–(Zo–Czo)–(Hbl–Act); Grt–Chl–Pl (± Ksp, Qz, Mag, Ms)] episodes of metamorphism. The retrograde metamorphism was associated with the origin of zoned Ep and Qz–Ep (±Grt, Act) veins, patches, stripes, and small bodies of epidosites and actinolites. The mineral assemblages of the final episodes of the rock transformations contain prehnite and pumpellyite (Prh–Pmp–Alb; Prh–Pmp–Grs; Pmp–Grs–Alb; Prh–Cc–Act; and Prh–Grs–Cc). The composition of the garnet and amphibole was determined to broadly vary (Alm–Sps to Grs and Prg–Ts to Act and Cum, Gru, respectively). The garnet is contrastingly zoned (comprises three zones), with the boundaries of the zones marking drastic changes in the crystallization parameters (episodes of transformations). The identified sequence of the epigenetic events was as follows: amphibolite-facies metamorphism under elevated pressures (580–680°C at 7.2–10 kbar), with a clockwise P-T-t path and retrogression to the greenschist facies → Ca(Mn) metasomatism → metamorphism to the prehnite–pumpellyite facies. The metamorphic evolution of the CBGC rocks in the Bundelkhand Craton is in good agreement with the geodynamic model of cratonic crustal growth, with Archean subduction–accretion processes and Paleoproterozoic intraplate rifting.

Microstructure and texture data on the Main Central Thrust zone (MCTz) in central Himalaya, on two nearly N-S oriented valleys in the Manaslu range (Western Nepal), are provided. Kinematic indicators at the meso and microscale support a south-directed flow. From south to north, greenschist facies paragneiss in the garnet-zone pass to amphibolite facies rocks in the kyanite-zone, suggesting an up-section metamorphic temperature increase. Combining microstructures and data from two different texture analysers (X-ray Texture goniometry and crystal-fabric microanalyzer) allowed to link the temperature path (from 460°C to 600°C up-section) and kinematic vorticity estimates. The “orientation of oblique grain shape fabrics” method was applied, pointing out a general shear flow (40-56% of pure shear) at the MCTz top. Results are in line with a “decelerating strain-path” model, as relatively high simple shear components are recorded at deeper structural levels. This work highlights that the combination of X-ray texture goniometry and crystal-fabric microanalyzer techniques is a good strategy to ensure quartz full-fabric.

The late Archean was a crucial transition period for global geodynamics. Metavolcanic rocks, as one of the predominant components of Archean cratons, are key to deciphering the geodynamic regimes of early Earth crust-mantle interactions. Neoarchean supracrustal rocks in the central K-rich granitoid belt of the eastern Hebei-western Liaoning Province, northern North China Craton, may be subdivided into a lower metavolcanic sequence and an upper metavolcanic-sedimentary sequence by an angular unconformity. The lower sequence metavolcanic rocks consist primarily of 2558–2536 Ma amphibolite to granulite facies metamorphosed basaltic-andesitic rocks and high- and low-MgO dacitic rocks. The basaltic-andesitic samples display calc-alkaline affinity, high MgO contents, low (Nb/La)N and moderate (Hf/Sm)N values and were most likely derived from partial melting of mantle materials metasomatized by subducted slab- and sediment-derived melts and fluids. The high-MgO dacitic samples are characterized by strongly fractionated rare earth element (REE) patterns and relatively high MgO contents, which resemble typical high-SiO2 adakites. The magmatic precursors originated from subducted oceanic slabs and sediments. The samples with low-MgO dacite compositions have the highest SiO2 and lowest MgO contents, and the magmatic precursors were generated by partial melting of metamorphosed high-K mafic rocks and sedimentary rocks in the lower crustal level. The upper sequence metavolcanic rocks chiefly comprise greenschist to amphibolite facies metamorphosed tholeiites, tholeiitic to transitional basalts, calc-alkaline basalts, andesites, and dacites with magmatic crystallization ages of 2522–2511 Ma. The tholeiite samples are characterized by left-declined REE patterns and high (Nb/La)N and chondrite-like (Hf/Sm)N values resembling typical N-MORBs and were formed by partial melting of a depleted mantle source. The tholeiitic to transitional basalt samples resemble back-arc basin basalts and display weakly right-declined REE patterns, mildly negative Nb and Ti anomalies, and low (Nb/La)N and chondrite-like (Hf/Sm)N values. Their magmatic precursors were derived from partial melting of a slightly fluid- and melt-metasomatized depleted mantle source. The calc-alkaline basalt and andesite samples exhibit fractionated REE patterns and apparent Nb, Ta, and Ti depletions and originated from a strongly fluid- and melt-metasomatized depleted mantle source. The dacite samples show the highest SiO2 and lowest MgO contents in the upper sequence metavolcanic rocks and were derived from partial melting of lower crustal metasedimentary rocks. Systematic petrological, geochemical, and petrogenetic studies indicate that a mature continental arc setting and a back-arc basin setting may account for the formation of the lower and upper sequence metavolcanic rocks, respectively. Three stages of deformation can be identified in the K-rich granitoid belt, including 2525–2505 Ma extensional deformation in a back-arc basin setting (D1), ca. 2500 Ma top-to-the-NEE-SSE thrusting in a collisional orogenic setting (D2) and 2500–1800 Ma nearly N-S-oriented strike-slip shearing (D3), with D2 deformation accompanied by the synchronous occurrence of paired high-pressure and high-temperature medium-pressure granulite facies metamorphism. Integrating the petrogenesis, spatiotemporal relationships, deformational and metamorphic features of the Archean lithological assemblages, we consider that the late Neoarchean K-rich granitoid belt was formed in an active continental margin setting with a southeastward subduction polarity and experienced multi-stage trench retreats and a subsequent collision between the arc and continent.

The article describes the fold-thrust structure of the Golets Vysochaishy deposit located at the Baikal-Patom Upland in the Marakan-Tunguska megasyncline. The latter is composed of terrigenous-carbonate carbonaceous rocks metamorphosed in greenschist facies conditions. The deposit is detected in the hanging wing of the asymmetric Kamenskaya anticline. In a cross section, the anticline is an S-shaped structure extending in the latitudinal direction. The main feature of the Golets Vysochaishy deposit is the development of interlayer sulfidization zones (pyrite, pyrrhotite), including gold-bearing ones. Its gold-ore zones tend to occur in layered areas of interlayer sliding in the rocks of the Khomolkhinskaya suite.Four structural markers revealed within the deposit area are indicative of repeated deformation processes: (1) sublatitudinal folding, cleavage of the axial surface and its subsequent transformation into schistosity; (2) crenulation cleavage; (3) interlayer sliding and rock breakdown with interlayer drag folds, parallel microfractures and polished slickensides; (4) large quartz veins and veinlets that cross cut the main structural elements in plan.

The large Hebaoshan gold deposit (41.5 t Au, average grade: 3.5 g/t) is located in a hitherto poorly documented gold province in the northeastern part of the South China Block. It is hosted by Precambrian metasedimentary rocks that experienced Triassic greenschist- to amphibolite-facies metamorphism. Three hydrothermal stages can be distinguished: quartz + sericite + pyrite + pyrrhotite (stage I), quartz + magnetite + sulfide (stage II), and quartz + carbonate + pyrite + hematite (stage III). Auriferous pyrite samples yielded a Rb-Sr isochron age of 234 ± 3 Ma (2σ, MSWD = 0.24), and ore-related hydrothermal sericite yielded a 40Ar-39Ar plateau age of 226.4 ± 2.0 Ma (2σ, MSWD = 1.01), which are distinctly younger than ca. 430 Ma granitic rocks in the mining district and older than 170–130 Ma granites in the region, ruling out any genetic link between granite emplacement and gold mineralization. The mineralizing fluid system can be described as carbonic-aqueous with low to moderate salinity (2.2–10.1 wt% NaCl equiv.) and medium temperature of 290 to 350 °C (stage I) and 230 to 280 °C (stage II). The δ18O quartz ranges from 13.3 to 15.4 ‰, and the δD values for fluid inclusions in quartz range from − 97 to − 60 ‰. The calcite has C-isotopes ranging from − 6.1 to − 3.8 ‰ and O-isotopes from 2.8 to 13.6 ‰. H-O-C isotope data are consistent with a metamorphic fluid derived from devolatilization of Neoproterozoic basement rocks during regional metamorphism in the Late Triassic Indosinian period. The δ34S values of sulfides for stages I, II, and III are 0.1 to 7.8 ‰, − 10.6 to 5.1 ‰, and − 18.9 to − 14.1 ‰, respectively, indicating an increase in oxygen fugacity during fluid ascent which resulted in more negative sulfur isotope values of sulfides and precipitation of gold. Pyrite separates have 206Pb/204Pb ratios of 17.340 to 17.687, 207Pb/204Pb ratios of 15.539 to 15.604, and 208Pb/204Pb ratios of 37.749 to 38.094. The S-Pb isotope data suggest derivation of S and Pb from the Precambrian metasedimentary country rocks. Auriferous pyrite yielded elevated 3He/4He ratios (0.78–1.46 Ra), which suggest a mantle component as can be expected from fluids derived from a subduction setting. It is concluded that Hebaoshan is an orogenic gold deposit that formed during Triassic flat-slab subduction of the paleo-Pacific plate beneath the South China Block and thus constitutes the first Triassic deposit of this type recognized in the coastal area of Southeast China.

Um Trambishi area consists of volcano-sedimentary sequence intruded by syntectonic pluton of granitoids composition with marginal fissures injected by aplite, had been subjected to dynamic metamorphism and obliterated by recrystallization forming different rock units varying in composition, forming greenschist terrains. These are an assemblage of recrystalline schists, meta-acid, cataclastic tonalite, granodiorites, meta-andesite, chlorite schists, quartzite, marble, metabanded chert, together with two generations of unmineralized deformed and undeformed white quartz, which are oriented mainly in E-W and N-S direction following faults trend. The area is subjected to four deformational phases of brittle-ductile transition. The metamorphic grade is Green Schist Facies. The alteration around the endo-contact zone is characterized by minerals: albite, chlorite, epidote, sericite, carbonate and kaolin with anomalous Au=0.91ppm, Ag=1.75ppm, As=44.6XRF, Co=15.70XRF, V=65XRF, Ti=4796XRF, Cr=23XRF, Sr=269XRF, and base metals Pb=1.51ppm, Zn=22.02ppm and Cu=13.59ppm. The first phase of hydrothermal solution carrying gold is related to the magmatic high temperature associated with granitoidal intrusions, deposited into the planar fabric S1 and has a characteristic signature of hypothermal processes .The second mode of occurrence is the regeneration of auriferous quartz stringers filling into the tectonic fissures trending 340⁰ and oblique to S1 as a result of D3 (Keraf Shear Zone) and has a characteristic signature of mesothermal processes.

International audience; We describe a singular structure in Upper Cretaceous rocks of the Eaux-Chaudes massif of the western Pyrenees, consisting of a kilometre-scale fold nappe with a sheared overturned limb. High ductile strain attests a deformation style rarely reported for the alpine Pyrenees, and peak temperature in Upper Cretaceous carbonates is estimated by Raman spectroscopy of carbonaceous material palaeothermometry in the lower greenschist facies (>300°C). The normal fold limb retains the original sedimentary textures, while the overturned limb shows calcite crystal-plastic deformation and dynamic recrystallization, with crystallographic preferred orientation. The observed ductility and metamorphic temperature bear similarities with the lower Helvetic nappes of the Alps, suggesting deep burial and/or possibly high geothermal gradient in this part of the Pyrenees.

Up to 2 km of siliciclastic and chemical sedimentary rocks, metamorphosed to greenschist facies, are preserved in the Baraboo Hills of southern Wisconsin. The strata compose two sedimentary...

Recent petro-structural investigations on the Faboula gold deposit located in the Bougouni-Kekoro basin, in southern Mali, north-west of the Leo-Man Shield, have provided new data on the nature and spatial organization of the lithostratigraphic units as well as their deformation style. The deposit is covered by a thick lateritic layer and is hosted by a metavolcano-sedimentary sequence of Paleoproterozoic age intersected by intrusive bodies and filled fractures of various shapes and types. The lithostratigraphic units consist of metagreywackes, metasiltstones, meta-argillites, slates and schists. Metagreywackes and metasiltstones are generally feldspathic, both may contain biotite and locally amphibole, just as slates may contain andalusite which is locally stretched. Plutonic units most often occur as stocks or as dikes on the drill core, up to 1 m. The metavolcano-sedimentary rocks are schistose and deformed under greenschist facies conditions, and locally they reach the epidote-amphibolite facies. The structural study revealed that the deposit is affected by several stages of deformation evolving from a ductile type to a brittle type via a ductile-brittle type. The dominant ductile and brittle-ductile deformations show a combination of isoclinal folding and strike-slip faults. Both the isoclinal folding and the strike-slip faults whose sigmoidal en-echelon tension gashes indicate a dextral movement in the NNE-SSW direction are the result of the same ENE-WSW regional shortening. Consequently, they highlight a transpressive deformation. This deformation noted here D2Fb, could be equivalent to the regional D2 or D3 deformations identified at the scale of the Leo-Man Shield if we refer to the style of deformation. There is an abundance of quartz veins networks. Their relation within the structural features indicates that the mineralization is structurally controlled during a hydrothermal event linked certainly to the circulations of fluids during the transpressive event D2Fb.

High/ultrahigh-pressure (HP/UHP) metamorphic complexes, such as eclogite and blueschist, are generally regarded as significant signature of paleo-subduction zones and paleo-suture zones. Glaucophane eclogites have been recently identified within the Lancang Group characterized by accretionary melange in the Changning-Menglian suture zone, at Bangbing in the Shuangjiang area of southeastern Tibetan Plateau. The authors report the result of petrological, mineralogical and metamorphism investigations of these rocks, and discuss their tectonic implications. The eclogites are located within the Suyi blueschist belt and occur as tectonic lenses in coarse-grained garnet muscovite schists. The major mineral assemblage of the eclogites includes garnet, omphacite, glaucophane, phengite, clinozoisite and rutile. Eclogitic garnet contains numerous inclusions, such as omphacite, glaucophane, rutile, and quartz with radial cracks around. Glaucophane and clinozoisite in the matrix have apparent optical and compositional zonation. Four stages of metamorphic evolution can be determined: The prograde blueschist facies (M1), the peak eclogite facies (M2), the decompression blueschist facies (M3) and retrograde greenschist facies (M4). Using the Grt-Omp-Phn geothermobarometer, a peak eclogite facies metamorphic P-T condition of 3000–3270 MPa and 617–658°C was determined, which is typical of low-temperature ultrahigh-pressure metamorphism. The comparison of the geological characteristics of the Bangbing glaucophane eclogites and the Mengku lawsonite-bearing retrograde eclogites indicates that two suites of eclogites may have formed from significantly different depths or localities to create the tectonic melange in a subduction channel during subduction of the Triassic Changning-Menglian Ocean. The discovery of the Bangbing glaucophane eclogites may represent a new oceanic HP/UHP metamorphic belt in the Changning-Menglian suture zone. ©2021 China Geology Editorial Office.

Exhumed high-pressure/low-temperature (HP/LT) metamorphic rocks provide insights into deep (∼20–70 km) subduction interface dynamics. On Syros Island (Cyclades, Greece), the Cycladic Blueschist Unit preserves blueschist-to-eclogite facies oceanic- and continental-affinity rocks that record the structural and thermal evolution linked to Eocene subduction. Despite decades of research, the metamorphic and deformation history (P-T-D) and timing of subduction and exhumation are matters of ongoing discussion. We suggest that Syros comprises three coherent tectonic slices and that each slice underwent subduction, underplating, and syn-subduction return flow along similar P-T trajectories, but at progressively younger times. Subduction and exhumation are distinguished by lineations and ductile fold axis orientations, and are kinematically consistent with previous studies that document top-to-the-S-SW shear (prograde-to-peak subduction), top-to-the-NE shear (blueschist facies exhumation), and then E-W coaxial stretching (greenschist facies exhumation). Amphibole zonations record cooling during decompression, indicating return flow above a cold slab. Multi-mineral Rb-Sr isochrons and compiled metamorphic geochronology show that the three slices record distinct stages of peak subduction (53–52, ∼50, and 45 Ma) that young with structural depth. Retrograde blueschist and greenschist facies fabrics span ∼50–40 and ∼43–20 Ma, respectively, and also young with structural depth. Synthesized data sets support a revised tectonic framework for Syros, involving subduction of structurally distinct coherent slices and simultaneous return flow of previously accreted tectonic slices in the subduction channel shear zone. Distributed, ductile, dominantly coaxial return flow in an Eocene-Oligocene subduction channel proceeded at rates of ∼1.5–5 mm/yr and accommodated ∼80% of the total exhumation of this HP/LT complex., Tectonics, 41 (6)

Chrome spinels in carbonate veins of the Onguren Complex, East Siberia, Western Baikal region are predominantly ferrichromite and chrommagnetite (MgO ≤ 0.3 wt %, Mg# ≤ 0.04, Al2O3 ≤ 2.5 wt %; Cr# 0.91–1.00, Fe2+/Fe3+ 0.8–1.4) with a high ZnO content (0.9–4.6 wt %). In the calcite vein, titanian chrome-magnetite is transformed into Cr-bearing titanomagnetite, which decomposes into Ti-depleted magnetite and ilmenite at temperature of 970–1000°С and $${{f}_{{{{{\text{O}}}_{{\text{2}}}}}}}$$ approximately of +0.5…+0.7 QFM. In the dolomite vein, ferrichromite and chrome-magnetite grains contain relict cores of subferrialumochromite (Al2O3 10.6–14.4 wt %, Cr# 0.63–0.73, Fe2+/Fe3+ 4.1–5.2, MgO ≤ 0.52 wt %) with elevated ZnO (3.7–5.1 wt %), TiO2 (3.2–4.1 wt %), and MnO (0.6–1.1 wt %). Ferrichromite and chrome-magnetite are formed during the high-temperature (>600°C) metamorphism of the vein. Superimposed deformations under greenschist facies conditions lead to the formation of magnetite rims around chrome-magnetite grains.

Diverse geological complexes that form the crystalline basement of the East Antarctic Platform crop out in the Prince Charles Mountains. The Ruker Group is a member of the metasedimentary complexes that make up the Paleoproterozoic through Neoproterozoic suprastructure of the Ruker Terrane. It is divided into two sequences consisting of highly deformed and greenschist facies metamorphosed sedimentary and volcanic rocks. The mineral and major element compositions of metavolcanic rocks have been studied and physicochemical modeling of mineral parageneses has been performed to reconstruct the P–T parameters of metamorphism. The dependence of the mineralogy of metabasic schists on the protolith composition and the ratio of components in the H2O–CO2 fluid involved in the phase reactions were analyzed. The calculated mole fraction of CO2 in the fluid equilibrated with carbonate-bearing parageneses is 0.13–0.27. It is assumed that chloritoid schist consists of metamorphosed laterites derived from basalt. Modeling and the data of chlorite–phengite thermobarometry indicate that the Ruker Group rocks were metamorphosed under conditions of the high-pressure part of the greenschist facies (300–450°C, 7–8 kb). These conditions are significantly higher than the stable continental geotherm and are close to those in the zone of a slow subduction geotherm. According to the available geological data, a similar geodynamic setting could be caused by the evolution of the Neoproterozoic intraplate sedimentary basin in connection with deep-sinking basement blocks as a result of tectonic aggregation during the closure of the basin.

The abundance of garnet — hornblende pair in a wide range of rocks primarily from upper green schist to granulite facies has made it one of the most widely used pairs for estimation of temperature at which once rocks equilibrated. Several models of garnet- hornblende thermometer have been formulated by a number of researchers in last four decades. In this contribution, four thermometers: Graham & Powell (1984); Perchuk et al., (1985); Powell, (1985) and Ravna, (2000) formulated since 1984 have been applied. 79 sample data (32 granulites facies, 37 amphibolite facies, 1 greenschist facies, 6 UHP/eclogite facies, 1 UHT and 2 migmatites) from the global literature were collected and processed through the “Gt-Hbl.EXE” software. Based on the present study, the best among all the four models have been identified where the regression bearing on inverse of temperature verses LnKD of each model as well as relation of distribution coefficient on composition were compared. It is concluded that Perchuk et al., (1985) is the most valid and reliable thermometers for a wide range of rock types such as greenschist to eclogite facies.

The Gurupi Belt, in north-northeastern Brazil, is a mobile belt developed in the south-southwestern margin of the Sao Luis cratonic fragment and crops out as a tectonic and erosional window within the Phanerozoic cover. Field, petrographic, geochemical, geochronological, and Nd isotopic information (new and published) constrain the timing and types of magmatic associations present in the belt and the tectonic settings in which they formed. The Rhyacian was the main period of magmatic activity, which can be grouped into two main stages. (1) ~2185–2130 ​Ma: pre-collisional, juvenile, calc-alkaline magnesian and calcic ferroan granitoid suites, and minor calc-alkaline and tholeiitic mafic plutonism (now amphibolites), formed in intra-oceanic to transitional/continental arcs; and intra- or back-arc volcano-sedimentary basin. (2) ~2125–2070 ​Ma: syn- (two-mica granites) to late-collisional (potassic to shoshonitic granites and quartz-syenite) plutonic suites produced after crustal thickening and melting, with localized migmatization, that intruded during the compressive D1 deformational phase and concomitantly with greenschist to amphibolite metamorphism. There is a zonation of the Rhyacian episodes, with intra-oceanic stages occurring to the northeast, and the continental arc and collisional phases occurring to the southwest, indicating the presence of an active continental margin to the southwest, and subduction from NE to SW (present-day configuration). This magmatic framework is a continuation to the south of what is described for the Sao Luis cratonic fragment to the north, and the orogenic scenario is identical to what is observed for the same period in the West African Craton (Eburnean/Birrimian orogen), which additionally supports previous geological correlations. In the Neoproterozoic, a few magmatic occurrences are recognized. An extensional event allowed the intrusion of an anorogenic, nepheline syenite at ca. 730 Ma, which was followed by the intrusion of a crustal, calc-alkaline microtonalite, of uncertain tectonic setting, at 624 ​Ma. Both intrusions underwent greenschist to amphibolite facies metamorphism between 580 Ma and 529 ​Ma. This metamorphic event is probably related to crustal thickening, which produced crustal melting and intrusion of two-mica granites between 595 Ma and 549 ​Ma. The absence of oceanic and arc-related assemblages, along with geophysical information about the basement of the Phanerozoic cover indicates an intracontinental setting for the Neoproterozoic–Early Cambrian evolution of the Gurupi Belt, with rifting and posterior closure of the basin, without oceanization. Rifting and closure correlate in time with the onset of Rodinia breakup and West Gondwana assembly, respectively, but we interpret the events in the Gurupi Belt as having no direct role in these two global supercontinent-related events, but, instead, as being related to orogenic events occurring in the periphery of the West African and Amazonian cratons at that time.

The Mocicos Cu-deposit is part of a cluster of ancient copper mines in the Sousel-Barrancos metallogenic belt in the Ossa-Morena Zone at the SW Iberia. The orebodies develop along NNW-SSE quartz-carbonate-sulfides veins with pyrite and chalcopyrite as the main sulfide phases, and ore emplacement has been attributed to copper remobilization from the metasedimentary host-rocks, though no detailed studies were conducted. A novel multi-stage fluid circulation model is hereby proposed, supported by petrography and fluid inclusion data evidencing the P–T–V-x evolution of the deposit. Stage (i) is an early metamorphic stage with a predominance of carbonic fluids, identified in highly deformed milky quartz (QzI), with estimated pressures between 338 and 486 MPa compatible to the regional metamorphic events (greenschist facies). Stage (ii) corresponds to a late-metamorphic manifestation of H2O–NaCl–CO2 fluids, with low-salinity (eq. w(NaCl) from 0.4 to 5.0%) and CO2 dominated. Stage (iii) in which ore emplacement took place and is characterized by dominant multisolid H2O–NaCl hypersaline, halite-bearing fluid inclusions (eq. w(NaCl) from 29.3 to 44.3%) with an H2O–NaCl–CO2 endmember and features indicative of magmatic-hydrothermal brines. Many of these inclusions homogenize by halite dissolution, with pressures as high as 320 MPa, and the coexistence of both fluids in the same fluid inclusion assemblages (FIA) could indicate phase separation caused by fluid pressure variations. Although there is no direct evidence of the magmatism responsible for these fluids, the geodynamic settings could favor deep-seated magmatism. Stage (iv) is characterized by low-salinity (eq. w(NaCl) from 0.18 to 15.57%) and low-temperature (68 to 160°C) primary two-phase fluid inclusions hosted by late-stage quartz (QzIV), suggesting a late-meteoric fluid circulation phase responsible for the leaching, oxidation and supergene enrichment observed at surficial levels. Throughout the P–T evolution of the system a decrease in pressure and temperature was registered, especially in fluid inclusions hosted in quartz from the sulfide bearing veins, suggesting that the transition from ductile to brittle regimes might have favored ore deposition.

Background/Objectives: Talcose rocks within Precambrian Basement Complex serve as relics of Archean greenstones. alterations associated with polycyclic-orogenies that affected this complex is studied to understand mineralogical and geochemical alterations. Methods: Five fresh samples of talcose rocks were collected during field mapping. These samples were cut into thin sections to reveal modal mineralogy, altered minerals and degree of alteration of such minerals. Mineral phase identification of the talcose rocks was conducted using X-ray Broker D8 ADVANCE diffractometer while whole rock analysis was carried out using Inductively Coupled Plasma Mass Spectrometry. Findings: Lithological relationship revealed from field evidence showed that the talc bodies occurred in close association with micaceous schist. The mineral assemblage of talc, tremolite, actinolite, chlorite and calcite suggest low grade greenschist metamorphic facies from possible hydrothermal alteration. Geochemical results revealed the following range of concentrations; SiO2 42.19-59.03%; Al2O3 1.1 - 11.8%; Fe2O3 7.64-9.56%; MgO 24.47-26.639%; Ni 594-1207ppm; Co 43.2-113.9ppm; Sn 6-41ppm; V 32-75ppm and Zr 1.3-58.7ppm, and these are typical of talcose rocks. Petrogenetic studies suggest a komatiitic origin with a peridotitic komatiite precursor for the talc-chlorite-tremolite schist. Enrichment in LREE, depletion in HREE and a negative Eu anomaly suggest alteration of the parent magma for the talcose rock and plagioclase fractionation. The trends observed for the LILE, HFSE and REE suggest possible contamination or mixing of crustal and mantle materials during the formation of the protolith. Ni and Co concentrations are higher than average crustal values with implication for ultrabasic to basic magma composition for the komatiitic progenitor and also suggestive of possible mineralisation. Conclusion: Mineralogical examination has revealed a talc-chlorite-tremolite composition for the talcose rocks with peridotitic komatiite precursory while geochemical composition supported ultrabasic magmatism similar to those with the Ilesha schist belt.Keywords: Ila Orangun-Oyan; Talcose rocks; Hydrothermal alteration; Peridotitic Komatiite; Ilesha schist belt

The timing and processes of the Paleo-Asian Ocean (PAO) closure are still controversial issues due to ambiguous interpretation of the regional geological records. We describe the structural and kinematic features of two Permian greenschist-/blueschist-facies tectonic melanges at Zhurihe and Erdaojing in Inner Mongolia (northeastern China), separated by the Solonker Suture. The tectonic melanges have block-in-matrix fabrics. The Zhurihe tectonic melange in the south is dominated by NE-trending folds, and east–west- to NE-trending reverse/strike-slip faults, indicating a NW–SE compressive direction. Blocks in the Zhurihe melange include ophiolitic fragments (c. 292 Ma) and ocean island sequences (c. 274 Ma), which show E-MORB and OIB geochemical affinities, respectively. The matrix includes blueschist, greenschist, quartz schist and clastics, of which the blueschist yielded a zircon U–Pb age of c. 255 Ma, and is geochemically E-MORB-like. The Erdaojing melange north of the Solonker Suture is dominated by east–west-trending folds, and NE- and NW-trending reverse faults, indicating a north–south compressive orientation. The Erdaojing melange is composed of early Permian (c. 281 Ma) ophiolite blocks, and middle Permian (c. 266 Ma) actinolite schist and clastics as the matrix. The Erdaojing ophiolitic rocks are geochemically N-MORB tholeiitic. Our results define two parallel Permian MORB-type ophiolitic belts separated by the central Solonker Suture. These observations are evidence for the Permian divergent double subduction and Early Triassic soft-collision model for the PAO along the Solonker Suture. Supplementary material: Detailed analytical methods and results are available at: https://doi.org/10.6084/m9.figshare.c.5008910

Características geoquímicas e petrológicas de diques lamprófitos em Kalagalla intrudidas em rochas xistosas auríferas do cinturão de RamagiriPenakacherla, no distrito de Anantapur, Andhra Pradesh, Índia. O lamprófiro Kalagalla (KGL) é uma rocha melanocrática que exibe uma textura nodular típica na superfície. As micro-texturas e a mineralogia típica dos lamprófiros são obscurecidas pelo metamorfismo; no entanto, exibe textura porfirítica, nemato-granoblástica, representativa das fácies de xisto verde do metamorfismo. A rocha é cisalhada e possui vários glóbulos formados por agregados policristalinos de calcita (ocelli), envolvidas por plagioclásio coronítico sub-édrico e biotita, evidenciando sua origem manto-magmática. As assembleias minerais observadas em seções delgadas incluem anfibólio, plagioclásio, biotita, flogopita e calcita ocelli como essenciais, enquanto apatita, zircão, magnetita, ilmenita, calcopirita e pirita contendo Ni como fases acessórias. A investigação com SEM-EDS nos minerais acessórios revelou fases de sulfeto e silicato, como pirita livre de As, Ni-calcopirita hematitizada e minerais de Ni-As-Co indicativos de sulfetação associada aos veios auríferos de greenstones, além de silicatos como LREE-titanita parcialmente transformada em fases como leucoxeno e óxido como magnetita alterada para goethita em alguns locais. Com base na química mineral, geoquímica de rocha total, presença de anfibólio e dominância da plagioclásio, o KGL é classificada como uma variedade cálcio-alcalina em geral e como espessartita em particular, com afinidade shoshonítica. Nenhuma composição química anômala é observada na calcita ocelar. A titanita contendo LREE parece ser responsável pelo enriquecimento de LREE. O alto Mg # (77-79), Ni (153-162 ppm) e Cr (380-470 ppm) dão suporte a uma fonte mantélica. A ausência de anomalia de Eu reflete a falta de fracionamento do plagioclásio. A alta relação Zr / Hf (163-202) indica ausência de contaminação crustal e contribuição de carbonato magmático na fonte para formar ocelos como produto da imiscibilidade tardia de líquido silicato-carbonato líquido no mecanismo de segregação. Os padrões de traços e de REE (ƩREE: 326-343 ppm, LREE> HREE) indicam envolvimento de granada residual na fonte presumivelmente enriquecida em flogopita em um ambiente "relacionado à subducção". Geochemical and petrological characteristics of lamprophyre dykes at Kalagalla intruded into the auriferous schistose rocks of the RamagiriPenakacherla Schist Belt, Anantapur district, Andhra Pradesh, India are presented here. The Kalagalla lamprophyre (KGL) is a melanocratic rock exhibiting typical knobby or pustular texture on the surface. The microtextures and mineralogy typical of lamprophyres are obscured by metamorphism; however, it exhibits porphyritic, nemato-granoblastic texture representative of greenschist facies of metamorphism. The rock is sheared and possesses several globules formed by polycrystalline aggregates of calcite rimmed by coronitic subhedral plagioclase and biotite, evidencing its mantle-magmatic origin. The mineral assemblages noticed in thin-sections include amphibole, plagioclase, biotite, phlogopite and calcite ocelli as essential while apatite, zircon, magnetite, ilmenite, Ni-bearing chalcopyrite and pyrite as accessory phases. The SEM-EDS investigation on the accessory minerals revealed accessory sulphide and silicate phases like As-free pyrite, haematitised Ni-bearing chalcopyrite and Ni-As-Co- minerals indicative of sulphidation associated with greenstone auriferous lodes, along with silicates like LREE-bearing titanite partially transformed into leucoxene and oxide phases like magnetite altered to goethite at places. Based on mineral chemistry, whole rock geochemistry, presence of amphibole and dominance of plagioclase, the KGL is classified as a calc-alkaline variety in general and as spessartite in particular possessing shoshonitic affinity. No anomalous chemical composition is noticed in the ocellar calcite. The LREE-bearing titanite appears to be the contributor of LREE enrichment. The high Mg# (77- 79), Ni (153-162 ppm) and Cr (380-470 ppm) support a mantle source. The absence of Eu anomaly reflects lack of plagioclase fractionation. The high Zr/Hf ratio (163-202) indicates absence of crustal contamination and contribution of magmatic carbonate at the source to form ocelli as product of late-stage liquid silicate-carbonate immiscibility of segregation mechanism. The trace and REE patterns (ƩREE: 326-343 ppm, LREE>HREE) indicate involvement of residual garnet at the source presumably enriched in phlogopite in a ‘subduction-related’ environment. Fil: Pothuri, Rameshchandra Phani. Cyient Limited Hyderabad; India Fil: Lira, Raul. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Museo de Mineralogía y Geología "Dr. A. Stelzner"; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina Fil: Espeche, María José. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Museo de Mineralogía y Geología "Dr. A. Stelzner"; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina Fil: Rokalla, Ananda Reddy. Geological Survey of India; India

The results of 40Ar/39Ar dating of pseudotachylytes, first identified in the Paleoproterozoic zonally metamorphosed (greenschist to granulite facies) Ladoga complex of svecofennides, are presented. A wide age range of the formation of pseudotachylytes in the Riphean (1.59–1.31 Ga), presumably caused by the exhumation of deep rocks during the Svecofennian tectonogenesis and the subsequent orogenesis and riftogenesis in southeastern Fennoscandia, has been established.