Search

We measured the 14C age of pre-bomb suspension-feeding bivalves of known-age from coastal West Africa (n = 30) across a latitudinal transect extending from 33° N to 15° S. The specimens are from the collections of the Muséum National d’Histoire Naturelle (Paris, France). They were carefully chosen to ensure that the specimens were alive when collected or died not long before collection. From the 14C-dating of these know-age bivalves, we calculated the marine reservoir age (as ΔR and R values) for each specimen. ΔR values were calculated relative to the Marine20 calibration curve and the R values relative to Intcal20 or SHcal20 calibration curves. Except five outliers, the ΔR and R values were quite homogenous to a mean value of −77 ± 47 14C yrs (1sd, n = 25), and of 400 ± 59 14C yrs (1sd, n = 25), respectively. These values are typical of low latitude marine reservoir age values. Five suspension-feeding species living in five different ecological habitats were studied. For localities were different species were available, the results yielded similar results whatever the specie considered suggesting that the habitat has only a limited impact on the marine reservoir age reconstruction. We show that our measured marine reservoir ages follow the declining trend of the global marine reservoir age starting ca. 1900 AD, suggesting that marine reservoir age of coastal West Africa is driven, at least at first order, by the global carbon cycle and climate rather than by local effects. Each outlier was discussed. Sub-fossil specimens likely explain the older 14C age and thus larger marine reservoir age measured for these samples. Bucardium ringens might not a best choice for marine reservoir age reconstructions.

Sedimentary rocks can release carbon dioxide (CO2) during the weathering of rock organic carbon and sulfide minerals. This sedimentary carbon could act as a feedback on Earth’s climate over millennial to geological timescales, yet the environmental controls on the CO2 release from rocks are poorly constrained. Here, we directly measure CO2 flux from weathering of sedimentary rocks over 2.5 years at the Draix-Bleone Critical Zone Observatory, France. Total CO2 fluxes approached values reported for soil respiration, with radiocarbon analysis confirming the CO2 source from rock organic carbon and carbonate. The measured CO2 fluxes varied seasonally, with summer fluxes five times larger than winter fluxes, and were positively correlated with temperature. The CO2 release from rock organic carbon oxidation increased by a factor of 2.2 when temperature increased by 10 °C. This temperature sensitivity is similar to that of degradation of recent-plant-derived organic matter in soils. Our flux measurements identify sedimentary-rock weathering as a positive feedback to warming, which may have operated throughout Earth’s history to force the surface carbon cycle. The release of carbon dioxide during oxidative weathering of sedimentary rocks acts as a positive feedback to warming, according to 2.5 years of CO2 flux measurements from the Draix-Bleone Critical Zone Observatory, France.

Quantifying the local marine reservoir age (ΔR) and its change over time is critical for precise radiocarbon calibration of marine samples and for the study of the ocean carbon cycle. ΔR values are scarce for the African coast facing the Indian Ocean, and the few values available were obtained from pre-bomb shells collected during the 19th century. Here, the ΔR value for calibrated year 1110 ± 25 (1σ) CE was reconstructed from radiocarbon dating and Bayesian analysis of marine and terrestrial materials coexisting in a tsunami deposit discovered in Pangani Bay (Tanzania, western Indian Ocean coast). The reconstructed ΔR of –8 ± 40 (1σ, n = 3) is similar to pre-bomb regional estimates and provides new information to investigate regional ΔR change over time. The Bayesian analysis of the dated samples revises the age of the tsunami event found in Pangani Bay to 1064–1157 cal CE (95.4% confidence level) or 1110 ± 25 (1σ) cal CE, about one century younger compared to the previous estimate. Our results indicate that the new ΔR value and the proposed calibration approach can be used to refine existing chronologies in the region, with implications for paleo-environmental reconstructions and archaeological studies of Early Swahili societies.

Deforestation of steep mountain forests can result in a large increase in physical erosion rates. A growing body of work has highlighted that erosion may set the pace of oxidative weathering of sulfide minerals, which results in the production of sulfuric acid and can release CO2 from carbonate minerals in rocks to the atmosphere. However, the role of land use change on this CO2 release pathway has not been assessed, primarily due to the lack of measurements to isolate this driver over other potential environmental controls (e.g. temperature, hydrology). Here we study the stream water chemistry of two marl-dominated catchments, the Laval (0.86 km2) and the Brusquet (1.07 km2), in the Draix-Bléone Critical Zone Observatory, Provence, France. The Laval has very high rates of physical erosion (sediment yields of 8,700 t km-2yr-1 and 15,800 t km-2yr-1 in 2016-2017 and 2017-2018, respectively) that result from the combination of deforestation, bare rock surfaces, weak rocks and the hydroclimatic setting. In contrast, the Brusquet catchment was reforested at the end of the 19th Century and has much lower present day sediment yields (45 t km-2 yr-1 and 492 t km-2 yr-1 in 2016-2017 and 2017-2018, respectively).We collected samples from every storm event and during flow over two water years in each catchment. We measure the major ions and the sulfur and oxygen isotopic composition of dissolved sulfate (SO4). In both catchments cation partitioning shows a dominance of carbonate (>70%) over silicate weathering. The stable sulfur isotopic signature suggests sulfide oxidation is the dominant source of sulfate in these catchments. Examination of dissolved ion rations (HCO3/∑Cat+, SO4//∑Cat+) shows that sulfuric acid governs mineral dissolution, rather than carbonic acid, accounting for 90±6% and 63±9% in the Laval and Brusquet, respectively.In the highly erosive Laval catchment, the estimated CO2 release from sulfide oxidation coupled to carbonate weathering was very high, at 22.1±7.1 tC km-2 yr-1. We also find evidence for seasonal changes in sulfate flux which suggest that the rates are moderated by changes in air temperature, with elevated sulfide oxidation rates in summer. These observations support independent measurements in the shallow weathering zone of the Laval catchment, that shows an increase in CO2 release from sulfide oxidation with temperature. In marked contrast, the CO2 release estimated in the reforested Brusquet catchment is 4 to 5 x lower (at 4.6±0.8 tC km-2 yr-1) and the fluxes are not seasonally moderated (i.e. not temperature controlled). We suggest this relates to changes in the supply of mineral surfaces to the shallow, oxygenated weathering zone. Reforestation could result in a marked decrease in the release of carbon from rock to the atmosphere in areas where sulfide and carbonate minerals outrcop, and make the resultant fluxes less sensitive to changing climate.

International audience; The upper branch of the Atlantic meridional overturning circulation (AMOC) plays a critical role in ocean circulation and climate change, yet its variability during the last glacial period is poorly documented. Here, we investigate the northward-flowing Glacial Eastern Boundary Current (GEBC) in the North Atlantic, known today as the European Slope Current, and representing the easternmost portion of the upper branch of the AMOC. Based on flow speed and isotopic records, we show that Dansgaard-Oeschger (D-O) interstadials (stadials) correspond to a faster (weaker) GEBC during the ∼50–15 ka period. This, by analogy to present-day conditions, suggests enhanced (reduced) strength of the subpolar gyre and, by extension, of northern-sourced water production and AMOC during D-O interstadials (stadials). Concomitant fluctuations of both the GEBC and the European Ice Sheet between ∼30 and 17 ka suggest an active role of the upper branch of AMOC in the poleward transport of heat and freshwater to the northern North Atlantic, with direct impacts on deep water formation and AMOC strength. We explore these ice-sheet—AMOC interactions and the associated abrupt climate changes over the last glacial period and the last deglaciation.

Yanchilina et al. (2017) describe a sequence of hydrological events that led to the abrupt submergence of the Black Sea shelf by Mediterranean waters. A key aspect of the study is an attempt to provide a reliable calendar chronological framework to interpret their set of geophysical and geochemical data. However, the approach used to build the calendar age framework suffers a fundamental methodological flaw. In addition, the reservoir age offsets appear to be miscalculated based on the data provided. Both observations cast doubt on the robustness of some of the conclusions drawn by Yanchilina et al. (2017).

Offshore archives retrieved from marine/lacustrine environments receiving sediment from large river systems are valuable Quaternary continental records. In the present study, we reconstruct the Danube River activity at the end of the last glacial period based on sedimentological, mineralogical and geochemical analyses performed on long-piston cores from the north-west Black Sea margin. Our data suggest that the Danube River produced hyperpycnal floods throughout the ca. 33-17 ka period. Four main periods of enhanced Danube flood frequency, each of 1.5-3 kyr duration, are recorded at ca. 32.5 30.5 ka (equivalent to the first part of Heinrich Stadial HS 3), at ca. 29-27.5 ka (equivalent to Greenland Stadial 4), at ca. 25.3-23.8 ka (equivalent to HS 2) and at ca. 22.3-19 ka. Based on mineralogical and geochemical data, we relate these events to enhanced surface melting of the Alpine Ice Sheet (AIS) that covered -50,000 km2 of the Danube watershed at the Last Glacial Maximum (LGM). Our results suggest that (i) the AIS growth from the inner Alps to its LGM position in the northern Alpine foreland started from ca. 30.5 ka, ended no later than ca. 25.3 ka, and was interrupted by a melting episode ca. 29 27.5 ka; (ii) the AIS volume drastically decreased from ca. 22.3 to 19 ka, as soon as summer insolation energy at the AIS latitude increased; and (iii) HSs strongly impacted the AIS mass balance through enhanced summer surface melt. This, together with evidence of severely cool winters and the rapid expansion of sea ice in the North Atlantic, implies strong seasonality in continental Europe during stadials. (C) 2019 Elsevier Ltd. All rights reserved.

We estimate the blank carbon mass over the course of a typical Ramped PyrOx (RPO) analysis (150–1000°C; 5°C×min–1) to be (3.7±0.6) μg C with an Fm value of 0.555±0.042 and a δ13C value of (–29.0±0.1) ‰ VPDB. Additionally, we provide equations for RPO Fm and δ13C blank corrections, including associated error propagation. By comparing RPO mass-weighted mean and independently measured bulk δ13C values for a compilation of environmental samples and standard reference materials (SRMs), we observe a small yet consistent 13C depletion within the RPO instrument (mean–bulk: μ=–0.8‰; ±1σ=0.9‰; n=66). In contrast, because they are fractionation-corrected by definition, mass-weighted mean Fm values accurately match bulk measurements (mean–bulk: μ=0.005; ±1σ=0.014; n=36). Lastly, we show there exists no significant intra-sample δ13C variability across carbonate SRM peaks, indicating minimal mass-dependent kinetic isotope fractionation during RPO analysis. These data are best explained by a difference in activation energy between 13C- and 12C-containing compounds (13–12∆E) of 0.3–1.8 J×mol–1, indicating that blank and mass-balance corrected RPO δ13C values accurately retain carbon source isotope signals to within 1–2‰.

Constraining radiocarbon (14C) reservoir age offsets is critical to deriving accurate calendar-age chronologies from 14C dating of materials which did not draw carbon directly from the atmosphere. The application of 14C dating to such materials is severely limited in hydrologically sensitive environments like the Black Sea because of the difficulty to quantify reservoir age offsets, which can vary quickly and significantly through time, due to the dynamics of the biogeochemical cycling of carbon. Here we reconstruct 14C reservoir age offsets (Rshell-atm) of Holocene bivalve shells from the coastal Black Sea relatively to their contemporaneous atmosphere. We show that the 14C reservoir age offset and the stable carbon isotope composition of bivalve shells are linearly correlated in this region. From a biogeochemical standpoint, this suggests that inorganic stable carbon isotope and 14C compositions of Black Sea coastal waters are controlled by the balance between autochthonous primary productivity and heterotrophic respiration of allochthonous pre-aged terrestrial organic matter supplied by rivers. This provided an important implication for Black Sea geochronology as the reservoir age offset of 14C-dated bivalve shell can be inferred from its stable carbon isotope composition. Our results provide a fundamental and inexpensive geochemical tool which will considerably improve the accuracy of Holocene calendar age chronologies in the Black Sea.

Reconstructing Northern Hemisphere ice-sheet oscillations and meltwater routing to the ocean is important to better understand the mechanisms behind abrupt climate changes. To date, research efforts have mainly focused on the North American (Laurentide) ice-sheets (LIS), leaving the potential role of the European Ice Sheet (EIS), and of the Scandinavian ice-sheet (SIS) in particular, largely unexplored. Using neodymium isotopes in detrital sediments deposited off the Channel River, we provide a continuous and well-dated record for the evolution of the EIS southern margin through the end of the last glacial period and during the deglaciation. Our results reveal that the evolution of EIS margins was accompanied with substantial ice recession (especially of the SIS) and simultaneous release of meltwater to the North Atlantic. These events occurred both in the course of the EIS to its LGM position (i.e., during Heinrich Stadial –HS– 3 and HS2; ∼31–29 ka and ∼26–23 ka, respectively) and during the deglaciation (i.e., at ∼22 ka, ∼20–19 ka and from 18.2 ± 0.2 to 16.7 ± 0.2 ka that corresponds to the first part of HS1). The deglaciation was discontinuous in character, and similar in timing to that of the southern LIS margin, with moderate ice-sheet retreat (from 22.5 ± 0.2 ka in the Baltic lowlands) as soon as the northern summer insolation increase (from ∼23 ka) and an acceleration of the margin retreat thereafter (from ∼20 ka). Importantly, our results show that EIS retreat events and release of meltwater to the North Atlantic during the deglaciation coincide with AMOC destabilisation and interhemispheric climate changes. They thus suggest that the EIS, together with the LIS, could have played a critical role in the climatic reorganization that accompanied the last deglaciation. Finally, our data suggest that meltwater discharges to the North Atlantic produced by large-scale recession of continental parts of Northern Hemisphere ice sheets during HS, could have been a possible source for the oceanic perturbations (i.e., AMOC shutdown) responsible for the marine-based ice stream purge cycle, or so-called HE's, that punctuate the last glacial period.

Reservoir 14C age offsets are invaluable tracers for past changes in carbon cycle and oceanic circulation. Reconstruction of reservoir age offsets with time is also required for calibration purposes (reconstruction of atmospheric calibration curve, calibration of non-atmospheric radiocarbon ages). Thus, properly propagating the various uncertainties linked to reservoir age offset is important for proper interpretation. However, approaches for reservoir age offset calculation – especially when considering pairs of reservoir-derived 14C and calendar ages – are usually not detailed and inadequate for proper propagation of uncertainties. Here, the various ways to properly calculate reservoir age offsets are described with a focus on a new approach when considering pairs of 14C and calendar ages. This approach maps the calendar age distribution onto the 14C time scale prior to reservoir age offset calculation – the “uncalibration-convolution process”. R codes computing reservoir age offsets based on available data are presented. Finally, a case study focusing on the reconstruction of the speleothem-atmosphere 14C age offsets of speleothem 14C data used in the latest release of the atmospheric calibration curve is discussed.

Oxidative weathering of sedimentary rocks can release carbon dioxide ( CO2 ) to the atmosphere and is an important natural CO2 emission. Two mechanisms operate – the oxidation of sedimentary organic matter and the dissolution of carbonate minerals by sulfuric acid. It has proved difficult to directly measure the rates at which CO2 is emitted in response to these weathering processes in the field, with previous work generally using methods which track the dissolved products of these reactions in rivers. Here we design a chamber method to measure CO2 production during the oxidative weathering of shale bedrock, which can be applied in erosive environments where rocks are exposed frequently to the atmosphere. The chamber is drilled directly into the rock face and has a high surface-area-to-volume ratio which benefits measurement of CO2 fluxes. It is a relatively low-cost method and provides a long-lived chamber (several months or more). To partition the measured CO2 fluxes and the source of CO2 , we use zeolite molecular sieves to trap CO2 “actively” (over several hours) or “passively” (over a period of months). The approaches produce comparable results, with the trapped CO2 having a radiocarbon activity (fraction modern, Fm) ranging from Fm = 0.05 to Fm = 0.06 and demonstrating relatively little contamination from local atmospheric CO2 (Fm = 1.01). We use stable carbon isotopes of the trapped CO2 to partition between an organic and inorganic carbon source. The measured fluxes of rock-derived organic matter oxidation (171 ± 5 mgC m −2 day −1) and carbonate dissolution by sulfuric acid ( 534±16 mgC m −2 day −1) from a single chamber were high when compared to the annual flux estimates derived from using dissolved river chemistry in rivers around the world. The high oxidative weathering fluxes are consistent with the high erosion rate of the study region. We propose that our in situ method has the potential to be more widely deployed to directly measure CO2 fluxes during the oxidative weathering of sedimentary rocks, allowing for the spatial and temporal variability in these fluxes to be determined.

International audience; Using benthic foraminiferal-based proxies in sediments from the Celtic margin, we provide a well-dated record across the last deglaciation of the Channel River dynamics and its potential impact on the hydrology of intermediate water masses along the European margin. Our results describe three main periods: 1) During the Last Glacial Maximum, and before ∼21 ka BP, the predominance of meso-oligotrophic species suggests well oxygenated water masses. After ∼21 ka BP, increasing proportions of eutrophic species related to enhanced riverine supply occurs concomitantly with early warming in Greenland air-temperatures; 2) A thick laminated deposit, occurring during a 1500-years long period of seasonal melting of the European Ice Sheet (EIS), is associated with early Heinrich Stadial 1 period (∼18.2–16.7 ka BP). The benthic proxies describe low salinity episodes, cold temperatures, severe dysoxia and eutrophic conditions on the sea floor, perhaps evidence for cascading of turbid meltwaters; 3) During late HS1 (∼16.7–14.7 ka BP), conditions on the Celtic margin's seafloor changed drastically and faunas indicate oligotrophic conditions as a result of the ceasing of EIS meltwater discharges. While surface waters were cold due to Laurentide Ice Sheet (LIS) icebergs releases, increasing benthic Mg/Ca ratios reveal a progressive warming of intermediate water masses whereas oxygen proxies indicate overall well oxygenated conditions. In addition to the well known effect of EIS meltwaters on surface waters in the Celtic margin, our benthic record documents a pronounced impact on intermediate water depths during HS1, which coincided with major AMOC disruptions.

Continental ice sheets are a key component of the Earth’s climate system, but their internal dynamics need to be further studied. Since the last deglaciation, the northern Eurasian Fennoscandian Ice Sheet (FIS) has been connected to the Black Sea (BS) watershed, making this basin a suitable location to investigate former ice-sheet dynamics. Here, from a core retrieved in the BS, we combine the use of neodymium isotopes, high-resolution elemental analysis, and biomarkers to trace changes in sediment provenance and river runoff. We reveal cyclic releases of meltwater originating from Lake Disna, a proglacial lake linked to the FIS during Heinrich Stadial 1. Regional interactions within the climate–lake–FIS system, linked to changes in the availability of subglacial water, led to abrupt drainage cycles of the FIS into the BS watershed. This phenomenon raised the BS water level by ∼100 m until the sill of the Bosphorus Strait was reached, flooding the vast northwestern BS shelf and deeply affecting the hydrology and circulation of the BS and, probably, of the Marmara and Aegean Seas.

Chronologies of sediments that document the last glacial history of the Black Sea "Lake" are hampered by issues relating to reservoir age. Regulated by basin hydrology, reservoir ages represent a tool that could potentially be used to better understand the response of Black Sea "Lake" hydrology to climate change. Therefore, deciphering reservoir age evolution is crucial both for better constraining the basin chronological framework and for providing new insights into our understanding of Black Sea "Lake" hydrology. By tuning a meaningful new high-resolution geochemical dataset (obtained from core MD04-2790) to a climate reference record, here, we propose a reliable chronology spanning the last 32 kyr BP. The chronology is compared to a large AMS radiocarbon dataset (n = 51). Pairs of calendar and radiocarbon ages allowed us to compute reservoir ages, and to, then, reconstruct a high-resolution quantitative reservoir age record for the last glacial history of the Black Sea "Lake". The main factor controlling reservoir ages in lakes is the Hard Water Effect (HWE), which is regulated by basin hydrology. Therefore, changes in the reconstructed reservoir age record have been qualitatively interpreted in terms of the hydrologic responses of the Black Sea "Lake" to climate change. Our results allowed us to determine periods of complete isolation or outflow for the Black Sea "Lake". During Heinrich Event 2 (HE2) and during the Last Glacial Maximum (LGM) the basin was strictly isolated, whereas prior to HE2 and during HE1 it outflowed into the Marmara Sea. Following the onset of the Bralling-Allerod, factors other than the HWE are thought to have influenced the reservoir age, preventing conclusive interpretations. We also determined an undocumented, to date, phase of Black Sea "Lake" stratification during the full glacial (HE2 and LGM). Our results indicate that reservoir age is a powerful tool for investigating and better understanding past hydrologic changes in lakes and inland seas. (C) 2011 Elsevier B.V. All rights reserved.

During the last decade, a debate arose regarding the timing and pattern of the last reconnection of the Black Sea "Lake" with the global ocean. On a geochemical basis, the radiocarbon age of Black Sea "Lake" surface water, during the time of reconnection, was determined to be similar to 8400 C-14 a. BP. Despite the potential bias induced by the hard water effect in lakes, the reconnection age was calibrated without any reservoir age correction, which led to an estimate of similar to 9400 cal a. BR Since knowledge for the actual calendar age has important hydrologic implications that would provide new insights regarding the mechanism of reconnection, determining the actual calendar age for the last reconnection remains important. Based upon modeling experiments and micropaleontological reconstructions, the Black Sea "Lake" reconnection occurred in two steps, as follows: 1) Initial Marine Inflow (IMI) followed by 2) a period of increasing basin salinity that led to the Disappearance of Lacustrine Species (DLS). In order to better define the actual calendar age for the last reconnection, a review of the sedimentary expressions of the IMI and DLS boundaries was performed in order to correlate them throughout the Black Sea sedimentary environments. This correlation reconciles the apparent inconsistency in the published radiocarbon dataset, and provides the atmospheric radiocarbon age of the last reconnection, which represents the reference for reservoir age calculations and which can be directly calibrated. We determine reservoir ages for the water column, as well as the reconnection calendar age to be similar to 9000 cal a. BP. At the reconnection with the global ocean, Black Sea "Lake" reservoir ages were non-negligible and water-depth-dependent, consistent with a weak water column stratification during the Early Holocene. The calibrated age of Initial Marine Inflow (9000 cal a. BP) implies that the former Bosphorus sill was shallower by similar to 10 m than is commonly assumed in the literature. Compared to the sedimentary context of the Sakarya coastal plain, this result suggests that the level of the isolated Black Sea was below the former Bosphorus sill depth at the time of the last reconnection. Furthermore, a lag of 900 yr between Initial Marine Inflow and the Disappearance of Lacustrine Species indicates that approximately ten centuries were needed to establish the currently observed two-way flow exchange with the global ocean. (C) 2011 Elsevier Ltd. All rights reserved.

Chloride and delta O-18 compositions of interstitial water extracted from a long sediment core retrieved from the NW coast of the Black Sea allowed us to constrain the main hydrologic changes of the Back Sea during the Late Pleistocene and Holocene. Prior to its reconnection with the Mediterranean Sea (through the Marmara Sea) at approximately 9000 calendar yr before present (9 ka cal BP), the Black Sea has evolved as a fresh to brackish water lake. At the time of reconnection, hydrologic changes were drastic. Bottom water salinities changed from a few psu (practical salinity unit) to similar to 22 psu. Since solutes in the interstitial water column within sediments are advected and diffused the measured concentrations do not reflect those of past bottom waters. In order to reconstruct these former concentrations, we used an advection/diffusion model. Different scenarios of bottom water chloride and delta O-18 variations were accounted for in this model in order to simulate "present day" vertical profiles for concentrations of interstitial water in order to compare them to measured ones. The comparison suggests that the glacial Black Sea was a homogeneous freshwater lake (with a delta O-18 of similar to - 10 parts per thousand M. and a salinity of similar to 1 psu). Modem hydrologic conditions would only have been reached at similar to 2 ka cal BP, concomitant with the onset of coccolith-rich thin layers that characterize modern basin sediments. Such delayed salinization (over similar to 7000 yr) in the basin may have been due to higher precipitation during the early Holocene. We also simulated the impact of a catastrophic reconnection and a smoother reconnection. Both salinity scenarios lead to undistinguishable modelled "present day" profiles, indicating that the precise impact of the last reconnection was lost due to the advection/diffusion processes. (C) 2010 Elsevier B.V. All rights reserved.

The combined use of Lu-Hf and Sm-Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf-Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (epsilon(Nd)similar to - 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by epsilon(Hf) values (from -1.1 to +13) far more radiogenic than associated sediments (from -7.1 to -12.0) and turbidite sands (from -27.2 to -31.6). epsilon(Hf) values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between epsilon(Hf) of secondary clay minerals and chemical weathering intensity. These results combined with data from the literature have global implications for understanding the Hf-Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the 'seawater array' (i.e. the correlation defined by deep-sea Fe-Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the,seawater array', which we refer to as the 'zircon-free sediment array' (epsilon(Hf)=0-91 epsilon(Nd)+3.10). Finally, we show that the Hf-Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (epsilon(Hf)= 1.80 epsilon(Nd)+2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust. (C) 2008 Elsevier B.V. All rights reserved.

African pollen data have been used in many empirical or quantitative palaeoenvironmental reconstructions. However, the pollen types used in these studies were not controlled and standardised, preventing the precise understanding of pollen–plant and pollen–climate relation that is necessary for the accurate quantification of continental scale climate change or ecological processes in the past. This paper presents a summary of the progress made with the African Pollen Database (APD) inventory of plant diversity from pollen data extracted from 276 fossil sites and more than 1500 modern samples, with a focus on tropical tree pollen types. This inventory (1145 taxa) gives, for each pollen taxon whose nomenclature is discussed, information on the habit, habitat and phytogeographical distribution of the plants they come from. Special attention has been paid to pollen types with similar morphology, which include several plant species or genera, whose biological or environmental parameters can differ considerably.

Il y a environ 21 000 ans, la géographie de l’Europe était bien différente de celle d’aujourd’hui. Une véritable montagne de glace, la calotte fennoscandienne, recouvrait toute l’Europe du Nord depuis les îles britanniques jusqu’à la Sibérie. Le niveau des océans était alors plus bas de 120 mètres. Un fleuve géant, le fleuve Manche, coulait sur une plaine entre la France et l’Angleterre. En Europe centrale, la mer Noire n’était pas connectée à la mer Méditerranée et formait un grand lac dont ...

Reservoir age offsets are widely used to correct marine and speleothem radiocarbon age measurements for various calibration purposes. They also serve as a powerful tracer for carbon cycle dynamics. However, a clear terminology regarding reservoir age offsets is lacking, sometimes leading to miscalculations. This note seeks to provide consistent conventions for reporting reservoir 14C disequilibria useful to a broad range of environmental sciences. This contribution introduces the F14R and δ14R metrics to express the relative 14C disequilibrium between two contemporaneous reservoirs and the R metric as the associated reservoir age offset.