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32. Effect of the structure of macromonomer in polycarboxylate superplasticizer on slump-retention of concrete.

Author

Pang, Jianjun, Guo, Jintang, Li, Wenke, and Chang, Qinglu

Subjects
*CONCRETE mixing, *CONCRETE, *STERIC hindrance, *CONCRETE additives, *POLYMERS, *MACROMONOMERS, *CEMENT mixing, *AQUEOUS solutions
Abstract

Three kinds of slump-retention polycarboxylate superplasticizers(52HPC4, 52IPC4, and 52EPC4) were synthesized by using HPEG, IPEG, or EPEG as macromonomers. The effects of polycarboxylate superplasticizers on the slump-retention of cement and concrete were investigated. The mechanism of action was explained by the composition of PCE polymers and monomer sequences (EHE, HHE, or HHH), which were investigated by using conductivity, GPC, 1H-NMR, and 13C-NMR. The results indicated that the slump flow of cement paste mixed with 52EPC4 was increased quickly within 120 min, while 52IPC4 doesn't change within 240 min. Concrete mixed with 52IPC4 had the best slump-retention performance reaching 440 mm after 150 min, but concrete mixed with 52HPC4 was almost no fluidity after 120 min which had the largest slump flow loss through time than that containing other PCEs, and the conductivity of 52IPC4 aqueous solution decreased more slowly than other PCEs. Because of the highest content of effective PCE polymers, and the largest steric hindrance to ester bond resulting in the concrete had the best slump-retention performance when mixed with 52IPC4, because of the smallest steric hindrance to ester bond resulting in the fastest increase spread flow of cement paste which mixed 52EPC4, because of the highest content of low molecular polymers and the lowest content of effective PCE polymers in 52HPC4 resulting in the smallest initial slump flow of concrete, and the largest slump flow loss through time of concrete, even though the steric hindrance effect was larger than 52EPC4. [ABSTRACT FROM AUTHOR]

Published
2024
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33. Defoaming and Toughening Effects of Highly Dispersed Graphene Oxide Modified by Amphoteric Polycarboxylate Superplasticizer on Oil Well Cement.

Author

Zeng, Min, Xing, Yubing, Xie, Yongxu, Xu, Dawei, Miao, Xia, and Guo, Jintang

Subjects
OIL well cementing, GRAPHENE oxide, FOAM, POROSITY, CEMENT admixtures, ELECTROSTATIC interaction, COMPRESSIVE strength
Abstract

The aggregation of graphene oxide (GO) during the hydration process limits its wide application. Polymer superplasticizers have been used to improve the dispersion state of GO due to their adsorption and site-blocking effects, though the formation of a large amount of foam during the mixing process weakens the mechanical properties of cement. A highly dispersed amphoteric polycarboxylate superplasticizer-stabilized graphene oxide (APC/GO) toughening agent was prepared by electrostatic self-assembly. Results demonstrate that the APC/GO composite dispersed well in a cement pore solution due to the steric effect offered by the APC. Additionally, the well-dispersed GO acted as an antifoaming agent in the cement since GO nanosheets can be absorbed at the air–liquid interface of APC foam via electrostatic interactions and eliminate the air-entraining effect. The well-dispersed APC/GO sheets promoted cement hydration and further refined its pore structure owing to the nucleation effect. The flexural and compressive strength of the cement containing the APC/GO composite were enhanced by 21.51% and 18.58%, respectively, after a 7-day hydration process compared with a blank sample. The improved hydration degree, highly polymerized C-S-H gel, and refined pore structure provided enhanced mechanical properties. [ABSTRACT FROM AUTHOR]

Published
2024
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