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Direct current (DC) power transmission systems have received great attention because it can easily integrate many types of renewable energies and have low energy loss in long-distance and large-capacity power transmission for electricity global sharing. Nanoparticles (NPs) have a positive effect on the insulation properties of polymers, but weak interaction between NPs and polymer matrix greatly decreases the effort of NPs on the enhancement of insulation properties, and thereby limits its engineering application. In this work, grafting strategy was used to link the modified NPs and polymer matrix to improve their interactions. Silica NPs (SiO2-NPs) were modified by 3-(methacrylyloxy) propyl-trimethoxysilane (MPS) to introduce highly active groups on the SiO2-NPs surface, followed by the pre-irradiated linear low-density polyethylene (LLDPE) being easily grafted onto the MPS modified SiO2-NPs (MPS-SiO2-NPs) in the melt blending process to obtain LLDPE-g-MPS-SiO2-NPs nanocomposites. Fourier-transform infrared (FT-IR) spectrum and X-ray photoelectron spectroscopy (XPS) confirm the successful incorporation of MPS into SiO2-NPs. Transmission electron microscopy (TEM) verifies that the modified SiO2-NPs exhibits more uniform distribution. The rheology result shows that the interaction between MPS-SiO2-NPs and LLDPE significantly improves. More importantly, the LLDPE-g-MPS-SiO2-NPs nanocomposites displays superior DC breakdown strength to that fabricated by conventional modification methods. When the addition of MPS-SiO2-NPs is 0.1 wt%, the highest DC breakdown strength values of 525 kV/mm and 372 kV/mm are obtained at 30 °C and 70 °C, respectively, and high DC breakdown strength can be well maintained in a wide loading range of NPs. [ABSTRACT FROM AUTHOR]

Ag‐based nanocrystals have emerged as an important candidate for CO2 reduction reaction (CO2RR) owing to the increasing amount of CO2 in the atmosphere, which has shown a propensity to alleviate environmental problems and produce high value‐added chemicals. This paper reviews the surface and interface engineering of Ag‐based catalysts towards CO2RR, which involve in the morphology control, composition manipulation, and support effects. Various synthesis approaches are presented to discuss their influence on the size, crystal structure and morphology of Ag‐based catalysts, including pure Ag NPs, Ag‐based alloys, Ag/metal oxides composites as well as Ag/carbon materials. Next, the development of Ag‐based surface and interface engineering that is essential to accelerate the formation of CO and its further conversion to C1 or even multicarbon products is systematically discussed. Finally, we give a short conclusion, and perspectives on the rational design of Ag‐based catalysts based on surface and interface engineering will be discussed. [ABSTRACT FROM AUTHOR]

A heterogeneous particle catalyst (CuO-Fe2O3/CTS-ATP) was synthesized via injection molding and ultrasonic immersion method, which is fast and effective. The particle catalyst applied attapulgite (ATP) wrapped by chitosan (CTS) as support, which was loaded dual metal oxides CuO and Fe2O3 as active components. After a series of characterizations of catalysts, it was found that CuO and Fe2O3 were successfully and evenly loaded on the surface of the CTS-ATP support. The catalyst was used to degrade methylene blue (MB) and ciprofloxacin (CIP), and the experimental results showed that the degradation ratios of MB and CIP can reach 99.29% and 86.2%, respectively, in the optimal conditions. The degradation mechanism of as-prepared catalyst was analyzed according to its synthesis process and ∙OH production, and the double-cycle catalytic mechanism was proposed. The intermediate products of MB and CIP degradation were also identified by HPLC-MS, and the possible degradation pathways were put forward. [ABSTRACT FROM AUTHOR]