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The Ediacaran-Cambrian (E-C) transition period witnessed one of the most important environmental changes in Earth’s history. The western margin of the South China Block (SCB), a shallow-water environment, shows a complete sedimentary record of the E-C transition. Section surveys revealed that dolostone, microbial carbonate, chert, and phosphorite predominantly compose the lithologies of the western margin of the SCB during the E-C transition. Petrological analysis indicates that microbial carbonates in this region exhibit stromatolitic, thrombolytic, cavitated, and sporadic microbial structures. Microbial carbonates with stromatolitic, thrombolytic/cavitated, and sporadic structures correspond to strong, moderate, and weak hydrodynamic conditions, respectively. Microcrystalline dolomites crystallize during the syngenesis stage, while meso- to macrocrystalline and sparry dolomites develop during the burial diagenesis stage. Analysis of major elements and rare earth elements anomalies (δCe: 0.580 ~ 0.753; δEu: 1.234 ~ 1.433) suggests that the siliceous component originates from hot-water sources and is transported into shallow-water environments by upwelling. The absence of a δEu anomaly and the morphology of peloids indicate that the phosphatic component is primarily influenced by biological activity and upwelling. During the Tongwan Movement (545–535 Ma) in the E-C transition period, cyclical upwelling transported increased amounts of deep-source materials into shallow platform waters, leading to higher concentrations of siliceous components and widespread microbial mortality. Following the widespread microbial mortality, the phosphatic component became enriched in deep-water environments. Subsequently, the upwelling transported siliceous- and phosphatic-rich fluids back into the shallow-water environments. The phosphatic component was ultimately assimilated by small shelly fauna and deposited in the phosphatic-rich strata of the early Cambrian period. This study elucidates the origins of complex lithological compositions and the sedimentary evolution model in shallow water environments of the E-C transition period in western SCB, offering evidence for global environmental changes during this period. [ABSTRACT FROM AUTHOR]

• Authigenic Mg-clays are widely found in the Ediacaran Doushantuo Formation. • The Doushantuo Formation experienced an expansive restricted, evaporitic environment. • Petrography work with novel SEM-EDS technique can help to distinguish clay origins. • Clay mineralogy can be used as environment indicators in the Earth System science. The carbonate-rich shelf facies of the Ediacaran Doushantuo Formation (South China) have produced a broad array of microfossil and isotope proxy records which underpin much of our understanding of environmental change and biospheric evolution during this key time period. Recent reports of locally abundant authigenic, Mg-rich saponite clay in the Yangtze Gorges Area hint at potentially widespread evaporitic conditions in a lagoonal setting. Despite the implications for interpretation of proxy records and the environmental setting of early metazoans, the spatiotemporal extent of restricted, evaporitic conditions across the Yangtze Block remains largely unexplored. Here we use mineralogical and petrographic techniques to document the spatial and stratigraphic distribution of authigenic clay minerals across seven sites, representing a transect from shallow proximal shelf to deep basinal settings. Our results demonstrate the widespread and persistent occurrence of authigenic saponite in proximal shelf settings, whereas talc is identified at more distal shelf sites, consistent with Mg-clay authigenesis in an evaporitic lagoon with spatially variable detrital aluminosilicate input. Slope and basinal sites contain no Mg-clays and are instead characterized by abundant authigenic illite, consistent with an open marine setting. Stratigraphically, illite was found in the basal cap carbonate and uppermost Doushantuo Formation, with Mg-clays only present in the interval in-between, suggesting gradual development of an extensive carbonate rimmed lagoon over the Yangtze shelf that restricted seawater exchange, followed by stronger marine influence due to erosion of the carbonate rim and subsequent marine transgression. We conclude that restricted, evaporitic conditions were much more expansive than previously assumed, potentially providing favorable conditions for the Doushantuo Biota. Further, the widespread presence of authigenic clays across the shelf supports the case for enhanced reverse weathering before the advent of biosilicification. [ABSTRACT FROM AUTHOR]

The 5th-generation (5G) mobile networks and beyond need to support massive machine-type communications (MTC) devices with limited available radio resources. In this paper, we study the power-domain non-orthogonal multiple access (NOMA) technology to support energy-efficient massive MTC networks, where MTC devices exchange information using sporadic and low-rate short packets. We investigate the subchannel allocation and power control policy to maximize the achievable effective energy efficiency (EE) for uplink NOMA-based massive MTC networks, taking into account of short-packet communication characteristics. We model the subchannel allocation problem as a multi-agent Markov decision process and propose an efficient Q-learning algorithm to solve it. Furthermore, we obtain the optimal transmission power policy by approximating the achievable effective rate of uplink NOMA-based short packet communications. Compared with the existing OFDMA scheme, simulations validate that the proposed scheme can improve the achievable effective EE of massive MTC networks with 5.93%. [ABSTRACT FROM AUTHOR]

Two semi-alicyclic thermoplastic polyimides (PI) have been prepared from stereoisomeric hydrogenated pyromellitic dianhydrides, including 1S,2R,4S,5R-hydrogenated pyromellitic dianhydride (ccHPMDA or H-PMDA) and 1R,2S,4S,5R-hydrogenated pyromellitic dianhydride (ctHPMDA or Hʹʹ-PMDA) and a fluorine-containing diamine, 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (BDAF), respectively. The derived PI-1 (ccHPMDA-BDAF) and PI-2 (ctHPMDA-BDAF) resins were easily soluble in polar aprotic solvents, such as N-methyl-2-pyrrolidinone (NMP) and N,N-dimethylacetamide (DMAc) and meanwhile they also exhibited good thermoplasticities. Thus, the PI films (thickness: ~25 μm) and sheets (thickness: ~3 mm) were separately prepared from the PI solutions in DMAc and the PI powders, respectively. The stereoisomeric effects in the ccHPMDA-derived PI-1 and the ctHPMDA-derived PI-2 apparently affected the melt-flowability of the polymers. PI-2 exhibited lower melting viscosities than that of the PI-1 counterpart. The PI sheets exhibited obviously reduced optical transparency compared with those of the PI films; however better optical transparency than those of the common thermoplastic PI sheets. For example, PI-2 sheet showed the optical transmittance value at the wavelength of 760 nm (T760) of 69.6%, which was 19.5% lower than that of the analogous PI-2 film (T760 = 89.1%), however 50.3% and 65.7% higher than those of the commercially available PI-ref1 sheet (T760 = 19.3%) derived from 3,3ʹ,4,4ʹ-oxydiphthalic dianhydride (ODPA) and 4,4ʹ-oxydianiline (ODA) and the PI-ref2 sheet (T760 = 3.9%, Aurum® PL450C, Mitsui Chem. Co, Ltd., Japan), respectively. Meanwhile, the PI-1 and PI-2 sheets showed the heat deflection temperatures (HDT) of 261.0 °C and 265.0 °C, respectively, which were obviously higher than those of the referenced PIs. At last, the PI sheets exhibited good mechanical properties, including high flexural strength (130.0 ~ 132.0 MPa), flexural modulus (2.87 ~ 2.96 GPa), compression strength (124.4 ~ 149.3 MPa), compression modulus (1.49 ~ 1.59 GPa), and impact strength (129.0 ~ 139.6 KJ/m2). [ABSTRACT FROM AUTHOR]

Diagenesis significantly influences sandstone reservoir quality, so that a detailed understanding of diagenesis is essential for the identification and prediction of favorable reservoirs. Several studies have been conducted on individual sandstone reservoirs in the Bonan Sag, a typical half-graben, oil-producing sag in eastern China, but few have explicitly considered the potential impact of the asymmetric shape of the sag, which is steep in the north and gentle in the south. This research takes full consideration of the tectonic setting and distribution of source rocks in the sag to compare the style, magnitude and timing of diagenesis in the northern Steep Slope and Sag Zone (SSSZ) and the southern Gentle Slope Zone (GSZ) by means of drill core observations, thin section petrography, high resolution scanning electron microscopy, fluid inclusion microthermometry, as well as cathodoluminescence and carbonate stable isotope analysis. Petrographic observations identify the wide-spread occurrence of authigenic quartz and clay minerals in association with dissolved feldspar, as well as abundant carbonate cements occurring as several distinct generations due to evolving pore fluid composition. The SSSZ has variable carbonate mineralogy while ankerite dominates in the GSZ. The homogenization temperature of fluid inclusions in authigenic quartz in the SSSZ has a wider range (93°C–157.9 °C) and lower starting temperature (93 °C) compared with the GSZ (106.2 °C) and is characterized by more lighter carbonate δ13C and δ18O values (δ18O: −14.8‰~-11.3‰, δ13C: 1.1‰–2.7‰ for the SSSZ; δ18O: −11.9‰~-5.8‰, δ13C: 2.9‰–5.5‰ for the GSZ). The results indicate that (1) Diagenetic conditions in the Bonan Sag evolved from alkaline to acidic to alkaline in general, but with distinct late stage carbonate cementation in SSSZ vs GSZ; (2) the diagenetic processes as well as the nature of pore waters varied across different zones and also temporally. Acidic conditions in the SSSZ started earlier and persisted for longer than in the GSZ. (3) The regional differentiation of the diagenetic processes and pore fluid evolution result from the source rock distribution and burial histories which differ across the Bonan Sag because of the asymmetric shape of the half-graben. We propose a model of fluid evolution over space and time which may provide a new framework for understanding the diagenetic processes and the fluid evolution of oil-producing sags and also contribute to the prediction of favorable reservoirs. • The E s 3 in Bonan Sag went through an alkaline-acid-alkaline diagenetic conditions. • The structure of the sag leads to temporal and spatial differences in diagenesis. • Source rock distribution and burial histories are significant controls in diagenesis. • A temporal and spatial diagenesis evolution model was put forward. [ABSTRACT FROM AUTHOR]

The particle size of sediments below the seabed is a crucial factor affecting the formation and enrichment of gas hydrates. Apart from the formation and enrichment law of gas hydrate in coarse‐grained sediments (dominated by a sandy‐sized fraction), in the fine‐grained sediments (<62.5 μm) which accounts for more than 90% of offshore gas hydrate resources globally, the control effect of sediment particle size on gas hydrate is still unclear. Therefore, understanding the relationship between the fine‐grained sediment particle size and gas hydrate enrichment is essential for revealing the global distribution and dynamic evolution of gas hydrates. Here, we analyzed the vertical gas hydrate saturation, particle size parameters of sediments, whole‐rock minerals, and clay mineral components based on drilling data and sediment samples from fine‐grained gas hydrate reservoirs (GHRs) in the Shenhu area of the northern South China Sea. The results show that in fine‐grained sediments, the coarse particles cannot improve the reservoir quality or enrich the gas hydrate because many fine particles fill the intergranular pores formed by the coarse particles. Meanwhile, the fine particles were dominated by clay minerals, especially in the illite/smectite mixed layer, which significantly reduced the permeability of the sediment layer and was not conducive to the enrichment of gas hydrates. Moreover, sedimentary processes directly control the sediment particle size and mineral composition, which play an essential role in controlling GHRs at the macroscale. In the fine‐grained sediments, very fine sediments (<8 μm) have a more significant negative impact on gas hydrate enrichment. Plain Language Summary: Offshore gas hydrates have great global resources and environmental significance. Gas hydrate is the important pool that stores methane in offshore fine‐grained sediments. However, the formation and enrichment rules of gas hydrate in fine‐grained sediments still need to be clarified. We collected sediment samples from the gas hydrate reservoirs and adjacent layers in the northern South China Sea and analyzed the controlling effect of sediment particle size on the formation and enrichment of gas hydrate in the fine‐grained sediments. We found that the coarse particles in the fine‐grained sediments cannot play a positive role in the enrichment of gas hydrate. The very fine‐grained particles (<8 μm) seriously restrict the formation and enrichment of gad hydrate, which is worthy of attention in fine‐grained reservoirs. Our results on natural sediments partly conform to previous laboratory simulation results on induced gas hydrate formation, effectively establishing potential links between laboratory simulations and natural deposition records. Key Points: Pore‐filling type dominates the gas hydrate in fine‐grained reservoir, particle size between 5 and 6 Φ is beneficial to gas hydrate enrichmentIn fine‐grained gas hydrate reservoir, the very fine‐grained particles (≤8 μm) restricting the enrichment of gas hydrateDifferent sedimentary processes playing an essential role in the formation and enrichment of gas hydrate [ABSTRACT FROM AUTHOR]

Massive Machine-Type Communication (mMTC) is proposed by ITU to provide a large scale of connectivity services for billions of machine-type communications devices (MTCDs) via cellular networks. However, MTCDs are generally energy-constrained, security capability limited and short-packet transmission dominated. It has great challenges for massive MTCDs to perform short-packet transmission simultaneously while guaranteeing the confidentiality and energy efficiency of the information transmission. In this paper, we investigate the energy-efficient secure short-packet transmission of Non-Orthogonal Multiple Access (NOMA) assisted mMTC networks, in which MTCDs aim to transmit secrecy messages to the destination base station via trusted relays with a passive eavesdropper present. To realize secure, reliable and energy-efficient transmission, we maximize the secrecy energy efficiency (SEE) by implementing joint relay and power level selection. Furthermore, we formulate a decentralized stateless Q-learning-based multi-agent reinforcement learning (MARL) algorithm for the dynamic and complex mMTC systems. The simulation results show that adopting the proposed decentralized MARL algorithm and relaying with NOMA can improve the performance of SEE while reducing information exchange overhead. [ABSTRACT FROM AUTHOR]

Colorless and transparent polyimide (CPI) films with good atomic oxygen (AO) resistance and high thermal endurance are highly required in low earth orbit (LEO) space exploration. Conventional CPI films based on fluoro-containing 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) have been widely used in space applications. However, the AO erosion yields and glass transition temperatures (Tg) of the 6FDA-based CPI films have to be modified in order to meet the severe serving environments. In the current work, novel CPI films based on a multi-ring fluoro-containing 9,9-bis(trifluoromethyl)xanthene-2,3,6,7-tetracarboxylicdianhydride (6FCDA) monomer were developed. In order to enhance the AO resistance of the derived CPI film, a phosphorus-containing aromatic diamine, 2,5-bis[(4-aminophenoxy)phenyl]diphenylphosphine oxide (BADPO) was used to polymerize with the dianhydride to create the organo-soluble resin. Then, two phosphorus-containing CPI films (PPI), including PPI-1 (6FDA-BADPO) and PPI-2 (6FCDA-BADPO) were prepared by thermally curing of the PPI solutions at elevated temperatures. The PPI films maintained good optical transparency with transmittance values over 80% at a wavelength of 450 nm. PPI-2 exhibited a Tg value of 311.0 °C by differential scanning calorimetry (DSC) measurement, which was 46.7 °C higher than that of the PPI-1 counterpart (Tg = 264.3 °C). In addition, the PPI-2 film showed a coefficient of linear thermal expansion (CTE) value of 41.7 × 10−6/K in the range of 50~250 °C, which was apparently lower than that of the PPI-1 sample (CTE = 49.2 × 10−6/K). Lastly, both of the two PPI films exhibited good AO resistance with the erosion yields (Ey) of 6.99 × 10−25 cm3/atom for PPI-1 and 7.23 × 10−25 cm3/atom for PPI-2 at an exposure flux of 5.0 × 1020 atoms/cm2. The Ey values of the current PPI films were obviously lower than that of the standard polyimide (PI) film based on pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA) (Ey = 3.0 × 10−24 cm3/atom). [ABSTRACT FROM AUTHOR]

Polymeric optical films with light colors, good optical transparency and high thermal resistance have gained increasing attention in advanced optoelectronic areas in recent years. However, it is somewhat inter-conflicting for achieving the good optical properties to the conventional thermal resistant polymers, such as the standard aromatic polyimide (PI) films, which are well known for the excellent combined properties and also the deep colors. In this work, a series of wholly aromatic PI films were prepared via the polycondensation chemistry of one fluorene-containing dianhydride, 9,9-bis(3,4-dicarboxyphenyl)fluorene dianhydride (FDAn) and several aromatic diamines with amide linkages in the main chain, including 9,9-bis [4-(4-aminobenzamide)phenyl]fluorene (FDAADA), 2,2′-bis(trifluoromethyl)-4,4′-bis[4-(4-aminobenzamide)] biphenyl (ABTFMB), and 2,2′-bis(trifluoromethyl)-4,4′-bis[4-(4-amino-3-methyl)benzamide] biphenyl (MABTFMB). The derived FLPI-1 (FDAn-FDAADA), FLPI-2 (FDAn-ABTFMB) and FLPI-3 (FDAn-MABTFMB) resins showed good solubility in the polar aprotic solvents, such as N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc) and dimethyl sulfoxide (DMSO). The solution-processing FDAn-PI films exhibited good optical transmittance over 80.0% at a wavelength of 500 nm (T500), yellow indices (b*) in the range of 1.01–5.20, and haze values lower than 1.0%. In addition, the FDAn-PI films showed low optical retardance with optical retardation (Rth) values in the range of 31.7–390.6 nm. At the same time, the FDAn-PI films exhibited extremely high glass transition temperatures (Tg) over 420 °C according to dynamic mechanical analysis (DMA) tests. The FDAn-PI films showed good dimensional stability at elevated temperatures with linear coefficients of thermal expansion (CTE) in the range of (31.8–45.8) × 10−6/K. [ABSTRACT FROM AUTHOR]

Polyimide (PI) optical films with high glass transition temperatures (high-Tg), high optical transparency, and low optical retardations (low-Rth) are highly desired in advanced optoelectronic applications. However, the standard PI films usually suffer from deep colors, high optical anisotropies and limited Tg values. In the current work, a series of semi-alicyclic colorless and transparent PI (CPI) films were developed from hydrogenated pyromellitic dianhydride stereoisomers, 1S,2R,4S,5R-hydrogenated pyromellitic dianhydride and 1R,2S,4S,5R-hydrogenated pyromellitic dianhydride, and fluorene-containing diamines, including 9,9-bis(4-aminophenyl)fluorene and 9,9-bis(3-fluoro-4-aminophenyl)fluorene, respectively. The derived CPI films showed Tg values higher than 420 °C according to differential scanning calorimetry measurements. In addition, the fluorene-based CPI film showed optical transmittances higher than 80% at the wavelength of 400 nm, with yellow indices in the range of 0.60~1.01 and haze values below 3.0%. The CPI films showed average refractive indices from 1.5407 to 1.6309, extremely low birefringence at the level of minus fourth power of ten, and further exhibited quite low optical retardations below 10 nm. [ABSTRACT FROM AUTHOR]

Sequences of wave‐enhanced sediment‐gravity flows (WESGFs) have been widely recognized in the marine shelf environment. In this study, we show observations of WESGF deposits in lacustrine settings using well core and thin section data from the Paleogene in the Jiyang sub‐basin, Bohai Bay basin, eastern China. The findings of this study include the following: 1) the sequence of WESGFs in the lacustrine basin is similar to that of marine; it consists of three units, MF1 unit: siltstone with basal erosion surface, MF2 unit: silt‐streaked claystone, and MF3 unit: silty‐mudstone; and 2) prodelta sand sheets are found in the lacustrine WESGF sequence and are classified as the MFd unit: clay‐streaked siltstone. However, because the system size and variability in hydrodynamic conditions are different between the lacustrine and marine basins, lacustrine WESGFs do appear to have three distinguishable features: 1) the sediment grain size and sand content are slightly higher than those of the marine WESGFs; 2) lacustrine WESGFs may contain prodelta sediments or sedimentary sequences of other types of gravity flows, such as hyperpycnal flows; and 3) the scale of the sedimentary structures for lacustrine WESGFs is smaller. The WESGFs found in the continental lacustrine basin provide a new model for sediment dispersal processes in lake environments and may be helpful to explain and predict the distribution of sandy reservoirs for oil and gas exploration. [ABSTRACT FROM AUTHOR]

Light-colored and transparent polyimide (PI) films with good high-temperature dimensional stability are highly desired for advanced optoelectronic applications. However, in practice, the simultaneous achievement of good optical and thermal properties in one PI film is usually difficult due to the inter-conflicting molecular design of the polymers. In the present work, a series of PI-SiO2 nanocomposite films (ABTFCPI) were developed based on the PI matrix derived from hydrogenated pyromellitic anhydride (HPMDA) and an aromatic diamine containing benzanilide and trifluoromethyl substituents in the structure, 2,2′-bis(trifluoromethyl)-4,4′-bis [4-(4-aminobenzamide)]biphenyl (ABTFMB). The inorganic SiO2 fillers were incorporated into the nanocomposite films in the form of colloidal nanoparticles dispersed in the good solvent of N,N-dimethylacetamide (DMAc) for the PI matrix. The derived ABTFCPI nanocomposite films showed good film-forming ability, flexible and tough nature, good optical transparency, and good thermal properties with loading amounts of SiO2 up to 30 wt% in the system. The ABTFCPI-30 film with a SiO2 content of 30 wt% in the film showed an optical transmittance of 79.6% at the wavelength of 400 nm (T400) with a thickness of 25 μm, yellow index (b*) of 2.15, and 5% weight loss temperatures (T5%) of 491 °C, which are all comparable to those the pristine ABTFCPI-0 matrix without filler (T400 = 81.8%; b* = 1.77; T5% = 492 °C). Meanwhile, the ABTFCPI-30 film exhibited obviously enhanced high-temperature dimensional stability with linear coefficients of thermal expansion (CTE) of 25.4 × 10−6/K in the temperature range of 50 to 250 °C, which is much lower than that of the AMTFCPI-0 film (CTE = 32.7 × 10−6/K). [ABSTRACT FROM AUTHOR]

The thermal maturity gradient approach is widely used in comparative studies of mudrocks to assess the evolution of the pore system. The fundamental assumption in this approach is that the compared samples share similar geochemical, mineralogical and textural properties, so that any differences between them can be reasonably attributed to the impact of thermal maturity and burial alteration. However, achieving the desired range of thermal maturity often requires sampling from widely spaced localities which may result in unrecognised microtextural differences owing to regional variations in depositional controls, making it challenging to isolate the effects of thermal alteration on pore system evolution. We use samples from the widely studied siliceous Woodford Shale to highlight the importance of sample screening in characterization studies of pore evolution with progressive thermal maturity. Samples were collected from different cores spanning a gradient of thermal maturity (0.5–1.65 %VRc) across the Cherokee Platform, Arkoma and Anadarko basins, and capturing the wider geographic extent of the formation across Oklahoma. Samples were selected from the same lithofacies type but varying stratigraphic position and screened using the standard bulk geochemical and mineralogical criteria that are widely employed to ensure properties are comparable across a sample set. Notwithstanding this screening step, microscale electron microscope characterization revealed substantial microtextural and compositional differences within the sample set. Our results show that total pore volume is significantly influenced by these seemingly subtle differences, likely because pore evolution pathways vary with the abundance and distribution of primary (i.e. biogenic vs detrital grains) and diagenetic sediment constituents. We conclude that standard sample screening approaches that are limited to bulk mineralogical and geochemical characterization, and cannot identify differences in detrital, biogenic and authigenic components or account for textural differences, are insufficient for thermal gradient studies. A combination of high-resolution imaging, mineral mapping, x-ray diffraction, and low-pressure gas adsorption experiments proved better suited for sample screening ensuring an "apples" to "apples" comparison, as well as for detailed characterization bringing to light the impact of microtextural heterogeneity between samples on measured rock properties. • Sample selection based on thermal maturity and bulk sample analyses alone are poor predictors of microtextural differences controlling pore system evolution. • Alteration of the mineral matrix plays a critical role in the evolution of the pore system in this dataset. • Microtextural differences affect the pathway of pore system evolution and needs consideration during sample screening. • A new generation of automated SEM and mineral mapping facilitated identification of like-to-like samples. [ABSTRACT FROM AUTHOR]

[Display omitted] Designing recyclable photocatalysts with high activity and stability has drawn considerable attention in the fields of sewage treatment. Herein, a series of heterojunctions constructed by zirconium-based metal–organic frameworks (UiO-66-NH 2) and tungsten trioxide (WO 3) is immobilized on carbon cloth via a facile solvothermal method, resulting in highly recyclable photocatalysts. Multiple characterization techniques, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier-transform infrared spectroscopy, verify the successful synthesis of UiO-66-NH 2 nanospheres on the surface of needlelike WO 3 modified carbon cloth. Results show that the optimal heterojunction photocatalyst exhibits excellent photocatalytic degradation efficiency for the removal of tetracycline (TC) from water, for which nearly 100% of TC is degraded within 60 min under visible light. Trapping experiments and electron spin resonance (ESR) spectra analyses demonstrate that the superoxide radicals O 2 – and photogenerated hole h+ play a dominant role in the degradation process. Excellent photocatalytic activity is dominantly attributed to the effective separation of photoinduced carriers in this type-Ⅱ heterostructure system. Moreover, the possible photocatalytic oxidation degradation pathway is confirmed by analyzing intermediates using liquid chromatography mass spectrometry (LC-MS). This study offers a highly efficient strategy to design recyclable heterojunction photocatalysts for the degradation of refractory antibiotics in sewage. [ABSTRACT FROM AUTHOR]

Diagenesis typically exerts a crucial impact on the formation of high-quality sandstone reservoirs in the Eocene Shahejie Formation, Dongying Depression. To better understand the formation process of petrophysical properties, this research conducts petrographic and geochemical analyses to investigate the nature of diagenetic fluids. Petrographic observations suggest that the dominant cements are carbonate, authigenic quartz, and clay minerals, accompanied with the dissolution of feldspar and calcite. The homogenization temperature of aqueous inclusions in quartz overgrowth usually exceeds 90°C corresponding to the maturity of organic matter. Quartz overgrowths contain higher amounts of CaO and Al2O3 than detrital quartz. This indicates that the siliceous fluid mainly originates from the dissolution of feldspar. Moreover, the conversion of clay minerals also provides trace amounts of silica into pore water during the burial process. Carbonate cements consist of early-stage calcite as well as late-stage Fe-calcite and ankerite. Calcite with relatively higher MnO proportions shows yellow luminescence and dissolution signs. Fe-calcite and ankerite cements have a higher homogenization temperature than that of quartz overgrowth and mainly concentrate in FeO and MgO as well as contain a small amount of Na+, K+, and Sr2+. The rare earth element (REE) pattern of bulk mudstone and carbonate cements as well as C–O isotopic evidences indicate that the diagenetic fluids of carbonate cementation are primarily controlled by the adjacent mudstone, whereas mineral dissolution and altered clay minerals in sandstone provide additional cations for the local reprecipitation of late-stage carbonate. Therefore, diagenetic fluids within sandstone reservoirs are typically subject to alkaline–acid–alkaline conditions and are influenced by internal sources in a closed system. Compaction significantly reduces the pore space of sandstone reservoirs in the Boxing Sag. Carbonate cementation further increases the complexity of pore structure and obeys the principle of mass balance. [ABSTRACT FROM AUTHOR]

Millimeter-wave (mmWave) and ultra-dense networks are two key technologies for the fifth-generation (5G) and beyond communication system. However, the ultra-dense deployment of small base stations (SBSs) might introduce severe interference to users that connect to SBSs. This paper analyzes the performance of 5G communication networks where the SBSs with coordinated beamforming, operating at mmWave frequency band and macro base stations (MBSs) operating at sub-6 GHz coexist. First, by utilizing a stochastic geometry approach, we obtain the cell association probability expressions in terms of different cell association biases, base station density ratios and probabilities of line of sight (LoS) link. Furthermore, we propose a clustering method to choose some SBSs to eliminate intra-cell interference. Then, we put forward an average distance from the Kth SBS to a user to obtain signal-to-interference-ratio (SINR) and rate coverage probability expressions. The simulation results validate the correctness of the expressions, and indicate that the optimal cardinality of coordinated SBSs increases with the density of SBSs. In addition, the relationship between the cluster size K and the average energy efficiency is obtained, which can be used to guide the coordination principle in 5G and beyond communication systems. [ABSTRACT FROM AUTHOR]

The present research study was aimed to identifies the effect of the lithofacies (assemblages) on lacustrine shale oil accumulation, the shale oil layers of the Eocene Shahejie Formation in the Bohai Bay Basin, China, were characterized. The petrological analysis, included core, thin section and scanning electron microscopy observations and X-ray diffraction, indicated that the shale oil layers of the Shahejie Formation are dominated by carbonates, which are characterized by uniform or laminar distributions. The laminar carbonate components were formed through sedimentogenesis or diagenesis. Based on the genesis patterns and the petrology, five major lithofacies (assemblages) were identified in the formation: LF (lithofacies) 1 + 5 is characterized by thin lenticular laminae of crystalline carbonates with black shale; LF2+3 depicts laminae of micritic carbonates with massive lime mudstone; LF3 is a thick layer of massive lime mudstone; LF4 is massive claystone; and LF5 is black shale. The relationship between the lithofacies and the favorability for hosting shale oil reservoirs was investigated using microdrill sampling of the total organic content, reservoir quality analysis, and shale oil-bearing property. In LF1+5, the crystalline carbonates contain abundant interparticle pores, which can act as reservoir spaces, whereas the shale layers have a high potential for hydrocarbon generation. In addition, the hydrocarbon reserves can enter the crystalline carbonates of the assemblage after migrating a short distance. Consequently, LF1+5 is the most favorable assemblage for shale oil accumulation. In addition, LF4 and LF5 have high hydrocarbon generation potentials, and thus a relatively smaller amount of hydrocarbons could accumulate in these assemblages through clay mineral adsorption. Thus, LF4 and LF5 are also valuable sites for shale oil accumulation. • The lacustrine shale oil accumulation could be classified into two categories, "crystalline carbonate reservoir (CCR)" and "in-situ generation and in-situ reservoir (GR)" model. • In CCR model, the crystalline carbonate provides reservoir space and the adjacent shale generate hydrocarbon. • In GR model, the hydrocarbon in-situ is generated and accumulated in shale and mudstone. [ABSTRACT FROM AUTHOR]

Calcite veins, which developed parallel to the bedding, are widespread in laminated source rocks in the Eocene Dongying Depression. However, there is a lack of systematic description and classification of the veins. This study presents a systematic characterization of the calcite veins, host rocks, and micritic carbonate laminae by applying petrographic and geochemical methods to understand vein-forming mechanisms. Antitaxial and syntaxial veins are examined. Antitaxial veins contain typical fibrous crystals with the most intense fluorescence, and the median zone of these veins is often the micritic carbonate. Calcite crystals in syntaxial veins develop a blocky morphology of various sizes, indicating obvious growth competition. Data of rare earth elements and trace elements obtained from the micritic laminae, host rocks, and calcite veins are very similar. This indicates that the vein-forming nutrients originated from the carbonate in the host rocks and micritic laminae. The minor difference in C and Sr isotopes between calcite veins and micritic carbonate within the host rock and the negative shift in O isotopes in the veins are caused by ion exchange and dehydration of swelling clay minerals in the burial environment. This further proves that the calcite veins are formed in a closed system. Geochemical analysis suggests that the rocks are in the oil window and have good hydrocarbon potential. Thermal evolution of the acidic fluids generated from organic matter (OM) resulted in the dissolution of carbonate and formed fluid overpressure in the rocks. Fluid overpressure induced the formation of fractures in the interlayer and expanded the veins with the force of crystallization due to fibrous calcite growth. Blocky crystals grow in the fractures from the margins toward the center. Hydrocarbon expulsed via OM maturation in the host rock fills the intercrystalline pores. Moreover, shale with bedding-parallel calcite has the characteristics of high-quality shale oil reservoirs. These characteristics will probably provide guidance for shale oil exploration. [ABSTRACT FROM AUTHOR]

Algae CO 2 biofixation provides a promising opportunity due to earn carbon credits and valuable end uses. For balancing technology, energy and economy issues in practical utilization, this approach quantitively interprets the contradictions from upstream CO 2 source with a wide range of initial concentration to downstream CO 2 biofixation product including edible algae and algal biomass. The influence of upstream CO 2 deliverable on algal quantity and quality have been assessed, and the influence of CO 2 concentration on CO 2 transport mode choice has been also assessed coupling the transportation distance. In downstream algal fixation, quantitively relationship of algal growth have been established. The assessment discovered that direct energy consumptions complied with logarithmic relationship with specific productivities while both direct energy and indirect energy consumption complied with linear relationship with protein content. According to sensitive uncertainty analysis, initial CO 2 concentration is a critical parameter to influence significantly energy consumption in upstream CO 2 deliverables and algal quality while the contents of protein and specific productivity are the critical sensitive parameters in downstream algae deliverables. Potential modification systems are achieved for significantly reducing energy consumption by improving specific productivity and carbon abundance with low protein content in algae. Unlabelled Image • Establish quantitively relationship of algal growth and CO 2 fixation efficiency • Correlation of upstream flue gas and downstream CO 2 biofixation product choice • Effects of algae growth rate and protein contents on energy consumption • Effects of initial CO 2 concentration on algal products quality • Key impact factors extracted by the sensitive uncertainty analysis [ABSTRACT FROM AUTHOR]

A new cis-caffeoyl coumarin glycoside, cichorigenin-5-O-(4′-cis-caffeoyl)-β-D-glucopyranoside (1), wasisolated from the stem barks of Fraxinus depauperata, together with two known coumarins, cichorigenin (2) and esculin (3). The chemical structures of compounds 1-3 were elucidated through spectroscopic and chemical analysis, as well as by comparison with the literature. Compounds 2 and 3 are reported from this species for the first time. [ABSTRACT FROM AUTHOR]

Shale oil is attracting increasing attention in the petroleum industry as an essential target of unconventional oil and gas exploration. Recent exploration efforts have indicated that laminar carbonates are closely related to the favorable depositional strata of shale oil. This research focused on inter-bedded layers of laminar carbonates as well as mudstone and shale in the Dongying depression of the Bohai Bay Basin in eastern China, and attempted to reveal the genesis and evolution of the carbonates by means of drill core observations, thin sections, high resolution scanning electron microscopic observations, and fluorometric, cathodoluminescence and geochemical analyses. The results demonstrated that: (1) the carbonates could be categorized into two groups, crystalline carbonates and micritic carbonates; (2) the crystalline carbonates were well crystallized and greenish under fluorescent light; and (3) the micritic carbonates were not well crystallized and had biotic textures. It was discovered that the crystalline carbonates were mainly developed in the shale layer and were formed from the late-filling effects of the diagenetic cracks along the shale fissility planes; shale layers with crystalline carbonates are usually favorable for shale oil reserves. The micritic carbonates were formed from direct deposition controlled by biological effects in the stratified flows of the seasonal lake basins and are unfavorable for shale oil reserves. [ABSTRACT FROM AUTHOR]

As a potential major energy resource, gas hydrates are widely found in sub-oceanic sediments and could play an important role in the future of fuels. Many studies have been applied on gas hydrates reservoir to understand its accumulation as well as potential industrial values, while the characteristics of sediments favoring gas hydrates accumulation are still unclear. Here, we investigate a gas hydrates reservoir in Shenhu area, Pearl River Mouth Basin, South China Sea (SCS), studying reservoir sediments features to understand controlling factors of gas hydrates accumulation. We sampled sediments of drilling site W19 in this area, which has thick, high saturation gas hydrate layers, for sediments' physical properties analysis (including the grain size, mineral composition, and specific surface area), as well as biological abundance in the gas hydrate-bearing layer and adjacent layers. The results show fine-grained turbidite sediments characterized by poor sorting, high foraminifera abundance, and low clay mineral content, are beneficial to gas hydrate accumulation, while suspended sediments characterized by fine sorting, high calcareous ultra-microfossil abundance, and high clay mineral content, are not conducive to gas hydrate accumulation. Based on these results, we propose that the gas hydrate accumulation in the SCS is controlled by multiple factors, including the sedimentary processes, sorting, biological abundance, mineral composition, and specific surface area. It could potentially reveal the regularity of gas hydrate accumulation on a global scale. • The absorption capacity and binging effect of minerals on pore water and methane will affect the reserve of gas hydrate. • The effects of different biological components on gas hydrate accumulation are quite different. • The sedimentary process plays a significant role in controlling favorable gas hydrate reservoirs. • The gas hydrate accumulation in low-flux type and diffusion reservoirs is controlled by multiple factors. [ABSTRACT FROM AUTHOR]

The Dongying Depression is an oil-bearing rift depression and mainly consists of beach bar, turbidite, and sublacustrine fan sandstone reservoirs. The pore systems of these sandstones have a crucial impact on maintaining and enhancing oil recovery, but the complexity of pore-throat structure and distribution cannot be described in detail using a single method; in particular, the pore systems of tight sandstones are principally composed of small-scale and discontinuous pores. Petrological observation of these sandstones demonstrated that the main pore systems in beach bar and sublacustrine fan sandstones are composed of micropores related to clay minerals, and few residual intergranular and secondary intragranular pores, because of intense compaction and cementation. In contrast, turbidite sandstones preserve abundant intergranular and secondary intragranular pores due to moderate compaction. High-pressure mercury injection (HPMI), nuclear magnetic resonance (NMR), and X-ray computed tomography (X-ray CT) were conducted to explore the features of full-scale pore systems. The NMR and HPMI demonstrated that turbidite sandstones have larger pore and throat sizes than beach bar and sublacustrine fan sandstones, consistent with the petrophysical characteristics and petrological observations. Moreover, X-ray CT analysis also indicated that turbidite sandstone has a larger pore radius and a higher proportion of connected pores, than beach bar sandstone. The fractal characteristics of pore systems are quantificationally described by NMR and HPMI. Fractal dimension (Df 2) of pore sizes (T 2 > 1 ms) show a positive relationship with BVI value, as well as negative relationships with T 2peak and T 2gm ; and fractal dimension (Df S) from HPMI exhibit a positive correlation with the radius of small pore throats (< r apex), indicating that the high proportion of small pore structure increases the heterogeneity of sandstone reservoirs. The fractal dimension of tortuosity (Dτ) is negatively correlated with permeability and can be regarded as parameters to quantificationally describe reservoir quality. Therefore, the simplified numbers of fractal theory obtained from NMR and HPMI experiments provide insights and conveniences for evaluating and comparing pore systems in sandstone reservoirs in the Dongying Depression. • Turbidite, beach bar and sublacustrine fan are almost tight sandstone reservoirs. • Turbidite sandstone has lower Df and less complex pore systems than the two others. • The reservoir quality of turbidite sandstone is the best in three sandstones. [ABSTRACT FROM AUTHOR]

Low dose non-toxic disulfide cross-linked micelle (DCM) encapsulated paclitaxel (PTX) was found to be highly efficacious as a radiosensitizer against oral cancer preclinical model. Intensity-modulated radiation therapy was locally administered for three consecutive days 24 h after intravascular injection of DCM-[PTX] at 5 mg/kg PTX. DCM-[PTX] NPs combined with conventional radiotherapy (2 Gy) resulted in a 1.7-fold improvement in therapeutic efficacy compared to conventional PTX plus radiotherapy. Interestingly, we found that radiotherapy can decrease tight junctions and increase the accumulation of DCM-[PTX] in tumor sites. Stereotactic body radiotherapy (SBRT) given at 6 Gy was used to further investigate the synergistic anti-tumor effect. Tumor tissues were collected to analyze the relationship between the time interval after SBRT and the biodistribution of the nanomaterials. Compared to combination DCM-[PTX] with conventional radiation dose, combination DCM-PTX with SBRT was found to be more efficacious in inhibiting tumor growth. [ABSTRACT FROM AUTHOR]

Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P21/n with lattice constants a = 10.449(11) A˚ , b = 9.414(10) A˚ , c = 11.690(12) A˚ , and b = 105.888(11)º for Rb3ZnB5O10, while a = 7.6391(5)A˚ , b =19.2304(13)A˚ , c = 7.6905(5)A˚ , and β = 116.698(4)º for Rb3CdB5O10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10]1∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10]1∞ (M = Zn, Cd) layers, Rb3ZnB5O10 and Rb3CdB5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB5O10 and Rb3CdB5O10, respectively. [ABSTRACT FROM AUTHOR]

• LG- g -PDLA can simultaneously improving the original properties and recovery efficiency of PLLA. • A small amount of PDLA in LG- g -PDLA did not lead to an increase of D-LA production of PLLA. • More L-LA and less D- and meso -LA were recovered from PLLA/LG- g -PDLA at 240 °C. • The thermal degradation of PLLA/LG- g -PDLA was put forward as less random and more unzipping depolymerization.. The biorefinery and high-value utilization are the development tendency in the study of lignin. Lignin- graft -poly(D-lactic acid) (LG- g -PDLA) is a new kind of poly(L-lactide) (PLLA) filler. In order to clarify the effects of LG- g -PDLA on PLLA pyrolysis, PLLA/LG- g -PDLA (1 wt% filler) and pure PLLA were prepared and subjected to reveal the degradation mechanisms with proton and carbon-13 nuclear magnetic resonance spectrometer (H- and 13C-NMR) and gel permeation chromatography (GPC). More L-LA and less D- and meso -lactide (D- and meso -LA) were recovered from PLLA/LG- g -PDLA at 240 °C. By analyzing the NMR and GPC data, the thermal degradation of PLLA/LG- g -PDLA was put forward as being possible mechanisms of less random and more unzipping depolymerization. The results of lactides yields at different conditions better guide the optimization of PLLA recovery. Moreover, this innovative blending approach can simultaneously achieve high-value utilization of lignin and recovery efficiency of PLLA. [ABSTRACT FROM AUTHOR]