Search

The study aims to assess the marine environmental hazards resulting from some industrial activities areas being found at the Suez Bay. The survey was done to select five industrial locations along the studied areas where different water and sediment samples were collected during September 2020. The study methods showed that different concentrations were measured in the collected water and sediment samples, such as; Al, Fe, Mn, Hg, Cd, Cr, Co, Mo, V, Pb, Ni, Cu, Zn, where the digested samples were measured by using Inductively Coupled Argon Plasma spectroscopy (ICAP 6500 Duo), while the natural radioactivity concentrations of the selected radio-nuclides such as 238U, 226Ra, 232Th, 40K, were measured in both water and sediments samples by using Hyper germanium detector, as the radiological risk assessment of different samples was detected by using ERICA modeling software. The study results showed that the concentrations of the measured trace elements in the selected five industrial sites were slightly higher than the standard limits, while the measured radioactivity concentrations of the selected radio-nuclides in both water and sediment samples were below the standard limits. The results showed that the calculated distribution coefficient of the selected trace elements was (Kd Metal Pollution Index < 3), which indicated that the measured trace elements were more dissolved in the aqueous than the sediment medium. The study used the mean probable effect Level (m-PEL-Q) for estimating the metal concentration hazards in the sediment samples at the selected sites, where these values were ranged from 0.04 to 0.1, indicating that the combined concentration effects for these metals were caused 9% toxic probability. The study showed that both the calculated quotient risk (QR) and dose rate values of the marine organisms which were being calculated by the ERICA model were below the recommended limits. [ABSTRACT FROM AUTHOR]

The CO2 methanation technique not only gives a solution for mitigating CO2 emissions but can also be used to store and convey low-grade energy. The basic character and large surface area of mesoporous carbon nitride, (MCN), are considered promising properties for the methanation of CO2. So, a series (5–20 wt.%) of Ni-doped mesoporous carbon nitride catalysts were synthesized by using the impregnation method for CO2 methanation. the prepared catalysts were characterized by several physicochemical techniques including XRD, BET, FT-IR, Raman spectroscopy, TEM, TGA analysis, Atomic Absorption, H2-TPR, and CO2-TPD. The catalytic performance was investigated at ambient pressure and temperature range (200–500 °C) using online Gas chromatography system. The prepared catalysts showed good performance where 15%Ni/MCN exhibited the best catalytic conversion and methane yield with 100% methane selectivity at 450 °C for investigated reaction conditions. [ABSTRACT FROM AUTHOR]

In this work, a novel system composed of non-precious nickel-based metal oxide/reduced graphene oxide nanocomposite (Ni–PbO2–GN) is used for electrooxidation of ethylene glycol (EG) in 1.0 M NaOH solution and compares its activity with that of Ni, Ni–GN, and Ni–PbO2. The facile electrodeposition technique is used to prepare the catalysts on glassy carbon (GC) substrates. The outcomes of electrochemical measurements show a high performance towards EG oxidation is obtained for Ni-nanocomposite electrodes compared to that of Ni mainly due to their higher surface areas. The excellent electrocatalytic properties of the Ni-nanocomposite could be ascribed to the synergistic contributions of PbO2 and graphene (GN) nano-sheets that help the reduction of Ni grains. A smaller charge transfer resistance value of 34.5 Ω cm2 for EG oxidation reaction at + 360 mV is recorded for GC/Ni–PbO2–GN compared to the other prepared electrodes. Moreover, it exhibits higher kinetic parameters of EG such as diffusion coefficient (D = 3.9 × 10–10 cm2 s−1) and charge transfer rate constant (ks = 32.5 mol−1 cm3 s−1). The overall performance and stability of the prepared catalysts towards EG electrooxidation have been estimated to be in the order of GC/Ni–PbO2–GN > GC/Ni–GN > GC/Ni–PbO2 > GC/Ni. [ABSTRACT FROM AUTHOR]

2 Egyptian goats and Boscat rabbits were experimentally inoculated with peste des petits ruminants (PPR) local Egyptian strain (PPR, Egypt 87). The inoculated animals contracted the disease with minor clinical manifestations, accompanied by rise of neutralizing antibodies to PPR virus. Virus was isolated from ocular and nasal secretions, buffy coat, spleen, and liver. No contact infection was observed between inoculated and healthy goats.