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1. Heterologous synthesis of the complex homometallic cores of nitrogenase P- and M-clusters in Escherichia coli.

2. X-ray Spectroscopic Study of the Electronic Structure of a Trigonal High-Spin Fe(IV)═O Complex Modeling Non-Heme Enzyme Intermediates and Their Reactivity.

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3. Incorporation of an Asymmetric Mo-Fe-S Cluster as an Artificial Cofactor into Nitrogenase.

4. Radical SAM-dependent formation of a nitrogenase cofactor core on NifB

5. Characterization of a Nitrogenase Iron Protein Substituted with a Synthetic [Fe4 Se4 ] Cluster.

6. S K-edge XAS of CuII, CuI, and ZnII oxidized Dithiolene complexes: Covalent contributions to structure and the Jahn-Teller effect

8. Tracing the incorporation of the “ninth sulfur” into the nitrogenase cofactor precursor with selenite and tellurite

9. Spectroscopic Characterization of an Eight‐Iron Nitrogenase Cofactor Precursor that Lacks the “9th Sulfur”

12. Sulfur K‑Edge XAS Studies of the Effect of DNA Binding on the [Fe4S4] Site in EndoIII and MutY

14. Assembly scaffold NifEN: A structural and functional homolog of the nitrogenase catalytic component

17. Uncoupling binding of substrate CO from turnover by vanadium nitrogenase

18. Short-lived metal-centered excited state initiates iron-methionine photodissociation in ferrous cytochrome c

19. Goniometer-based femtosecond crystallography with X-ray free electron lasers

20. A Zinc Linchpin Motif in the MUTYH Glycosylase Interdomain Connector Is Required for Efficient Repair of DNA Damage

25. Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H2O2 Activation

26. Geometric Structure Determination of N694C Lipoxygenase: A Comparative Near-Edge X-Ray Absorption Spectroscopy and Extended X-Ray Absorption Fine Structure Study

29. Tuning the Type 1 Reduction Potential of Multicopper Oxidases: Uncoupling the Effects of Electrostatics and H-Bonding to Histidine Ligands

37. Radical SAM-dependent formation of a nitrogenase cofactor core on NifB.

40. Millisecond timescale reactions observed via X-ray spectroscopy in a 3D microfabricated fused silica mixer. Corrigendum

42. Synchrotron X-radiolysis of l-cysteine at the sulfur K-edge: Sulfurous products, experimental surprises, and dioxygen as an oxidoreductant.

44. The Biochemistry Of the Particulate Methane Monooxygenase