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The aim of this study is to analyze the effect of the addition of TiO2 nanoparticles (NTs) on the physical and mechanical properties, as well as the microstructural changes, of cementitious composites containing partially substituted natural aggregates (NAs) with aggregates derived from the following four recycled materials: glass (RGA), brick (RGB), blast-furnace slag (GBA), and recycled textolite waste with WEEE (waste from electrical and electronic equipment) as the primary source (RTA), in line with sustainable construction practices. The research methodology included the following phases: selection and characterization of raw materials, formulation design, experimental preparation and testing of specimens using standardized methods specific to cementitious composite mortars (including determination of apparent density in the hardened state, mechanical strength in compression, flexure, and abrasion, and water absorption by capillarity), and structural analysis using specialized techniques (scanning electron microscopy (SEM) images and energy dispersive X-ray spectroscopy (EDS)). The analysis and interpretation of the results focused primarily on identifying the effects of NT addition on the composites. Results show a decrease in density resulting from replacing NAs with recycled aggregates, particularly in the case of RGB and RTA. Conversely, the introduction of TiO2 nanoparticles resulted in a slight increase in density, ranging from 0.2% for RTA to 7.4% for samples containing NAs. Additionally, the introduction of TiO2 contributes to improved compressive strength, especially in samples containing RTA, while flexural strength benefits from a 3–4% TiO2 addition in all composites. The compressive strength ranged from 35.19 to 70.13 N/mm2, while the flexural strength ranged from 8.4 to 10.47 N/mm2. The abrasion loss varied between 2.4% and 5.71%, and the water absorption coefficient varied between 0.03 and 0.37 kg/m2m0.5, the variations being influenced by both the nature of the aggregates and the amount of NTs added. Scanning electron microscopy (SEM) images and energy dispersive X-ray spectroscopy (EDS) analysis showed that TiO2 nanoparticles are uniformly distributed in the cementitious composites, mainly forming CSH gel. TiO2 nanoparticles act as nucleating agents during early hydration, as confirmed by EDS spectra after curing. [ABSTRACT FROM AUTHOR]

The conservation of the environment and the protection of natural resources are urgent and current challenges. The objective of this experimental investigation was to evaluate the potential use of aggregates derived from recycled glass waste, blast furnace slag, recycled brick waste aggregates and recycled electronic waste aggregates (textolite) as replacements for natural aggregates in cement-based composites. The experimental tests aimed to investigate how the replacement of natural aggregates with recycled waste aggregates affects various physico-mechanical parameters, including density, compressive strength, flexural strength, abrasion resistance and capillary water absorption. This investigation also included detailed microstructural analysis using optical microscopy, SEM, EDX and XRD techniques. The aim of the research was to explore the potential for soil conservation by reducing the amount of waste to be disposed of, and at the same time to conserve natural resources by identifying alternatives using recycled materials, thereby contributing to the implementation of the circular economy concept. The results of the research confirmed this potential; however, depending on the nature of the recycled aggregates, there are influences on the physico-mechanical performance of the cement composite that can be seen at the microstructural level. [ABSTRACT FROM AUTHOR]

The urgent need for sustainable construction that corresponds to the three pillars of sustainable development is obvious and continuously requires innovative solutions. Cementitious composites with TiO2 nanoparticles (NT) addition show potential due to their improved durability, physico–mechanical characteristics, and self-cleaning capacity. This study aimed to evaluate the influence of NT on cementitious composites by comparing those with 2%–5% nanoparticles with a similar control sample without nanoparticles, as well as an analysis of cost growth. The experimental results showed an increase in bulk density of the material (4.7%–7.4%), reduction in large pore sizes by min. 12.5%, together with an increase in cumulative volume and cumulative specific surface area of small pore sizes, indicating densification of the material, also supported by SEM, EDS, and XRD analyses indicating acceleration of cement hydration processes with formation of specific products. The changes at microstructural level support the experimental results obtained at macrostructural level, i.e., modest but existent increases in flexural strength (0.6%–7.9%) and compressive strength (0.2%–2.6%) or more significant improvements in abrasion resistance (8.2%–58%) and reduction in water absorption coefficient (37.5%–81.3%). Following the cost–benefit analysis, it was concluded that, for the example case considered of a pedestrian pavement with a surface area of 100 m2, using 100 mm thick slabs, if these slabs were to be made with two layers, the lower layer made of cementitious composite as a reference and the upper layer with a thickness of 10 mm made of cementitious composite with 3% NT or 4% NT, the increase in cost would be acceptable, representing less than 15% compared to the cost for the exclusive use of cementitious composite without NT. [ABSTRACT FROM AUTHOR]

In a time when the attention paid to identifying the possibilities of reducing problems due to urban pollution is increasing, the construction industry has a lot to gain if it aligns itself with the new trends of sustainable development in the field. In this context, the objective of obtaining a concrete with self-healing properties of cracks is more than appropriate, becoming a sustainable alternative for reducing the maintenance costs of transport infrastructure by increasing their operating time and by decreasing the need for the volume of repair and maintenance works, thus indirectly contributing to the reduction of environmental pollution. Preliminary results obtained using a cementitious composite with waterproofing admixture content by mass crystallization are encouraging by identifying the existence of an autonomous healing degree (closure of cracks with average opening 20-40 µm) in a proportion of at least 65% after only 96 hours of exposure in a wet-dry environment, respectively and of at least 96% after 480 hours of conditioning. The degree of novelty and value of this research is mainly due to the approach of this type of composite produced by adapting the general principles to local raw materials, including the use of specific industrial waste and by-products available in Romania (fly ash and limestone slurry).

As the architectural trend for ever greater spans for glass framing elements keeps its momentum, we are dealing with larger reaction loads onto the elements connecting these to the concrete slab, respectively onto the anchoring system. Therefore, this numerical study has the scope of researching the use of standard cast-in anchor channels, commonly used to support curtain wall façade systems, that are positioned and cast-in relatively close to the edge of the reinforced concrete slab; as well as researching the evolution of the relationship between the concrete strength, slab thickness, anchorage length, the distances between the anchors, the T-bolt positioning, (lever arm of shear force on t-bolt), and the geometry of the “ski plates”. Whilst many studies have been performed regarding the performance of both the concrete and these fastening systems, there is not sufficient information/classification relating to the influence of the welded “skis “, and as to what the optimal sizes and geometries are, when used in a class of concrete where this is critical. The main conclusion desired to be achieved is to find the optimal reinforcement plate (ski) shape and position for the given concrete and anchorage depth, allowing for a more accurate connection design, and to provide options for the instances where clashes occur.

Pollution negative influences the environmental, human health, buildings and increase the production of waste. We are currently witnessing pollution and degradation in some cases irreversible, of the environment. Environmental issues are extremely complex and cover all sectors. Worldwide, industrial pollution strategies necessary to reduce emissions to the atmosphere hydrocarbons, volatile organic compounds (VOCs) and other polluants in urban areas. The highest concentrations of volatile organic compounds of more than 80 mg/m3 occur in densely populated areas. The latest data reported in the residential area of Cluj-Napoca values did not exceed 20 m /m3. However peaks reported VOC concentrations, depending on the season, exceeding the upper limit that according to Law. 104/2011 is 75 μ/m3. It was identified due to increase annual mean concentration of VOCs as, in particular, road traffic exceeding sanitary standards on the main traffic routes within the city. In this paper the results obtained after carrying out an analysis of the average VOC concentration recorded in the city Cluj-Napoca as a result of car traffic. They were pursued average concentrations of VOCs resulting from the combustion of liquid fuels, petrol and diesel type. Analyzing the results obtained are proposed solutions for reducing VOC emissions. The rule under which these solutions have been proposed to reduce the concentration of VOCs took into account the possibility implementation and maintenance costs thereof.

This research investigates the feasibility of developing clay composites using natural materials and incorporating waste by-products suitable for plastering diverse support structures. The study identified a versatile composition suitable for a wide range of support materials and explored the potential of revaluing industrial waste and by-products by reintegrating them into the Circular Economy. The experimental investigation outlines the process of evaluating the influence of different raw materials on the performance of the clay composite. The findings confirm that using limestone sludge and fly ash as additives to clay contributes to reducing axial shrinkage and increasing mechanical strengths, respectively. The optimal percentage of additives for the clay used are identified and provided. Using hydraulic lime as a partial substitute for clay reduces the apparent density of dried clay composites, axial shrinkage, and fissures formation while improving adhesion to the substrate. Introducing dextrin into this mix increases the apparent density of the hardened plaster while keeping axial shrinkage below the maximum threshold indicated by the literature. Mechanical strengths improved, and better compatibility in terms of adhesion to the support was achieved, with composition S3 presenting the best results and a smooth, fissure-free plastered surface after drying. [ABSTRACT FROM AUTHOR]

Starting from the context of the principles of Sustainable Development and Circular Economy concepts, the paper presents a synthesis of research in the field of the development of materials of interest, such as cementitious composites or alkali-activated geopolymers. Based on the reviewed literature, the influence of compositional or technological factors on the physical-mechanical performance, self-healing capacity and biocidal capacity obtained was analyzed. The inclusion of TiO2 nanoparticles in the matrix increase the performances of cementitious composites, producing a self-cleaning capacity and an anti-microbial biocidal mechanism. As an alternative, the self-cleaning capacity can be achieved through geopolymerization, which provides a similar biocidal mechanism. The results of the research carried out indicate the real and growing interest for the development of these materials but also the existence of some elements still controversial or insufficiently analyzed, therefore concluding the need for further research in these areas. The scientific contribution of this study consists of bringing together two apparently distinct research directions in order to identify convergent points, to create a favorable framework for the development of an area of research little addressed so far, namely, the development of innovative building materials by combining improved performance with the possibility of reducing environmental impact, awareness and implementation of the concept of a Circular Economy. [ABSTRACT FROM AUTHOR]

SH-FECM (Fibre Engineered Cementitious Materials with Self-Healing capacity), developed at NIRD “URBAN-INCERC” Cluj-Napoca Branch in the last five years, are consistently based on Engineered Cementitious Composites (ECCs) concept, elaborated in the early nineties at Michigan University (USA). They all represent a cement-based typology of dispersed reinforcement composites able to develop high deformability by the means of multiple cracking pattern under loading, leading to a cumulative set of valuable material features: metal like behaviour when subjected to loads, brittle failure prevention, increased self-healing potential via the compositional design, etc. The process of development and constant improvement of the SH-FECMs represents a long term theoretical and experimental approach, aiming to establish the optimum raw materials (mostly locally available) compatibility within the cementitious matrix so that the composites would present superior performance under comparative evaluation. This paper presents the first results, evaluated as positive for both, fresh and hardened state materials, regarding the inclusion of Slurry Lime (SL) addition as replacement of the initial lime powder addition (L) in the material composition. The long-term effects are on ongoing investigation, but the initial results are clearly promising, starting from a better fresh state aspect and evaluating for faster setting time and improved early age mechanical behaviour. The beneficial effects are also in terms of economic and ecological aspects, considering that the used lime slurry (SL) addition represents an actual waste resulted from a local, natural stone processing factory. Its use as direct addition in the SH-FECMs mixtures could represent an efficient recycling and waste prevention action, with long term beneficial potential, in terms of Circular Economy principles.

Contemporary urban architecture faces two important issues: degradation of buildings, caused by exposure to various environmental factors (air and water pollution, mainly generated by the fuels combustion used for transport and heating) and also the costs for repair, cleaning and maintenance of the buildings facades. Regarding the last mentioned aspects, recent research led to development of materials with self-cleaning potential and consequently pollution reduction. Self-cleaning concrete represents a state-of-the-art material with photocatalytic properties generated by the addition in its composition of nanomaterials like TiO2. Already known for its intrinsic photocatalytic character, TiO2 has the ability to catalyse the decomposition of organic substances like grease and dirt, facilitating their quick removal only by rainwater action. Therefore, a building façade made of TiO2-SiO2-containing material develops substantial savings regarding maintenance costs, water consumption and less detergents contamination due to its intrinsic super hydrophilic effect of the surface in the presence of UV radiation, leading to easy dirt removal when water reaches it. The aim of present paper is presenting the latest stage of worldwide research regarding the obtaining of self-cleaning concrete and also the possibility of adapting the concept to the actual Romanian architecture needs, as a sustainable solution for urban pollution reduction.

Fibre Engineered Cementitious Materials (FECM) represent composites with similar overall performance as Engineered Cementitious Composites (ECC), namely developing strain hardening behaviour under loading, which generates the material capacity of high deformability. The pattern of multiple microcracks successively developed under increasing loading is proved to be the key of material self-consolidating potential and ability to support loads after the first crack occurrence. The matrix to fibre compatibility is considered to be one essential parameter controlling the multiple micro-cracking pattern (MC) and consequently, the strain hardening effect in the material. Factors like fibre type and reinforcement percent in the mixture represent sensitive variables, with major influence for matrix to fibre compatibility and overall performance of the composite. Cement based materials, whose compositional heterogeneity traditionally represents a lack in their regular usage, can be valorised and designed to produce the width controlled cracking typology, beneficial for material behaviour. This paper presents an experimental study on the fibre to matrix compatibility effect in the FECM design and producing process. Several types of dispersed reinforcing typologies for FECM development are experimentally tested and analysed. The results confirm the importance of matrix to fibre compatibility in enhancing superior material performance: physical, mechanical and even durability (Self-Healing potential evaluation).

The development of biofilms of micro-organisms on the surface of buildings, in addition to the negative impact and risk to the health of the population, leads to their degradation and the need for continuous sanitation operations. Inducing superhydrophilicity and self-cleaning performance of cement surfaces by adding TiO2 nanoparticles to the composite matrix, as a result of photoactivation reactio. This method, can become an effective for the production of new materials in order to increase the durability of buildings and to increase the degree of hygiene, due to the ability of these new materials to inhibit the growth of microorganisms. Experimental results have shown that in case of contamination with two types of moulds (Aspergillus niger, Penicillium notatum) and four types of bacteria (Escherichia Coli, Pseudomonas Aeruginosa, Staphylococus Aureus, Streptococus Pyogenes) respectively, the development of harmful biofilm is inhibited. This performance was monitored using the dimensional development of the specific inhibition halo as a quantifiable indicator. It can be said that it is influenced by the type of contaminant and the nanoparticle content of the cementitious composite matrix, but is manifested in all cementitious composites containing TiO2 nanoparticles photoactivated under laboratory conditions. [ABSTRACT FROM AUTHOR]

The use of waste from industrial activities is of particular importance for environmental protection. Fly ash has a high potential in the production of construction materials. In the present study, the use of fly ash in the production of geopolymer paste and the effect of Fe2O3, MgO and molarity of NaOH solution on the mechanical strength of geopolymer paste are presented. Samples resulting from the heat treatment of the geopolymer paste were subjected to mechanical tests and SEM, EDS and XRD analyses. Samples were obtained using 6 molar and 8 molar NaOH solution with and without the addition of Fe2O3 and MgO. Samples obtained using a 6 molar NaOH solution where Fe2O3 and MgO were added had higher mechanical strengths compared to the other samples. [ABSTRACT FROM AUTHOR]

Both Circular Economy and Sustainable Development are concepts that focus on resource efficiency. This involves a complex waste management process with a high degree of recycling and recovery. Rapid population growth and urbanization in developing countries have led to large amounts of solid waste and, consequently, increased environmental degradation of the environment. Designing resilient, sustainable materials and buildings by using recycled materials or industrial by-products, which can replace some or all of the cement, leads to the development of a sustainable, low-carbon economy and furthermore to the conservation of natural resources. Industry is developing at an accelerated pace, consequently the development of modern construction materials in the economic world is more than necessary. The aim of this research is to present preliminary results regarding the design of the alkali-activated fly ash-based geopolymer paving blocks produced using Romanian local raw materials, to present several parameters that affect their mechanical properties and to assess their intended use in terms of legislation. [ABSTRACT FROM AUTHOR]