1. Enhanced contact flexibility from nanoparticles in capillary suspensions.
- Author
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Liu, Lingyue, Allard, Jens, and Koos, Erin
- Subjects
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NANOPARTICLES , *LIQUID-liquid interfaces , *HERTZIAN contacts , *YIELD stress , *CAPILLARIES , *FLUX pinning , *LIQUID films - Abstract
Hypothesis: Sample-spanning particle networks are used to induce structure and a yield stress, necessary for 3D printing of porous ceramics and paints. In capillary suspensions, a small quantity of immiscible secondary fluid is incorporated into a suspension. By further adding nanoparticles with a range of hydrophobicities, the structure of the bridges and microparticle-microparticle contacts is expected to be modified, resulting in a tunable yield stress and shear moduli. Moreover, the compressibility of these samples, important in many processing and application steps, is expected to be sensitive to these changes. Experiment: The nanoparticle hydrophobicity was altered and their position relative to the microparticles and the bridges was examined using confocal microscopy where the correlation between bridge size and network structure was observed. A step-wise uniaxial compression test on the confocal was conducted to monitor the microparticle movement and structural changes between capillary suspension networks with and without nanoparticles. Findings: Our observation suggests that nanoparticles induce the formation of thin liquid films on the surface of the microparticles, mitigating contact line pinning and promoting internal liquid exchange. Additionally, nanoparticles at microparticle contact regions further diminish Hertzian contact, enhancing the capacity for rearrangement. These effects enhance microparticle movement, narrowing the bridge size distribution. Nanoparticles added to capillary suspensions : The nanoparticles either homogeneously aggregate around the microparticles or stabilize the liquid-liquid interface. These capillary nanosuspensions readily rearrange and compress, opening new opportunities for tunable design of porous ceramics, printed electronics, and low-fat spreadable chocolate. • Nanoparticles in capillary suspensions aggregate on microparticles or stabilize interfaces depending on the wettability. • Nanoparticles induce thin layers of liquid films, promoting internal liquid exchange, and reducing Hertzian contacts. • Capillary nanosuspensions demonstrate a reduction in elastic moduli and less pronounced peak in the viscous modulus. • The structures of capillary nanosuspensions rearrange more easily when subjected to compression. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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