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1. Chlorotrimethylsilane-sodium nitrite or nitrate. Efficient deoximating reagents for aldoximes and ketoximes

Author

Gun Lee Jong, Hoon Kwak Ki, and Pil Hwang Je

Subjects
chemistry.chemical_classification, Nitrosonium, Organic Chemistry, Inorganic chemistry, Biochemistry, Chloride, Aldehyde, chemistry.chemical_compound, Nitrate, chemistry, Sodium nitrate, Reagent, Drug Discovery, medicine, Nitrite, Sodium nitrite, medicine.drug
Abstract

A 2:1 mixture of chlorotrimethylsilane and sodium nitrite or nitrate was found very effective for deoximation. Trimethylsilyl nitrate or nitrite seems to be initially formed, which further reacts with chlorotrimethylsilane to produce a nitrosonium or nitronium chloride. The deoximation reaction can also be successfully performed by t-butyl nitrite and chlorotrimethylsilane.

Published
1990
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