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In drinking water catchments, exploiting ecosystem services provided by stream buffers has the potential to complement conventional engineering solutions such as water treatment and reduce the overall public health risks to consumers. These stream buffers interrupt the movement of contaminants and sediments from non-point source sources, such as agricultural land, to surface waters. Effectively managing stream buffers can be challenging due to the complexity and diversity of factors that can directly and indirectly impact efficacy. This study uses System Theoretic Process Analysis (STPA) and Early Warning Signal Analysis based on STPA (EWaSAP) methodology to systematically examine the sociotechnical structures for managing stream buffers in surface water catchments using a theoretical scenario representative of typical surface water supplies. The combination of STPA and EWaSAP provides a practical approach for developing requirements for stream buffers in drinking water catchments, focusing on hazard assessment and management measures. The evaluation considers the complex management arrangements for land uses within catchment areas. The performance and effectiveness of these actions can be tracked through the selected sensors and early warning measures. As a practical matter, this approach would help specify requirements for catchment management and drinking water source protection that can be systematically integrated into relevant management strategies. [ABSTRACT FROM AUTHOR]

The technology available to water quality management applications needs to be advanced due to greater use of automation to increase ease of operation, support remote operation and reduce risks due to operator error. In this case study, a comparison is made between System-Theoretic Process Analysis (STPA) and the Bow-tie methodology for identifying process hazards and countermeasures which can be used to guide the design and testing of an automated water quality management system (AWQMS). For this study, the application considered is a small hydroponics installation where water quality management has been automated. The STPA methodology uses a system theory-based approach to identify hazards, which include operational failures, human errors, and component interactions. The Bow-tie diagram focuses on individual barriers for a given threat which can prevent the realisation of a hazardous event and unwanted consequences. Thus, the 22 preventative barriers and seven recovery barriers identified through the Bow-tie diagram provide the design process with broad requirements for reducing the risks of user error as well as the ones associated with ongoing operations. The STPA method identified many Causal Factors (CF) generated from the Unsafe Control Actions after considering all the feasible scenarios. For design input, the STPA provided the design process with 204 specific CFs which were used to create 94 countermeasures to be included in software and hardware design as well as user information material. Both methods identified useful measures to control the hazards associated with human interaction with the AWQMS. However, the measures differed in the level of detail and the involvement in the evolution in the final system losses. In this study, the STPA process was able to identify several hazards which did not visibly relate to the Bow-tie barriers. However, the Bow-tie diagram illustrates a distinction between preventative and recovery hazard controls.

Ciprofloxacin (CIP) is a commonly used antibiotic, however, once in the environment, it is highly toxic with a poor biodegradability. Given these attributes, an effective strategy for the removal of CIP is urgently needed for the protection of water resources. Herein, a novel copper metal-organic framework (CuxO/MOF) multifunctional material has been produced, in this work, by the calcination of Cu-MOF urea at 300 °C, in the presence of a 5% H2 atmosphere. The morphological, structural, and thermal properties of the prepared CuxO/MOF were determined through various techniques, and its photocatalytic behavior was investigated for the degradation of CIP under visible-light irradiation. The prepared CuxO/MOF bifunctional material is presented as a graphitic carbon-layered structure with a particle size of 9.2 ± 2.1 nm. The existence of CuO-Cu2O-C, which was found on the CuxO/MOF surface, enhanced the adsorption efficiency and increased the photosensitivity of CuxO/MOF, towards the degradation of CIP in aqueous solutions. The tailored CuxO/MOF, not only shows an excellent CIP degradation efficiency of up to 92% with a constant kinetic rate (kobs) of 0.048 min−1 under visible light, but it can also retain the stable photodegradation efficiency of >85%, for at least six cycles. In addition, CuxO/MOF has an excellent adsorption capacity at pH 6.0 of the maximum Langmuir adsorption capacity of 34.5 mg g−1 for CIP. The results obtained in this study demonstrate that CuxO/MOF is a reliable integrated material and serves as an adsorbent and photocatalyst, which can open a new pathway for the preparation of visible-light-responsive photocatalysts, for the removal of antibiotics and other emerging pollutants. [ABSTRACT FROM AUTHOR]

This study investigated the indoor air quality (IAQ) conditions of carbon dioxide (CO2), carbon monoxide (CO), ozone (O3), formaldehyde (HCHO), total volatile organic compounds (TVOCs), and bio-aerosols (bacteria and fungi) in a respiratory type of medical facility in Chia-Yi County in southern Taiwan. Among those IAQ conditions, the concentrations of CO, O3, and HCHO exceeded the regulation values of the Taiwan Environmental Protection Administration (EPA) mostly in the morning. The concentrations of bacteria and fungi did not exceed the regulation values but still posed potential health and environment problems for workers, patients, and visitors. Therefore, self-made silver-coated zeolite (AgZ) was used as a filter material in air cleaners to remove bio-aerosols in the respiratory care ward (RCW), and the removals were still effective after 120 hr. The cumulative bio-aerosol removals for bacteria and fungi were 900 and 1,088 colony-forming units (CFU) g−1after 24 hr and were above 3,100 and 2,700 CFU g−1after 120 hr. From the research results, it is suggested that AgZ filtering could be used as a feasible engineering measure for hospitals to control their bacteria and fungi parameters in IAQ management. Hospitals should maintain their environmental management and monitoring programs and use different engineering measures to improve different IAQ parameters. [ABSTRACT FROM PUBLISHER]