1. High-Performance Ammonia QCM Sensor Based on SnO 2 Quantum Dots/Ti 3 C 2 T x MXene Composites at Room Temperature.
- Author
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Li, Chong, Tao, Ran, Hou, Jinqiao, Wang, Huanming, Fu, Chen, and Luo, Jingting
- Subjects
SEMICONDUCTOR nanocrystals ,QUARTZ crystal microbalances ,STANNIC oxide ,QUANTUM dots ,DETECTION limit - Abstract
Ammonia (NH
3 ) gas is prevalent in industrial production as a health hazardous gas. Consequently, it is essential to develop a straightforward, reliable, and stable NH3 sensor capable of operating at room temperature. This paper presents an innovative approach to modifying SnO2 colloidal quantum dots (CQDs) on the surface of Ti3 C2 Tx MXene to form a heterojunction, which introduces a significant number of adsorption sites and enhances the response of the sensor. Zero-dimensional (0D) SnO2 quantum dots and two-dimensional (2D) Ti3 C2 Tx MXene were prepared by solvothermal and in situ etching methods, respectively. The impact of the mass ratio between two materials on the performance was assessed. The sensor based on 12 wt% Ti3 C2 Tx MXene/SnO2 composites demonstrates excellent performance in terms of sensitivity and response/recovery speed. Upon exposure to 50 ppm NH3 , the frequency shift in the sensor is −1140 Hz, which is 5.6 times larger than that of pure Ti3 C2 Tx MXene and 2.8 times higher than that of SnO2 CQDs. The response/recovery time of the sensor for 10 ppm NH3 was 36/54 s, respectively. The sensor exhibited a theoretical detection limit of 73 ppb and good repeatability. Furthermore, a stable sensing performance can be maintained after 30 days. The enhanced sensor performance can be attributed to the abundant active sites provided by the accumulation/depletion layer in the Ti3 C2 Tx /SnO2 heterojunction, which facilitates the adsorption of oxygen molecules. This work promotes the gas sensing application of MXenes and provides a way to improve gas sensing performance. [ABSTRACT FROM AUTHOR]- Published
- 2024
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