Search

• A facile method of directly converting electroplating sludge into nickel-based energy storage composites. • The unique embedded multilevel nanostructure improves the effective reaction of active substances with electrolyte. • Fe-Al co-doped α-Ni(OH) 2 and Ni(HCO 3) 2 composites show high specific capacitance and good cycling stability. The recovery of heavy metals from electroplating sludge is an important technology, which can not only reduce environmental pollution, but also serve as a secondary source of metals. However, the current techniques are either non-selective or difficult to operate, which limits its applications in recovery technologies. Herein, based on the existence of multiple metal ions in electroplating sludge, Fe and Al co-doped ultrathin α-Ni(OH) 2 nanosheets embedded in Ni(HCO 3) 2 nanowire assembly spheres were prepared by adjusting the ratio of urea under hydrothermal condition. Under the optimum conditions, the recovery of Ni, Fe, and Al are 92.58%, 81.52%, and 61.19% respectively. In addition, at the current density of 1 A g−1, the specific capacitance of the spherical composite electrode is as high as 495.6 C g−1, and the retention rate of the initial capacity is 55.58% after 3500 cycles in 6 M KOH electrolyte, showing good cycling stability. Furthermore, the ASC device (NN-4//AC) achieved a high energy density of 30.27 Wh kg−1 at a power density of 0.37 kW kg−1. A new method for converting electroplating sludge into nickel-based energy storage materials was developed, which provided a new strategy and idea for the harmless and resourceful treatment of electroplating sludge. [ABSTRACT FROM AUTHOR]

Grassland aboveground biomass (AGB) is an important indicator for studying the change in grassland ecological quality and carbon cycle. The rapid development of high-resolution remote sensing and unmanned aerial vehicles (UAV) provides a new opportunity for accurate estimation of grassland AGB on the plot scale. In this study, the mountain grassland was taken as the research object. Using UAV Light Detection and Ranging (LiDAR) data and multispectral satellite images, the influence of topographic correction methods on AGB estimation was compared and a series of LiDAR metrics and vegetation indices were extracted. On this basis, a comprehensive indicator, the vegetation index-height-intensity model (VHI), was proposed to estimate AGB quickly. The results show that: (1) Among the four topographic correction methods, the Teillet regression has the best effect, and can effectively improve the accuracy of AGB estimation in mountain grassland. The correlation between corrected ratio vegetation index and AGB was the highest (correlation coefficient: 0.682). (2) Among the height and intensity metrics, median height and max intensity yielded the higher accuracy in estimating AGB, with Root Mean Square Error (RMSE) of 322 g/m2 and 333 g/m2, respectively. (3) The VHI integrated spectrum and LiDAR information, and its accuracy for AGB estimation for mountain grassland, was obviously better than other indicators, with an RMSE of 272 g/m2. We also found that the accuracy of VHI in univariate models was comparable to that of complex multivariate models such as stepwise regression, support vector machine, and random forest. This study provides a new approach for estimating grassland AGB with multi-source data. As a simple and effective indicator, VHI has shown strong application potential for grassland AGB estimating in mountainous areas, and can be further applied to grassland carbon cycle research and fine management. [ABSTRACT FROM AUTHOR]

[Display omitted] • The northwest area of the BTSSCP suffered severe dust-affected zones based on the dust flow trajectory. • The ESs in severe dust-affected areas were relatively poor. • ESs and the dust flow trajectory were integrated to identify ecological governance zones. • Governance suggestions were proposed for the ecological management zone combined with the driving forces. Achieving ecological conservation and governance based on ecosystem services (ESs) can balance regional ecological protection and development, which is of great significance for sustainable development. Existing research has mainly focused on the extraction of priority ecological conservation areas, thereby neglecting to consider the classification and management of ecological engineering areas. To improve regional ecological governance, we combine ESs and dust movement trajectory, using the Beijing-Tianjin Sandstorm Source Control Project (BTSSCP) as the research object to generate watersheds' ecological governance zones. Six ESs were assessed to determine ecological zones. Trajectory simulation of dust movement, using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model and potential source contribution function, was used to determined zones affected by dust. By combining these two aspects, five main ecological governance clusters were identified. We found that: (1) the area with low ESs in the northwest of the BTSSCP suffered from severe dust impacts; (2) slight dust-affected zones were mainly distributed in the eastern of the BTSSCP, and in the area, ESs gradually decreased from south to north; (3) ESs in the region was primarily influenced by natural factors and the influencing factors of ESs vary among different zones. These findings will not only contribute to the overall planning and governance of the BTSSCP, but can offer general guidance for the formulation of targeted ecological protection and restoration measures in other areas. [ABSTRACT FROM AUTHOR]

• CoNi-LDH with a hierarchical hollow cage structure has been synthesized. • Two-step water-assisted coprecipitation method is utilized at room temperature. • The synergic effect of nickel nitrate adsorption on bimetallic CoNi-ZIF is optimized. • The assembled ASC supercapacitor device delivers excellent energy density, power density and cyclic stability. Single imidazolate framework-67 (ZIF-67) is commonly used as a template to prepare layered double hydroxides (LDHs) with specific morphology to improve the performance of materials. Herein, the Co2+ ion in ZIF-67 is partially substituted by Ni2+ to obtain the dodecahedron bimetallic imidazolate framework (CoNi-ZIF). Subsequently, using bimetallic CoNi-ZIF as the sacrificial template, CoNi-LDH hierarchical hollow cage structures with wrinkled nanosheet arrays are synthesized at room temperature and in aqueous solution by an inexpensive and environment friendly surfactant-free approach. The optimized etched CoNi-LDH4 has a maximum specific capacitance of 1877 F g−1 at a current density of 1 A g−1, and cycling stability of 99.89% after 5000 cycles, which is significantly better than that of ZIF-67 derived CoNi-LDH67 (1357 F g−1 at 1 A g−1, cycling stability of 73.35%). The asymmetric supercapacitor with CoNi-LDH4 as a cathode and activated carbon (AC) as anode has an energy density of 49.3 Wh kg−1 at 750 W kg−1 power output and stable cycling performance (capacity retention of 92.13% after 5000 cycles). This study shows the prospect of bimetallic CoNi-ZIF derived LDHs nanostructures prepared at room temperature and in aqueous solution to improve the performance and stability of supercapacitors. [ABSTRACT FROM AUTHOR]

Changed land use patterns are the most direct manifestation of ecological engineering implemented by humans, being among the driving factors for changes in ecosystem services (ESs). However, different ecological engineering governance measures can lead to different changes in land use, resulting in corresponding changes to ESs and ecosystem service value (ESV), yet these changes is the content that needs to be clarified. In this study, four kinds of ESs, namely water yield, soil conservation, carbon storage and water purification, were quantified in part region of the Beijing-Tianjin Sandstorm Source Control Project (BTSSCP). In addition, eight scenarios were simulated according to the land use change caused by engineering management measures, and the ESs and ESV ensuing under these differing scenarios quantified accordingly. The results show that the main land use types in the study area from 2000 to 2020 were cropland and forestland, while during this period land use change mainly consisted of the expansion of grassland (+466.79 km2) and loss of cropland (−2095.27 km2). For different engineering management measures, protective governance will play a greater role in improving ESs than restoration governance. Protecting the existing governance outcomes from degrading can maintain a water yield of 36.85 × 108 m3, soil conservation of 73.72 × 106 t, carbon storage of 89.01 × 106 t, the purified water nitrogen content of 1.21 × 106 t, with the total ESV maintained at 54.237 billion yuan. Moreover, the high-investment counties clearly engage in ecological restoration that provides high ESV. Yet, there are still some counties with high project investment where the gains in ESV are low, such as Luanping county and Pingquan county. Therefore, it should be reasonably distributed based on the existing governance results in the next round of project investment allocation. In the past 20 years, engineering governance measures have significantly improved the ESs in the region. Nevertheless, looking ahead, it remains necessary to strengthen the emphasis on protecting governance outcomes. [Display omitted] • Scenario simulations were run under governance measures for ecological engineering. • Ecosystem service value (ESV) under differing governance measures were simulated. • ESV is higher when ecological protection rather than restoration measures are used. • Project investment vis-à-vis ESV under the different scenarios were analyzed. [ABSTRACT FROM AUTHOR]

The main objective of this study was to investigate the effects of combining subsoil and incorporation of corn stover on soil profile, soil physicochemical properties, and corn yield. A five-year field trial was conducted that consisted of two treatments arranged in a completely random design and replicated three times. Two soil management operations were tested: subsoil + corn stover incorporation (plow construction [PC] treatment) and conventional rotary tillage (control check [CK] treatment). Compared with rotary tillage, it was found that combining subsoil and corn stover incorporation significantly affected corn grain yield in all seasons. Further, combining subsoil and corn stover incorporation significantly increased the thickness of the plow layer, quantity of plow layer soil, thickness of the plow pan and soil bulk density, as well as soil organic matter, available nitrogen, available phosphorus, and available potassium. Evidence indicates that reconstructing the soil plow layer through combination of subsoil and corn stover incorporation improved soil structure, nutrient content, and corn yield. It is of interest that farmers are now applying subsoil and returning crop straw instead of solely relying on rotary tillage. [ABSTRACT FROM PUBLISHER]