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Pollen and spore records in prodeltaic sediments hold significant potential for reconstructing paleoecologic and paleoclimatic evolution. However, uncertainties in these reconstructions arise from millennial-scale prodelta evolution, which dominates stratigraphic development and consequently influences sedimentary processes and/or pollen provenance. Here we explore the intricate relationship between pollen/spore records and prodelta stratigraphic evolution, using established seismic stratigraphy and ten sediment cores (five new, five from literature) within both the proximal and distal (mud belt) parts of the Huanghe (Yellow River) prodelta. In the proximal region, dominant lobate stratigraphic development, accompanied by shifts in river mouth and depocenter, leads to variations in pollen assemblages and contents within individual cores and differences in vertical pollen distribution across core sites. Transport distance appears to be a key factor, with arboreal pollens, particularly saccate ones (e.g., Pinus), positively correlating with the distance from the river mouth in their percentages within a single delta lobe, while non-arboreal and non-saccate arboreal pollens show higher percentages within shorter transport distances, despite longer distances leading to decreased total pollen concentrations. Likely due to the total pollen concentration after extended long-distance transport, this pattern is not observable in the distal mud belt. Subsurface stratigraphy in this mud belt reveals a complex pollen provenance characterized by Artemisia-Ulmus-Chenopodiaceae-Pinus, with non-arboreal pollens in dominance. Therein, non-arboreal pollens are not consistent with deposition from long-distance transport, and Ulmus pollens are uncommon in the western Bohai Sea. Interestingly, surface sediments in the mud belt display a different assemblage, characterized by Pinus-Artemisia-Quercus, consistent with the nearby Luanhe River prodelta, suggesting recent pollen supply from nearby sources, possibly due to the recent abandonment of the mud belt. Additionally, an energetic longshore transport/erosional regime reduces pollen content at the mud-belt margins and create pollen sinks (with the highest concentration) in the mud patch (accumulation area) within the erosion-dominated region adjacent to the mud belt. Our findings confirm that stratigraphic evolution, alongside hydrodynamic conditions and pollen provenance, governs pollen assemblages in deltaic/prodeltaic sediments. They can provide insights for palynological and pollen-based paleoclimatic and paleoecologic studies in other deltas. [ABSTRACT FROM AUTHOR]

The hydrographic, climate, hydrological, and landscape features of the Huanghe R. Basin are considered. Water runoff and suspended sediment load in the Huanghe R. are shown to have dropped significantly in 1950-2009 under the effect of regional climate changes and economic activity in the basin. Water balance method and the concept of flow transport competency were used to assess the contribution of natural and anthropogenic factors (decline in precipitation, water withdrawal for economic needs, and the effect of reservoirs) to the decrease in river water runoff and suspended sediment load. [ABSTRACT FROM AUTHOR]

The magnesium (Mg) isotopic composition of river waters is mainly controlled by riverine Mg sources and geochemical processes. It is meaningful to characterize Mg isotope behavior for us in understanding chemical weathering and other geochemical processes, such as secondary mineral formation linked to environmental conditions. The Huanghe basin was chosen to investigate the behavior of Mg isotopes during river erosion in temperate-semiarid and arid climate. Dissolved Mg shows a wide range of δ 26 Mg values, ranging from − 1.53 ‰ to − 0.11 ‰, with most values being close to − 1.09 ‰. By comparison, most of the suspended loads are enriched in heavy Mg isotope, with δ 26 Mg values ranging from − 2.00 ‰ to − 0.62 ‰, which is controlled by mineralogy. The Mg isotopic composition in the upstream is mainly determined by the mixture between carbonate and silicate sources. When the Huanghe flows through the Loess Plateau, the dissolved Mg decreased due to the dissolution of easily dissoluble phases in loess, such as MgCl 2 or MgSO 4 . Carbonates weathering and evaporites dissolution are the major controlling factor of the evolution of Mg isotopic composition in dissolved phase, though evaporation-related precipitation of secondary carbonates also influences the dissolved Mg isotope composition in some tributaries. The strong relationships between δ 26 Mg and pH, temperature, and δ 18 O suggest that the Mg isotope system bears significant information about the hydrogeochemical characteristics and climate conditions of the Huanghe basin. [ABSTRACT FROM AUTHOR]

The influence of hydrodynamics on the chemical composition of sediments is based on the uneven distribution of element abundances in different size fractions. In this study, 72 size-fractional sediments from the Huanghe (Yellow River) and Changjiang (Yangtze River) riverbeds were measured with XRD, SEM, ICP-AES and ICP-MS. The analysis results show that the mineral and chemical characteristics change with grain size in the Huanghe and Changjiang sediments. According to the principal components analysis, three independent geochemical factors were found. The first factor elements, Zr, Hf, Th, U, Y, La and TiO2 are influenced by the existence of heavy minerals. The second factor elements, Al2O3, alkalis, alkaline earth (excluding Ca and Sr) and most of the transitional metals are dominated by clay minerals. The third factor group includes Ca and Sr, which were controlled by calcium-bearing mineral contents and chemical weathering intensities. The various grain size distributions greatly affect the mineralogical and chemical compositions of bulk sediments. Compared to other size fractions, the 5-6PHI size fractions of the Huanghe and Changjiang sediments have special mineralogical and chemical compositions, and intermediate volume percentages. Weight or volume percentage of each size fraction may be more suitable than mean grain-size of the bulk sediment to elucidate the grain size effects. Chemical Index of Alteration (CIA) values increase steeply with decreasing grain size, while Weathering Index of Parker (WIP) values are relatively stable. Because of the big influence of the abundance of clay minerals on CIA values, it is questionable to use CIA as a proxy of weathering intensity. Considering the clay mineral effects, stability in values and heterogeneous material properties, WIP has the potential to indicate the chemical weathering intensity of sediments. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Nutrient transport patterns in the Huanghe (Yellow River) were investigated using biogeochemical observations carried out during 2001–2011 to examine how nutrient transports were affected by water–sediment regulation events and their potential effects on the adjacent Bohai ecosystem. The concentrations and composition of nutrients in the Huanghe had an obvious change during the water–sediment regulation events, which increased dissolved nutrient transports with a similar amplitude like freshwater discharge, while amplified particulate nutrient transports. Dissolved inorganic nitrogen was the predominant species of total dissolved nitrogen. Particulate phosphorus was the major form of phosphorus affected by high content of suspended particulate matter. Phosphate represented 68% of total dissolved phosphorus. The BSi was 20% of the sum of BSi and dissolved silicate. Nutrient transport patterns highly depend on freshwater discharge. The regulation events have shifted the seasonal patterns of water and nutrient transports with high flow condition occurring at least two months prior to the normal peak flow. Abundant nutrients were transported to the coastal water and nutrient imbalance was aggravated, most likely resulting in strong impacts on the adjacent Bohai ecosystem. [ABSTRACT FROM AUTHOR]

Abstract: We present a provenance study of core ZK2 from the Huanghe (Yellow River) Delta in order to assess the impacts of climate change on the sediment supplies during the last glacial–interglacial cycle. Facies analysis and sequence stratigraphy methods are used to construct the age model. Sr isotopic compositions of ZK2 range from 0.716389 to 0.723884, with 87Sr/86Sr increased with decreasing grain size. Nd and Pb isotopic compositions display two large major excursions during Marine Oxygen Isotope stages (MIS) 2 and 4, with less radiogenic εNd and lower 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb values during these periods. These excursions have been explained in terms of changes in the mixing proportion of sediments from the Loess Plateau and Ordos Plateau, resulting from East Asian monsoon intensity variations. The weak summer monsoon precipitation resulted in decreased erosion of Loess Plateau during MIS 2, 4 and the middle of MIS 3. Meanwhile, both the intensified East Asian winter monsoon and the southward expansions of Mu Us desert significantly enhanced the eolian sand entering the Huanghe. Therefore, our results highlight the impact of monsoon variability on erosion patterns in the Huanghe basin. [Copyright &y& Elsevier]

The Huanghe River (Yellow River) had been the second largest river in the world in terms of sediment load to the sea; however, the river water discharge and sediment flux to the sea and their seasonal variability have been significantly altered by the dam activities and recent water–sediment regulation. These changes are believed to have important impacts on the flux of phosphorus that is generally transported in particulate form. In this article, the samples of suspended particulate matter (SPM) were collected at the Lijin Station during two high-discharge events in 2005 and were separated by particle size. Sequential extractions were applied to determine the forms of P in different particle size fractions and to assess the potential bio-availability of particulate phosphorus (PP). Based on the in-laboratory measurement, the impacts of different hydrological regimes on the source of PP and its bio-availability were also analyzed. The results indicate that exchangeable, organic, authigenic, and refractory P were preferentially associated with clay, very fine, and fine silt fractions. Detrital P was mainly associated with the medium and coarse silt fractions. Detrital P and authigenic P (two forms of calcium bound phosphorus) were the dominant fractions in all samples. Thus, the potential bio-available PP (exchangeable P and organic P) was mainly associated with the finer particles, such as clay. Higher content of exchangeable, organic, authigenic, and residual P and lower content of detrital P were found during the period of rainstorm compared to that of WSR. P forms and partitioning of P forms among different particle size fractions were assumed to depend on the sources of SPM. It is likely that the pathways and fates of PP forms were controlled by damming and by the related changes of hydrological regime. Therefore, anthropogenic changes of hydrological regime and particle size dominanted the amount and distribution pattern of bio-available P transportation to the estuary and the adjacent sea, which will have profound impacts on the marine ecosystems at the Huanghe River Estuary and even the Bohai Sea. [ABSTRACT FROM AUTHOR]

Concentrations of 25 elements in the fine-grained fraction (<63 μm) of bottom sediments of the Changjiang and the Huanghe were determined to characterize the geochemical compositions of each riverine origin. Most of the elements, except for alkali and alkaline earth elements (Na, Ca, Sr and Ba), are highly enriched in the Changjiang sediments compared to those in the Huanghe sediments. Differences in source rocks and weathering mechanisms between the two drainage basins are the major factors controlling those compositional characteristics. The provenance index of core sediments from the northern Jiangsu coastal plain, calculated with nine elements with distinct compositional differences between both river sediments, indicates that the Changjiang had prevailed in the coastal plain sedimentation during the early stage of Holocene, while the Huanghe dominated over the area during the late Holocene. However, neither of the signatures of the modern Changjiang- and Huanghe-derived sediments is remarkable in the present-day coastal plain. [Copyright &y& Elsevier]