23 results on '"Hui Je Jo"'
Search Results
2. U–Th isotopic microanalysis of zircon reference materials and KBSI working standards
- Author
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Youn-Joong Jeong, Shinae Lee, Sook Ju Kim, Hui Je Jo, Keewook Yi, and Albert Chang-sik Cheong
- Subjects
Zircon standard ,U–Th isotopes ,Uranium-series disequilibrium dating ,Laser ablation-ICPMS ,Chemistry ,QD1-999 ,Analytical chemistry ,QD71-142 - Abstract
Abstract Background The 238U–230Th disequilibrium dating of the mineral zircon (ZrSiO4) provides an efficient tool for investigating the time scales of Quaternary magmatic processes. In situ mass spectrometric U–Th microanalysis of zircon requires careful calibration and correction of the measured isotope data, particularly for the instrumental fractionation of U and Th isotopes. Findings For the selection of suitable calibration materials for U–Th isotopic analysis using a laser ablation multiple collector inductively coupled plasma mass spectrometer (LA-MCICPMS), we estimated the homogeneity of four reference zircons (91500, TEMORA 2, FC1, and Plešovice) and two zircon working standards (LKZ-1 and BRZ-1) in terms of their 232Th/238U ratios, based on the Pb isotopic compositions measured by a sensitive high-resolution ion microprobe (SHRIMP). The measured LA-MCICPMS 232Th/238U ratios of the zircons were calibrated externally using the SHRIMP 208Pb/206Pb-based average value of the 91500 zircon, 232Th/238U = 0.351 ± 0.035 (error corresponds to 1 standard deviation). The molecular interference-corrected 230Th/232Th ratios of the zircons were calibrated based on the assumption that the Plešovice zircon is in 238U–230Th secular equilibrium. After the calibration and correction, the activity ratios of 230Th/232Th and 238U/232Th for all reference zircons and working standards were plotted on the equiline. Conclusions This study confirms that the 91500 zircon is relatively homogeneous in terms of U/Th ratios (relative standard deviation = ~ 10%) and does not support a recent claim that the Plešovice zircon is not in 238U–230Th radioactive equilibrium. The working standards LKZ-1 and BRZ-1 can be used to check the reliability of U–Th isotopic analyses for Quaternary zircons.
- Published
- 2018
- Full Text
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3. Determination of Sr–Nd–Pb Isotopic Ratios of Rock Reference Materials Using Column Separation Techniques and TIMS
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Hui Je Jo, Hyo Min Lee, Go-Eun Kim, Won Myung Choi, and Taehoon Kim
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separation chemistry ,TIMS ,Sr–Nd–Pb isotopes ,rock reference material ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Thermal ionization mass spectrometry (TIMS) can provide highly accurate strontium (Sr), neodymium (Nd), and lead (Pb) isotope measurements for geological and environmental samples. Traces of these isotopes are useful for understanding crustal reworking and growth. In this study, we conducted a sequential separation of Sr, Nd, and Pb and subsequently measured the 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of 13 widely used rock certified reference materials (CRMs), namely BCR-2, BHVO-2, GSP-2, JG-1a, HISS-1, JLk-1, JSd-1, JSd-2, JSd-3, LKSD-1, MAG-1, SGR-1, and 4353A, using TIMS. In particular, we reported the first isotopic ratios of Sr, Nd, and Pb in 4353A, Sr and Nd in HISS-1 and SGR-1, and Sr in JLk-1, JSd-2, JSd-3, and LKSD-1. The Sr–Nd–Pb isotopic compositions of most in-house CRMs were indistinguishable from previously reported values, although the Sr and Pb isotopic ratios of GSP-2, JSd-2, JSd-3, and LKSD-1 obtained in different aliquots and/or batches varied slightly. Hence, these rock reference materials can be used for monitoring the sample accuracy and assessing the quality of Sr–Nd–Pb isotope analyses.
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- 2021
- Full Text
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4. Tectonomagmatic evolution of a Jurassic Cordilleran flare-up along the Korean Peninsula: Geochronological and geochemical constraints from granitoid rocks
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Albert Chang-sik Cheong and Hui Je Jo
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Subduction ,Pluton ,Geochemistry ,Geology ,Massif ,010502 geochemistry & geophysics ,01 natural sciences ,Mantle (geology) ,Cretaceous ,Magmatism ,Arc system ,Shear zone ,0105 earth and related environmental sciences - Abstract
This study used new and published U-Pb geochronological, chemical, and Sr-Nd-Hf-O isotopic data (n > 2500) from Jurassic granite-granodiorite-diorite-monzonite-gabbro plutons in the southern part of the Korean Peninsula to assess the spatiotemporal evolution of a flare-up magmatism, its tectonic connection, and specific contributions of mantle and crustal reservoirs to the magmas generated. After a ~15 m.y. magmatic gap in the Late Triassic, calc-alkaline granitoids intruded into the outboard Yeongnam Massif, then magmatic activity migrated systematically toward the inboard Gyeonggi Massif. The early phase of the Jurassic magmatism is represented by relatively sodic plutons showing distinctly primitive isotopic signatures. The crustal signature of the plutons became increasingly prominent with decreasing age. Voluminous inboard plutons in the Gyeonggi Massif and the intervening Okcheon Belt are dominated by Middle Jurassic peraluminous granites that show isotopic compositions conspicuously shifted toward old crustal values. The Nd-Hf isotopic compositions of the inboard plutons are distinctly less radiogenic than those of Jurassic plutons in Southwest Japan and southeastern China, which corroborates the North China affinity of the Yeongnam and Gyeonggi massifs. The geochronological and geochemical data compiled in this study suggest a tectonomagmatic model consisting sequentially of (1) an extension-dominated arc system in the margin of the Yeongnam Massif (ca. 200–190 Ma); (2) low-angle subduction and the development of an advancing arc system (ca. 190–180 Ma); (3) continued low-angle subduction, extensive underthrusting of fertile crustal materials to the arc root, and consequent magmatic flare-up (ca. 180–170 Ma); and (4) flat subduction and the development of the Honam Shear Zone (ca. 170–160 Ma). The subsequent magmatic lull and previous dating results for synkinematic rocks and minerals indicate that the compressional arc system was maintained until the Early Cretaceous.
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- 2020
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5. Determination of Sr–Nd–Pb Isotopic Ratios of Rock Reference Materials Using Column Separation Techniques and TIMS
- Author
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Go-Eun Kim, Won Myung Choi, Hui Je Jo, Hyo Min Lee, and Tae Hoon Kim
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Strontium ,Materials science ,Isotope ,Physics ,QC1-999 ,Analytical chemistry ,chemistry.chemical_element ,Filtration and Separation ,Thermal ionization mass spectrometry ,Sr–Nd–Pb isotopes ,Neodymium ,Analytical Chemistry ,Chemistry ,Certified reference materials ,chemistry ,separation chemistry ,TIMS ,rock reference material ,QD1-999 - Abstract
Thermal ionization mass spectrometry (TIMS) can provide highly accurate strontium (Sr), neodymium (Nd), and lead (Pb) isotope measurements for geological and environmental samples. Traces of these isotopes are useful for understanding crustal reworking and growth. In this study, we conducted a sequential separation of Sr, Nd, and Pb and subsequently measured the 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of 13 widely used rock certified reference materials (CRMs), namely BCR-2, BHVO-2, GSP-2, JG-1a, HISS-1, JLk-1, JSd-1, JSd-2, JSd-3, LKSD-1, MAG-1, SGR-1, and 4353A, using TIMS. In particular, we reported the first isotopic ratios of Sr, Nd, and Pb in 4353A, Sr and Nd in HISS-1 and SGR-1, and Sr in JLk-1, JSd-2, JSd-3, and LKSD-1. The Sr–Nd–Pb isotopic compositions of most in-house CRMs were indistinguishable from previously reported values, although the Sr and Pb isotopic ratios of GSP-2, JSd-2, JSd-3, and LKSD-1 obtained in different aliquots and/or batches varied slightly. Hence, these rock reference materials can be used for monitoring the sample accuracy and assessing the quality of Sr–Nd–Pb isotope analyses.
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- 2021
- Full Text
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6. Lithospheric thinning and ignition of a Cordilleran magmatic flare-up: Geochemical and O-Hf isotopic constraints from Cretaceous plutons in southern Korea
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Albert Chang-sik Cheong, Min-Ji Jung, Hui Je Jo, Jeongmin Kim, Shinae Lee, and Youn-Joong Jeong
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General Earth and Planetary Sciences - Published
- 2023
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7. Recurrent Quaternary magma generation at Baekdusan (Changbaishan) volcano: New zircon U-Th ages and Hf isotopic constraints from the Millennium Eruption
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Albert Chang-sik Cheong, Young Kwan Sohn, Youn-Joong Jeong, and Hui Je Jo
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Geochemistry ,Trachyte ,Geology ,Magma chamber ,010502 geochemistry & geophysics ,01 natural sciences ,Volcano ,Magma ,Caldera ,Stratovolcano ,Quaternary ,0105 earth and related environmental sciences ,Zircon - Abstract
It is well known that Baekdusan (Changbaishan), an active 2744-m-high stratovolcano located on the border between North Korea and China, initiated trachytic/commenditic eruption in the Pleistocene but the petrogenetic and temporal evolutions of this alkaline magma system remain insufficiently constrained. The so-called “Millennium Eruption” (ME) in the mid-10th century, which resulted in the formation of the world's highest caldera lake (Cheonji, or Tianchi) atop the mountain, was one of the largest and most violently explosive volcanic eruptions to have occurred on Earth in the past 2000 years. Here, we present U–Th disequilibrium ages and Hf isotopic compositions of zircons from trachydacitic pumices ejected during the ME. Taken together with the previous U–Th isotope data, our laser ablation-multicollector ICPMS analyses of the zircons yielded multiple age components consisting of an earliest Holocene cluster (11.3 ± 1.3 ka) and Middle–Late Pleistocene populations (ca. 230 and 110 ka), which indicates that Baekdusan magma has been generated episodically at intervals of ca. 120–100 ky. If the eruption ages assigned for the samples analyzed in the previous isotopic studies are correct, the consistent age pattern of zircon may suggest the persistent existence of the same magmatic plumbing system beneath Baekdusan since the ME. The wide range of zircon eHf values (+5.8 to −3.5) reflects an interaction between the EM1-type primitive magma and pre-existing crustal materials, evidenced by the presence of a xenocrystic zircon core showing a significantly negative eHf value (=−21). A broad negative correlation observed between zircon eHf and the published δ18O values can be ascribed to the progressive assimilation of weathered supracrustal rocks, likely in the course of magma chamber expansion.
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- 2019
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8. Magmatic response to the interplay of collisional and accretionary orogenies in the Korean Peninsula: Geochronological, geochemical, and O-Hf isotopic perspectives from Triassic plutons
- Author
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Youn-Joong Jeong, Xian-Hua Li, Albert Chang-sik Cheong, and Hui Je Jo
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Peninsula ,Pluton ,Geochemistry ,Geology ,010502 geochemistry & geophysics ,01 natural sciences ,0105 earth and related environmental sciences - Published
- 2018
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9. U–Th isotopic microanalysis of zircon reference materials and KBSI working standards
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Hui Je Jo, Albert Chang-sik Cheong, Shinae Lee, Keewook Yi, Sook Ju Kim, and Youn-Joong Jeong
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Microprobe ,010504 meteorology & atmospheric sciences ,lcsh:Analytical chemistry ,General Physics and Astronomy ,Mineralogy ,010502 geochemistry & geophysics ,Mass spectrometry ,01 natural sciences ,Microanalysis ,General Biochemistry, Genetics and Molecular Biology ,lcsh:Chemistry ,General Materials Science ,0105 earth and related environmental sciences ,General Environmental Science ,Isotope analysis ,Laser ablation-ICPMS ,lcsh:QD71-142 ,Isotope ,General Chemistry ,Secular equilibrium ,Zircon standard ,U–Th isotopes ,lcsh:QD1-999 ,Inductively coupled plasma ,Uranium-series disequilibrium dating ,Geology ,Zircon - Abstract
Background The 238U–230Th disequilibrium dating of the mineral zircon (ZrSiO4) provides an efficient tool for investigating the time scales of Quaternary magmatic processes. In situ mass spectrometric U–Th microanalysis of zircon requires careful calibration and correction of the measured isotope data, particularly for the instrumental fractionation of U and Th isotopes. Findings For the selection of suitable calibration materials for U–Th isotopic analysis using a laser ablation multiple collector inductively coupled plasma mass spectrometer (LA-MCICPMS), we estimated the homogeneity of four reference zircons (91500, TEMORA 2, FC1, and Plešovice) and two zircon working standards (LKZ-1 and BRZ-1) in terms of their 232Th/238U ratios, based on the Pb isotopic compositions measured by a sensitive high-resolution ion microprobe (SHRIMP). The measured LA-MCICPMS 232Th/238U ratios of the zircons were calibrated externally using the SHRIMP 208Pb/206Pb-based average value of the 91500 zircon, 232Th/238U = 0.351 ± 0.035 (error corresponds to 1 standard deviation). The molecular interference-corrected 230Th/232Th ratios of the zircons were calibrated based on the assumption that the Plešovice zircon is in 238U–230Th secular equilibrium. After the calibration and correction, the activity ratios of 230Th/232Th and 238U/232Th for all reference zircons and working standards were plotted on the equiline. Conclusions This study confirms that the 91500 zircon is relatively homogeneous in terms of U/Th ratios (relative standard deviation = ~ 10%) and does not support a recent claim that the Plešovice zircon is not in 238U–230Th radioactive equilibrium. The working standards LKZ-1 and BRZ-1 can be used to check the reliability of U–Th isotopic analyses for Quaternary zircons.
- Published
- 2018
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10. Juxtaposition of allochthonous terranes in the central Korean Peninsula: Evidence from zircon U-Pb ages and O-Hf isotopes in Jurassic granitoids
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Xian-Hua Li, Hui Je Jo, Keewook Yi, and Albert Chang-sik Cheong
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Continental collision ,Metamorphism ,Geology ,Orogeny ,Massif ,010502 geochemistry & geophysics ,01 natural sciences ,Paleontology ,Craton ,Geochemistry and Petrology ,Protolith ,0105 earth and related environmental sciences ,Terrane ,Zircon - Abstract
The eventual docking of an exotic continental mass over the course of a Wilson cycle is marked by intracontinental sites of prograde metamorphism, contractional deformation, and syn- or post-collisional magmatism. This study shows that inherited premagmatic zircon in subsequently emplaced granitoid rocks provides another line of evidence for the collisional orogeny. Following the continental collision between the North and South China Cratons, Jurassic granitoids intruded widely throughout the central Korean Peninsula in association with the subduction of the Paleo-Pacific plate. The latest Early to Middle Jurassic (177–167 Ma) granitoids occur throughout the cratonic Gyeonggi Massif, whereas Early Jurassic (194–184 Ma) granitoids occur locally along the Okcheon Metamorphic Belt to the southeast of the massif. These two spatiotemporal groups differ profoundly in their age patterns and O-Hf isotopic signatures of inherited zircon. The younger group yields a typically North China-like Archean-Paleoproterozoic (mostly 2.5–1.8 Ga) zircon inheritance. In contrast, inherited zircons from the older group exhibit exclusively Neoproterozoic (ca. 0.9–0.7 Ga) and Paleozoic (ca. 0.4 Ga) cluster along with Archean-Paleoproterozoic populations. The exotic feature of the protolith of the older group is further indicated by significantly lower δ18O (− 0.9 to + 4.9‰) and positive eHf (+ 3 to + 15) values of the Cryogenian zircon cores. The results of zircon analysis demonstrate that South and North China-like terranes were juxtaposed infracrustally along the southeastern margin of the Gyeonggi Massif during the pre-Jurassic collisional orogeny, and then selectively provided major source material to the older and younger Jurassic granitoids, respectively.
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- 2018
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11. Latest Pleistocene crustal cannibalization at Baekdusan (Changbaishan) as traced by oxygen isotopes of zircon from the Millennium Eruption
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Kye-Hun Park, Hui Je Jo, Young Kwan Sohn, Albert Chang-sik Cheong, Xian-Hua Li, Youn-Joong Jeong, and Youn Soo Lee
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Earth science ,Geochemistry ,Silicic ,Geology ,Magma chamber ,Volcanism ,Volcanic explosivity index ,010502 geochemistry & geophysics ,01 natural sciences ,Isotopes of oxygen ,Dense-rock equivalent ,Volcano ,Geochemistry and Petrology ,0105 earth and related environmental sciences ,Zircon - Abstract
The silicic volcanism of Baekdusan (Changbaishan), which is on the border between North Korea and China, was initiated in the Late Pleistocene and culminated in the 10th century with a powerful (volcanic explosivity index = 7) commendite–trachyte eruption commonly referred to as the “Millennium Eruption.” This study presents oxygen isotope data of zircon in trachydacitic pumices ejected during the Millennium Eruption, together with whole-rock geochemical and Sr–Nd–Pb isotopic data that manifest once again the A-type and EM1 affinities of the Millennium Eruption magma. The zircon crystals, dated by previous studies at ca. 12–9 ka, show a moderate inter-grain variation in δ18O from 3.69‰ to 5.03‰. These values are consistently lower than the normal mantle range, and interpreted to have resulted from the digestion of meteoric-hydrothermally altered intracaldera rocks in the shallow magma chamber beneath Baekdusan just prior to the crystallization of the zircons, rather than from derivation from low-δ18O sources deep in the mantle. The whole-rock geochemical/isotopic considerations suggest that the magma mainly self-cannibalized the earlier erupted volcanic carapace around the magma chamber. This study highlights the usefulness of zircon oxygen isotopes for characterizing past volcanic activity that has now been commonly eroded away and implies that the generation of Yellowstone-type low-δ18O magma is not a rare phenomenon in large-volume silicic eruptions.
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- 2017
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12. Crustal evolution in the Gyeongsang Arc, southeastern Korea: Geochronological, geochemical and Sr-Nd-Hf isotopic constraints from granitoid rocks
- Author
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Hui Je Jo and Albert Chang-sik Cheong
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010504 meteorology & atmospheric sciences ,Subduction ,Pluton ,Geochemistry ,Crust ,010502 geochemistry & geophysics ,01 natural sciences ,Adakite ,General Earth and Planetary Sciences ,Arc system ,Petrology ,Paleogene ,Geology ,0105 earth and related environmental sciences ,Terrane ,Zircon - Abstract
A loosely assembled patchwork of Cretaceous to Paleogene granitoid plutons comprise the platform of the Gyeongsang Arc in southeastern Korea and represent a high-flux pulse of magmatism in Northeast Asia. The present study uses new and published zircon U-Pb ages, whole-rock geochemical and Sr-Nd isotopic data, and zircon Hf isotopic data of the plutons to decipher the crustal evolution in the Gyeongsang Arc and compare it with adjacent accretionary terranes. The ion microprobe zircon U-Pb ages range from 91 to 27 Ma, revealing the selective occurrence of Paleogene plutons in the eastern coastal area, to the east of the NNE-trending Yangsan fault system. Paleoproterozoic to Paleogene xenocrystic cores are occasionally observed in the zircon grains. The plutons are composed of dominantly magnesian, high- to medium-K calc-alkaline granites-granodiorites exhibiting typical geochemical characteristics of subduction zone magma, and less abundant ferroan alkaline granites. Their trace element patterns require residual amphibole and feldspar, but not garnet in the source. The whole-rock Sr-Nd and zircon Hf isotopic compositions of the granitoids (initial 87Sr/86Sr = 0.7043 to 0.7069; eNd(t) = –4.8 to +2.9; eHf(t) = –5.0 to +19.7) are distinctly more primitive than those of inland granitoids distributed outside of the Gyeongsang backarc basin. An important role of relatively young, most likely Paleozoic juvenile crust in the formation of the Late Cretaceous granitoids is suggested by the time-eHf trend of high-eHf zircons that converges toward data points of the Late Permian Yeongdeok adakite composing the arc basement. The asthenospheric mantle input is highlighted by significantly high (>+17) eHf(t) values of some zircons from the early Eocene alkaline plutons. Subsequent reworking of the rejuvenated crust yielded granitoid plutons possessing slightly but recognizably higher eNd(t) and eHf(t) values than the older plutons. These isotopic features demonstrate that the Cretaceous-Paleogene calc-alkaline granitoids in the Gyeongsang Arc are not “juvenile” (sensu stricto) despite their mostly positive epsilon Nd and Hf values, but are basically a product of crustal reworking. The Sr-Nd-Hf isotopic compositions of Late Cretaceous granitoids in the Gyeongsang Arc are comparatively more primitive than those in adjacent accretionary terranes such as Southwest Japan and Fujian province in southeastern China, reflecting differences in the formation age of the basement on which the arc system was built.
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- 2017
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13. LKZ-1: A New Zircon Working Standard for the In Situ Determination of U–Pb Age, O–Hf Isotopes, and Trace Element Composition
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Albert Chang-sik Cheong, Xian-Hua Li, Youn-Joong Jeong, Ho-Sun Lee, Shinae Lee, Sandra L. Kamo, Keewook Yi, Nak Kyu Kim, Hui Je Jo, and Changkun Park
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lcsh:QE351-399.2 ,Analytical chemistry ,zircon ,010502 geochemistry & geophysics ,Mass spectrometry ,01 natural sciences ,Hf isotopes ,Chemical composition ,working standard ,0105 earth and related environmental sciences ,Laser ablation ,lcsh:Mineralogy ,Isotope ,Rare-earth element ,Chemistry ,O isotopes ,010401 analytical chemistry ,Trace element ,trace element ,Geology ,Geotechnical Engineering and Engineering Geology ,0104 chemical sciences ,U–Pb age ,LKZ-1 ,Inductively coupled plasma ,Zircon - Abstract
This study introduces a new zircon reference material, LKZ-1, for the in situ U&ndash, Pb dating and O&ndash, Hf isotopic and trace element analyses. The secondary ion mass spectrometric analyses for this gem-quality single-crystal zircon yielded a weighted mean 206Pb/238U age of 572.6 ±, 2.0 Ma (2&sigma, n = 22, MSWD = 0.90), with moderately high U concentrations (619 ±, 21 ppm, 1 SD), restricted Th/U ratios (0.146 ±, 0.002, 1 SD), and negligible common Pb content (206Pbc <, 0.2%). A comparable 206Pb/238U age (570.0 ±, 2.5 Ma, 2&sigma, ) was produced by the isotope dilution-thermal ionization mass spectrometry. The secondary ion mass spectrometric and laser ablation-assisted multiple collector inductively coupled plasma mass spectrometer analyses respectively showed that LKZ-1 had little variation in O (&delta, 18OV-SMOW = 10.65 ±, 0.14&permil, laser fluorination value = 10.72 ±, 0.02&permil, 1 SD) and Hf (176Hf/177Hf = 0.281794 ±, 0.000016, 1 SD) isotopic compositions. LKZ-1 was also fairly homogeneous in its chemical composition (RSD of laser ablation ICPMS data &le, 10%), displaying a relatively uniform chondrite-normalized rare earth element pattern ((Lu/Gd)N = 31 ±, 3, Eu/Eu* = 0.43 ±, 0.17, Ce/Ce* = 44 ±, 32, 1 SD). These consistencies suggest that the LKZ-1 zircon is a suitable working standard for geochronological and geochemical analyses.
- Published
- 2019
14. Geochronology and petrogenesis of the Late Triassic A-type granitoids in the Yeongnam Massif and its implication for Late Triassic geodynamics of northeast Asia
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Youn-Joong Jeong, Byung Choon Lee, Seung Hwan Lee, and Hui Je Jo
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geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Pluton ,Geochemistry ,Geology ,Orogeny ,Massif ,Geodynamics ,010502 geochemistry & geophysics ,01 natural sciences ,Geochemistry and Petrology ,Delamination (geology) ,Geochronology ,0105 earth and related environmental sciences ,Petrogenesis ,Zircon - Abstract
The Late Triassic A-type granitoids along the continental margins of East Asia are important for deciphering the crust-mantle interactions, transformation of tectonic regime, and termination of the Indosinian Orogeny (known as the Songrim Orogeny in South Korea). The newly identified Wangdong plutons are distributed in the southwestern part of Yeongnam Massif, South Korea. U–Pb dating of zircons from the Wangdong plutons has established its date of emplacement at ca. 226–221 Ma, similar to the emplacement ages of the Daegang and Ian alkali granites. Geochemical data have shown that the Wangdong granitoid samples are magnesian to ferroan in composition and can be further classified in the range from alkalic to calc-alkalic. They have a high zircon saturation temperature (~ 850 °C), K2O/Na2O and, Ga/Al ratios, and are enriched with high field strength elements (e.g., Zr and Y), indicating an A-type granite affinity. Their classification into A2-type granites based on the A-type subdivision diagrams suggest that they formed in an extension-related tectonic setting. Moreover, the Wangdong A-type granitoids have high (La/Nb)N and (Th/Nb)N ratios with peraluminous characteristics (value of aluminum saturation index >1.0). In addition, magmatic zircons from the Wangdong granitoids have negative ɛHf(t) values (−6.6 to −15.5) with a Paleoproterozoic to Mesoproterozoic two-stage Hf model ages (from 1.99 to 1.49 Ga). This suggests that the Wangdong granitoids were derived from ancient crustal materials with compositions similar to metagraywackes. Based on geochemical, isotopic, and geochronological studies, we concluded that the lithospheric mantle delamination induced by slab roll-back of the subducted Paleo-Pacific plate is the main trigger in the production of Late Triassic magmatism in Yeongnam Massif, South Korea.
- Published
- 2021
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15. In-situoxygen isotope records of crustal self-cannibalization selectively captured by zircon crystals from high-δ26Mg granitoids
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Xian-Hua Li, Jong-Sik Ryu, Keewook Yi, Hui Je Jo, Namhoon Kim, Haemyeong Jung, and Albert Chang-sik Cheong
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Basalt ,010504 meteorology & atmospheric sciences ,Pluton ,Geochemistry ,Geology ,engineering.material ,010502 geochemistry & geophysics ,01 natural sciences ,Isotopes of oxygen ,Mantle (geology) ,Continental arc ,engineering ,Biotite ,0105 earth and related environmental sciences ,Zircon ,Petrogenesis - Abstract
Zircon oxygen-hafnium and biotite magnesium isotopic compositions of Late Cretaceous to Oligocene (88–27 Ma) granitoids from the Gyeongsang continental arc, southeastern Korea, collectively provide a new insight into shallow magma petrogenesis. Zircon crystals extracted from eight calc-alkaline or alkaline plutons commonly contain xenocrystic cores and typically show magmatic cathodoluminescence zonings and sharp Raman spectra. Most zircons have positive eHf values plotting below the mid-ocean-ridge basalt evolution path, indicating that the arc magmatism was dominated by the recycling of juvenile crustal materials. Zircon δ18O values shifted upward or downward from the mantle range attest to the O isotopic exchange of crustal protoliths with surface waters at various temperature conditions. Small (
- Published
- 2016
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16. Geochemical and Sr-Nd isotopic constraints on the petrogenesis of the Goesan monzodiorite pluton in the central Okcheon belt, Korea
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Youn-Joong Jeong, Chan-Soo Park, Moonsup Cho, Hui Je Jo, and Chang-Sik Cheong
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010504 meteorology & atmospheric sciences ,Pluton ,Geochemistry ,Geology ,010502 geochemistry & geophysics ,01 natural sciences ,0105 earth and related environmental sciences ,Petrogenesis - Abstract
The Permian–Triassic high pressure metamorphism and potassic magmatism in central Korea attest to the extension of the Dabie-Sulu collision belt in central-eastern China towards the Korean Peninsula and possibly the Japanese Islands. We present major and trace element and Sr–Nd isotope data for a ca. 230 Ma monzodiorite pluton emplaced in the Goesan area, central Okcheon belt, Korea. This pluton shows geochemical features comparable with those of the coeval monzonite–syenite–gabbro–mangerite suite documented recently in the Gyeonggi massif. The metaluminous and alkali–calcic signatures of the Goesan intrusives correspond to the Caledonian-type post-orogenic granitoids. The K2O/Na2O ratios of all analyzed samples are greater than 1, and are not correlative with their SiO2 contents. The enrichment of both large-ion-lithophile elements and highly compatible elements in the Goesan pluton is probably indicative of metasomatized mantle origin. The elemental fractionation in the source region must have occurred in the distant past, possibly the Paleoproterozoic, to generate significantly negative eNd(t) values (< –16). Chondrite-normalized rare earth element patterns as well as Rb/Sr and Ba/Rb ranges suggest that the source consists of amphibole-bearing rocks. Progressive decreases in negative Eu anomaly and Ba, Sr, Ni, Cr and V contents with increasing SiO2 contents reflect an important role of plagioclase, biotite and hornblende for the fractionation process. Zr is undersaturated in the potassic, metaluminous melt. The initial Sr–Nd isotopic compositions of the samples are correlated with their SiO2 contents, substantiating a role of crustal assimilation during the magmatic differentiation. The Sr–Nd elemental and isotopic modeling suggests that the Goesan pluton was initially slightly heterogeneous in its isotopic composition, and underwent concurrent assimilation and fractional crystallization. The occurrence of the Goesan pluton provides further evidence corroborating the amalgamation of allochthonous terranes within the Okcheon belt during the Permian–Triassic collisional orogeny. 韓国中央Okcheon(沃川)帯のGoesan(槐山)モンゾ閃緑岩の成因に関する地球化学的及びSr-Nd同位体的制約 抄録 要旨 韓国中央部のペルム紀-三畳紀高圧変成作用とカリウム系列火成作用は,中国中央東部の大別-蘇魯衝突帯が韓半島から恐らく日本列島まで続くことの証左である.本論では韓国沃川帯,槐山地域に定置した230 Maのモンゾ閃緑岩体の主要・微量元素及びSr-Nd同位体データを報告する.本深成岩体は近年Gyeonggi (京畿)地塊において記載された同時代のモンゾニ岩-閃長岩-ガブロ-マンゲライト岩類に地球化学的に対比できる.メタアルミナ及びアルカリ-カルク質の槐山貫入岩体はカレドニア型の後造山期花崗岩類に相当する.K2O/Na2O比は1を超え,SiO2含有量とは相関しない.槐山深成岩体のLIL元素と不適合元素の濃集は恐らくメタソマティズムを受けたマントル起源であることを示す.起源物質は古い地質時代に元素分別を受けたために,顕著な負のeNd(t)値(< -16)を示す.コンドライトで規格化した希土類元素パターンやRb/Sr比及びBa/Rb比は起源物質に角閃石が含まれることを示唆する.SiO2が増えるにつれてEuの負異常やBa,Sr,Ni,Cr,V含有量が減少することは,主として斜長石,黒雲母,普通角閃石の分別が起きたことを反映している.Zrは高カリウム,メタアルミナ質のメルト中では不飽和である.Sr-Nd同位体の初期値はSiO2と相関を示し,マグマの分化作用に地殻の同化が関わっていることを裏付ける.Sr-Nd元素及び同位体モデルは,槐山深成岩体が初期には同位体的にやや不均質であり,同化と結晶分別を同時に経験したことを示唆する.槐山深成岩体はペルム紀-三畳紀の衝突造山運動の間に沃川帯において起きた異地性テレーンの集合を証拠立てるものである.
- Published
- 2016
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17. Recurrent rare earth element mineralization in the northwestern Okcheon Metamorphic Belt, Korea: SHRIMP U–Th–Pb geochronology, Nd isotope geochemistry, and tectonic implications
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Tsuyoshi Iizuka, Sang-Mo Koh, Hui Je Jo, Namhoon Kim, Keewook Yi, Yoonsup Kim, Youn-Joong Jeong, and Chang-Sik Cheong
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Metamorphic rock ,Geochemistry ,Geology ,engineering.material ,Allanite ,Geochemistry and Petrology ,Isotope geochemistry ,Titanite ,Geochronology ,engineering ,Ordovician ,Economic Geology ,Petrology ,Biotite ,Zircon - Abstract
Rare earth element (REE) mineralization is hosted within Neoproterozoic alkaline metaigneous rocks in the northwestern part of the Okcheon Metamorphic Belt (OMB), a polymetamorphosed fold-and-thrust belt transecting the Paleoproterozoic Gyeonggi and Yeongnam Massifs in the southern Korean Peninsula. The principal carrier phase of REEs is allanite. Allanite grains can be subdivided into several types based on the texture and mineral assemblage including quartz, K-feldspar, biotite, britholite, apatite, fergusonite, andradite, magnetite, zircon, titanite and fluorite. Electron microprobe analysis of allanite clearly distinguishes sample-to-sample variations in total REEs, Ca, Al, Fe and Y but the textural varieties from each rock sample do not show marked differences in those elements. Sensitive high-resolution ion microprobe dating of allanite and zircon reveals a complex history of multistage mineralization. Allanite grains from REE ores yielded Late Ordovician (444.6 ± 8.0 Ma), Permian to Triassic (ca. 300–220 Ma) and Early Jurassic (199–183 Ma) 208Pb/232Th ages. These multiple age components often coexist in single grains showing slight differences in backscattered electron brightness. The Ordovician components have distinctly higher Th/U than the younger domains in the same rock sample. The cores and rims of zircon from a syenite hosting REE ore bodies yielded Neoproterozoic (858.2 ± 6.3 Ma) and Early Jurassic (ca. 190 Ma) 206Pb/238U ages, respectively. The Early Jurassic ages (194–187 Ma) also obtained from zircon grains from granites taken from dykes occurring close to the ores and a drill core indicate the correspondence between granitic magmatism and REE mineralization. The Neoproterozoic zircon inheritance (weighted mean = 853.9 ± 3.8 Ma) in these granites is in sharp contrast to the dominant Paleoproterozoic inherited zircon from the widespread earliest Middle Jurassic granites enclosing the mineralized zone. The geotectonic significance of the Late Ordovician event recorded in the allanite, as well as in detrital zircon from the OMB, is still unclear but its temporal coincidence with intraplate volcanism and arc-related igneous activity, respectively, reported from the southwestern edge of the adjacent Taebaeksan Basin and the southwestern Gyeonggi Massif is noteworthy. The following Permian–Triassic and Early Jurassic mineralization events are probably linked to the continental suturing between the North and South China blocks and subsequent post-orogenic magmatism, and arc magmatism resulting from the paleo-Pacific plate subduction, respectively. Sub-grain Sm–Nd isotopic analyses of allanite by laser ablation multiple collector ICPMS yielded initial eNd values plotting along the Nd isotopic evolution path of the Neoproterozoic metaigneous rocks, indicating that REEs originating from the host rock have been recycled during multistage mineralization events. The profound differences in inherited zircon ages and Nd isotopic compositions between the Early and Middle Jurassic granites may reflect the presence of a major thrust-bounded crustal structure beneath the OMB.
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- 2015
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18. Lithospheric mantle signatures as revealed by zircon Hf isotopes of Late Triassic post-collisional plutons from the central Korean peninsula, and their tectonic implications
- Author
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Chang-Sik Cheong, Hongying Zhou, Hui Je Jo, Jian-zhen Geng, Namhoon Kim, Moonsup Cho, and Sung Hi Choi
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geography ,Tectonics ,geography.geographical_feature_category ,Continental collision ,Lithosphere ,Pluton ,Geochemistry ,Geology ,Massif ,Metasomatism ,Mantle (geology) ,Zircon - Abstract
The Mesozoic tectonic architecture of the Korean peninsula is largely governed by the continental collision between the North and South China blocks. Zircon Hf isotopic compositions presented in this study and whole-rock geochemical and Sr-Nd isotope data in the literature collectively suggest that the lithophile-elements-enriched signature of the Late Triassic post-collisional plutons from the Gyeonggi massif in central Korea is a primary feature inherited from the metasomatized mantle lithosphere. Highly negative zircon eHf (t) values (−23 to −19) of plutons from the middle and eastern parts of the massif indicate an ancient metasomatism of their mantle source. Distinctly higher zircon eHf (t) values (−15 to −12) from the southwestern plutons are ascribed to a contribution from an accreted component of the South China-like block. The involvement of asthenospheric mantle is not recognized in zircons from either group. The implications of these isotopic features are discussed in the context of Mesozoic collisional tectonics.
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- 2015
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19. SHRIMP U-Pb Ages of the Namwon and Sunchang Granites
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Keewook Yi, Kye-Hun Park, and Hui Je Jo
- Subjects
Geochemistry ,Geology ,Shrimp - Published
- 2013
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20. Regional variations in the lead isotopic composition of galena from southern Korea with implications for the discrimination of lead provenance
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Dongbok Shin, Kwang-Sik Lee, Youn-Joong Jeong, Mukesh Kumar Gautam, Chang-Sik Cheong, Insung Lee, and Hui Je Jo
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Provenance ,geography ,Radiogenic nuclide ,geography.geographical_feature_category ,Geochemistry ,Geology ,Skarn ,Massif ,engineering.material ,Precambrian ,Basement (geology) ,Galena ,engineering ,Carbonate rock ,Earth-Surface Processes - Abstract
This study presents a comprehensive database (n = 215) of lead isotopes in galena from the southern Korean peninsula using new and published data. Of the 69 metal mines examined, predominantly skarn- and hydrothermal-type Pb–Zn–Au–Ag–Cu deposits were observed and were associated with Mesozoic magmatic activities. Galena samples from each geotectonic unit showed discrete lead isotopic signatures. The Gyeongsang basin samples were characteristically unradiogenic and had restricted variations in lead isotopic composition (206Pb/204Pb = 18.16–18.59, 207Pb/204Pb = 15.48–15.64, 208Pb/204Pb = 37.87–38.77). Their 208Pb/204Pb range indicated an involvement of source materials less thorogenic than the associated granites. The galena samples from Cambro–Ordovician carbonate rocks of the northeastern Yeongnam massif and eastern Taebaeksan basin had the most radiogenic 206Pb/204Pb (19.28 ± 0.14) and 207Pb/204Pb (15.833 ± 0.027) ratios. Their lead isotopic trend indicated a combined contribution of ore lead from granitic magmas, Precambrian basements, and overlain host rocks. Less radiogenic galena samples from the middle to southwestern parts of the Yeongnam massif and Okcheon belt showed limited lead isotopic variations (206Pb/204Pb = 18.332 ± 0.065, 207Pb/204Pb = 15.693 ± 0.012, 208Pb/204Pb = 38.93 ± 0.07 on average), probably resulted from mixing with a common crustal basement. The differences in lead isotopes between the radiogenic and unradiogenic groups from the Yeongnam massif and Okcheon belt may reflect the spatial dissimilarity of involved crustal rocks. The old crust appears to have significantly contributed ore lead to galenas from the western Gyeonggi massif, but the geochronological meaning of their steep 207Pb/204Pb–206Pb/204Pb trend is not clear. The comprehensive database constructed by the present study suggests that lead province in the southern Korean peninsula may be subdivided into four discrete zones. Linear discriminant analysis showed that more than 90% of the compiled data were correctly reclassified within their a priori zones. Such discrimination may be useful for a wide range of applications, including mineral exploration, archaeological correlation, and environmental characterization.
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- 2012
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21. SHRIMP Zircon Ages of the Basement Gneiss Complex in the Pyeongchang-Wonju Area, Gyeonggi Massif, Korea
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Yong-Sun Song, Jaehyeon Seo, Hui-Je Jo, Kye-Hun Park, and Keewook Yi
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geography ,Precambrian ,geography.geographical_feature_category ,Basement (geology) ,Metamorphic rock ,Geochemistry ,Metamorphism ,Orogeny ,Massif ,Geology ,Zircon ,Gneiss - Abstract
Precambrian gneiss complex in the Pyeongchang-Wonju area, which lies west of the Paleozoic sedimentary basin of the Yeongwol-Taebaek area, is being considered as a part of the Gyeonggi massif, but its ages of formation and metamorphic events are not well defined yet. In this study, SHRIMP zircon U-Pb ages were determined from the gneiss complex in the area, We obtained the discrete ages of magmatic (ca. 1960 Ma) and metamorphic (ca. 1860 Ma) events through the interpretation of the SHRIMP data based on the internal structures of zircons. These are almost the same to the ages of main intrusion and metamorphism reported from the Precambrian basements of Gyeonggi, Yeongnam and Nangnim massifs of the Korean Peninsula, Ages of 3200~3300 Ma, 2900 Ma, 2660 Ma, 2430 Ma, 2260 Ma, and 2080~2070 Ma obtained from inherited cores of studied zircons are also very similar to the frequently reported ages from the basement rocks of the Gyeonggi and Yeongnam massifs, Lower intercept age of about 270 Ma calculated from the rim data seems to indicate that the study area suffered from a late Paleozoic metamorphism (Okcheon Orogeny), but we need more reasonable and sufficient data to confirm it. According to the results of this study, it is suggested that the Bangnim group unconformably overlying the gneiss complex was deposited after the Paleoproterozoic granitic magmatism (ca. 1960 Ma) and metamorphism (ca. 1860 Ma).
- Published
- 2011
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22. Magmatic response to the interplay of collisional and accretionary orogenies in the Korean Peninsula: Geochronological, geochemical, and O-Hf isotopic perspectives from Triassic plutons.
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Chang-sik Cheong, Albert, Hui Je Jo, Youn-Joong Jeong, and Xian-Hua Li
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- *
IGNEOUS intrusions , *PENINSULAS , *ISOTOPIC signatures , *OROGENIC belts , *LITHOSPHERE , *AGE differences - Abstract
Phanerozoic internal and peripheral orogens in Northeast Asia converge toward the Korean Peninsula situated between cratonic Asia and the outboard magmatic arc. Widespread Mesozoic plutons in the peninsula provide first-hand information about the magmatic response to the continental and oceanic plate subduction. The present study addresses this issue using comprehensive (n >1100) whole-rock geochemical, zircon U-Pb geochronological, and O-Hf isotopic data obtained from Triassic gabbro-pyroxenitemangerite- monzonite-syenite-granodioritegranite plutons in the central and southern parts of the peninsula. The intrusion of ca. 265-250 Ma calc-alkaline granitoids, including the high-silica adakite, along the outboard (in present coordinates) Yeongnam Massif is coeval with or slightly younger than the Barrovian metamorphism recognized in fold-and-thrust belts surrounding the inboard (northward, present coordinates) Gyeonggi Massif, suggesting a close link between the collisional orogenesis and subduction initiation as commonly documented in Phanerozoic supercontinents. Subsequent Late Triassic plutons emplaced in the Yeongnam Massif are subdivided into the older (232-224 Ma) magnesian and alkalicalcic to calc-alkalic group and the younger (220-217 Ma) ferroan and alkalic to alkalicalcic group temporally intervened by the geochemically arc-like Andong ultramafic complex (222 Ma). Zircon O-Hf isotopic compositions of the older plutons reflect the mixing of metasomatized lithospheric mantle, young (probably Paleozoic) arc crust, and Precambrian basement crust, whereas those of the younger plutons reflect input of the asthenospheric/lithospheric mantle and mafic lower crust. Meanwhile, the Late Triassic (233-224 Ma) potassic plutons in and around the Gyeonggi Massif represent postcollisional magmatism most likely induced by slab breakoff, which may also have been responsible for the shoshonitic magmatism in the Yeongnam Massif. Spatial differences in the age pattern and O-Hf isotopic signature of inherited and synmagmatic zircons from the potassic plutons indicate a selective contribution from an ancient metasomatized lithospheric mantle beneath the North China-like craton and an allochthonous South China-like lithosphere. The formation of the Triassic plutons could be explained by a series of tectonomagmatic events consisting sequentially of the ridge subduction, low-angle subduction, slab breakoff beneath the collisional orogen, tectonic switch to an extension-dominated arc system, and delamination of an overthickened arc lithosphere. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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23. In-situ oxygen isotope records of crustal self-cannibalization selectively captured by zircon crystals from high-δ26Mg granitoids.
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Hui Je Jo, Albert Chang-sik Cheong, Jong-Sik Ryu, Namhoon Kim, Keewook Yi, Haemyeong Jung, and Xian-Hua Li
- Subjects
- *
OXYGEN isotopes , *SEISMIC anisotropy , *ZIRCON , *IGNEOUS intrusions , *PETROGENESIS - Abstract
Zircon oxygen-hafnium and biotite magnesium isotopic compositions of Late Cretaceous to Oligocene (88-27 Ma) granitoids from the Gyeongsang continental arc, southeastern Korea, collectively provide a new insight into shallow magma petrogenesis. Zircon crystals extracted from eight calc-alkaline or alkaline plutons commonly contain xenocrystic cores and typically show magmatic cathodoluminescence zonings and sharp Raman spectra. Most zircons have positive εHf values plotting below the mid-ocean-ridge basalt evolution path, indicating that the arc magmatism was dominated by the recycling of juvenile crustal materials. Zircon δ18O values shifted upward or downward from the mantle range attest to the O isotopic exchange of crustal protoliths with surface waters at various temperature conditions. Small (<1‰) but discernable core-to-rim decreases of d18O values are recognized selectively in magmatic zircon grains from four plutons possessing biotite δ26Mg values (-0.07‰ to +2.32‰) distinctly higher than the mantle range. Such a concomitant O-Mg isotopic variation provides compelling evidence for a series of self-induced hydrothermal alteration and assimilation processes (i.e., "crustal self-cannibalization”). This study shows that the supracrustal input to magmas in a young and juvenile orogen can be traced effectively by the combination of stable isotope records from the plutonic root. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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