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Hydrophobic-hydrophilic hybrid surfaces, sometimes termed biphilic surfaces, have shown potential to enhance condensation and boiling heat transfer, anti-icing, and fog harvesting performance. However, state of art techniques to develop these surfaces have limited substrate selection, poor scalability, and lengthy and costly fabrication methods. Here, we develop a simple, scalable, and rapid stamping technique for hybrid surfaces with spatially controlled wettability. To enable stamping, rationally designed and prefabricated polydimethylsiloxane (PDMS) stamps, which are reusable and independent of the substrate and functional coating, were used. To demonstrate the stamping technique, we used silicon wafer, copper, and aluminum substrates functionalized with a variety of hydrophobic chemistries including heptadecafluorodecyltrimethoxy-silane, octafluorocyclobutane, and slippery omniphobic covalently attached liquids. Condensation experiments and microgoniometric characterization demonstrated that the stamped surfaces have global hydrophobicity or superhydrophobicity with localized hydrophilicity (spots) enabled by local removal of the functional coating during stamping. Stamped surfaces with superhydrophobic backgrounds and hydrophilic spots demonstrated stable coalescence induced droplet jumping. Compared to conventional techniques, our stamping method has comparable prototyping cost with reduced manufacturing time scale and cost. Our work not only presents design guidelines for the development of scalable hybrid surfaces for the study of phase change phenomena, it develops a scalable and rapid stamping protocol for the cost-effective manufacture of next-generation hybrid wettability surfaces.

Biofouling disrupts the surface functionality and integrity of engineered substrates. A variety of natural materials such as plant leaves and insect wings have evolved sophisticated physical mechanisms capable of preventing biofouling. Over the past decade, several reports have pinpointed nanoscale surface topography as an important regulator of surface adhesion and growth of bacteria. Although artificial nanoengineered features have been used to create bactericidal materials that kill adhered bacteria, functional surfaces capable of synergistically providing antiadhesion and bactericidal properties remain to be developed. Furthermore, fundamental questions pertaining to the need for intrinsic hydrophobicity to achieve bactericidal performance and the role of structure length scale (nano vs micro) are still being explored. Here, we demonstrate highly scalable, cost-effective, and efficient nanoengineered multifunctional surfaces that possess both antiadhesion and bactericidal properties on industrially relevant copper (Cu) and aluminum (Al) substrates. We characterize antiadhesion and bactericidal performance using a combination of scanning electron microscopy (SEM), atomic force microscopy (AFM), live/dead bacterial staining and imaging, as well as solution-phase and Petrifilm measurements of bacterial viability. Our results showed that nanostructures created on both Cu and Al were capable of physical deformation of adhered

Solid–liquid interactions are ubiquitous phenomena in nature and industry. Wettability of a liquid on a solid is governed by the chemical heterogeneity and physical roughness of the solid surface and can be characterized by measuring the advancing and receding contact angles of the liquid droplet residing on the solid. To characterize contact angle, goniometry and the Wilhelmy plate method have been widely used. Although powerful, these methods have difficulty characterizing microdroplets, can be cumbersome and expensive, and have trouble handling surfaces with local wetting heterogeneity and deformed noncircular contact lines. Furthermore, past methods are incapable of measuring contact angle in situ during experiments (e.g., condensation). Here, we develop simple yet powerful contact angle measurement techniques using conventional optical microscopy that utilizes focal plane shift imaging, ray optics, and wave interference. We used our techniques to study the wetting characteristics for a wide range of ...

Lubricant-infused surfaces (LISs) and slippery liquid-infused porous surfaces (SLIPSs) have shown remarkable success in repelling low-surface-tension fluids. The atomically smooth, defect-free slippery surface leads to reduced droplet pinning and omniphobicity. However, the presence of a lubricant introduces liquid-liquid interactions with the working fluid. The commonly utilized lubricants for LISs and SLIPSs, although immiscible with water, show various degrees of miscibility with organic polar and nonpolar working fluids. Here, we rigorously investigate the extent of miscibility by considering a wide range of liquid-vapor surface tensions (12-73 mN/m) and different categories of lubricants having a range of viscosities (5-2700 cSt). Using high-fidelity analytical chemistry techniques including X-ray photoelectron spectroscopy, nuclear magnetic resonance, thermogravimetric analysis, and two-dimensional gas chromatography, we quantify lubricant miscibility to parts per billion accuracy. Furthermore, we quantify lubricant concentrations in the collected condensate obtained from prolonged condensation experiments with ethanol and hexane to delineate mixing and shear-based lubricant drainage mechanisms and to predict the lifetime of LISs and SLIPSs. Our work not only elucidates the effect of lubricant properties on miscibility with various fluids but also develops guidelines for developing stable and robust LISs and SLIPSs.

Boiling is an effective energy-transfer process with substantial utility in energy applications. Boiling performance is described mainly by the heat-transfer coefficient (HTC) and critical heat flux (CHF). Recent efforts for the simultaneous enhancement of HTC and CHF have been limited by an intrinsic trade-off between them-HTC enhancement requires high nucleation-site density, which can increase bubble coalescence resulting in limited CHF enhancement. In this work, this trade-off is overcome by designing three-tier hierarchical structures. The bubble coalescence is minimized to enhance the CHF by defining nucleation sites with microcavities interspersed within hemi-wicking structures. Meanwhile, the reduced nucleation-site density is compensated for by incorporating nanostructures that promote evaporation for HTC enhancement. The hierarchical structures demonstrate the simultaneous enhancement of HTC and CHF up to 389% and 138%, respectively, compared to a smooth surface. This extreme boiling performance can lead to significant energy savings in a variety of boiling applications.

The surface free energy of rare earth oxides (REOs) has been debated during the last decade, with some reporting REOs to be intrinsically hydrophilic, while others reporting hydrophobic. Quantitative studies exist supporting each conclusion, showing either intrinsic hydrophobicity, or transition from hydrophilicity to hydrophobicity due to adsorption of volatile organic compounds (VOCs). Here, we investigate the wettability and surface chemistry of pristine and smooth REO surfaces, conclusively showing that hydrophobicity stems from wettability transition due to VOC adsorption. We show that for indoor ambient atmospheres as well as well-controlled saturated hydrocarbon atmospheres, the apparent advancing and receding contact angles of water on CeO2, Er2O3 and Yb2O3 increase with exposure time. To study the free interface, we examined the surfaces comprehensively with X-ray photoelectron microscopy (XPS) and time-of-flight secondary ion mass spectroscopy (ToF-SIMS) to confirm hydrocarbon adsorption and correlate it to wettability transition mechanisms. We demonstrate that both physisorption and chemisorption occur on the surface, with chemisorbed hydrocarbons promoting further physisorption due to their high affinity with similar hydrocarbon molecules. This study offers a better understanding of the intrinsic wettability of REOs and provides design guidelines for REO-based durable hydrophobic coatings.

Condensation is a universal phenomenon that occurs in nature and industry. Previous studies have used superhydrophobicity and liquid infusion to enable superior liquid repellency due to reduced contact angle hysteresis. However, small condensate droplets remain immobile on condensing surfaces until they grow to the departing size at which the body force can overcome the contact line pinning force. Hence, condensation heat transfer is limited by these remaining droplets that act as thermal barriers. To break these limitations, we introduce vibrational actuation to a slippery liquid-infused nanoporous surface (SLIPS) and show enhanced droplet mobility, controllable condensate repellency, and more efficient heat transfer compared to static SLIPSs. We demonstrate 39% smaller departing droplet size and 8× faster droplet departing speeds on the dynamic vibrating SLIPS compared to the nonactuated SLIPS. To understand the implications of these behaviors on heat transfer, we investigate the condensate area coverage and droplet distribution to verify enhanced dewetting on dynamic vibrating SLIPSs. Using well-validated heat transfer models, we demonstrate enhanced condensation heat transfer on dynamic SLIPSs due to the higher population of smaller condensate droplets (

This soft machine can pick up and release an ultrathin “living” cell sheet and electronics without crumpling., “Living” cell sheets or bioelectronic chips have great potentials to improve the quality of diagnostics and therapies. However, handling these thin and delicate materials remains a grand challenge because the external force applied for gripping and releasing can easily deform or damage the materials. This study presents a soft manipulator that can manipulate and transport cell/tissue sheets and ultrathin wearable biosensing devices seamlessly by recapitulating how a cephalopod’s suction cup works. The soft manipulator consists of an ultrafast thermo-responsive, microchanneled hydrogel layer with tissue-like softness and an electric heater layer. The electric current to the manipulator drives microchannels of the gel to shrink/expand and results in a pressure change through the microchannels. The manipulator can lift/detach an object within 10 s and can be used repeatedly over 50 times. This soft manipulator would be highly useful for safe and reliable assembly and implantation of therapeutic cell/tissue sheets and biosensing devices.

Coalescence-induced droplet jumping has the potential to enhance the performance of a variety of applications including condensation heat transfer, surface self-cleaning, anti-icing, and defrosting to name a few. Here, we study droplet jumping on hierarchical microgrooved and nanostructured smooth superhydrophobic surfaces. We show that the confined microgroove structures play a key role in tailoring droplet coalescence hydrodynamics, which in turn affects the droplet jumping velocity and energy conversion efficiency. We observed self-jumping of individual deformed droplets within microgrooves having maximum surface-to-kinetic energy conversion efficiency of 8%. Furthermore, various coalescence-induced jumping modes were observed on the hierarchical microgrooved superhydrophobic surface. The microgroove structure enabled high droplet jumping velocity (≈0.74U) and energy conversion efficiency (≈46%) by enabling the coalescence of deformed droplets in microgrooves with undeformed droplets on adjacent plateaus. The jumping velocity and energy conversion efficiency enhancements are 1.93× and 6.67× higher than traditional coalescence-induced droplet jumping on smooth superhydrophobic surfaces. This work not only demonstrates high droplet jumping velocity and energy conversion efficiency but also demonstrates the key role played by macroscale structures on coalescence hydrodynamics and elucidates a method to further control droplet jumping physics for a plethora of applications.

Hydrophilic solid surfaces having low contact angle hysteresis can induce stable dropwise condensation., Droplet nucleation and condensation are ubiquitous phenomena in nature and industry. Over the past century, research has shown dropwise condensation heat transfer on nonwetting surfaces to be an order of magnitude higher than filmwise condensation heat transfer on wetting substrates. However, the necessity for nonwetting to achieve dropwise condensation is unclear. This article reports stable dropwise condensation on a smooth, solid, hydrophilic surface (θa = 38°) having low contact angle hysteresis (

Superhydrophobicity has received significant attention over the past three decades owing to its significant potential in self-cleaning, anti-icing and drag reduction surfaces, energy-harvesting devices, antibacterial coatings, and enhanced heat transfer applications. Superhydrophobicity can be obtained via the roughening of an intrinsically hydrophobic surface, the creation of a re-entrant geometry, or by the roughening of a hydrophilic surface followed by a conformal coating of a hydrophobic material. Intrinsically hydrophobic surfaces have poor thermophysical properties, such as thermal conductivity, and thus are not suitable for heat transfer applications. Re-entrant geometries, although versatile in applications where droplets are deposited, break down during spatially random nucleation and flood the surface. Chemical functionalization of rough metallic substrates, although promising, is not utilized because of the poor durability of conformal hydrophobic coatings. Here we develop a radically different approach to achieve stable superhydrophobicity. By utilizing laser processing and thermal oxidation of copper (Cu) to create a high surface energy hierarchical copper oxide (CuO), followed by repeatable and passive atmospheric adsorption of hydrophobic volatile organic compounds (VOCs), we show that stable superhydrophobicity with apparent advancing contact angles ≈160° and contact angle hysteresis as low as ≈20° can be achieved. We exploit the structure length scale and structure geometry-dependent VOC adsorption dynamics to rationally design CuO nanowires with enhanced superhydrophobicity. To gain an understanding of the VOC adsorption physics, we utilized X-ray photoelectron and ion mass spectroscopy to identify the chemical species deposited on our surfaces in two distinct locations: Urbana, IL, United States and Beijing, China. To test the stability of the atmosphere-mediated superhydrophobic surfaces during heterogeneous nucleation, we used high-speed optical microscopy to demonstrate the occurrence of dropwise condensation and stable coalescence-induced droplet jumping. Our work not only provides rational design guidelines for developing passively durable superhydrophobic surfaces with excellent flooding-resistance and self-healing capability but also sheds light on the key role played by the atmosphere in governing wetting.

Understanding the fundamental mechanisms governing vapor condensation on nonwetting surfaces is crucial to a wide range of energy and water applications. In this paper, we reconcile classical droplet growth modeling barriers by utilizing two-dimensional axisymmetric numerical simulations to study individual droplet heat transfer on nonwetting surfaces (90°θa170°). Incorporation of an appropriate convective boundary condition at the liquid-vapor interface reveals that the majority of heat transfer occurs at the three phase contact line, where the local heat flux can be up to 4 orders of magnitude higher than at the droplet top. Droplet distribution theory is incorporated to show that previous modeling approaches underpredict the overall heat transfer by as much as 300% for dropwise and jumping-droplet condensation. To verify our simulation results, we study condensed water droplet growth using optical and environmental scanning electron microscopy on biphilic samples consisting of hydrophobic and nanostructured superhydrophobic regions, showing excellent agreement with the simulations for both constant base area and constant contact angle growth regimes. Our results demonstrate the importance of resolving local heat transfer effects for the fundamental understanding and high fidelity modeling of phase change heat transfer on nonwetting surfaces.

Dropwise condensation (DWC) on non-wetting surfaces has remarkable potential to enhance heat transfer performance compared to filmwise condensation on wetting substrates. In this article, we discuss important recent developments and challenges in the field of DWC, including durability of DWC-promoting coatings, DWC of low surface tension fluids, physical mechanisms governing DWC, unconventional methods to achieve DWC, and promising metrology techniques for DWC. We end the article by providing a road map detailing where we believe the community should direct both fundamental and applied efforts in order to solve the identified century-old challenges that limit DWC implementation.

Water vapor condensation on superhydrophobic surfaces has received much attention in recent years because of its ability to shed water droplets at length scales 3 decades smaller than the capillary length (∼1 mm) via coalescence-induced droplet jumping. Jumping-droplet condensation has been demonstrated to enhance heat transfer, anti-icing, and self-cleaning efficiency and is governed by the theoretical inertial-capillary scaled jumping speed (U). When two droplets coalesce, the experimentally measured jumping speed (Uexp) is fundamentally limited by the internal fluid dynamics during the coalescence process (Uexp0.23U). Here, we theoretically and experimentally demonstrate multidroplet (2) coalescence as an avenue to break the two-droplet speed limit. Using side-view and top-view high-speed imaging to study more than 1000 jumping events on a copper oxide nanostructured superhydrophobic surface, we verify that droplet jumping occurs as a result of three fundamentally different mechanisms: (1) coalescence between two droplets, (2) coalescence among more than two droplets (multidroplet), and (3) coalescence between one or more droplets on the surface and a returning droplet that has already departed (multihop). We measured droplet-jumping speeds for a wide range of droplet radii (5-50 μm) and demonstrated that while the two-droplet capillary-to-inertial energy conversion mechanism is not identical to that of multidroplet jumping, speeds above the theoretical two-droplet limit (0.23U) can be achieved. However, we discovered that multihop coalescence resulted in drastically reduced jumping speeds (≪0.23U) due to adverse momentum contributions from returning droplets. To quantify the impact of enhanced jumping speed on heat-transfer performance, we developed a condensation critical heat flux model to show that modest jumping speed enhancements of 50% using multidroplet jumping can enhance performance by up to 40%. Our results provide a starting point for the design of enhanced-performance jumping-droplet surfaces for industrial applications.

Water vapor condensation on hydrophobic surfaces has received much attention due to its ability to rapidly shed water droplets and enhance heat transfer, anti-icing, water harvesting, energy harvesting, and self-cleaning performance. However, the mechanism of heterogeneous nucleation on hydrophobic surfaces remains poorly understood and is attributed to defects in the hydrophobic coating exposing the high surface energy substrate. Here, we observe the formation of high surface energy nanoscale agglomerates on hydrophobic coatings after condensation/evaporation cycles in ambient conditions. To investigate the deposition dynamics, we studied the nanoscale agglomerates as a function of condensation/evaporation cycles via optical and field emission scanning electron microscopy (FESEM), microgoniometric contact angle measurements, nucleation statistics, and energy dispersive X-ray spectroscopy (EDS). The FESEM and EDS results indicated that the nanoscale agglomerates stem from absorption of sulfuric acid based aerosol particles inside the droplet and adsorption of volatile organic compounds such as methanethiol (CH

High speed images of coalescence induced three-droplet jumping on a nanostructured superhydrophobic carbon nanotube (CNT) surface are presented (θaapp ≈ 173º). When two or more droplets coalesce on a nanostructured superhydrophobic surface, the resulting droplet can jump away from the surface due to the release of excess surface energy. To more easily study the jumping phenomena, we have developed focal plane shift imaging (FPSI) to determine both jumping speed and direction. Figure 1(a) shows a schematic of the FPSI concept. A high speed camera was attached to an upright optical microscope, and samples were horizontally mounted on a cold stage. Initial conditions were obtained by moving the focal plane to be coincident with the middle of the droplets prior to coalescence (Figure 1b). Then the focal plane was shifted above the droplets by a known distance (Figure 1c), followed by measurement of the time taken for the jumping droplet to pass through the shifted focal plane (Figure 1d). By analyzing the initial and final conditions of the departing droplet for multiple three-droplet coalescence events, the three-droplet jumping droplet speed was determined (Figure 2b). Experimentally measured jumping speeds determined by the FPSI imaging technique show good agreement with three-droplet inertial capillary scaling (Figure 2b, dotted line, equation inset). The FPSI visualization technique provides a novel imaging platform for the study of complex multi-droplet jumping-droplet phenomena.

Experiments show, for the first time, two water droplets coalescing and jumping on a superhydrophobic surface. Adhesion, contact angle hysteresis, and initial wetting behavior governed by the surface structure morphology and length scale, are all shown to play a role in droplet jumping.

As-grown randomly aligned networks of carbon nanotubes (CNTs) invariably suffer from limited transport properties due to high resistance at the crossed junctions between CNTs. In this work, Joule heating of the highly resistive CNT junctions is carried out in the presence of a spin-coated layer of a suitable chemical precursor. The heating triggers thermal decomposition of the chemical precursor, tris(dibenzylideneacetone)dipalladium (Pd2(dba)3), and causes local deposition of Pd nanoparticles at the CNT junctions, thereby improving the on/off current ratio and mobility of CNT network devices by an average factor of ∼6. This process can be conducted either in air or under vacuum depending on the characteristics of the precursor species. The solution-mediated nanosoldering process is simple, fast, scalable with manufacturing techniques, and extendable to the nanodeposition of a wide variety of materials.