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Microplastic pollution is a pervasive issue, with remarkably high concentrations observed even in the most remote locations such as Arctic sea ice and snow. The reason for such large microplastic abundances in sea ice is still speculative and applies mainly to saline or freshwater conditions. In this study, we investigated seasonal ice core samples collected in March 2021 from the northern Baltic Sea (Gulf of Bothnia) for their microplastic distributions. The Baltic Sea is characterized by low salinity and can be ice-covered for up to six months annually. Microplastics were analyzed in the melted ice samples using an adsorption technique and Raman microscopy to identify their abundances, colors, shapes, and sizes to calculate their masses. Due to the strong dynamic of the ice layer and the repeated melting and freezing processes during the ice formation, no discernible trends in microplastic abundances, masses, or polymer types were observed throughout the ice core length. The average microplastic abundance (±SD) in the Baltic Sea ice was determined to be 22.3 ± 8.6 N L−1, with 64.9% of the particles exhibiting a particulate shape and 35.1% having a fibrous shape. The most prevalent polymer type was polyethylene terephthalate (PET), accounting for 44.4% of all polymers. This is likely due to the high proportion of PET fibers (93.8%). The majority of particle-shaped microplastics were identified as polyethylene (PE; 37.2%), followed by PET (17.2%), polyvinyl chloride (PVC; 15.9%), and polypropylene (PP; 15.9%). No correlations were found between microplastic concentrations and proximity to land, cities, industries, or rivers, except for PP mass concentrations and particle sizes, which correlated with distances to industries in Luleå, Sweden. [ABSTRACT FROM AUTHOR]

Marine phytoplankton are primary producers in ocean ecosystems and emit dimethyl sulfide (DMS) into the atmosphere. DMS emissions are the largest biological source of atmospheric sulfur and are one of the largest uncertainties in global climate modeling. DMS is oxidized to methanesulfonic acid (MSA), sulfur dioxide, and hydroperoxymethyl thioformate, all of which can be oxidized to sulfate. Ice core records of MSA are used to investigate past DMS emissions but rely on the implicit assumption that the relative yield of oxidation products from DMS remains constant. However, this assumption is uncertain because there are no long-term records that compare MSA to other DMS oxidation products. Here, we share the first long-term record of both MSA and DMS-derived biogenic sulfate concentration in Greenland ice core samples from 1200 to 2006 CE. While MSA declines on average by 0.2 µg S kg-1 over the industrial era, biogenic sulfate from DMS increases by 0.8 µg S kg-1. This increasing biogenic sulfate contradicts previous assertions of declining North Atlantic primary productivity inferred from decreasing MSA concentrations in Greenland ice cores over the industrial era. The changing ratio of MSA to biogenic sulfate suggests that trends in MSA could be caused by time-varying atmospheric chemistry and that MSA concentrations alone should not be used to infer past primary productivity.

Antarctic trace metal records provide important information for grasping the influence of human activities on the environment over the last centuries. The CA2016-75 ice core is located along the East Antarctic Zhongshan Station–Dome A, enhances the record of metals research in the East Antarctic region, and its high-resolution supplies data support for the study of high-frequency climatic drivers and the effect of human activities on the Antarctic environment. A thorough dataset on seven trace metals (Al, Fe, Mn, Cu, Zn, Ba and Pb) in a coastal ice core in eastern Antarctica during the previous 102 years (1915–2016) is presented in this study. Pb has the lowest concentration (9.51 ± 20.95 pg g−1), and Ba has the highest concentration (36.57 ± 51.35 ng g−1). Notable variations are observed between the pre-1968 AD and post-1968 AD phases for Mn, Zn and Ba. The abrupt, remarkable increase in the concentrations coincided with the change of metal smelting production in the southern hemisphere. In addition to this, it may also be related to local Antarctic scientific research activities. Al and Fe, the primary crustal elements, are essentially obtained from soil dust; Cu shows high crustal enrichment factors (EFc, >10), indicating that it is notably affected by anthropogenic activities. Moreover, the anthropogenic activities in the Southern Hemisphere have had an impact on lead deposition in Antarctica. This study not only enriches the trace metal historical record along the Zhongshan Station–Dome A but also provides a high-resolution ice core record, which is very crucial for the reconstruction of trace metal concentration changes in the last 100 years.

Identification of tephra and its allocation (association) with known eruptive events allows obtainng chronostratigraphic markers, on the basis of which an age scale for dating glacial strata can be developed. To determine the sources of ash in the ice core obtained in 2022 during drilling of glacier in the crater of the Ushkovsky volcano in Kamchatka, the chemical composition of volcanic glass in individual ash particles was analyzed. The accuracy of determination of the volcanic glass composition was verified by analyzing of international standard samples of volcanic and synthetic glass. Based on a comparison of the data we obtained with published data on the composition of tephra glasses from the present-day eruptions in Kamchatka, we determined affiliation of each tephra horizon to specific volcano-source. We have found that the main source of tephra in the ice core of the Ushkovsky Glacier is the Kliuchevskoi volcano, which is the closest and the most productive one among the Kamchatka volcanoes. Ash particles from Bezymyannyi volcano were identified in two horizons. A mixed population of particles was found in one of the horizons, including the ash particles from volcanoes Kizimen, Kliuchevskoi and Bezymyannyi. Analysis of published data on the chronology and distribution of ash plumes from known eruptive events made it possible to confidently correlate the tephra horizon at a depth of 762–777 cm with the initial phase of the eruption of the Kizimen volcano in late 2010–early 2011. Ash from the uppermost tephra buried in the glacier at depths of 89–94 cm belongs to the Bezymyannyi volcano eruption, which the most likely occurred in October 2020. Single particles with rhyolitic composition of glass in the sample from the depth of 348–354 cm may belong to the eruption of the Shiveluch volcano in December 2018. The results of our work can be used on further studying of the ice core from the Ushkovsky volcano, in particular for comparison and correlation with the chronostratigraphic data obtained by glacio-chemical and isotope methods.

Explosive submarine arc volcanoes can cause tsunamis, affect climate, and pose hazards to airplanes and ships. Although 70 % of the Earth is submarine, only 15 % of Holocene arc volcanoes in the Smithsonian Global Volcanism database are submarine. Merging locations of active submarine hydrothermal vents in arcs and the above database, we found 71 unlisted submarine arc volcanoes. Using Baker [2017, doi: 10.1016/j.oregeorev.2017.02.006], only 44 % of hydrothermal vents in arcs are known. Only 77 of the vent fields are on volcanoes in the Smithsonian database. Assuming that unknown submarine arc volcanoes are present in the same proportions as unknown vents, there are ~160 as-yet undiscovered Holocene age submarine arc volcanoes. Using geophysical data, we located 291 unsurveyed seamounts 32 % of Holocene arc volcanoes are submarine.

The last glacial period was punctuated by cold intervals in the North Atlantic region that culminated in extensive iceberg discharge events. These cold intervals, known as Heinrich Stadials, are associated with abrupt climate shifts worldwide. Here, we present CO2 measurements from the West Antarctic Ice Sheet Divide ice core across Heinrich Stadials 2 to 5 at decadal-scale resolution. Our results reveal multi-decadal-scale jumps in atmospheric CO2 concentrations within each Heinrich Stadial. The largest magnitude of change (14.0 ± 0.8 ppm within 55 ± 10 y) occurred during Heinrich Stadial 4. Abrupt rises in atmospheric CO2 are concurrent with jumps in atmospheric CH4 and abrupt changes in the water isotopologs in multiple Antarctic ice cores, the latter of which suggest rapid warming of both Antarctica and Southern Ocean vapor source regions. The synchroneity of these rapid shifts points to wind-driven upwelling of relatively warm, carbon-rich waters in the Southern Ocean, likely linked to a poleward intensification of the Southern Hemisphere westerly winds. Using an isotope-enabled atmospheric circulation model, we show that observed changes in Antarctic water isotopologs can be explained by abrupt and widespread Southern Ocean warming. Our work presents evidence for a multi-decadal-to century-scale response of the Southern Ocean to changes in atmospheric circulation, demonstrating the potential for dynamic changes in Southern Ocean biogeochemistry and circulation on human timescales. Furthermore, it suggests that anthropogenic CO2 uptake in the Southern Ocean may weaken with poleward strengthening westerlies today and into the future. [ABSTRACT FROM AUTHOR]

Earth’s climate has changed throughout history. Just in the last 800,000 years there have been eight cycles of ice ages and warmer periods, with the end of the last ice age about 11,700 years ago marking the beginning of the modern climate era and of human civilization. Most of these climate changes are attributed to very small variations in Earth’s orbit that change the amount of solar energy our planet receives. The current warming trend is different because it is clearly the result of human activities since the mid-1800s, and is proceeding at a rate not seen over recent millennia. It is undeniable that human activities have produced abundance of gases in the atmosphere that have trapped more of the Sun’s energy in the Earth system. This extra energy has earned the ocean and lands, which lead to widespread and rapid changes in the environment. In this paper there are analysed anthropogenic changes, nature’s own role and climate disasters in comparing the results obtained into perspective with incidents in the year 536.

Accurate segmentation of 3D micro CT scans is a key step in the process of analysis of the microstructure of porous materials. In polar ice core studies, the environmental effects on the firn column could be detected if the microstructure is digitized accurately. The most challenging task is to obtain the microstructure parameters of the bubbly ice section. To identify the minimum, necessary resolution, the bubbly ice micro CT scans with different resolutions (120, 60, 30, 12 μm) were compared object-wise via a region pairing algorithm. When the minimum resolution was found to be 60 μm, for generating the training/validation dataset, 4 ice core samples from a depth range of 96 to 108 meters (bubbly ice) were scanned with 120 μm (input images) and another time with 4 times higher resolution (30 μm) to build ground truth. A specific pipeline was designed with non-rigid image registration to create an accurate ground truth from 4 times higher resolution scans. Then, two SOTA deep learning models (3D-Unet and FCN) were trained and later validated to perform super-resolution segmentation by taking input of 120μm resolution data and giving the output of binary segmented with two times higher resolution (60μm). Finally, the outputs of CNN models were compared with traditional rule-based and unsupervised methods on blind test data. It is observed the 3D-Unet can segment low-resolution scans with an accuracy of 96% and an f1-score of 80.8% while preserving microstructure having less than 2% error in porosity and SSA.

Stable water isotopes in inland Antarctic ice cores are powerful paleoclimate proxies; however, their relationship with dynamical atmospheric circulations remains controversial. Using a water isotope climate model (MIROC5‐iso), we assessed the influence of the Last Glacial Maximum (LGM; ∼21,000 years ago) sea surface temperatures (SST) and sea ice (SIC) on Antarctic precipitation isotopes (δ18Op) through atmospheric circulation. The results revealed that the synoptic circulation mostly maintained southward moisture transport, reaching inland Antarctica. The steepened meridional SST gradient in the mid‐latitudes increased δ18Op in inland Antarctica with the enhanced baroclinic instability and synoptic moisture transport. In contrast, expanded SIC distribution decreased δ18Op over Antarctica by enhanced preferential removal of heavy isotopes during vapor transport due to the increased transport distance and enhanced surface cooling. These findings propose to use Antarctic ice cores to describe the southern hemisphere atmospheric circulation, represented by the westerly jets, during the LGM and other past climates. Plain Language Summary: Stable water isotopes are widely used to reconstruct past variations of Earth's climate, such as the temperature in Antarctica during the Last Glacial Maximum (LGM) ∼21,000 years ago. This is an essential period for the climate community, given the order of magnitude of the temperature change between the LGM and today, which is similar to that of today's warming. However, the relationship between stable water isotopes and temperature is still subject to debate because of the influence of other climatic factors. Using an isotope‐enabled climate model, we found that the isotopic composition of Antarctic precipitation was not simply associated with the high and low average Antarctic temperature, but was substantially influenced by changes in dynamical atmospheric circulation related to sea surface temperature and sea ice expansion. We also suggest that representation of the past atmospheric circulations, such as westerly jets, can be constrained using water isotopic signals in Antarctic ice cores. Key Points: Synoptic circulations sustained the moisture transport toward inland AntarcticaMeridional sea surface temperature gradient enhanced moisture and heavy isotope precipitations on Antarctica, unlike sea ice expansionAntarctic ice core isotopes may refine southern hemisphere atmospheric circulations during the last glacial maximum [ABSTRACT FROM AUTHOR]

To reconstruct the history of organic carbon (OC) aerosol over south‐eastern Europe, dissolved organic carbon (DOC) and its 14C signature (DO14C) were investigated along an ice core drilled at the Mount Elbrus (ELB) in Caucasus. In summer, compared to pre‐1945 levels, the DOC concentrations increased by 45% after 1960, the mean DO14C depletion in recent ELB ice relative to atmospheric 14CO2 of 32% being attributed to fossil‐fuel sources. DO14C content of ice deposited during the bomb‐peak era (1955–1980) closely followed atmospheric 14CO2 changes caused by atmospheric nuclear tests, suggesting the living biosphere as the main biogenic source of DOC in summer in this region. ELB data contrast with those previously obtained in summer Alpine (western Europe) ice in which a post‐1950 doubling of DOC was observed and attributed to enhanced emissions of organic compounds from vegetation in France. This regional difference is discussed with respect to changes of biogenic organic compound emissions in response to past change of use‐land and global warming. ELB data document, for the first time, changes of DOC and DO14C in winter mountain ice showing an increase by 44% of DOC levels associated with a 14C signature being 47% lower than that of atmospheric 14CO2 in ELB ice deposited after 1960. The 14C winter ELB ice record followed atmospheric 14CO2 changes with a delay of ∼3 years, suggesting that remaining emissions from the living biosphere, together with a small contribution from wood burning, are the main biogenic sources of DOC in winter in this region. Plain Language Summary: A good knowledge of past aerosol load and composition is important for climate change. In addition to sulfate, organic carbon aerosol (OC) is a major constituent of present‐day aerosol but its budget remains far less understood. Ice‐core chemical studies help to quantify natural versus anthropogenic sources over the past. Previous investigations of OC and its radiocarbon signature in Alpine ice had shown a doubling of summer OC due to enhanced emissions from vegetation contrasting with a weak impact of fossil‐fuel emissions in western Europe. The regional character of biogenic emissions motivated, however, further studies conducted in other regions. Investigations of OC and its radiocarbon signature in an ice core extracted in the Caucasus permitted to reconstruct past OC changes in the south‐eastern Europe. It is shown that, even in 1970, vegetation emissions still dominate fossil‐fuel emissions as source of OC in summer. A quite large temporal variability of OC is observed and attributed to variations of vegetation emissions in response to past fluctuations of summer temperature in this region. After 1960, fossil‐fuel emissions in winter became almost as large as biogenic emissions that were related to the living biosphere with a small contribution from wood burning at that season. Key Points: Biogenic sources dominate fossil‐fuel sources of present‐day summer organic carbon aerosol (70% vs. 30%) in south‐eastern EuropeLarge pre‐industrial variability of organic carbon aerosol in summer driven by vegetation emissions modulated by past temperaturesLiving biosphere with a small contribution from wood burning slightly exceeds present‐day fossil‐fuel sources of organic carbon in winter [ABSTRACT FROM AUTHOR]

[Display omitted] Understanding the impact of meltwater discharge during the final stage of the Laurentide Ice Sheet (LIS) has important implications for predicting sea level rise and climate change. Here we present a high-resolution ice-core isotopic record from the central Tibetan Plateau (TP), where the climate is sensitive to the meltwater forcing, and explore possible signals of the climate response to potential LIS meltwater discharges in the early to mid-Holocene. The record shows four abrupt large fluctuations during the 7–9 ka BP (kiloannum before present), reflecting large shifts of the mid-latitude westerlies and the Indian summer monsoon (ISM) over this period, and they corresponded to possible LIS freshwater events documented in other paleoclimate records. Our study suggests that multiple rapid meltwater discharge events might have occurred during the final stage of LIS. The finding implies the possibility of rapid sea level rise and unstable climate in the transition zone between the mid-latitude westerlies and the ISM due to fast polar ice retreat under the anthropogenic global warming. [ABSTRACT FROM AUTHOR]

Rapid warming and human exploitation threaten boreal forests. Understanding links among vegetation, climate, and people in this vast biome requires highly resolved long‐term records that integrate regional inputs. We developed an 850‐year pollen‐based record of supraregional vegetation change using a southern Greenland ice core and atmospheric modeling that identified the boreal and mixed‐conifer forests of eastern Canada as the dominant pollen source regions. Conifer pollen increased ∼1400 CE at the onset of the cooler and drier Little Ice Age. A subsequent decline began ∼1650 CE and a statistically significant pollen change after 1760 CE suggests ecological consequences of the Little Ice Age cooling and initial human exploitation that persisted until recent decades. These supraregional changes are broadly consistent with local records and demonstrate intensification of human impacts on northern forests, suggesting a shift from a climate‐modulated to an increasingly human‐controlled system during recent centuries. Plain Language Summary: Understanding the consequences of climate warming and human exploitation for northern forests requires long‐term regional records of this sparsely populated region. We present a first 850‐year vegetation record from a low‐elevation ice core in Southern Greenland. The ice core integrates pollen from Eastern Canadian forests and other boreal forests, providing temporal precision and regional coverage not available from previous paleoecological investigations. We show that climate change drove changes in the abundances of coniferous species during the Little Ice Age. Subsequent warming coincided with the onset of timber exploitation that brought a shift from a climate‐controlled to an increasingly human‐controlled system. Current warming trends likely will further alter vegetation distribution, productivity, and disturbance regimes of northern forests, but they will be moderated by the legacy of human impacts. Key Points: Atmospheric model FLEXPART identifies boreal and mixed‐conifer forests in Canada as pollen source area for Southern Greenland ice corePollen in Greenland ice track conifer pollen increases ∼1400 CE at the onset of the cooler and drier Little Ice AgeConifer pollen declines ∼1650 CE coincident with cold LIA climate and initial commercial forest exploitation [ABSTRACT FROM AUTHOR]

Abstract Stable water isotopes in inland Antarctic ice cores are powerful paleoclimate proxies; however, their relationship with dynamical atmospheric circulations remains controversial. Using a water isotope climate model (MIROC5‐iso), we assessed the influence of the Last Glacial Maximum (LGM; ∼21,000 years ago) sea surface temperatures (SST) and sea ice (SIC) on Antarctic precipitation isotopes (δ18Op) through atmospheric circulation. The results revealed that the synoptic circulation mostly maintained southward moisture transport, reaching inland Antarctica. The steepened meridional SST gradient in the mid‐latitudes increased δ18Op in inland Antarctica with the enhanced baroclinic instability and synoptic moisture transport. In contrast, expanded SIC distribution decreased δ18Op over Antarctica by enhanced preferential removal of heavy isotopes during vapor transport due to the increased transport distance and enhanced surface cooling. These findings propose to use Antarctic ice cores to describe the southern hemisphere atmospheric circulation, represented by the westerly jets, during the LGM and other past climates.

We present new data from the debris-rich basal ice layers of the NEEM ice core (NW Greenland). Using mineralogical observations, SEM imagery, geochemical data from silicates (meteoric 10Be, εNd, 87Sr/86Sr) and organic material (C/N, δ13C), we characterize the source material, succession of previous glaciations and deglaciations and the paleoecological conditions during ice-free episodes. Meteoric 10Be data and grain features indicate that the ice sheet interacted with paleosols and eroded fresh bedrock, leading to mixing in these debris-rich ice layers. Our analysis also identifies four successive stages in NW Greenland: (1) initial preglacial conditions, (2) glacial advance 1, (3) glacial retreat and interglacial conditions and (4) glacial advance 2 (current ice-sheet development). C/N and δ13C data suggest that deglacial environments favored the development of tundra and taiga ecosystems. These two successive glacial fluctuations observed at NEEM are consistent with those identified from the Camp Century core basal sediments over the last 3 Ma. Further inland, GRIP and GISP2 summit sites have remained glaciated more continuously than the western margin, with less intense ice-substratum interactions than those observed at NEEM.

Shallow firn cores, in addition to a near-basal ice core, were recovered in 2018 from the Quelccaya ice cap (5470 m a.s.l) in the Cordillera Vilcanota, Peru, and in 2017 from the Nevado Illimani glacier (6350 m a.s.l) in the Cordillera Real, Bolivia. The two sites are ~450 km apart. Despite meltwater percolation resulting from warming, particle-based trace element records (e.g. Fe, Mg, K) in the Quelccaya and Illimani shallow cores retain well-preserved signals. The firn core chronologies, established independently by annual layer counting, show a convincing overlap indicating the two records contain comparable signals and therefore capture similar regional scale climatology. Trace element records at a ~1–4 cm resolution provide past records of anthropogenic emissions, dust sources, volcanic emissions, evaporite salts and marine-sourced air masses. Using novel ultra-high-resolution (120 μm) laser technology, we identify annual layer thicknesses ranging from 0.3 to 0.8 cm in a section of 2000-year-old radiocarbon-dated near-basal ice which compared to the previous annual layer estimates suggests that Quelccaya ice cores drilled to bedrock may be older than previously suggested by depth-age models. With the information collected from this study in combination with past studies, we emphasize the importance of collecting new surface-to-bedrock ice cores from at least the Quelccaya ice cap, in particular, due to its projected disappearance as soon as the 2050s.

In recent decades, surface melting on the inland Greenland ice sheet has increased, leading to significant meltwater-refreezing in the snow and firn. Increased knowledge of the physical and chemical characteristics of these melt features (i.e., ice layers) is needed to help estimate future global sea-level rise. Here, using a combination of microscopy and spectroscopy, we investigate the size, shape, location, and chemical compositions of inclusions in 12 ice layers of the SIGMA-A ice core in the northwestern Greenland ice sheet (78°03′06″N, 67°37′42″W, 1490 m a.s.l.). In the ice layers, we found inclusions exceeding 30 μm diameter that could only be formed by melting–refreezing, which we classify into columnar-, particle-, and rod-like inclusions. We propose that the smaller columnar- and particle-like inclusions of solid Na2SO4⋅10H2O and CaSO4⋅2H2O form first, within the ice grains, followed by the larger rod-like inclusions of brines with mainly Na+ and Cl− in grain boundaries. Our results suggest a new proxy that may help identify past warm climates in deeper ice cores in Greenland and for studying future ice sheet melting behavior.

Microplastic pollution is a pervasive issue, with remarkably high concentrations observed even in the most remote locations such as Arctic sea ice and snow. The reason for such large microplastic abundances in sea ice is still speculative and applies mainly to saline or freshwater conditions. In this study, we investigated seasonal ice core samples collected in March 2021 from the northern Baltic Sea (Gulf of Bothnia) for their microplastic distributions. The Baltic Sea is characterized by low salinity and can be ice-covered for up to six months annually. Microplastics were analyzed in the melted ice samples using an adsorption technique and Raman microscopy to identify their abundances, colors, shapes, and sizes to calculate their masses. Due to the strong dynamic of the ice layer and the repeated melting and freezing processes during the ice formation, no discernible trends in microplastic abundances, masses, or polymer types were observed throughout the ice core length. The average microplastic abundance (±SD) in the Baltic Sea ice was determined to be 22.3 ± 8.6 N L−1, with 64.9% of the particles exhibiting a particulate shape and 35.1% having a fibrous shape. The most prevalent polymer type was polyethylene terephthalate (PET), accounting for 44.4% of all polymers. This is likely due to the high proportion of PET fibers (93.8%). The majority of particle-shaped microplastics were identified as polyethylene (PE; 37.2%), followed by PET (17.2%), polyvinyl chloride (PVC; 15.9%), and polypropylene (PP; 15.9%). No correlations were found between microplastic concentrations and proximity to land, cities, industries, or rivers, except for PP mass concentrations and particle sizes, which correlated with distances to industries in Luleå, Sweden.

Monte Perdido Glacier, located in the central Pyrenees, is one of the southernmost glaciers in Europe. Due to climate change, this glacier is suffering an accelerated mass loss, especially in the last decades. If the current trends persist, this glacier is expected to disappear in the next 50 years. As part of the efforts of the scientific community to increase the knowledge about this glacier, this research presents the first microstructural characterization of the Monte Perdido Glacier, focused on a high-impurity concentration segment that belongs to an ice core drilled in 2017. The results reveal the ice has a layering defined by air bubbles and non-soluble impurities. The bubble-defined layering exhibits features of both a primary (sedimentary) and a secondary (strain-induced) origin. We found a clear inverse correspondence between the particle concentration and the grains' size and roundness index. A preliminary micro-Raman characterization of the particles shows the occurrence of atacamite, anatase (likely related to ancient mining activities in the vicinity of the glacier) and quartz. The latter could be an indicator of mineral dust, probably suggesting the arrival of dust-laden air masses from the north of the African continent.

Deciphering the localisation of solid and dissolved impurities on the micron-scale in glacial ice remains a challenge, but is critical to understand the integrity of ice core records and internal deformation. Here we report on the state-of-the-art in microstructural impurity research by highlighting recent progress in bringing together cryo-Raman spectroscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We show the potential of both methods and discuss possibilities to improve inter-method approaches aiming for a more holistic understanding of the evolution of impurity localisation throughout the ice column, including post-depositional processes. In this framework, we elaborate on future research priorities such as LA-ICP-MS imaging on firn samples and integrating a large cryo-cell with imaging capabilities.

Hercules Dome, Antarctica, has long been identified as a prospective deep ice core site due to the undisturbed internal layering, climatic setting and potential to obtain proxy records from the Last Interglacial (LIG) period when the West Antarctic ice sheet may have collapsed. We performed a geophysical survey using multiple ice-penetrating radar systems to identify potential locations for a deep ice core at Hercules Dome. The surface topography, as revealed with recent satellite observations, is more complex than previously recognized. The most prominent dome, which we term ‘West Dome’, is the most promising region for a deep ice core for the following reasons: (1) bed-conformal radar reflections indicate minimal layer disturbance and extend to within tens of meters of the ice bottom; (2) the bed is likely frozen, as evidenced by both the shape of the measured vertical ice velocity profiles beneath the divide and modeled ice temperature using three remotely sensed estimates of geothermal flux and (3) models of layer thinning have 132 ka old ice at 45–90 m above the bed with an annual layer thickness of ~1 mm, satisfying the resolution and preservation needed for detailed analysis of the LIG period.

The British Antarctic Survey's (BAS) Rapid Access Isotope Drill (RAID), designed for rapid drilling to survey prospective ice core sites, has been deployed at multiple Antarctic locations over 6 years. This drilling method creates ice chippings that can be discretely sampled and analysed for their chemical and water isotopic composition. Ice sampling methods have evolved since the first uses of the BAS RAID, enabling a more quantifiable sample resolution. Here, we show that water isotope records obtained from RAID ice are comparable to those of equivalent depth resolution from proximal ice cores. Records of chemical impurities also show good agreement with nearby cores. Our findings suggest that the RAID is suitable for both chemical and isotopic reconnaissance of drilling sites. Residual contamination of certain ions is discussed, with proposed design changes to avoid this issue with future use.

Abstract Rapid warming and human exploitation threaten boreal forests. Understanding links among vegetation, climate, and people in this vast biome requires highly resolved long‐term records that integrate regional inputs. We developed an 850‐year pollen‐based record of supraregional vegetation change using a southern Greenland ice core and atmospheric modeling that identified the boreal and mixed‐conifer forests of eastern Canada as the dominant pollen source regions. Conifer pollen increased ∼1400 CE at the onset of the cooler and drier Little Ice Age. A subsequent decline began ∼1650 CE and a statistically significant pollen change after 1760 CE suggests ecological consequences of the Little Ice Age cooling and initial human exploitation that persisted until recent decades. These supraregional changes are broadly consistent with local records and demonstrate intensification of human impacts on northern forests, suggesting a shift from a climate‐modulated to an increasingly human‐controlled system during recent centuries.

Abstract This article compares isotopic, ionic and climatic data from two firn cores from the West Antarctic Ice Sheet (WAIS). The IC-02 (88°01’21.3”S , 82°04’21.7”W) and the IC-05 (82°30’30.8”S , 79°28’02.7”W) closer to the coast. The IC-02 had 488 samples analyzed covering 14.58 meters depth while the IC-05 had 602 samples analyzed covering 19.73 meters depth. The time interval for both ice cores is 25 years ranging from 1978 to 2003. Sodium, sulfate and chloride were analyzed via ion chromatography using three DionexTM ionic chromatographers at the laboratories of Centro Polar e Climático (CPC) and at the Climate Change Institute. Stable isotope data was determined using cavity ring-down spectroscopy in a Picarro® spectrometer at the CPC. Annual accumulation was greater at IC-05 with an average of 0.35 m.eq.w.a-1 compared to 0.25 m.eq.w.a-1 at the IC-02. Stable isotope data was approximately 1.3 times more negative at the IC-02 which also presented higher d values. Na+ and Cl- were in higher concentrations at the IC-05 however Cl/Na was greater in the IC-02. The Cl excess was found to be derived from fractionation of sea salt aerosols and not related to volcanism. This work presents new insights regarding the chemical differences between ice cores.

Arctic warming has accelerated surface melting even in the highland areas of the Greenland ice sheet (GrIS). Understanding the relationship between climate and surface melting is essential for improving the estimates of ice‐sheet mass loss due to warming. Here we analyze a 250 m‐long ice core from the southeastern dome of GrIS (SE‐Dome site; 67°19′17″ N, 36°47′03″ W, 3,161 m a.s.l.), where the annual mean temperature is −20.9°C and the accumulation rate is high and there is a large discrepancy among climate models regarding snow accumulation estimates. A time scale was established for 1799–2020 with a half‐year uncertainty using annual counting of H2O2 concentration and five time horizons determined by electrical conductivity, melt events, and tritium concentration. The annual accumulation rate from the ice core shows no significant trend over 221 years and has an average of 1.04 ± 0.20 m w.e. year−1. In contrast, the frequency and thickness of refrozen melt layer (ML) have increased over 221 years, and are synchronized with temperature changes in the Arctic. The thickness of MLs correlates positively with the time‐integrated summer temperature anomaly using a reanalysis of air temperature. The in‐situ accumulation records in the southeastern GrIS provide an important basis for correcting reanalysis data such as ERA5, which in turn are valuable for improving regional climate models. Plain Language Summary: In recent years, Arctic temperatures have been increasing faster than global temperatures. In the inland Greenland ice sheet (GrIS), the surface snow melts on warm days, then the meltwater percolates in the snowpack and refreezes into melt layers (MLs). Here we describe an ice core, collected from the southeastern GrIS, which contains records of precipitation and MLs from 1799 to 2020. We then compare these results with the climatic data. The annual precipitation rate obtained from the ice core shows neither a decrease nor an increase over 221 years, suggesting no significant trend in the southeastern region. On the other hand, with Arctic warming, the ML thickness per year has increased through the 19th–21st centuries. In addition, there is a positive correlation between ML thickness and summer temperature. We conclude that the annual precipitation rate in southeastern GrIS is constant regardless of Arctic warming and the ice core is favorable for reconstructing environmental records from the pre‐industrial era to the present. Key Points: From an ice core in the southeastern Greenland ice sheet, we establish a time scale spanning 1799–2020 with a half‐year uncertaintyOver 221 years, the annual accumulation rate shows no significant trend, while the melt layer thickness has increased with Arctic warmingThe in‐situ accumulation records provide an important basis for correcting reanalysis data, which in turn are valuable for improving models [ABSTRACT FROM AUTHOR]

In 2019, four ice cores were recovered from the world's highest tropical mountain, Nevado Huascarán (Cordillera Blanca, Peru; 9.11°S, 77.61°W). Composite hydroclimate records of the two Col cores (6,050 masl) and the two Summit cores (6,768 masl) are compared to gridded gauge‐analysis and reanalysis climate data for the most recent 60‐year. Spatiotemporal correlation analyses suggest that the ice core oxygen stable isotope (δ18O) record largely reflects tropical Pacific climate variability, particularly in the NINO3.4 region. By extension, the δ18O record is strongly related to rainfall over the Amazon Basin, as teleconnections between the El Niño Southern Oscillation and hydrological behavior are the main drivers of the fractionation of water isotopes. However, on a local scale, modulation of the stable water isotopes appears to be more closely governed by upper atmospheric temperatures than by rainfall amount. Over the last 60 years, the statistical significance of the climate/δ18O relationship has been increasing contemporaneously with the atmospheric and oceanic warming rates and shifts in the Walker circulation. Isotopic records from the Summit appear to be more sensitive to large‐scale temperature changes than the records from the Col. These results may have substantial implications for modeling studies of the behavior of water isotopes at high elevations in the tropical Andes. Plain Language Summary: The oxygen stable isotope records (δ18O) of the new Huascarán ice cores (collected in 2019 from Peru) are a natural archive of tropical Pacific climate and hydrological conditions over the Amazon Basin. This is evidenced by strong correlations between δ18O and spatiotemporal sea surface temperature (SST) and precipitation data sets that cover the most recent 60 years of the ice core records. Additionally, the Huascarán δ18O records are significantly related to temperatures in the upper atmosphere, suggesting that temperature may also play a critical role in modifying the isotope values. The statistical significance of each of these relationships has also been increasing over the last 60 years, and the rates of increase are greatest between the δ18O records from the higher elevation ice core site and the temperature‐related climate data sets. This suggests that the isotope records from the Huascarán Summit (6,768 masl) are more sensitive to large‐scale changes in temperature than the isotope records on the Huascarán Col (6,050 masl). This is the first study to examine ice core records from the Summit of Earth's highest tropical mountain and offers valuable insights into the behavior of δ18O in the tropical Andes. Key Points: Oxygen stable isotope (δ18O) records from the new Huascarán ice cores strongly reflect Pacific climate variability of the most recent 60‐yearTropical Pacific influences on the Huascarán δ18O records have strengthened significantly in the last six decadesδ18O from the higher elevation Summit appears to be more sensitive to large‐scale climate change than δ18O from the lower‐elevation Col [ABSTRACT FROM AUTHOR]

In this study, we have investigated the oxygen isotope compositions (δ17O and δ18O) of modern rain and ice cores using published isotopic data. We find that, contrary to existing interpretations, precipitation δ17O is influenced by two factors: mass-dependent fractionation (MDF), which occurs during ocean evaporation, and mass-independent fractionation (MIF), which happens in the stratosphere. The MDF contribution remains constant and can be understood by studying tropical rain, as the overall movement of mass in the tropics is upward toward the stratosphere. On the other hand, the MIF effect comes from the mixing of stratospheric air in the troposphere, which is a result of the Brewer–Dobson circulation. This MIF effect on precipitation 17O increases from the tropics toward the poles and is observed consistently in modern precipitation and ice cores. The relative δ17O and δ18O composition, denoted as ∆'17O, in modern precipitation can be calibrated with surface air temperature, creating a new and independent tool for estimating past temperatures. We used this calibration along with the ∆'17O of Antarctic and Greenland ice cores, and our reconstructed past temperatures are in excellent agreement with those derived from borehole thermometry or gas phase analysis of air trapped in the ice. The ∆'17O method overcomes the problems associated with using δ18O alone for paleothermometry. Our findings align with climate models that suggest a weakening of the Brewer–Dobson circulation during the Last Glacial Maximum. Furthermore, our approach could be used to monitor future changes in stratosphere–troposphere mass exchange in response to a warming climate caused by increasing greenhouse gases. [ABSTRACT FROM AUTHOR]

We present new data from the debris-rich basal ice layers of the NEEM ice core (NW Greenland). Using mineralogical observations, SEM imagery, geochemical data from silicates (meteoric 10Be, εNd, 87Sr/86Sr) and organic material (C/N, δ13C), we characterize the source material, succession of previous glaciations and deglaciations and the paleoecological conditions during ice-free episodes. Meteoric 10Be data and grain features indicate that the ice sheet interacted with paleosols and eroded fresh bedrock, leading to mixing in these debris-rich ice layers. Our analysis also identifies four successive stages in NW Greenland: (1) initial preglacial conditions, (2) glacial advance 1, (3) glacial retreat and interglacial conditions and (4) glacial advance 2 (current ice-sheet development). C/N and δ13C data suggest that deglacial environments favored the development of tundra and taiga ecosystems. These two successive glacial fluctuations observed at NEEM are consistent with those identified from the Camp Century core basal sediments over the last 3 Ma. Further inland, GRIP and GISP2 summit sites have remained glaciated more continuously than the western margin, with less intense ice-substratum interactions than those observed at NEEM. [ABSTRACT FROM AUTHOR]

In recent decades, surface melting on the inland Greenland ice sheet has increased, leading to significant meltwater-refreezing in the snow and firn. Increased knowledge of the physical and chemical characteristics of these melt features (i.e., ice layers) is needed to help estimate future global sea-level rise. Here, using a combination of microscopy and spectroscopy, we investigate the size, shape, location, and chemical compositions of inclusions in 12 ice layers of the SIGMA-A ice core in the northwestern Greenland ice sheet (78°03′06″N, 67°37′42″W, 1490 m a.s.l.). In the ice layers, we found inclusions exceeding 30 μm diameter that could only be formed by melting–refreezing, which we classify into columnar-, particle-, and rod-like inclusions. We propose that the smaller columnar- and particle-like inclusions of solid Na2SO4⋅10H2O and CaSO4⋅2H2O form first, within the ice grains, followed by the larger rod-like inclusions of brines with mainly Na+ and Cl− in grain boundaries. Our results suggest a new proxy that may help identify past warm climates in deeper ice cores in Greenland and for studying future ice sheet melting behavior. [ABSTRACT FROM AUTHOR]

Shallow firn cores, in addition to a near-basal ice core, were recovered in 2018 from the Quelccaya ice cap (5470 m a.s.l) in the Cordillera Vilcanota, Peru, and in 2017 from the Nevado Illimani glacier (6350 m a.s.l) in the Cordillera Real, Bolivia. The two sites are ~450 km apart. Despite meltwater percolation resulting from warming, particle-based trace element records (e.g. Fe, Mg, K) in the Quelccaya and Illimani shallow cores retain well-preserved signals. The firn core chronologies, established independently by annual layer counting, show a convincing overlap indicating the two records contain comparable signals and therefore capture similar regional scale climatology. Trace element records at a ~1–4 cm resolution provide past records of anthropogenic emissions, dust sources, volcanic emissions, evaporite salts and marine-sourced air masses. Using novel ultra-high-resolution (120 μm) laser technology, we identify annual layer thicknesses ranging from 0.3 to 0.8 cm in a section of 2000-year-old radiocarbon-dated near-basal ice which compared to the previous annual layer estimates suggests that Quelccaya ice cores drilled to bedrock may be older than previously suggested by depth-age models. With the information collected from this study in combination with past studies, we emphasize the importance of collecting new surface-to-bedrock ice cores from at least the Quelccaya ice cap, in particular, due to its projected disappearance as soon as the 2050s. [ABSTRACT FROM AUTHOR]

Deciphering the localisation of solid and dissolved impurities on the micron-scale in glacial ice remains a challenge, but is critical to understand the integrity of ice core records and internal deformation. Here we report on the state-of-the-art in microstructural impurity research by highlighting recent progress in bringing together cryo-Raman spectroscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We show the potential of both methods and discuss possibilities to improve inter-method approaches aiming for a more holistic understanding of the evolution of impurity localisation throughout the ice column, including post-depositional processes. In this framework, we elaborate on future research priorities such as LA-ICP-MS imaging on firn samples and integrating a large cryo-cell with imaging capabilities. [ABSTRACT FROM AUTHOR]

Monte Perdido Glacier, located in the central Pyrenees, is one of the southernmost glaciers in Europe. Due to climate change, this glacier is suffering an accelerated mass loss, especially in the last decades. If the current trends persist, this glacier is expected to disappear in the next 50 years. As part of the efforts of the scientific community to increase the knowledge about this glacier, this research presents the first microstructural characterization of the Monte Perdido Glacier, focused on a high-impurity concentration segment that belongs to an ice core drilled in 2017. The results reveal the ice has a layering defined by air bubbles and non-soluble impurities. The bubble-defined layering exhibits features of both a primary (sedimentary) and a secondary (strain-induced) origin. We found a clear inverse correspondence between the particle concentration and the grains' size and roundness index. A preliminary micro-Raman characterization of the particles shows the occurrence of atacamite, anatase (likely related to ancient mining activities in the vicinity of the glacier) and quartz. The latter could be an indicator of mineral dust, probably suggesting the arrival of dust-laden air masses from the north of the African continent. [ABSTRACT FROM AUTHOR]

The British Antarctic Survey's (BAS) Rapid Access Isotope Drill (RAID), designed for rapid drilling to survey prospective ice core sites, has been deployed at multiple Antarctic locations over 6 years. This drilling method creates ice chippings that can be discretely sampled and analysed for their chemical and water isotopic composition. Ice sampling methods have evolved since the first uses of the BAS RAID, enabling a more quantifiable sample resolution. Here, we show that water isotope records obtained from RAID ice are comparable to those of equivalent depth resolution from proximal ice cores. Records of chemical impurities also show good agreement with nearby cores. Our findings suggest that the RAID is suitable for both chemical and isotopic reconnaissance of drilling sites. Residual contamination of certain ions is discussed, with proposed design changes to avoid this issue with future use. [ABSTRACT FROM AUTHOR]

Hercules Dome, Antarctica, has long been identified as a prospective deep ice core site due to the undisturbed internal layering, climatic setting and potential to obtain proxy records from the Last Interglacial (LIG) period when the West Antarctic ice sheet may have collapsed. We performed a geophysical survey using multiple ice-penetrating radar systems to identify potential locations for a deep ice core at Hercules Dome. The surface topography, as revealed with recent satellite observations, is more complex than previously recognized. The most prominent dome, which we term 'West Dome', is the most promising region for a deep ice core for the following reasons: (1) bed-conformal radar reflections indicate minimal layer disturbance and extend to within tens of meters of the ice bottom; (2) the bed is likely frozen, as evidenced by both the shape of the measured vertical ice velocity profiles beneath the divide and modeled ice temperature using three remotely sensed estimates of geothermal flux and (3) models of layer thinning have 132 ka old ice at 45–90 m above the bed with an annual layer thickness of ~1 mm, satisfying the resolution and preservation needed for detailed analysis of the LIG period. [ABSTRACT FROM AUTHOR]

The limited observations pose challenges to understanding long‐term variations of atmospheric ammonium (NH4+ ${\text{NH}}_{4}^{+}$) deposition. Glaciers on the margins of the Tibetan Plateau (TP) adjacent to heavily populated regions can capture and preserve unique records of natural and anthropogenic ammonium aerosol. However, relatively little has been known about spatiotemporal variations and anthropogenic influences on ammonium deposition on the central TP. Here, we present a high‐resolution ammonium record spanning the period 1900–2011, reconstructed from the Qiangtang (QT) ice core on the central TP. Empirical orthogonal function and interspecies correlation analysis reveal that NH4+ ${\text{NH}}_{4}^{+}$ has a source and/or transport route that differs from the dust species, especially after the 1950s. The QT ammonium record is also likely influenced by temperature‐dependent biogenic emissions from northwestern South Asia. Comparison with other ice core records shows that intensified anthropogenic emissions have caused a widespread increase in ammonium records in the inner TP after the 1950s. Furthermore, the significant positive relationship with the December–April Arctic Oscillation (AO) suggests that enhanced westerlies during the positive AO phase transport NH4+ ${\text{NH}}_{4}^{+}$ aerosol more efficiently to the QT. As a result, the decrease in ammonium concentrations after 1990, when anthropogenic emissions were still increasing, could be attributed to the weakening of westerlies associated with the transitioning of the AO phase from positive to negative. Our results may enhance the understanding of the influence of the westerlies on the transport of atmospheric pollutants to the central TP. Plain Language Summary: Glaciers on the Tibetan Plateau (TP) are ideal natural archives that capture and preserve air pollutants released by human activities. Ammonium is one of the cations widely measured in ice cores from the TP glaciers. In the last decades of the 20th century, the enhancement of ammonia from anthropogenic emissions (such as fertilizer application, animal waste, biomass burning, and industrial processes) contribute to the increase in ammonium concentrations in ice cores retrieved from the south and west margins of the TP. However, the ammonium record in the inner TP should be affected by a combination of variations in climatic and environmental conditions. Here, we analyzed ammonium record extracted from the Qiangtang (QT) glacier, located in the central TP. Results show that ammonium has discernible noncrustal inputs in the late 20th century. QT ammonium concentration also displays an increasing trend after the 1950s, which could be attributed to the enhanced agricultural emissions in south and central Asia. However, after 1990, when anthropogenic emissions were still increasing, the decrease in ammonium concentrations could be attributed to the weakening of the westerlies. Key Points: An ice core from Qiangtang No. 1 Glacier, central Tibetan Plateau (TP), is used to reconstruct the ammonium record spanning 1900–2011Enhanced anthropogenic emissions after the 1950s can contribute to high ammonium concentrations on glaciers in the inner TPThe decrease in ammonium record after 1990 could be attributed to the weakening westerlies associated with the shifting of the Arctic Oscillation phase [ABSTRACT FROM AUTHOR]

Biomass burning is an important component of the Earth system in terms of global biogeochemistry, atmospheric composition, climate, terrestrial ecology, and land use. This study examines published ice core trace gas measurements of acetylene, ethane, and methane, which have been used as proxies for paleofire emissions. We investigate the consistency of these records for the past 1,000 years in terms of (1) temporal trends in global fire emissions and (2) quantitative estimates for changes in global burning (dry matter burned per year). Three-dimensional transport and box models were used to construct emissions scenarios for the trace gases consistent with each ice core record. Burning histories were inferred from trace gas emissions by accounting for biome-specific emission factors for each trace gas. The temporal trends in fire inferred from the trace gases are in reasonable agreement, with a large decline in biomass burning emissions from the Medieval Period (MP: 1000–1500 CE) to the Little Ice Age (LIA: 1650–1750 CE). However, the three trace gas ice core records do not yield a consistent fire history, even assuming dramatic (and unrealistic) changes in the spatial distribution of fire and biomes. Substantial changes in other factors such as meteorological transport or atmospheric photochemical lifetimes appear to be required to reconcile the trace gas records.

The future contributions of the Antarctic Ice Sheet to sea level rise will depend on the evolution of its surface mass balance (SMB), which could amplify/dampen mass losses increasingly observed at the ice sheet's edge. In situ constraints of SMB over annual-to-decadal timescales consist mostly of firn/ice cores that have a surface footprint $\sim$cm$^{2}$. SMB constraints also come from climate models, which have a higher temporal resolution but a larger surface footprint of several km$^{2}$. We use ice-penetrating radar data to obtain an intermediate spatial and temporal resolution SMB record over three ice rises along the Princess Ragnhild Coast. The co-located ice cores allow us to obtain absolute radar-derived SMB rates at a multi-annual-to-decadal temporal resolution. By comparing the ice core SMB measurements and the radar-derived SMB records, we determine that pointwise measurements of SMB are representative of a small surface area, $\sim 200-500$ m radius extending from the ice core drill site for the ice rises studied here, and that the pointwise measurements are systematically 7–15 cm w.e. a$^{-1}$ lower than the mean SMB value calculated for the whole ice rises. However, ice core records are representative of an entire ice rise's temporal variability at the temporal resolution examined.

Sea-ice pore microstructure constrains ice transport properties, affecting fluid flow relevant to oil-in-ice transport and biogeochemical processes. Motivated by a lack of pore microstructural data, in particular for granular ice and across the seasonal cycle, throat size, tortuosity, connectivity, and other microstructural variables were derived from X-ray computed tomography for brine-filled pores in seasonal landfast ice off northern Alaska. Data were obtained for granular and columnar ice during the ice growth, transition, and melt season. While granular ice exhibits a more heterogeneous pore space than columnar ice, pore and throat size distributions are comparable. The greater tortuosity of pores in granular (1.2 < τg < 1.7) compared to columnar ice (1.0 < τc < 1.1) compounded with a less interconnected pore space translates into lower permeability for granular ice during the growth season for a given porosity. The microstructural data explain findings of granular ice hindering vertical oil-in-ice transport during ice growth and transition stage. With granular ice more frequent in the changing Arctic, data from studies such as this are needed to inform improved modeling of porosity-permeability relationships.

During the past 20 years, multi-channel radar emerged as a key tool for deciphering an ice sheet's internal architecture. To assign ages to radar reflections and connect them over large areas in the ice sheet, the layer genesis has to be understood on a microphysical scale. Synthetic radar trace modelling based on the dielectric profile of ice cores allows for the assignation of observed physical properties’ variations on the decimetre scale to radar reflectors extending from the coring site to a regional or even whole-ice-sheet scale. In this paper we rely on the available dielectric profiling data of the northern Greenland deep ice cores: NGRIP, NEEM and EGRIP. The three records are well suited for assigning an age model to the stratigraphic radar-mapped layers, and linking up the reflector properties to observations in the cores. Our modelling results show that the internal reflections are mainly due to conductivity changes. Furthermore, we deduce fabric characteristics at the EGRIP drill site from two-way-travel-time differences of along and across-flow polarized radarwave reflections of selected horizons (below 980 m). These indicate in deeper parts of the ice column an across-flow concentrated c-axis fabric.

Rock glaciers are relatively common in Antarctic permafrost areas and could be considered postglacial cryogenic landforms. Although the extensive presence of rock glaciers, their chemical–physical and biotic composition remain scarce. Chemical–physical parameters and fungal community (by sequencing the ITS2 rDNA, Illumina MiSeq) parameters of a permafrost core were studied. The permafrost core, reaching a depth of 6.10 m, was divided into five units based on ice content. The five units (U1–U5) of the permafrost core exhibited several significant (p < 0.05) differences in terms of chemical and physical characteristics, and significant (p < 0.05) higher values of Ca, K, Li, Mg, Mn, S, and Sr were found in U5. Yeasts dominated on filamentous fungi in all the units of the permafrost core; additionally, Ascomycota was the prevalent phylum among filamentous forms, while Basidiomycota was the dominant phylum among yeasts. Surprisingly, in U5 the amplicon sequence variants (ASVs) assigned to the yeast genus Glaciozyma represented about two-thirds of the total reads. This result may be considered extremely rare in Antarctic yeast diversity, especially in permafrost habitats. Based on of the chemical–physical composition of the units, the dominance of Glaciozyma in the deepest unit was correlated with the elemental composition of the core. [ABSTRACT FROM AUTHOR]

In 1976 M.W. Mahaffy published a basic ice-sheet model which did not make the usual steady-state assumption of constant height and which allowed for time-varying ice accumulation rates. For this reason his model should be of interest to creation researchers, who can use it to model the rapid growth of post-Flood ice sheets. This paper provides a brief overview of the theory and assumptions behind Mahaffy's model and its solution. The model is used to simulate the rapid growth of a long but thin isothermal ice ridge. The results are then compared with the results from the Vardiman model. A suggested technique for using the Dansgaard-Johnsen and Mahaffy ice sheet models to estimate annual layer thicknesses near an ice divide is also presented. [ABSTRACT FROM AUTHOR]

Cosmogenic radionuclide records from polar ice cores provide unique insights into past cosmic ray flux variations. They allow reconstructions of past solar activity, space weather, and geomagnetic field changes, and provide insights into past carbon cycle changes. However, all these applications rely on the proportionality of the ice core radionuclide records to the global mean production rate changes. This premise has been long debated from a model and data‐perspective. Here, we address this issue through atmospheric mixing model experiments and comparison to independent data. We find that all mixing scenarios, which do not assume complete tropospheric mixing, result in a polar bias. This bias is more prominent for geomagnetic field changes than solar modulation changes. The most likely scenario, supported by independent geomagnetic field records and marine 10Be during the Laschamps geomagnetic field minimum, results in a dampening of geomagnetic field induced changes by 23%–37% and an enhancement of solar‐induced changes by 7%–8%. During the Holocene, we do not find conclusive evidence for a polar bias. We propose a correction function that allows deconvolving the glacial ice core record in order to restore proportionality to the global mean signal. Plain Language Summary: Ice core records of cosmogenic radionuclides (e.g., 10Be) are unique archives providing information on past changes in galactic and solar cosmic ray fluxes. The atmospheric production rates vary in response to changes of the cosmic ray flux, which in turn is modulated by solar and geomagnetic shielding. Typically, it is assumed that the deposition of 10Be on the ice varies in proportion to changes in its atmospheric production rate. However, this assumption has been questioned early on, since the geomagnetic shielding against cosmic rays depends on the geomagnetic latitude, being essentially zero at the ice‐core locations. It was proposed, that ice cores may suffer from a "polar bias" which dampens the geomagnetic field signal and enhances the solar signal in ice core 10Be, thus questioning the use of ice‐core 10Be‐data as proxies for global cosmogenic radionuclide production rate changes. Here, we revisit this hypothesis using mixing model experiments in conjunction with a compilation of 10Be data from high and low‐latitude archives and geomagnetic field models. We deduce that a polar bias is likely present in glacial ice‐core 10Be‐records and provide a simple method to approximately restore the proportionality of ice core 10Be data to global production rate changes. Key Points: Mixing‐model experiments and independent data suggest that ice‐core 10Be‐records do not capture a global‐mean signalDuring the glacial, modulation by geomagnetic field changes is dampened by ∼23%. Effects of solar activity changes are enhanced by ∼7%A transfer function is proposed that restores the approximate proportionality of ice core data to global production rate changes [ABSTRACT FROM AUTHOR]

The study of the fabric and microstructure of ice at the shear margin of the Antarctic ice sheet is of great significance for understanding the ice flow and its contributions to sea level rise. In this study, twenty-three one-meter-long ice cores were drilled from blue ice areas at the shear margin of the Dalk Glacier, Antarctica. The ice fabric and microstructure of these ice cores are analyzed using a G50 fabric analyzer. This study shows that the shallow ice cores in this region present a cluster fabric as a consequence of shear stress. The grain size decreases following the direction of the ice flow towards the exposed bedrock at the end of the glacier, due to the blocking and squeezing by the bedrock. The formation mechanism of the shallow ice layers is that the ice from the original accumulation area flows here, lifted by the bedrock and shaped by the summer ablation and denudation. The basal ice at the shear margin of the Dalk Glacier is strongly rubbed by the bedrock and demonstrates a cluster fabric. The analysis of stable water isotopes shows a weak negative correlation between shallow ice fabric and stable water isotopes with depth. Bedrock topography and shear stress have a greater influence on grain microstructure among different ice cores over long distances at shear margins. [ABSTRACT FROM AUTHOR]

Warming temperatures and prolonged drought periods cause rapid changes of fire frequencies and intensities in high-latitude ecosystems. Associated smoke plumes deposit dark particles from incomplete combustion on the Greenland ice sheet that reduce albedo but also provide a detailed record of paleofire history. Here, we apply an emerging microscopic charcoal technique in combination with established black carbon and lead pollution measurements to an array of 10 ice cores from southern to central Greenland that span recent decades. We found that microscopic charcoal deposition is highly variable among sites, with a few records suggesting recently increasing biomass burning possibly in response to growing fire activity in boreal forest ecosystems. This stands in contrast to decreasing trends in black carbon measured in the same ice cores, consistent with contributions from industrial fossil fuel emissions. Decreasing trends of lead pollution and occurrence of microscopic spheroidal carbonaceous particles (SCP), a microfossil tracer of fossil fuel emissions, further support our interpretation that black carbon in this region is influenced by industrial emissions during recent decades. We conclude that microscopic charcoal analyses in ice may help disentangle biomass burning from fossil-fuel emissions during the industrial period and have potential to contribute to better understanding of regional high-latitude fire regimes. [ABSTRACT FROM AUTHOR]

The stable water isotopic composition in firn and ice cores provides valuable information on past climatic conditions. Because of uneven accumulation and post‐depositional modifications on local spatial scales up to hundreds of meters, time series derived from adjacent cores differ significantly and do not directly reflect the temporal evolution of the precipitated snow isotopic signal. Hence, a characterization of how the isotopic profile in the snow develops is needed to reliably interpret the isotopic variability in firn and ice cores. By combining digital elevation models of the snow surface and repeated high‐resolution snow sampling for stable water isotope measurements of a transect at the East Greenland Ice‐core Project campsite on the Greenland Ice Sheet, we are able to visualize the buildup and post‐depositional changes of the upper snowpack across one summer season. To this end, 30 cm deep snow profiles were sampled on six dates at 20 adjacent locations along a 40 m transect. Near‐daily photogrammetry provided snow height information for the same transect. Our data shows that erosion and redeposition of the original snowfall lead to a complex stratification in the δ18O signature. Post‐depositional processes through vapor‐snow exchange affect the near surface snow with d‐excess showing a decrease in surface and near‐surface layers. Our data suggests that the interplay of stratigraphic noise, accumulation intermittency, and local post‐depositional processes form the proxy signal in the upper snowpack. Plain Language Summary: We study the process of the formation of the stable water isotope signal in surface snow on the Greenland Ice Sheet to better understand temperature information which is stored as a climate proxy in snow and ice. Our data consist of high‐resolution surface topography information illustrating the timing and location of snowfall, erosion, and redeposition along a transect of 40 m, as well as stable water isotope records of the upper 30 cm of the snowpack sampled biweekly on 20 positions at the same 40 m long transect. The data cover a 2‐month period during the summer of 2019. We find that the isotopic composition shows spatial variability of layers with low and high values, presumably winter and summer layers. We further observe that prevailing surface structures, such as dunes, influence the snow deposition and contribute to the found variable structure of the climatic information. Eventually, snow accumulation alone cannot explain all of the observed patterns in the isotopic data which is likely related to exchange processes between the snow and the atmosphere which modify the signal in the snow column after deposition. Key Points: Combining digital elevation models and repeated snow sampling reveals the heterogeneous buildup of δ18O signal in the snow columnSurface structures (stratigraphic noise) substantially contribute to internal heterogeneity in δ18O signature in the upper snowpackProxy signals are formed in the surface layer by local processes, advected downwards with limited post‐depositional influences below 10 cm [ABSTRACT FROM AUTHOR]

Refreezing of meltwater in firn is a major component of Greenland ice-sheet's mass budget, but in situ observations are rare. Here, we compare the firn density and total ice layer thickness in the upper 15 m of 19 new and 27 previously published firn cores drilled at 15 locations in southwest Greenland (1850–2360 m a.s.l.) between 1989 and 2019. At all sites, ice layer thickness covaries with density over time and space. At the two sites with the earliest observations (1989 and 1998), bulk density increased by 15–18%, in the top 15 m over 28 and 21 years, respectively. However, following the extreme melt in 2012, elevation-detrended density using 30 cores from all sites decreased by 15 kg m−3 a−1 in the top 3.75 m between 2013 and 2019. In contrast, the lowest elevation site's density shows no trend. Thus, temporary build-up in firn pore space and meltwater infiltration capacity is possible despite the long-term increase in Greenland ice-sheet melting.

This paper presents a physics-based macroscale model for the densification of dry snow which provides for a smooth transition between densification by grain-boundary sliding (stage 1) and densification by power-law creep (stage 2). The model uses established values of the stage 1 and 2 densification rates away from the transition zone and two transition parameters with a simple physical basis: the transition density and the half-width of the transition zone. It has been calibrated using density profiles from the SUMup database and physically based expressions for the transition parameters have been derived. The transition model produces better predictions of the depth of the nominal bubble close-off horizon than the Herron and Langway model, both in its classical form and in a recent version with re-optimised densification rates.