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1. Preparation of cationic dinuclear hydrido complexes of ruthenium, rhodium, and iridium with bridging thiolato ligands and their reactions with nitrosobenzene

Author

Iwasa, Takafumi, Shimada, Hitoshi, Takami, Atsushi, Matsuzaka, Hiroyuki, Ishii, Youchi, and Hidai, Masanobu

Subjects
Cations -- Research, Ruthenium -- Research, Rhodium -- Research, Iridium -- Research, Ligands -- Research, Coordination compounds -- Research, Chemistry
Abstract

Research was conducted to examine the synthesis of cationic dinuclear hydrido complexes of ruthenium, rhodium, and iridium with bridging thiolato ligands and their reactions with nitrosobenzene. X-ray diffraction studies of the molecular structures of the three nitrosobenzene complexes showed that in each case, nitrosobenzene serves as a mu-eta(super 1):eta(super 1)-N,O ligand. The unpaired electron is considered to be located mainly on the nitrosobenzene ligand in the diruthenium and dirhodium complexes.

Published
1999

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