1. Polymorphic PtBi2: Growth, structure and superconducting properties
- Author
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R. Giraud, B. Büchner, Saicharan Aswartham, D. V. Efremov, A. Veyrat, S. Subakti, Christian Hess, Daniel Wolf, Axel Lubk, J. Dufouleur, S. Shokri, I. Kovalchuk, V. Labracherie, B. R. Piening, Federico Caglieris, and G. Shipunov
- Subjects
Superconductivity ,Condensed Matter - Materials Science ,Materials science ,Physics and Astronomy (miscellaneous) ,Rietveld refinement ,Fermi level ,Materials Science (cond-mat.mtrl-sci) ,FOS: Physical sciences ,Crystal growth ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Crystallography ,symbols.namesake ,0103 physical sciences ,symbols ,Density of states ,General Materials Science ,Selected area diffraction ,010306 general physics ,0210 nano-technology ,Electronic band structure ,Powder diffraction - Abstract
PtBi$_2$ is a polymorphic system with interesting electronic properties. Here we report optimized crystal growth and structural characterization of pyrite-type and trigonal modification of PtBi$_2$. Selected area electron diffraction, X-ray powder diffraction and further Rietveld refinement confirms that trigonal PtBi$_2$ crystallizes in non-centrosymmetric $P31m$ space group, pyrite-type PtBi$_2$ in $Pa\bar{3}$ space group. Series of Pt$_{1-x}$Rh$_x$Bi$_2$ samples was obtained for $x=0, 0.03, 0.35$ in the trigonal PtBi$_2$ structure. These Pt$_{1-x}$Rh$_x$Bi$_2$ compounds become superconducting where critical temperature increases from $T_c=600$ mK for $x=0$ up to $T_c=2.7$ K for $x=0.35$. Furthermore we calculate the electronic band structure, using the structure parameters obtained. The calculated density of states (DOS) shows a minimum for the stochiometric compound at the Fermi level. These findings warrant further research by broader array of experimental techniques, as well as the effect of the substitution on the non-trivial band structure.
- Published
- 2020
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