313 results on '"J. E. Hirsch"'
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2. Incompatibility of published ac magnetic susceptibility of a room temperature superconductor with measured raw data
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J. E. Hirsch and D. van der Marel
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Nuclear and particle physics. Atomic energy. Radioactivity ,QC770-798 - Abstract
A material termed “carbonaceous sulfur hydride” has recently been reported to be a high-pressure room temperature superconductor [Snider et al., Nature 586, 373 (2020)]. We have previously pointed out that certain anomalies observed in the published data for the ac magnetic susceptibility of this material would be cleared up once the measured raw data were made available [J. E. Hirsch, arXiv:2110.12854v1 (2021) and J. E. Hirsch, Physica C 590, 1353964 (2021) (temporarily removed)]. The measured raw data, as well as numerical values of the data presented in figures in the aforementioned paper by Snider et al., have recently been posted on the arXiv [R. P. Dias and A. Salamat, arXiv:2111.15017v1 (2021) and R. P. Dias and A. Salamat, arXiv:2111.15017v2 (2021)]. Here, we report the results of our analysis of these raw data and published data and our conclusion that the raw data are incompatible with the published data. Implications of these results for the claim that the material is a room temperature superconductor are discussed.
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- 2022
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3. The meaning of the h-index
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J. E. Hirsch and Gualberto Buela-Casal
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Psychology ,BF1-990 - Abstract
El índice h surge del presupuesto de que el número de citas que recibe un científico constituye un mejor indicador de la relevancia de su trabajo que el número de artículos que publica o en qué revistas lo hace. Se trata de un indicador que, a partir del balance entre el número de publicaciones y las citas a éstas, permite la comparación entre distintos científicos. En este artículo se da respuesta a las preguntas más frecuentes acerca del índice h. En concreto, se describe su origen, cuáles son sus ventajas con respecto a otros índices, los factores que pueden influirle (edad, campo de conocimiento, las propias temáticas de investigación o idioma en que se publica), sus variantes y sus injusticias. En definitiva, se expone de forma clara cuál es la función esperada del índice h en la evaluación de los científicos: que complemente a otros indicadores más subjetivos, y que contribuya en forma positiva al avance de la ciencia al ayudar la toma de decisiones de alocación de recursos para la investigación en forma más efectiva y de recompensar a los que contribuyen al avance científico en forma más ecuánime. © 2014 Asociación Española de Psicología Conductual. Publicado por Elsevier España, S.L. Todos los derechos reservados.
- Published
- 2014
4. On Magnetic Field Screening and Expulsion in Hydride Superconductors
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J. E. Hirsch and F. Marsiglio
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Condensed Matter Physics ,Electronic, Optical and Magnetic Materials - Abstract
Reference [1] presents evidence for magnetic field screening and “subtle” evidence for magnetic field expulsion in hydrides under high pressure, which is argued to support the claim that these materials are high temperature superconductors. We point out here that data presented in different figures of Ref. [1] are inconsistent (i) with one another, (ii) with other work by the same authors on the same samples [2, 3], and (iii) with the expected behavior of standard superconductors. This suggests that these magnetic phenomena reported for these materials are not associated with superconductivity, undermining the claim that these materials are high temperature superconductors.
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- 2023
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5. Comment on 'Carbon content drives high temperature superconductivity in a carbonaceous sulfur hydride below 100 GPa' by G. A. Smith, I. E. Collings, E. Snider, D. Smith, S. Petitgirard, J. S. Smith, M. White, E. Jones, P. Ellison, K. V. Lawler, R. P. Dias and A. Salamat, Chem. Commun., 2022, 58, 9064
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J. E. Hirsch
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Materials Chemistry ,Metals and Alloys ,Ceramics and Composites ,General Chemistry ,Catalysis ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials - Abstract
The mathematical finding presented here undermines confidence in the claim that any of the experimental evidence reported in the published paper reflects the properties of real physical samples of CSH.
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- 2023
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6. Evidence Against Superconductivity in Flux Trapping Experiments on Hydrides Under High Pressure
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J. E. Hirsch and F. Marsiglio
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Condensed Matter Physics ,Electronic, Optical and Magnetic Materials - Abstract
It has recently been reported that hydrogen-rich materials under high-pressure trap magnetic flux, a tell-tale signature of superconductivity (Minkov et al., Trapped magnetic flux in hydrogen-rich high-temperature superconductors, Ref. 1). Here, we point out that under the protocol used in these experiments the measured results indicate that the materials don’t trap magnetic flux. Instead, the measured results either are experimental artifacts or originate in magnetic properties of the sample or its environment unrelated to superconductivity. Together with other experimental evidence analyzed earlier, this clearly indicates that these materials are not superconductors.
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- 2022
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7. Electrical resistance of hydrides under high pressure: evidence of superconductivity or confirmation bias?
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J. E. Hirsch
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During the past 9 years, extensive experimental evidence has been presented that is claimed to demonstrate that hydrogen-rich materials under high pressure are high temperature superconductors, as predicted by conventional BCS-electron-phonon theory. Foremost among the experimental evidence are electrical resistance measurements, claimed to show that the resistivity of these materials falls well below that of the best normal metals within experimental accuracy. Here I propose an alternative explanation for the vanishingly small resistance reported for these materials that does not involve superconductivity.
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- 2023
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8. Superconductivity, what the H? the emperor has no clothes
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J. E. Hirsch
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Superconductivity (cond-mat.supr-con) ,Condensed Matter - Superconductivity ,Physics - History and Philosophy of Physics ,History and Philosophy of Physics (physics.hist-ph) ,FOS: Physical sciences ,Statistical and Nonlinear Physics ,Condensed Matter Physics - Abstract
A magnetic field H is expelled from the interior of a metal becoming superconducting. Everybody thinks the phenomenon is perfectly well understood, particularly scientists with the highest H-index think that. I don't. I will explain why I believe that without Holes, conceptualized by Heisenberg in 1931 fifty years after Hall had first detected them in some metals, neither magnetic field expulsion nor anything else about superconductivity can be understood. I have been a Heretic in the field of superconductivity for over 30 years, and believe that Hans' little story about the emperor perfectly captures the essence of the situation. Here is (a highly condensed version of) the wHole story.
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- 2023
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9. Erratum: Room-temperature superconductivy-or not? Comment on nature 586, 373 (2020) by E. Snider et al
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D. Van Der Marel and J. E. Hirsch
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Statistical and Nonlinear Physics ,Condensed Matter Physics - Published
- 2022
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10. Room-temperature superconductivity — or not? Comment on Nature 586, 373 (2020) by E. Snider et al
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D. van der Marel and J. E. Hirsch
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Statistical and Nonlinear Physics ,Condensed Matter Physics - Abstract
Recently, the discovery of room-temperature superconductivity was announced for a carbonaceous sulfur hydride (CSH) under high pressure [E. Snider et al., Nature 586, 373 (2020)]. The evidence for superconductivity was based on resistance and magnetic susceptibility measurements. In the figures showing the susceptibility it was stated that “the background signal, determined from a nonsuperconducting CSH sample at 108 GPa, has been subtracted from the data”. From a thorough data analysis we show that the data are incompatible with the notion that the susceptibility data are obtained from the “measured voltage” using a background correction. On the other hand, the data are compatible with the reverse procedure, namely the “measured voltage” is obtained by adding a “background signal” containing noise to what was reported as the background-corrected susceptibility. For all six of the reported pressures our analysis leads to the conclusion that: (i) the reported background-corrected susceptibility data are pathological, (ii) they were not obtained by the method described in this paper nor by any one of the alternative three methods that were subsequently provided by the authors and (iii) the “measured voltage” data are not raw data.
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- 2022
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11. On the 'User Defined Background' and 'Measured Voltage' that detected room temperature superconductivity in carbonaceous sulfur hydride (CSH)
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J e Hirsch
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It is shown that the reported "Measured Voltage" detecting a superconducting transition at room temperature in CSH under 160 GPa pressure [1] was in fact not "measured" but instead calculated starting from a "User Defined Background".
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- 2022
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12. Superconducting Materials: Judge, Jury and Executioner of BCS-electron-phonon Theory
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J e Hirsch
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By a recent count, there are 32 different classes of superconducting materials, only 12 of which are generally believed to be "conventional", i.e. described by the conventional BCS-electron-phonon theory of superconductivity. In this perspective I critically examine the successes and failures of the conventional theory to describe conventional superconductors, and discuss what is understood and not understood about hydrogen-rich materials claimed to be high temperature conventional superconductors under high pressure. I argue that the current state of affairs calls for dethroning the conventional theory of its privileged status and seriously explore the alternative possibility that a single theory, different from the conventional theory, may describe superconductivity of all materials in a unified way.
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- 2022
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13. Comment on 'On the analysis of the tin-inside-H3S Mossbauer experiment'
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J e Hirsch
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Condensed Matter Physics ,Electronic, Optical and Magnetic Materials - Abstract
Prozorov and Bud’ko (On the analysis of the tin-inside-H3S Mössbauer experiment, 2022) recently analyzed the nuclear resonant scattering (NRS) experiment that reportedly demonstrated magnetic field exclusion in sulfur hydride under pressure (Science 351, 1303, 2016), and concluded that the experiment is consistent with the expected behavior of a type II superconductor. Here I point out that their analysis shows that the reported NRS measurements are incompatible with the recently reported magnetization measurements by Minkov et al. (Nat Commun 13, 3194, 2022), indicating that at minimum one of these two experiments does not support the claim that sulfur hydride under pressure is superconducting.
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- 2022
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14. Clear evidence against superconductivity in hydrides under high pressure
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Frank Marsiglio and J. E. Hirsch
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Superconductivity ,Nuclear and High Energy Physics ,Materials science ,Condensed matter physics ,Hydride ,Condensed Matter - Superconductivity ,chemistry.chemical_element ,Sulfur hydride ,FOS: Physical sciences ,Atomic and Molecular Physics, and Optics ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,chemistry ,Nuclear Energy and Engineering ,Meissner effect ,High pressure ,Condensed Matter::Superconductivity ,Lanthanum ,Electrical and Electronic Engineering ,Physics::Chemical Physics ,Astrophysics::Galaxy Astrophysics - Abstract
The Meissner effect, magnetic field expulsion, is a hallmark of superconductivity. Associated with it, superconductors exclude applied magnetic fields. Recently Minkov et al. presented experimental results reportedly showing "definitive evidence of the Meissner effect" in sulfur hydride and lanthanum hydride under high pressure [1], and more recently Eremets et al. argued that "the arguments against superconductivity (in hydrides) can be either refuted or explained" [2]. Instead, we show here that the evidence presented in those papers does not support the case for superconductivity in these materials. Together with experimental evidence discussed in earlier papers, we argue that this strongly suggests that hydrides under pressure are not high-temperature superconductors., 10 pages 7 figures
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- 2022
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15. Granular Superconductivity in Hydrides Under Pressure
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J e Hirsch
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History ,Polymers and Plastics ,Condensed Matter::Superconductivity ,Business and International Management ,Condensed Matter Physics ,Industrial and Manufacturing Engineering ,Electronic, Optical and Magnetic Materials - Abstract
It has been suggested that the measured magnetic properties of hydrides under pressure claimed to be high temperature superconductors indicate that the materials are granular superconductors. Such materials will show reduced or no magnetic field expulsion under field cooling, and will trap magnetic fields when the external magnetic field is removed. They will also exhibit hysteretic behavior in magnetoresistance and other transport properties. Here we point out that hysteresis in transport properties has never been reported for hydrides under pressure. Its presence, with the expected features, would indicate that the materials trap magnetic flux, hence that they can sustain persistent currents without dissipation, something that all superconductors can do. Conversely, its absence would indicate that these materials are not superconductors.
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- 2022
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16. Incompatibility of Published ac Magnetic Susceptibility of a Room Temperature Superconductor with Measured Raw Data
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J. E. Hirsch
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condensed_matter_physics - Abstract
Room temperature superconductivity has recently been reported for a carbonaceous sulfur hydride (CSH) under high pressure by Snider et al [1]. The paper reports sharp drops in magnetic susceptibility as a function of temperature for five different pressures, that are interpreted as signaling a superconducting transition. Here I question the validity and faithfulness of the magnetic susceptibility data presented in the paper by comparison with the measured raw data reported by two of the authors of ref. [2]. This invalidates the assertion of the paper [1] that the susceptibility measurements support the case for superconductivity in this compound.
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- 2021
17. Absence of evidence of superconductivity in sulfur hydride in optical reflectance experiments
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J. E. Hirsch and F. Marsiglio
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Superconductivity (cond-mat.supr-con) ,Condensed Matter - Superconductivity ,Condensed Matter::Superconductivity ,FOS: Physical sciences ,General Physics and Astronomy ,Physics::Chemical Physics - Abstract
Capitani and coworkers [1] reported that infrared optical reflectance measurements provided evidence for a superconducting transition in sulfur hydride [2] under 150 GPa pressure, and that the transition is driven by the electron-phonon interaction. Here we argue that the measured data did not provide evidence that the system undergoes a transition to a superconducting state, nor do the data support any role of phonons in driving a transition. Rather, the data are consistent with the system remaining in the normal state down to temperature 50K, the lowest temperature measured in the experiment. This calls into further question [3,4] the generally accepted view [5] that sulfur hydride under pressure is a high temperature superconductor., 3 pages, 3 figures. Nature Physics 2022
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- 2021
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18. Superconducting Materials: the Whole Story
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J. E. Hirsch
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010302 applied physics ,Physics ,Superconductivity ,Scientific career ,Condensed Matter::Superconductivity ,0103 physical sciences ,Fundamental physics ,010306 general physics ,Condensed Matter Physics ,01 natural sciences ,Engineering physics ,Physics::Atmospheric and Oceanic Physics ,Electronic, Optical and Magnetic Materials - Abstract
Ted Geballe has contributed enormously to the knowledge of superconducting materials during an illustrious scientific career spanning seven decades, encompassing groundbreaking discoveries and studies of both so-called conventional and unconventional superconductors. On the year of his 100th birthday, I would like to argue that all superconducting materials that Ted investigated, as well as those he did not, have one thing in common that is not generally recognized: hole carriers. This includes PbTe doped with Tl, for which Ted has proposed that superconductivity is driven by negative-U pairing. I will discuss why hole carriers are necessary for a material to be a superconductor, and the implications of this for the understanding of the fundamental physics of superconductivity.
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- 2019
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19. Corrigendum to: 'Incompatibility of published ac magnetic susceptibility of a room temperature superconductor with measured raw data' [Matter Radiat. Extremes 7, 048401 (2022)]
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J. E. Hirsch and D. van der Marel
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Nuclear and High Energy Physics ,Nuclear Energy and Engineering ,Electrical and Electronic Engineering ,Atomic and Molecular Physics, and Optics - Published
- 2022
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20. Superconducting materials: Judge and jury of BCS-electron–phonon theory
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J e Hirsch
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Physics and Astronomy (miscellaneous) - Abstract
By a recent count, there are 32 different classes of superconducting materials [Physica C: Special Issue, “Superconducting materials: conventional, unconventional and undetermined. Dedicated to Theodore H. Geballe on the year of his 95th birthday,” edited by J. E. Hirsch, M. B. Maple, F. Marsiglio (▪, 2015), Vol. 514, pp. 1–444.], only 12 of which are generally believed to be “conventional,” i.e., described by the conventional BCS-electron–phonon theory of superconductivity. In this Perspective, I critically examine the successes and failures of the conventional theory to describe conventional superconductors and discuss what is understood and not understood about hydrogen-rich materials claimed to be high temperature conventional superconductors under high pressure. I argue that the materials' evidence accumulated to date calls for dethroning the conventional theory of its privileged status and seriously explore the alternative possibility that a single theory, different from the conventional theory, may describe superconductivity of all materials in a unified way.
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- 2022
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21. Flux trapping in superconducting hydrides under high pressure
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Frank Marsiglio and J. E. Hirsch
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Superconductivity ,High-temperature superconductivity ,Materials science ,Condensed matter physics ,Condensed Matter - Superconductivity ,Energy Engineering and Power Technology ,FOS: Physical sciences ,Condensed Matter Physics ,Magnetic flux ,Electronic, Optical and Magnetic Materials ,law.invention ,Superconductivity (cond-mat.supr-con) ,Flux trapping ,law ,Meissner effect ,High pressure ,Electrical and Electronic Engineering - Abstract
High-temperature conventional superconductivity in hydrogen-rich materials under high pressure has been reportedly found in twelve different compounds in recent years. However, the experimental evidence on which these claims are based has recently been called into question. Here we discuss the measurement of trapped magnetic flux, that should establish definitively that these materials are indeed high-temperature superconductors. Its absence should confirm claims to the contrary., Comment: minor changes; to be published in Physica C
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- 2021
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22. Unusual width of the superconducting transition in a hydride
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J E, Hirsch and F, Marsiglio
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Thermodynamics - Published
- 2020
23. Response to comment 'hα: the scientist as chimpanzee or bonobo', by Leydesdorff, Bornmann and Opthof
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J. E. Hirsch
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Combinatorics ,General Social Sciences ,Library and Information Sciences ,Computer Science Applications ,Mathematics - Abstract
In this comment by Leydesdorff, Bornmann and Opthof (Scientometrics https://doi.org/10.1007/s11192-019-03004-3 , 2019) the authors criticize the recently proposed $$h_{\alpha }$$ index (Scientometrics https://doi.org/10.1007/s11192-018-2994-1 , 2018) on the basis that “ $$h_{\alpha }$$ inherits most of the disadvantages of the h-index”, that it “can be extremely unstable”, and that “The empirical attribution of credit among co-authors is not captured by abstract models such as h, $$\bar{h}$$ , or $$h_{\alpha }$$ ”. I refute their arguments and present further evidence that $$h_{\alpha }$$ is a useful and essential complement to the h-index.
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- 2019
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24. hα: An index to quantify an individual’s scientific leadership
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J. E. Hirsch
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Discrete mathematics ,Index (publishing) ,Group (mathematics) ,05 social sciences ,General Social Sciences ,0509 other social sciences ,Library and Information Sciences ,050905 science studies ,050904 information & library sciences ,Computer Science Applications ,Mathematics ,Scientific achievement - Abstract
The $$\alpha$$ person is the dominant person in a group. We define the $$\alpha$$ -author of a paper as the author of the paper with the highest h-index among all the coauthors, and an $$\alpha$$ -paper of a scientist as a paper authored or coauthored by the scientist where he/she is the $$\alpha$$ -author. For most but not all papers in the literature there is only one $$\alpha$$ -author. We define the $$h_\alpha$$ index of a scientist as the number of papers in the h-core of the scientist (i.e. the set of papers that contribute to the h-index of the scientist) where this scientist is the $$\alpha$$ -author. We also define the $$h'_\alpha$$ index of a scientist as the number of $$\alpha$$ -papers of this scientist that have $$\ge$$ $$h'_\alpha$$ citations. $$h_\alpha$$ and $$h'_\alpha$$ contain similar information, while $$h'_\alpha$$ is conceptually more appealing it is harder to obtain from existing databases, hence of less current practical interest. We propose that the $$h_\alpha$$ and/or $$h'_\alpha$$ indices, or other variants discussed in the paper, are useful complements to the h-index of a scientist to quantify his/her scientific achievement, that rectify an inherent drawback of the h-index, its inability to distinguish between authors with different coauthorships patterns. A high h index in conjunction with a high $$h_\alpha /h$$ ratio is a hallmark of scientific leadership.
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- 2019
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25. Moment of inertia of superconductors
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J. E. Hirsch
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Physics ,Superconductivity ,Condensed matter physics ,Condensed Matter - Superconductivity ,London penetration depth ,FOS: Physical sciences ,General Physics and Astronomy ,Astrophysics::Cosmology and Extragalactic Astrophysics ,Electron ,Moment of inertia ,London moment ,01 natural sciences ,010305 fluids & plasmas ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Superfluidity ,Classical electron radius ,Condensed Matter::Superconductivity ,0103 physical sciences ,010306 general physics - Abstract
We find that the bulk moment of inertia per unit volume of a metal becoming superconducting increases by the amount $m_e/(\pi r_c)$, with $m_e$ the bare electron mass and $r_c=e^2/m_e c^2$ the classical electron radius. This is because superfluid electrons acquire an intrinsic moment of inertia $m_e (2\lambda_L)^2$, with $\lambda_L$ the London penetration depth. As a consequence, we predict that when a rotating long cylinder becomes superconducting its angular velocity does not change, contrary to the prediction of conventional BCS-London theory that it will rotate faster. We explain the dynamics of magnetic field generation when a rotating normal metal becomes superconducting., Comment: An error in Fig. 2 was corrected
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- 2019
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26. Unusual width of the superconducting transition in a hydride
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Frank Marsiglio and J. E. Hirsch
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Superconductivity ,Multidisciplinary ,Materials science ,Condensed matter physics ,Hydride ,0103 physical sciences ,02 engineering and technology ,021001 nanoscience & nanotechnology ,010306 general physics ,0210 nano-technology ,01 natural sciences - Published
- 2021
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27. Comment on 'Room-temperature superconductivity in a carbonaceous sulfur hydride' by Elliot Snider et al
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J. E. Hirsch
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General Physics and Astronomy - Published
- 2022
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28. Hole superconductivity xOr hot hydride superconductivity
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J. E. Hirsch
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Superconductivity ,Physics ,Theoretical physics ,High-temperature superconductivity ,law ,Hydride ,Meissner effect ,Condensed Matter::Superconductivity ,Alternative theory ,General Physics and Astronomy ,law.invention - Abstract
Under the spell of BCS-electron–phonon theory [M. Tinkham, Introduction to Superconductivity, 2nd ed. (McGraw Hill, New York, 1996)], during the last 6 years experimentalists have purportedly discovered a plethora of high temperature conventional superconductors among pressurized hydrides [Pickard et al., Ann. Rev. Condens. Matter Phys. 11, 57 (2020) and R. F. Service, Science 373, 954 (2021)], and theorists have been busy predicting and explaining those findings [Lv et al., Matter Radiat. Extremes 5, 068101 (2020); Flores-Livas et al., Phys. Rep. 856, 1 (2020); and Boeri et al., J. Phys. Condens. Matter. (to be published)]. The alternative theory of hole superconductivity (see https://jorge.physics.ucsd.edu/hole.html for a list of references) predicts instead that no superconductivity can exist in these materials. In this Tutorial, I will first argue that, unclouded by the prejudice of BCS’s validity, the existing experimental evidence for superconductivity in pressurized hydrides does not withstand scrutiny. Once it is established that superconductivity in pressurized hydrides is a myth and not a reality, the claim to validity of BCS-electron–phonon theory as a descriptor of superconductivity of real materials will be forever shattered, and an alternative theory will become imperative. I will explain the fundamentals of the theory of hole superconductivity, developed over the past 32 years [see https://jorge.physics.ucsd.edu/hole.html and J. E. Hirsch, Phys. Lett. A 134, 451 (1989)], and why it is compelling. Crucially, it explains the Meissner effect, that I argue the conventional theory does not. It applies to all superconducting materials and provides guidelines in the search for high temperature superconductors that are very different from those provided by BCS-electron–phonon theory. Light elements are predicted to be irrelevant to warm superconductivity because according to this theory the electron–phonon interaction plays no role in superconductivity.
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- 2021
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29. Magnetic flux expulsion in a superconducting wire
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J. E. Hirsch
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Superconductivity ,Physics ,Condensed matter physics ,Condensed Matter - Superconductivity ,Superconducting wire ,FOS: Physical sciences ,General Physics and Astronomy ,engineering.material ,Magnetic flux ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,London equations ,Meissner effect ,Condensed Matter::Superconductivity ,engineering ,Charge carrier ,Electric current - Abstract
An electric current generates a magnetic field, and magnetic fields cannot exist in the interior of type I superconductors. As a consequence of these two facts, electric currents can only flow near the surface of a type I superconducting wire so that the self-field vanishes in the interior. Here we examine how an electric current flowing through the entire cross-section of a normal conducting wire becomes a surface current when it enters a superconducting portion of the wire. This geometry provides insight into the dynamics of magnetic flux expulsion that is not apparent in the Meissner effect involving expulsion of an externally applied magnetic field. It provides clear evidence that the motion of magnetic field lines in superconductors is intimately tied to the motion of charge carriers, as occurs in classical plasmas (Alfven's theorem) and as proposed in the theory of hole superconductivity [1] , in contradiction with the conventional London-BCS theory of superconductivity.
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- 2021
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30. Nonstandard superconductivity or no superconductivity in hydrides under high pressure
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J. E. Hirsch and Frank Marsiglio
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Superconductivity ,Physics ,High-temperature superconductivity ,Condensed matter physics ,Orders of magnitude (temperature) ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,3. Good health ,law.invention ,Superconductivity (cond-mat.supr-con) ,law ,High pressure ,Condensed Matter::Superconductivity ,0103 physical sciences ,Critical current ,010306 general physics ,0210 nano-technology - Abstract
Over the past six years, superconductivity at high temperatures has been reported in a variety of hydrogen-rich compounds under high pressure. That high-temperature superconductivity should exist in these materials is expected according to the conventional theory of superconductivity, as shown by detailed calculations. However here we argue that experimental observations rule out conventional superconductivity in these materials. Our results indicate that either these materials are unconventional superconductors of a novel kind, which we term `nonstandard superconductors', or alternatively that they are not superconductors. If the former, we point out that the critical current in these materials should be five orders of magnitude larger than in standard superconductors, potentially opening up the way to important technological applications. If the latter, which we believe is more likely, we suggest that the signals interpreted as superconductivity are either experimental artifacts or they signal other interesting physics but not superconductivity., Comment: 11 pages, 13 figures
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- 2020
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31. Comment on 'Reply to 'Comment on Nature 586, 373 (2020) by E. Snider et al ''
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J E Hirsch
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- 2020
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32. How Alfven's theorem explains the Meissner effect
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J. E. Hirsch
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Physics ,Superconductivity ,Condensed matter physics ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Statistical and Nonlinear Physics ,02 engineering and technology ,Dissipation ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Meissner effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Magnetohydrodynamics ,010306 general physics ,0210 nano-technology - Abstract
Alfven’s theorem states that in a perfectly conducting fluid magnetic field lines move with the fluid without dissipation. When a metal becomes superconducting in the presence of a magnetic field, magnetic field lines move from the interior to the surface (Meissner effect) in a reversible way. This indicates that a perfectly conducting fluid is flowing outward. I point this out and show that this fluid carries neither charge nor mass, but carries effective mass. This implies that the effective mass of carriers is lowered when a system goes from the normal to the superconducting state, which agrees with the prediction of the unconventional theory of hole superconductivity and with optical experiments in some superconducting materials. The 60-year old conventional understanding of the Meissner effect ignores Alfven’s theorem and for that reason I argue that it does not provide a valid understanding of real superconductors.
- Published
- 2019
33. Alfven-like waves along normal-superconductor phase boundaries
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J. E. Hirsch
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010302 applied physics ,Physics ,Superconductivity ,Phase boundary ,Condensed matter physics ,media_common.quotation_subject ,Condensed Matter - Superconductivity ,Energy Engineering and Power Technology ,FOS: Physical sciences ,Condensed Matter Physics ,Inertia ,01 natural sciences ,Electronic, Optical and Magnetic Materials ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Transverse plane ,Effective mass (solid-state physics) ,Condensed Matter::Superconductivity ,0103 physical sciences ,Charge carrier ,Electrical and Electronic Engineering ,010306 general physics ,Backflow ,media_common - Abstract
Alfven waves are transverse magneto-hydrodynamic waves resulting from motion of a conducting fluid in direction perpendicular to an applied magnetic field, that propagate along the magnetic field direction. I propose that Alfven-like waves can propagate along normal-superconductor phase boundaries in the presence of a magnetic field. This requires charge flow and backflow across the normal-superconductor phase boundary when the boundary moves, which is predicted by the theory of hole superconductivity but not by the conventional theory of superconductivity. The magnetic field and the domain wall energy provide elasticity, and the normal charge carriers’ effective mass provides inertia. It is essential that the normal state charge carriers are holes. I propose an experimental search for Alfven-like waves in superconductors.
- Published
- 2019
34. Understanding electron-doped cuprate superconductors as hole superconductors
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J. E. Hirsch and Frank Marsiglio
- Subjects
010302 applied physics ,Superconductivity ,Physics ,High-temperature superconductivity ,Condensed matter physics ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Energy Engineering and Power Technology ,Observable ,Electron doped ,Condensed Matter Physics ,01 natural sciences ,Electronic, Optical and Magnetic Materials ,law.invention ,Superconductivity (cond-mat.supr-con) ,law ,Pairing ,Condensed Matter::Superconductivity ,0103 physical sciences ,Cuprate ,Condensed Matter::Strongly Correlated Electrons ,Electrical and Electronic Engineering ,010306 general physics ,Quantum tunnelling - Abstract
Since their experimental discovery in 1989, the electron-doped cuprate superconductors have presented both a major challenge and a major opportunity. The major challenge has been to determine whether these materials are fundamentally different from or essentially similar to their hole-doped counterparts; a major opportunity because answering this question would strongly constrain the possible explanations for what is the essential physics that leads to high temperature superconductivity in the cuprates, which is still not agreed upon. Here we argue that experimental results over the past 30 years on electron-doped cuprate materials have provided conclusive answers to these fundamental questions, by establishing that both in hole- and electron-doped cuprates, superconductivity originates in pairing of hole carriers in the same band. We discuss a model to describe this physics that is different from the generally accepted ones, and calculate physical observables that agree with experiment, in particular tunneling characteristics. We argue that our model is simpler, more natural and more compelling than other models. Unlike other models, ours was originally proposed before rather than after many key experiments were performed.
- Published
- 2019
35. TEMPORARY REMOVAL: On the ac magnetic susceptibility of a room temperature superconductor: anatomy of a probable scientific fraud
- Author
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J. E. Hirsch
- Subjects
Superconductivity ,Materials science ,Room-temperature superconductor ,Condensed matter physics ,High pressure ,Energy Engineering and Power Technology ,Sulfur hydride ,Electrical and Electronic Engineering ,Condensed Matter Physics ,Magnetic susceptibility ,Electronic, Optical and Magnetic Materials - Abstract
In Nature 586, 373 (2020) [1], Snider et al announced the experimental discovery of room temperature superconductivity in a carbonaceous sulfur hydride under high pressure, hereafter called CSH. The paper reported sharp drops in the measured magnetic susceptibility as a function of temperature for five different pressures, that were claimed to be a superior test signaling a superconducting transition. Here I present several arguments indicating that the susceptibility data published in [1] were probably fraudulent. This calls into question the validity of the entire paper and its claim of detection of room temperature superconductivity. I also describe the roadblocks that I have encountered in reaching this conclusion. A variety of implications of this situation are discussed.
- Published
- 2021
- Full Text
- View/download PDF
36. Meissner effect in nonstandard superconductors
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Frank Marsiglio and J. E. Hirsch
- Subjects
010302 applied physics ,Physics ,Superconductivity ,Condensed matter physics ,Hydride ,Thermodynamic equilibrium ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Energy Engineering and Power Technology ,Condensed Matter Physics ,7. Clean energy ,01 natural sciences ,Resonant scattering ,Electronic, Optical and Magnetic Materials ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Standard type ,Meissner effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Electrical and Electronic Engineering ,010306 general physics ,Type-II superconductor - Abstract
It was recently pointed out that so-called "superhydrides", hydrogen-rich materials that appear to become superconducting at high temperatures and pressures, exhibit physical properties that are different from both conventional and unconventional standard type I and type II superconductors [1,2]. Here we consider magnetic field expulsion in the first material in this class discovered in 2015, sulfur hydride [3]. A nuclear resonant scattering experiment has been interpreted as demonstration that the Meissner effect takes place in this material [4,5]. Here we point out that the observed effect, under the assumption that the system is in thermodynamic equilibrium, implies a Meissner pressure [6] in this material that is {\it much larger} than that of standard superconductors. This suggests that hydride superconductors are qualitatively different from the known standard superconductors {\it if} they are superconductors., 6 pages, 2 figures
- Published
- 2021
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37. Absence of magnetic evidence for superconductivity in hydrides under high pressure
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Frank Marsiglio and J. E. Hirsch
- Subjects
010302 applied physics ,Physics ,Superconductivity ,Magnetic measurements ,Condensed matter physics ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Energy Engineering and Power Technology ,Condensed Matter Physics ,01 natural sciences ,Magnetic susceptibility ,Electronic, Optical and Magnetic Materials ,Superconductivity (cond-mat.supr-con) ,Paramagnetism ,Magnetization ,Temperature and pressure ,Meissner effect ,High pressure ,0103 physical sciences ,Electrical and Electronic Engineering ,010306 general physics - Abstract
It is generally believed that magnetization measurements on sulfur hydride under high pressure performed in 2015 [1] provided “final convincing evidence of superconductivity” [2] in that material, in agreement with theoretical predictions [3] , [4] . Supported by this precedent, drops in resistance that were later observed in several other hydrides under high pressure [ [2] , 5] have been generally accepted as evidence of superconductivity without corroborating evidence from magnetic measurements. In this paper we challenge the original interpretation that the magnetic measurements on sulfur hydride performed in 2015 were evidence of superconductivity. We point out that a large p a r a m a g n e t i c contribution to the magnetic susceptibility was detected below T c and argue that its temperature dependence rules out the possibility that it would be a background signal; instead the temperature dependence indicates that the paramagnetic behavior originated in the sample. We discuss possible explanations for this remarkable behavior and conclude that standard superconductors would not show such behavior. We also survey all the other published data from magnetic measurements on this class of materials and conclude that they do not provide strong evidence for superconductivity. Consequently, we call into question the generally accepted view that conventional superconductivity in hydrogen-rich materials at high temperature and pressure is a reality, and discuss the implications if it is not.
- Published
- 2021
- Full Text
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38. About the pressure-induced superconducting state of europium metal at low temperatures
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J. E. Hirsch
- Subjects
010302 applied physics ,Superconductivity ,Materials science ,Condensed matter physics ,Hydride ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Energy Engineering and Power Technology ,chemistry.chemical_element ,State (functional analysis) ,Atmospheric temperature range ,Condensed Matter Physics ,01 natural sciences ,Electronic, Optical and Magnetic Materials ,Superconductivity (cond-mat.supr-con) ,Metal ,chemistry ,visual_art ,0103 physical sciences ,visual_art.visual_art_medium ,Electrical and Electronic Engineering ,010306 general physics ,Europium - Abstract
In Phys. Rev. Lett. 102, 197002 (2009) it was reported that the element Eu becomes superconducting in the pressure and temperature range [84-142GPa], [1.8-2.75K]. The claim was largely based on ac susceptibility measurements. Recently reported ac susceptibility measurements on a hydride compound under pressure that appears to become superconducting near room temperature (Nature 586, 373 (2020)) cast serious doubt on the validity of the results for Eu as well as for the hydride. Here I present results that shed new light on the true behaviour of Eu. It is argued that the experiments on Eu have to be repeated to either validate or rule out the claim that it is a superconducting element., Comment: arXiv admin note: This submission has been withdrawn by arXiv administrators due to inflammatory content and unprofessional language
- Published
- 2021
- Full Text
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39. On the reversibility of the Meissner effect and the angular momentum puzzle
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J. E. Hirsch
- Subjects
Physics ,Superconductivity ,Angular momentum ,Condensed matter physics ,Thermodynamic equilibrium ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,General Physics and Astronomy ,01 natural sciences ,Magnetic flux ,010305 fluids & plasmas ,law.invention ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,law ,Meissner effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Eddy current ,010306 general physics ,Joule heating - Abstract
It is generally believed that the laws of thermodynamics govern superconductivity as an equilibrium state of matter, and hence that the normal-superconductor transition in a magnetic field is reversible under ideal conditions. Because eddy currents are generated during the transition as the magnetic flux changes, the transition has to proceed infinitely slowly to generate no entropy. Experiments showed that to a high degree of accuracy no entropy was generated in these transitions. However, in this paper we point out that for the length of times over which these experiments extended, a much higher degree of irreversibility due to decay of eddy currents should have been detected than was actually observed. We also point out that within the conventional theory of superconductivity no explanation exists for why no Joule heat is generated in the superconductor to normal transition when the supercurrent stops. In addition we point out that within the conventional theory of superconductivity no mechanism exists for the transfer of momentum between the supercurrent and the body as a whole, which is necessary to ensure that the transition in the presence of a magnetic field respects momentum conservation. We propose a solution to all these questions based on the alternative theory of hole superconductivity. The theory proposes that in the normal-superconductor transition there is a flow and backflow of charge in direction perpendicular to the phase boundary when the phase boundary moves. We show that this flow and backflow explains the absence of Joule heat generated by Faraday eddy currents, the absence of Joule heat generated in the process of the supercurrent stopping, and the reversible transfer of momentum between the supercurrent and the body, provided the current carriers in the normal state are holes.
- Published
- 2016
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40. Proposed experimental test of the theory of hole superconductivity
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J. E. Hirsch
- Subjects
Physics ,Superconductivity ,Phase boundary ,Condensed matter physics ,Momentum transfer ,Energy Engineering and Power Technology ,Charge (physics) ,Condensed Matter Physics ,01 natural sciences ,010305 fluids & plasmas ,Electronic, Optical and Magnetic Materials ,Magnetic field ,Flow (mathematics) ,Hall effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Perpendicular ,Electrical and Electronic Engineering ,010306 general physics - Abstract
The theory of hole superconductivity predicts that in the reversible transition between normal and superconducting phases in the presence of a magnetic field there is charge flow in direction perpendicular to the normal-superconductor phase boundary. In contrast, the conventional BCS-London theory of superconductivity predicts no such charge flow. Here we discuss an experiment to test these predictions.
- Published
- 2016
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- View/download PDF
41. Joule heating in the normal-superconductor phase transition in a magnetic field
- Author
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J. E. Hirsch
- Subjects
Phase transition ,Materials science ,FOS: Physical sciences ,Energy Engineering and Power Technology ,01 natural sciences ,law.invention ,Superconductivity (cond-mat.supr-con) ,Physics::Fluid Dynamics ,law ,Condensed Matter::Superconductivity ,0103 physical sciences ,Eddy current ,Electrical and Electronic Engineering ,010306 general physics ,Critical field ,010302 applied physics ,Superconductivity ,Condensed matter physics ,Condensed Matter - Superconductivity ,Condensed Matter Physics ,Magnetic flux ,Electronic, Optical and Magnetic Materials ,Magnetic field ,Electric current ,Joule heating ,human activities - Abstract
Joule heating is a non-equilibrium dissipative process that occurs in a normal metal when an electric current flows, in an amount proportional to the metal’s resistance. When it is induced by eddy currents resulting from a change in magnetic flux, it is also proportional to the rate at which the magnetic flux changes. Here we show that in the phase transformation between normal and superconducting states of a metal in a magnetic field, the total amount of Joule heating is determined by the thermodynamic properties of the system and is independent of the resistivity of the normal metal. Under the reasonable assumption that the magnetic field at the phase boundary is given by the thermodynamic critical field, we show that Joule heating occurs only in the normal region of the material, hence no Joule heating occurs in the superconducting region next to the phase boundary where normal current is expected to flow according to the conventional theory of superconductivity. We discuss the significance of this result.
- Published
- 2020
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42. Reply to the Comment by Denis M. Basko and Robert S. Whitney
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J. E. Hirsch
- Subjects
General Physics and Astronomy - Published
- 2020
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43. Highlights from the previous volumes
- Author
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Ad Lagendijk, Pierre Le Doussal, Shu Guo, and J. E. Hirsch
- Subjects
Quantitative Biology::Neurons and Cognition ,General Physics and Astronomy - Abstract
Mutual extinction of light Active particle in a one-dimensional force field Simulating sleep apnea dynamics through random walk model Inconsistency of the conventional theory of superconductivity
- Published
- 2020
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44. Reply to the Comment by Jacob Szeftel et al
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J. E. Hirsch
- Subjects
Physics ,General Physics and Astronomy - Published
- 2020
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- View/download PDF
45. Thermodynamic inconsistency of the conventional theory of superconductivity
- Author
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J. E. Hirsch
- Subjects
Superconductivity ,Materials science ,Condensed matter physics ,Condensed Matter - Superconductivity ,London penetration depth ,FOS: Physical sciences ,Statistical and Nonlinear Physics ,Function (mathematics) ,Condensed Matter Physics ,01 natural sciences ,010305 fluids & plasmas ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Meissner effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Surface layer ,010306 general physics ,Joule heating - Abstract
A type I superconductor expels a magnetic field from its interior to a surface layer of thickness $\lambda_L$, the London penetration depth. $\lambda_L$ is a function of temperature, becoming smaller as the temperature decreases. Here we analyze the process of cooling (or heating) a type I superconductor in a magnetic field, with the system remaining always in the superconducting state. The conventional theory predicts that Joule heat is generated in this process, the amount of which depends on the rate at which the temperature changes. Assuming the final state of the superconductor is independent of history, as the conventional theory assumes, we show that this process violates the first and second laws of thermodynamics. We conclude that the conventional theory of superconductivity is internally inconsistent. Instead, we suggest that the alternative theory of hole superconductivity may be able to resolve this problem., Comment: Removed referees' comments to comply with arXiv policies
- Published
- 2019
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46. Inconsistency of the conventional theory of superconductivity
- Author
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J. E. Hirsch
- Subjects
Physics ,Superconductivity ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,General Physics and Astronomy ,01 natural sciences ,Laws of thermodynamics ,010305 fluids & plasmas ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Condensed Matter::Superconductivity ,0103 physical sciences ,Statistical physics ,010306 general physics ,Joule heating - Abstract
In a process where the temperature of a type I superconductor in a magnetic field changes, the conventional theory of superconductivity predicts that Joule heat is generated and that the final state is independent of the speed of the process. I show that these two predictions cannot be simultaneously reconciled with the laws of thermodynamics. I propose a resolution of this paradox., Comment: Final version. To be published in Europhysics Letters
- Published
- 2020
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47. Hole superconductivity in H2S and other sulfides under high pressure
- Author
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J. E. Hirsch and Frank Marsiglio
- Subjects
Superconductivity ,Physics ,High-temperature superconductivity ,Room-temperature superconductor ,Condensed matter physics ,Energy Engineering and Power Technology ,Condensed Matter Physics ,Kinetic energy ,Thermal conduction ,Electronic, Optical and Magnetic Materials ,law.invention ,Electron transfer ,Atomic orbital ,law ,Condensed Matter::Superconductivity ,Pairing ,Electrical and Electronic Engineering - Abstract
Superconductivity at temperatures up to 190 K at high pressures has recently been observed in H 2 S and interpreted as conventional BCS-electron–phonon-driven superconductivity (Drozdov et al., 2014). Instead we propose that it is another example of the mechanism of hole superconductivity at work. Within this mechanism high temperature superconductivity arises when holes conduct through negatively charged anions in close proximity. We propose that electron transfer from H to S leads to conduction by holes in a nearly full band arising from direct overlap of S = p orbitals in a planar structure. The superconductivity is non-phononic and is driven by pairing of heavily dressed hole carriers to lower their kinetic energy. Possible explanations for the observed lower critical temperature of D 2 S are discussed. We predict that high temperature superconductivity will also be found in other sulfides under high pressure such as Li 2 S, Na 2 S and K 2 S .
- Published
- 2015
- Full Text
- View/download PDF
48. Enhancement of Superconducting $T_c$ due to the Spin-orbit Interaction
- Author
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J. E. Hirsch, Joel Hutchinson, and Frank Marsiglio
- Subjects
Superconductivity ,Physics ,Condensed matter physics ,media_common.quotation_subject ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Fermi surface ,02 engineering and technology ,Electron ,Spin–orbit interaction ,021001 nanoscience & nanotechnology ,01 natural sciences ,Asymmetry ,Superconductivity (cond-mat.supr-con) ,Atomic orbital ,Condensed Matter::Superconductivity ,0103 physical sciences ,Density of states ,Wave vector ,010306 general physics ,0210 nano-technology ,media_common - Abstract
We calculate the superconducting $T_c$ for a system which experiences Rashba spin-orbit interactions. Contrary to the usual case where the electron-electron interaction is assumed to be wave vector-independent, where superconductivity is suppressed by the spin-orbit interaction (except for a small region at low electron or hole densities), we find an enhancement of the superconducting transition temperature when we include a correlated hopping interaction between electrons. This interaction originates in the expansion of atomic orbitals due to electron-electron repulsion and gives rise to superconductivity only at high electron (low hole) densities. When superconductivity results from this interaction it is enhanced by spin-orbit coupling, in spite of a suppression of the density of states. The degree of electron-hole asymmetry about the Fermi surface is also enhanced., 8 pages, 8 figures
- Published
- 2018
49. Spinning superconductors and ferromagnets
- Author
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J. E. Hirsch
- Subjects
Superconductivity ,Physics ,Magnetic moment ,Condensed matter physics ,Condensed Matter - Superconductivity ,General Physics and Astronomy ,FOS: Physical sciences ,Electron ,01 natural sciences ,010305 fluids & plasmas ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Magnetization ,Ferromagnetism ,Meissner effect ,Condensed Matter::Superconductivity ,0103 physical sciences ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,Spin (physics) - Abstract
When a magnetic field is applied to a ferromagnetic body it starts to spin (Einstein-de Haas effect). This demonstrates the intimate connection between the electron's magnetic moment $\mu_B=e\hbar/2m_ec$, associated with its spin angular momentum $S=\hbar/2$, and ferromagnetism. When a magnetic field is applied to a superconducting body it also starts to spin (gyromagnetic effect), and when a normal metal in a magnetic field becomes superconducting and expels the magnetic field (Meissner effect) the body also starts to spin. Yet according to the conventional theory of superconductivity the electron's spin only role is to label states, and the electron's magnetic moment plays no role in superconductivity. Instead, within the unconventional theory of hole superconductivity, the electron's spin and associated magnetic moment play a fundamental role in superconductivity. Just like in ferromagnets the magnetization of superconductors is predicted to result from an aggregation of magnetic moments with angular momenta $\hbar/2$. This gives rise to a "Spin Meissner effect", the existence of a spin current in the ground state of superconductors. The theory explains how a superconducting body starts spinning when it expels magnetic fields, it provides a dynamical explanation for the Meissner effect, and it explains how supercurrents stop without dissipation, all of which we argue the conventional theory fails to explain. Essential elements of the theory of hole superconductivity are that superconductivity is driven by lowering of kinetic energy, which we have also proposed is true for ferromagnets], that the normal state charge carriers in superconducting materials are holes, and that the spin-orbit interaction plays a key role in superconductivity. The theory is proposed to apply to all superconductors., Comment: this paper was written before the latest progress reported in arXiv:1808.02857
- Published
- 2018
- Full Text
- View/download PDF
50. Defying inertia: how rotating superconductors generate magnetic fields
- Author
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J. E. Hirsch
- Subjects
Superconductivity ,Physics ,Angular momentum ,Condensed matter physics ,media_common.quotation_subject ,Condensed Matter - Superconductivity ,General Physics and Astronomy ,FOS: Physical sciences ,02 engineering and technology ,Electron ,London moment ,Moment of inertia ,021001 nanoscience & nanotechnology ,Inertia ,01 natural sciences ,Magnetic field ,Superconductivity (cond-mat.supr-con) ,Condensed Matter::Superconductivity ,0103 physical sciences ,Simply connected space ,010306 general physics ,0210 nano-technology ,media_common - Abstract
I discuss the process of magnetic field generation in rotating superconductors in simply connected and multiply connected geometries. In cooling a normal metal into the superconducting state while it is rotating, electrons slow down or speed up depending on the geometry and their location in the sample, apparently defying inertia. I argue that the conventional theory of superconductivity does not explain these processes. Instead, the theory of hole superconductivity does. Its predictions agree with experimental observations of Hendricks, King and Rohrschach for solid and hollow cylinders., Comment: A section was added (IX)
- Published
- 2018
- Full Text
- View/download PDF
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