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1. Sesterterpenes. 1. Stereospecific construction of the ceroplastol and ophiobolin ring systems via a common bicyclic intermediate

Author

Jon Clardy, Barbara A. Solheim, James P. Bershas, and Robert K. Boeckman

Subjects
chemistry.chemical_compound, Stereospecificity, Bicyclic molecule, Chemistry, Stereochemistry, Organic Chemistry, Chemical preparation, Nonane, Ring (chemistry), Sesterterpenes
Abstract

The ring systems present in the two major classes of ophiobolane sesterterpenes have been obtained via a common bicyclic intermediate. In each case, the eight-membered ring was constructed by fragmentation of an appropriately functionalized bicyclo(3.3.1)nonane ring system.

Published
1977
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