256 results on '"Jean-Luc Adam"'
Search Results
2. Photonic Bandgap Propagation in All-Solid Chalcogenide Microstructured Optical Fibers
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Celine Caillaud, Gilles Renversez, Laurent Brilland, David Mechin, Laurent Calvez, Jean-Luc Adam, and Johann Troles
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chalcogenide glasses ,infrared fibers ,microstructured optical fibers (MOFs) ,photonic bandgap fibers ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
An original way to obtain fibers with special chromatic dispersion and single-mode behavior is to consider microstructured optical fibers (MOFs). These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. In this study, the first all-solid all-chalcogenide MOFs exhibiting photonic bandgap transmission have been achieved and optically characterized. The fibers are made of an As38Se62 matrix, with inclusions of Te20As30Se50 glass that shows a higher refractive index (n = 2.9). In those fibers, several transmission bands have been observed in mid infrared depending on the geometry. In addition, for the first time, propagation by photonic bandgap effect in an all-chalcogenide MOF has been observed at 3.39 µm, 9.3 µm, and 10.6 µm. The numerical simulations based on the optogeometric properties of the fibers agree well with the experimental characterizations.
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- 2014
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3. Chalcogenide Microstructured Optical Fibers for Mid-Infrared Supercontinuum Generation: Interest, Fabrication, and Applications
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Yiming Wu, Marcello Meneghetti, Johann Troles, and Jean-Luc Adam
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chalcogenide glasses ,chalcogenide fibers ,mid-infrared ,supercontinuum generation ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The mid-infrared spectral region is of great technical and scientific importance in a variety of research fields and applications. Among these studies, mid-infrared supercontinuum generation has attracted strong interest in the last decade, because of unique properties such as broad wavelength coverage and high coherence, among others. In this paper, the intrinsic optical properties of different types of glasses and fibers are presented. It turns out that microstructured chalcogenide fibers are ideal choices for the generation of mid-infrared supercontinua. The fabrication procedures of chalcogenide microstructured fibers are introduced, including purification methods of the glass, rod synthesis processes, and preform realization techniques. In addition, supercontinua generated in chalcogenide microstructured fibers employing diverse pump sources and configurations are enumerated. Finally, the potential of supercontinua for applications in mid-infrared imaging and spectroscopy is shown.
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- 2018
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4. Object Detection with Probabilistic Guarantees: A Conformal Prediction Approach.
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Florence de Grancey, Jean-Luc Adam, Lucian Alecu, Sébastien Gerchinovitz, Franck Mamalet, and David Vigouroux
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- 2022
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5. Challenges and future trends in fiber lasers.
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Stefano Taccheo, Kay Schuster, Maurizio Ferrari, Angela B. Seddon, Marian Marciniak, Christopher Taudt, Johann Troles, Gianluca Valentini, Dominik Dorosz, Francesco Prudenzano, Monika Jaeger, Cristiano D'Andrea, Mile Ivanda, Alessandro Chiasera, Slawomir Sujecki, Virginie Nazabal, Daniela Comelli, Hovik V. Baghdasaryan, Tobias Baselt, Peter Hartmann, Antonio Lucianetti, Pavel Peterka, Annett Klotzbach, Jean-Luc Adam, and Hrvoje Gebavi
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- 2016
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- View/download PDF
6. Original designs of chalcogenide microstructured optical fibers for mid-IR applications.
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Johann Troles, Celine Caillaud, Clement Gilles, Laurent Provino, Mathieu Carras, Mickael Brun, Jean-Luc Adam, and Laurent Brilland
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- 2016
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- View/download PDF
7. Chalcogenide glasses for infrared optics: A new method of elaboration.
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Laurent Calvez, Elena Petracovschi, Anna Novikova, and Jean-Luc Adam
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- 2016
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8. Novel pumping schemes of Mid-IR photonic crystal fiber lasers for aerospace applications.
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Mario Christian Falconi, Giuseppe Palma, F. Starecki, Virginie Nazabal, Johann Troles, Jean-Luc Adam, Stefano Taccheo, Maurizio Ferrari, and Francesco Prudenzano
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- 2016
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9. Optimization of Mid-IR microstructured fiber laser based on dysprosium doped chalcogenide glass.
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Mario Christian Falconi, William Scarcia, Giuseppe Palma, R. Chahal, F. Starecki, Virginie Nazabal, Johann Troles, Jean-Luc Adam, and Francesco Prudenzano
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- 2015
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10. Band Alignment and Optical Properties of 1D/2D Sb2Se3/PtSe2 Heterojunctions
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Kapil Bhorkar, Labrini Sygellou, Michel Cathelinaud, Donglou Ren, Jean-Luc Adam, Spyros N. Yannopoulos, Foundation for Research and Technology - Hellas (FORTH), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and European Union [721642]
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Sb2Se3 ,thermally assisted conversion (TAC) ,type-II heterostructure ,band alignment ,Materials Chemistry ,Electrochemistry ,PtSe2 ,[CHIM]Chemical Sciences ,self-powered photodetector ,Electronic, Optical and Magnetic Materials - Abstract
International audience; The heterojunction between two materials brought into contact, for example, in the form of vertical van der Waals heterostructures, exhibits interesting features offering functionalities to devices stimulated by light. We report in this article an investigation of the optical and electronic properties of the heterojunction formed between Sb2Se3, a material with a promising role in photovoltaics characterized by one-dimensional (1D) topology (ribbons), and an emerging two-dimensional (2D) material, PtSe2, exhibiting unique optical properties for photoelectronics and photonics. The controlled growth of PtSe2 on Sb2Se3 underlayer takes place using a transfer-free process by low-temperature selenization of 1-2 nm Pt films thermally evaporated on Sb2Se3 ultrathin substrates. X-ray photoelectron spectroscopy (XPS) data analyzed in the context of the Kraut method provided an estimate for the band offsets at the interface. The valence band offset and the conduction band offset of the PtSe2/Sb2Se3 heterojunction were found to be -0.25 and 1.0 eV, respectively, indicating a type-II heterojunction. The ultrabroad optical absorption of the heterojunction and the protection offered by PtSe2 to Sb2Se3, against oxidation of the latter, render this particular heterojunction a robust candidate for applications in photovoltaics. Finally, the current study of a heterojunction between materials of different dimensionalities may pave the way for a rational design in the field of trans-dimensional heterostructures.
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- 2022
11. Contributors
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Jean Luc Adam, Oseas Alvarez, Martin Ams, Yigit Ozan Aydin, Ole Bang, E. Barney, T.M. Benson, Martin Bernier, Gayathri Bharathan, Tommy Boilard, Lynda E. Busse, J. Butterworth, François Chenard, Solenn Cozic, R.W. Crane, Heike Ebendorff-Heidepriem, M. Farries, Vincent Fortin, Alex Fuerbach, D. Furniss, Rafael R. Gattass, Martin Gorjan, Ori Henderson-Sapir, Darren Hudson, Stuart Jackson, D. Jayasuriya, Frédéric Jobin, Myungkoo Kang, Zhe Kang, Jianfeng Li, Hongyu Luo, D.P. Mabwa, Frédéric Maes, Matthew R. Majewski, J.J. Nunes, David J. Ottaway, H. Parnell, Christian Rosenberg Petersen, S. Phang, Louis-Philippe Pleau, Marcel Poulain, Guanshi Qin, Mathew R. Majewski, Kathleen A. Richardson, Martin Rochette, H. Sakr, Jasbinder S. Sanghera, A.B. Seddon, L. Brandon Shaw, M. Shen, L. Sojka, S. Sujecki, Lauris Talbot, Z.Q. Tang, Shigeki Tokita, Réal Vallée, Pengfei Wang, and Robert I. Woodward
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- 2022
12. Fluoride glass and optical fiber fabrication
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Marcel Poulain, Solenn Cozic, and Jean Luc Adam
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- 2022
13. Chalcogenide fibers for infrared photonics: Recent developments.
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Jean-Luc Adam, Johann Troles, Virginie Nazabal, Laurent Brilland, Catherine Boussard, and Bruno Bureau
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- 2015
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14. Purification of Ge-As-Se ternary glasses for the development of high quality microstructured optical fibers
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Celine Caillaud, Johann Troles, Radwan Chahal, Marcello Meneghetti, Jean-Luc Adam, Laurent Brilland, Elodie Galdo, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), SelenOptics [Bruz] (SelenOptics), This project has received funding from the European Union's Horizon 2020 research and innovation program under Grant Agreement No. 722380., Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
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Microstructured optical fibers ,Optical fiber ,Materials science ,Chalcogenide glasses ,Chalcogenide ,02 engineering and technology ,01 natural sciences ,law.invention ,chemistry.chemical_compound ,law ,Impurity ,0103 physical sciences ,Materials Chemistry ,Absorption (electromagnetic radiation) ,010302 applied physics ,business.industry ,Attenuation ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Laser ,Casting ,Electronic, Optical and Magnetic Materials ,chemistry ,Ceramics and Composites ,Optoelectronics ,Chemical synthesis methods ,0210 nano-technology ,business ,Ternary operation - Abstract
International audience; The production of chalcogenide microstructured optical fibers with low optical losses, due to the broad transparency window of these glasses in the mid-IR, can allow for new breakthroughs in various research fields, e.g. new mid-IR laser sources and mid-IR spectroscopy. In this framework, high purity chalcogenide glasses are needed in order to minimize absorption losses. In this study, Ge10As22Se68 samples were prepared using a double distillation method, using different combinations of chlorides and metals as getters for the physico-chemical elimination of carbon, oxygen and hydrogen impurities. Comparing the attenuation spectra of the different samples, the choice of the getters seems to be indeed a significant factor in the quality of the glass. A holey fiber has been realized by casting method using the best sample, showing that the method is suitable for this composition and that the attenuation before and after the casting are comparable.
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- 2019
15. Elaboration of chalcogenide microstructured optical fibers preform by 3D additive manufacturing
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Ronan Lebullenger, François Cheviré, Johann Troles, Laurent Brilland, Elodie Galdo, David Le Coq, Radwan Chahal, Antoine Gautier, Gilles Renversez, Julie Carcreff, Jean-Luc Adam, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SelenOptics [Bruz] (SelenOptics), Institut FRESNEL (FRESNEL), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), ATHENA (ATHENA), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), DGA FOM-IR-2-20, Ministère de l’Éducation Nationale, de l'Enseignement Supérieur et de la Recherche, MESR, European Commission, EC, European Regional Development Fund, ERDF, Shibin Jiang, Michel J. F. Digonnet, ANR-17-ASTR-0011,FOM-IR-2-20,Fabrication de Fibres Optiques Microstructurées pour l'InfraRouge de 2 à 20 µm(2017), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU), Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU), Agence Nationale de la Recherche, ANR: ANR ASTRID DGA FOM-IR-2-20, Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche, MESR, and Jiang S.Digonnet M.J.F.
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Hollow core ,Materials science ,Fabrication ,Optical fiber ,business.industry ,Chalcogenide ,3D printing ,Chalcogenide glass ,chalcogenide glasses ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,Thermal ,Optoelectronics ,[CHIM]Chemical Sciences ,Fiber ,microstructured optical fibers ,business - Abstract
International audience; For several years, chalcogenide glasses have been studied as good candidates for numerous applications in the midinfrared region. Indeed, these glasses are transparent from 1 to 20 μm (depending on the composition), a mid- IR windows well-suited for sensing molecules whose optical signatures are located in the 2-16 μm range. In addition, thanks to appropriate thermal properties, chalcogenide glasses can be drawn into fibers, including microstructured optical fibers. In this work, a new method based on 3D-printing process is investigated to produce hollow chalcogenide glass preforms, which are then drawn into hollow-core fibers. The transmission of the "printed"hollow-core fiber has been measured and compared to the initial glass. A significant, but still manageable, increase by a factor of 2.5 is observed. This works opens a promising way for the fabrication of chalcogenide MOFs, more particularly for the elaboration of hollow core fibers. © 2021 SPIE.
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- 2021
16. Comparative study of Er3+-doped Ga-Ge-Sb-S thin films fabricated by sputtering and pulsed laser deposition
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Virginie Nazabal, Florent Starecki, Simone Normani, Marek Bouška, Jean-Luc Adam, Petr Němec, Younes Messaddeq, Jean-Louis Doualan, Yannick Ledemi, Geoffrey Louvet, Jan Gutwirth, Emeline Baudet, Department of Graphic Arts and Photophysics [University of Pardubice], Faculty of Chemical Technology [University of Pardubice], University of Pardubice-University of Pardubice, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes-Centre National de la Recherche Scientifique (CNRS), University of Pardubice, Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Université Laval [Québec] (ULaval), Centre d'Optique, Photonique et Laser (COPL), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), and Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)
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Photoluminescence ,Materials science ,Chalcogenide ,lcsh:Medicine ,02 engineering and technology ,01 natural sciences ,Pulsed laser deposition ,010309 optics ,chemistry.chemical_compound ,Sputtering ,0103 physical sciences ,[CHIM]Chemical Sciences ,Thin film ,lcsh:Science ,ComputingMilieux_MISCELLANEOUS ,Multidisciplinary ,business.industry ,lcsh:R ,Doping ,Sputter deposition ,021001 nanoscience & nanotechnology ,Amorphous solid ,chemistry ,Optoelectronics ,lcsh:Q ,0210 nano-technology ,business - Abstract
Despite the renewed interest in rare earth-doped chalcogenide glasses lying mainly in mid-infrared applications, a few comprehensive studies so far have presented the photoluminescence of amorphous chalcogenide films from visible to mid-infrared. This work reports the fabrication of luminescent quaternary sulfide thin films using radio-frequency sputtering and pulsed laser deposition, and the characterization of their chemical composition, morphology, structure, refractive index and Er3+ photoluminescence. The study of Er3+ 4I13/2 level lifetimes enables developing suitable deposition parameters; the dependency of composition, structural and spectroscopic properties on deposition parameters provides a way to tailor the RE-doped thin film properties. The surface roughness is very low for both deposition methods, ensuring reasonable propagation optical losses. The effects of annealing on the sulfide films spectroscopy and lifetimes were assessed. PLD appears consistent composition-wise, and largely independent of the deposition conditions, but radiofrequency magnetron sputtering seems to be more versatile, as one may tailor the film properties through deposition parameters manipulation. The luminescence via rare earth-doped chalcogenide waveguiding micro-structures might find easy-to-use applications concerning telecommunications or on-chip optical sensors for which luminescent sources or amplifiers operating at different wavelengths are required.
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- 2020
17. Mid-infrared detection of organic compounds with a 2-10 µm supercontinuum source generated from concatenated fluoride and chalcogenide fibers (Conference Presentation)
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Samuel Poulain, Thibaut Sylvestre, Marcello Meneghetti, Guillaume Huss, Franck Joulain, Catherine Boussard-Plédel, Bruno Bureau, Radwan Chahal, Laurine Bodin, Marcel Poulain, Solenn Cozic, Jean-Luc Adam, Laurent Brilland, Johann Troles, and Sébastien Venck
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Brightness ,Materials science ,Infrared ,Chalcogenide ,business.industry ,Mid infrared ,Physics::Optics ,Astrophysics::Cosmology and Extragalactic Astrophysics ,Supercontinuum ,chemistry.chemical_compound ,chemistry ,Optoelectronics ,Fiber ,business ,Spectroscopy ,Fluoride ,Astrophysics::Galaxy Astrophysics - Abstract
The mid-infrared spectral region is a great technical and scientific interest in numerous research field and applications. Among these studies, the generation of mid-infrared supercontinuum in fibers has attracted strong interest in the last decade, because of unique properties such as broad wavelength-coverage and brightness. In this work, a cascaded supercontinuum generated in a fluoride and a chalcogenide fiber spanning from 2 to 10 µm has been used for the detection of infrared signatures of organic compounds. Those results open a new way for remote sensing and spectroscopy in the mid-IR.
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- 2020
18. Comparative study of Er
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Simone, Normani, Geoffrey, Louvet, Emeline, Baudet, Marek, Bouška, Jan, Gutwirth, Florent, Starecki, Jean-Louis, Doualan, Yannick, Ledemi, Younes, Messaddeq, Jean-Luc, Adam, Petr, Němec, and Virginie, Nazabal
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Glasses ,Optical materials ,Lasers, LEDs and light sources ,Article ,Materials science ,Materials for optics - Abstract
Despite the renewed interest in rare earth-doped chalcogenide glasses lying mainly in mid-infrared applications, a few comprehensive studies so far have presented the photoluminescence of amorphous chalcogenide films from visible to mid-infrared. This work reports the fabrication of luminescent quaternary sulfide thin films using radio-frequency sputtering and pulsed laser deposition, and the characterization of their chemical composition, morphology, structure, refractive index and Er3+ photoluminescence. The study of Er3+ 4I13/2 level lifetimes enables developing suitable deposition parameters; the dependency of composition, structural and spectroscopic properties on deposition parameters provides a way to tailor the RE-doped thin film properties. The surface roughness is very low for both deposition methods, ensuring reasonable propagation optical losses. The effects of annealing on the sulfide films spectroscopy and lifetimes were assessed. PLD appears consistent composition-wise, and largely independent of the deposition conditions, but radiofrequency magnetron sputtering seems to be more versatile, as one may tailor the film properties through deposition parameters manipulation. The luminescence via rare earth-doped chalcogenide waveguiding micro-structures might find easy-to-use applications concerning telecommunications or on-chip optical sensors for which luminescent sources or amplifiers operating at different wavelengths are required.
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- 2020
19. Cascaded Mid-IR Supercontinuum generation in chalcogenide microstructured optical fibers from 2 to 10 μm
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Marcello Meneghetti, Marcel Poulain, Franck Joulain, Laurine Bodin, Sébastien Venck, Radwan Chahal, Johann Troles, Solenn Cozic, Jean-Luc Adam, Laurent Brilland, and Samuel Poulain
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Materials science ,Multi-mode optical fiber ,Optical fiber ,Chalcogenide ,Infrared ,business.industry ,Single-mode optical fiber ,law.invention ,Supercontinuum ,Chalcogen ,chemistry.chemical_compound ,chemistry ,law ,Optoelectronics ,Fiber ,business - Abstract
Compared to oxide based glasses, vitreous materials composed of chalcogen elements (S, Se, Te) show large transparency windows in the infrared. Indeed, chalcogenide fibers can be transparent from the visible up to 12-15 μm, depending on their compositions. The IR signatures of most molecules, including biomolecules, are located in this spectral domain, which allows in situ, non-invasive and real-time detection of gaz or organics molecules. Indeed, chalcogenide glasses can present a high non-linear coefficient (n2), 100 to 1000 times larger than for silica glass, depending on the composition. An original way to obtain fibers is to design microstructured optical fibers (MOFs). These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. Various chalcogenide MOFs operating in the mid-IR range have been elaborated in order to associate the high nonlinear properties of these glasses and the original MOF properties. Different glass compositions and different designs have been achieved depending on the intended application. Indeed, chalcogenide MOFs might lead to new devices with unique optical properties in the Mid-IR domain like multimode or endlessly single mode transmission of light, small or large mode area fibers, non-linear properties for wavelength conversion or generation of supercontinuum sources. In this work, a supercontinuum from 2 to 10 μm, with an average power of 15mW, has been obtained in a chalcogenide MOF by pumping with a supercontinuum generated in a fluoride fiber.
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- 2019
20. Original designs of chalcogenide microstuctured optical fibers
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Jean-Luc Adam, Laurent Brilland, Celine Caillaud, and Johann Troles
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lcsh:Applied optics. Photonics ,Optical fiber ,Materials science ,Infrared ,Chalcogenide ,Mid infrared ,Word ,Physics::Optics ,Infrared spectroscopy ,Astrophysics::Cosmology and Extragalactic Astrophysics ,02 engineering and technology ,01 natural sciences ,law.invention ,010309 optics ,chemistry.chemical_compound ,Optics ,law ,0103 physical sciences ,lcsh:TA401-492 ,Astrophysics::Galaxy Astrophysics ,business.industry ,lcsh:TA1501-1820 ,mid-infrared ,chalcogenide fibers ,Microstructured optical fiber ,chalcogenide glasses ,021001 nanoscience & nanotechnology ,Psychiatry and Mental health ,chemistry ,Infrared transmission ,lcsh:Materials of engineering and construction. Mechanics of materials ,microstructured optical fibers ,Astrophysics::Earth and Planetary Astrophysics ,0210 nano-technology ,business ,Photonic-crystal fiber - Abstract
The combination of the unique optical properties of chalcogenide glasses, in terms of infrared transmission and optical non-linearity, with the original guiding properties of microstructured optical fibers leads to a new category of fibers with promising applications in mid-infrared optics. The recent developments on chalcogenide microstructured optical fibers are exposed and discussed with regards to mid-IR guiding, infrared light transport and delivery, generation of new infrared sources, and infrared spectroscopy.
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- 2017
21. A Simple Approach for the Estimation of the Exhaust Noise Source at the Valves
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Jean-Luc Adam, Maxime Dubarry, Pablo Olmeda, Antonio Torregrosa, and Florent Morin
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Noise ,Simple (abstract algebra) ,Computer science ,Acoustics - Published
- 2019
22. MWIR and LWIR Emissions of Rare Earth Doped Chalcogenide Glasses and Waveguides Devoted to Optical Sensors
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Geoffrey Louvet, Nora Abdellaoui, Julien Ari, Emeline Baudet, Florent Starecki, Catherine Boussard-Plédel, Joel CHARRIER, Loïc Bodiou, Alain Braud, Jean-Louis Doualan, Patrice Camy, Petr Němec, Karine Michel, Lionel Quétel, Bruno Bureau, Jean-Luc Adam, Virginie Nazabal, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), University of Pardubice, Institut des Fonctions Optiques pour les Technologies de l'informatiON (Institut FOTON), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), IDIL Fibres Optiques, PME, Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
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[PHYS]Physics [physics] ,ComputingMilieux_MISCELLANEOUS - Abstract
International audience
- Published
- 2019
23. Fabrication of low loss chalcogenide microstructured optical fibers for Mid-IR QCL pigtailing
- Author
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Johann Troles, Marcello Meneghetti, Celine Caillaud, Laurent Brilland, Sébastien Venck, Jean-Luc Adam, Maxime Duris, Damien Deubel, Loïc Bodiou, Joel CHARRIER, Mathieu Carras, Mickaël Brun, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), SelenOptics [Bruz] (SelenOptics), Kerdry Thin Solid Films, Institut des Fonctions Optiques pour les Technologies de l'informatiON (Institut FOTON), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT), MirSense, Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
[PHYS]Physics [physics] ,ComputingMilieux_MISCELLANEOUS - Abstract
International audience
- Published
- 2019
24. Er3+-doped Ga-Ge-Sb-S glass thin films by PVD deposition
- Author
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Geoffrey Louvet, Emeline Baudet, Simone Normani, Florent Starecki, Patrice Camy, Marek Bouska, Jan Gutwirth, Petr Němec, Christophe Cardinaud, Christophe Calers, Yannick Ledemi, Alexandre Douaud, Sandra Messaddeq, Loïc Bodiou, Joel CHARRIER, Jean-Luc Adam, Younès Messaddeq, Virginie Nazabal, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre d'Optique, Photonique et Laser (COPL), Université Laval [Québec] (ULaval), University of Pardubice, Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Institut des Matériaux Jean Rouxel (IMN), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Fonctions Optiques pour les Technologies de l'informatiON (Institut FOTON), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), and Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT)
- Subjects
[PHYS]Physics [physics] - Abstract
International audience; In the frame of the major issues related to global warming and pollution, the microsensor based on mid-infrared (MIR) spectroscopy is a useful tool to allow continuous measurement of different bio-chemicals species that disturb our environment. In the aim of developing a MIR source potentially integrated in a microsensor, we fabricated rare earth doped chalcogenide thin films by different phase vapor deposition (PVD) technics. The RF magnetron sputtering, pulsed laser deposition (PLD) and electron beam evaporation were investigated.The selected glass system is Ge-Ga-(Sb)-S with Er3+ ions doping. Er3+ ions show emissions in NIR and MIR at 1.55 µm (4I13/2→4I15/2)and at 2.8 µm (4I11/2→4I13/2) under excitation at 808 nm. Deposition parameters were optimized for the three PVD techniques based on a comparison to define the higher fluorescence efficiency. Sulphide thin films were characterized by means of transmission, AFM, XPS, SEM, EDS, ellipsometry and Raman spectroscopy to better control the deposition behavior.
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- 2019
25. Guides d’onde optiques en verre fluoré - Technologie et applications
- Author
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Brigitte Boulard, Jean-Luc Adam, Institut des Molécules et Matériaux du Mans (IMMM), Le Mans Université (UM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Adam, Jean-Luc, Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
- Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry ,optical fiber ,[SPI.OPTI] Engineering Sciences [physics]/Optics / Photonic ,laser fiber ,fluoride glass ,fibre optique ,fibre laser ,waveguide ,[CHIM.MATE]Chemical Sciences/Material chemistry ,microsphère ,infrarouge ,laser ,planarwaveguide ,guided'onde planaire ,infrared ,microsphere ,guide d'ondes ,[SPI.OPTI]Engineering Sciences [physics]/Optics / Photonic ,verre fluoré - Abstract
This paper deals with optical fibers, planar waveguides and microspheresmade of fluoride glasses. Thermal, mechanical and optical (especially infrared) propertiesare detailed. Techniques of elaboration of the three types of waveguides are presented.Fluoride fibers are of interest for the following domains of application: spectrometry,astronomy, optical amplification, fiber lasers, and infrared supercontinuum sources. Planarwaveguides aims at application in integrated optics: optical amplifiers, compact lasers.Microspheres are studied for microlasers applications and their potential as miniaturizedoptical memory., Cet article traite des fibres optiques, guides d’onde planaires et microsphèresen verre fluoré. Les propriétés thermiques, mécaniques et optiques (notammentinfrarouges) sont détaillées. Les techniques d’élaboration des trois types de guides d’ondesont présentées. Les fibres de fluorures intéressent les domaines d’application suivants :spectrométrie, astronomie, amplification optique, fibres laser, sources supercontinuuminfrarouges. Les guides d’ondes planaires visent des applications en optique intégrée :amplificateurs optiques, lasers compacts. Les microsphères sont étudiées pour desapplications microlaser, et pour leur potentiel en tant que mémoire optique miniaturisée.
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- 2019
26. Single-mode chalcogenide microstructured optical fibers: A solution for mid-IR fibered QCL (Conference Presentation)
- Author
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Mickael Brun, Sébastien Venck, Mathieu Carras, Damien Deubel, Joël Charrier, Johann Troles, Celine Caillaud, Maxime Duris, Loïc Bodiou, Jean-Luc Adam, Laurent Brilland, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SelenOptics [Bruz] (SelenOptics), Institut des Fonctions Optiques pour les Technologies de l'informatiON (Institut FOTON), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS), Kerdry Thin Solid Films, MirSense, Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), and Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT)
- Subjects
Materials science ,Optical fiber ,Molecular lasers ,Chalcogenide ,Mid-IR ,Quantum cascade lasers ,Polarization-maintaining optical fiber ,02 engineering and technology ,Polarization Integrated optics ,01 natural sciences ,law.invention ,Semiconductor laser theory ,chemistry.chemical_compound ,law ,0103 physical sciences ,Optical fibers ,010302 applied physics ,Semiconductor lasers ,[PHYS]Physics [physics] ,Birefringence ,business.industry ,Single-mode optical fiber ,021001 nanoscience & nanotechnology ,Structured optical fibers ,Interferometry ,chemistry ,Optical sensors ,Optoelectronics ,0210 nano-technology ,Quantum cascade laser ,business ,Chalcogenides - Abstract
International audience; The mid-infrared molecular fingerprint region has gained great interest in the last decade thanks to development of on-chip semiconductor lasers and mid-IR optical fibers. For integrated-optic devices and optical sensors based on interferometric techniques, versatile and easy handling devices can be required. In this context, low-loss single-mode chalcogenide microstructured optical fibers (MOF) which presents an antireflection coating have been elaborated in order to be connected to a Distributed Feedback Quantum Quantum Cascade Laser (DFB-QCL). In addition, another original design of a chalcogenide MOF has been also realized in order to obtained high birefringence properties that can permit to maintain the polarization of the QCL at the output of the fiber. Finally, the fiber properties have been evaluated using a DFB-QCL emitting at 7.4 µm and the polarization maintaining of the chalcogenide fiber has been demonstrated[2]. The combination between a DFB-QCL with such non-conventional fibers has led to the development of single-mode fibered Mid IR lasers.
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- 2019
27. Chalcogenide Glasses
- Author
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Xiang-Hua Zhang, Jean-Luc Adam, and Bruno Bureau
- Subjects
010309 optics ,0103 physical sciences ,02 engineering and technology ,021001 nanoscience & nanotechnology ,0210 nano-technology ,01 natural sciences - Published
- 2019
28. Mid-infrared hollow core fiber drawn from a 3D printed chalcogenide glass preform
- Author
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Jean-Luc Adam, Ronan Lebullenger, Laurent Brilland, Antoine Gautier, David Le Coq, Johann Troles, Elodie Galdo, François Cheviré, Julie Carcreff, Radwan Chahal, Gilles Renversez, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SelenOptics [Bruz] (SelenOptics), Institut FRESNEL (FRESNEL), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), ATHENA (ATHENA), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), European Regional Development Fund, Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche, Région Bretagne, Rennes Métropole, Agence Nationale de la Recherche, Direction Générale de l’Armement (ANR ASTRID DGA FOM-IR-2-20)., ANR-17-ASTR-0011,FOM-IR-2-20,Fabrication de Fibres Optiques Microstructurées pour l'InfraRouge de 2 à 20 µm(2017), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU), and Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU)
- Subjects
Hollow core ,[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics] ,3d printed ,Materials science ,Fabrication ,Physics::Optics ,Chalcogenide glass ,[CHIM.MATE]Chemical Sciences/Material chemistry ,02 engineering and technology ,Microstructured optical fiber ,021001 nanoscience & nanotechnology ,Coupled mode theory ,01 natural sciences ,Finite element method ,Electronic, Optical and Magnetic Materials ,010309 optics ,0103 physical sciences ,[SPI.OPTI]Engineering Sciences [physics]/Optics / Photonic ,[CHIM]Chemical Sciences ,Fiber ,Composite material ,0210 nano-technology - Abstract
We report the fabrication of a microstructured optical fiber drawn from a soft glass 3D printed preform. For this proof of concept, a chalcogenide glass that is well known for its capability to be shaped at low temperature and its mid-infrared transmission was selected: Te20As30Se50. The obtained negative curvature hollow core fiber shows several transmission bands in the 2–12 µm range that are reproduced numerically using finite element-based simulations and coupled mode theory.
- Published
- 2020
29. Chalcogenide Microstructured Optical Fibers for Mid-Infrared Supercontinuum Generation: Interest, Fabrication, and Applications
- Author
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Marcello Meneghetti, Jean-Luc Adam, Johann Troles, Yiming Wu, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SUPUVIR ITN project, European Union's Horizon 2020 research and innovation program [722380], Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
- Subjects
Optical fiber ,Fabrication ,Materials science ,Chalcogenide ,Mid infrared ,02 engineering and technology ,01 natural sciences ,lcsh:Technology ,law.invention ,010309 optics ,lcsh:Chemistry ,chemistry.chemical_compound ,law ,0103 physical sciences ,[CHIM]Chemical Sciences ,General Materials Science ,Purification methods ,Instrumentation ,supercontinuum generation ,lcsh:QH301-705.5 ,Fluid Flow and Transfer Processes ,business.industry ,lcsh:T ,Process Chemistry and Technology ,General Engineering ,mid-infrared ,chalcogenide fibers ,021001 nanoscience & nanotechnology ,chalcogenide glasses ,lcsh:QC1-999 ,Computer Science Applications ,Supercontinuum ,Wavelength ,chemistry ,lcsh:Biology (General) ,lcsh:QD1-999 ,lcsh:TA1-2040 ,Optoelectronics ,0210 nano-technology ,business ,lcsh:Engineering (General). Civil engineering (General) ,lcsh:Physics ,Coherence (physics) - Abstract
International audience; The mid-infrared spectral region is of great technical and scientific importance in a variety of research fields and applications. Among these studies, mid-infrared supercontinuum generation has attracted strong interest in the last decade, because of unique properties such as broad wavelength coverage and high coherence, among others. In this paper, the intrinsic optical properties of different types of glasses and fibers are presented. It turns out that microstructured chalcogenide fibers are ideal choices for the generation of mid-infrared supercontinua. The fabrication procedures of chalcogenide microstructured fibers are introduced, including purification methods of the glass, rod synthesis processes, and preform realization techniques. In addition, supercontinua generated in chalcogenide microstructured fibers employing diverse pump sources and configurations are enumerated. Finally, the potential of supercontinua for applications in mid-infrared imaging and spectroscopy is shown.
- Published
- 2018
30. Chalcogenide microstructured optical fibers for Mid-IR Quantum Cascade Laser pigtailing
- Author
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Johann Troles, Celine Caillaud, Laurent Brilland, Sébastien Venck, Jean-Luc Adam, Maxime Duris, Damien Deubel, Loïc Bodiou, Joel CHARRIER, Mathieu Carras, Mickaël Bruniaux, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SelenOptics [Bruz] (SelenOptics), Institut des Fonctions Optiques pour les Technologies de l'informatiON (Institut FOTON), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS), Kerdry Thin Solid Films, MirSense, Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-IMT Atlantique Bretagne-Pays de la Loire (IMT Atlantique), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT), and CHARRIER, Joel
- Subjects
[PHYS]Physics [physics] ,ComputingMilieux_MISCELLANEOUS ,[PHYS] Physics [physics] - Abstract
International audience
- Published
- 2018
31. Verres - Propriétés et applications
- Author
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Jean-Luc Adam, Brigitte Boulard, Institut des Molécules et Matériaux du Mans (IMMM), Le Mans Université (UM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), and Adam, Jean-Luc
- Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry ,verre ,corrosion ,optical ,thermo-mechanical ,optique ,[CHIM.MATE]Chemical Sciences/Material chemistry ,glass ,thermo-mécanique - Abstract
This article presents the optical and mechanical properties of glasses andhighlights the specificities of the different families (oxide, fluoride and chalcogenideglasses). Thermal and chemical treatments for improving the strength of the glasses aredescribed. The article gives the application fields of glasses in relation to their opticalproperties: fibers for telecommunication, fiber lasers, fibers for chemical and biochemicalsensors, Cet article présente les propriétés optiques et mécaniques des verres etsouligne les particularités des différentes familles (verres d’oxydes, de fluorures et dechalcogénures). Des traitements thermiques ou chimiques permettant d’améliorer larésistance des verres sont décrits. L’article donne les domaines d’applications des verresen relation avec leurs propriétés optiques : fibres pour les télécommunications, fibreslaser, fibres pour capteurs chimiques et biochimiques.
- Published
- 2018
32. Chalcogenide glass-ceramic with self-organized heterojunctions application to photovoltaic solar cells
- Author
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Jean-Luc Adam, Jean-Jacques Simon, Laurent Le Brizoual, Bo Fan, Xianghua Zhang, Hervé Lhermite, Michel Cathelinaud, Marcel Pasquinelli, Hongli Ma, Ilia Korolkov, Odile Merdrignac, Laurent Calvez, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Institut d'Électronique et des Technologies du numéRique (IETR), Nantes Université (NU)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-CentraleSupélec-Centre National de la Recherche Scientifique (CNRS), Institut des Matériaux, de Microélectronique et des Nanosciences de Provence (IM2NP), Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU), Institut des Sciences Chimiques de Rennes ( ISCR ), Université de Rennes 1 ( UR1 ), Université de Rennes ( UNIV-RENNES ) -Université de Rennes ( UNIV-RENNES ) -Ecole Nationale Supérieure de Chimie de Rennes-Institut National des Sciences Appliquées ( INSA ) -Centre National de la Recherche Scientifique ( CNRS ), Institut d'Electronique et de Télécommunications de Rennes ( IETR ), Université de Nantes ( UN ) -Université de Rennes 1 ( UR1 ), Université de Rennes ( UNIV-RENNES ) -Université de Rennes ( UNIV-RENNES ) -Institut National des Sciences Appliquées - Rennes ( INSA Rennes ) -CentraleSupélec-Centre National de la Recherche Scientifique ( CNRS ), Institut des Matériaux, de Microélectronique et des Nanosciences de Provence ( IM2NP ), Aix Marseille Université ( AMU ) -Université de Toulon ( UTLN ) -Centre National de la Recherche Scientifique ( CNRS ), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-CentraleSupélec-Centre National de la Recherche Scientifique (CNRS), Aix Marseille Université (AMU)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes 1 (UR1), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Université de Nantes (UN)-Université de Rennes 1 (UR1)
- Subjects
Materials science ,heterojunction ,Chalcogenide ,[ INFO.INFO-NI ] Computer Science [cs]/Networking and Internet Architecture [cs.NI] ,lcsh:TJ807-830 ,lcsh:Renewable energy sources ,Chalcogenide glass ,02 engineering and technology ,7. Clean energy ,01 natural sciences ,010309 optics ,chemistry.chemical_compound ,chalcogenide ,[INFO.INFO-NI]Computer Science [cs]/Networking and Internet Architecture [cs.NI] ,Sputtering ,0103 physical sciences ,Electrical and Electronic Engineering ,Thin film ,photovoltaic solar cells ,Renewable Energy, Sustainability and the Environment ,business.industry ,Photovoltaic system ,Energy conversion efficiency ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,[ SPI.TRON ] Engineering Sciences [physics]/Electronics ,[SPI.TRON]Engineering Sciences [physics]/Electronics ,Semiconductor ,chemistry ,glass-ceramics ,Optoelectronics ,0210 nano-technology ,business - Abstract
In this work, we present for the first time the concept of chalcogenide glass-ceramic for photovoltaic applications with the GeSe2–Sb2Se3–CuI system. It has been demonstrated that thin films, deposited with the sputtering technique, are amorphous and can be crystallized with appropriate heat treatment. The thin film glass-ceramic behaves as a p-type semiconductor, even if it contains p-type Cu2GeSe3and n-type Sb2Se3. The conductivity of Sb2Se3has been greatly improved by appropriate iodine doping. The first photovoltaic solar cells based on the association of iodine-doped Sb2Se3and the glass-ceramic thin films give a short-circuit current density JSCof 10 mA/cm2and an open-circuit voltage VOCof 255 mV, with a power conversion efficiency of about 0.9%.
- Published
- 2018
33. Development of an evanescent optical integrated sensor in the mid-infrared for detection of pollution in groundwater or seawater
- Author
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Bruno Bureau, Karine Michel, A. Gutierrez-Arroyo, Petr Němec, Emeline Baudet, Marion Baillieul, Loïc Bodiou, Jonathan Lemaitre, Virginie Nazabal, Emmanuel Rinnert, Joël Charrier, Jean-Luc Adam, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Mathématiques de Marseille (I2M), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), Department of Graphic Arts and Photophysics [University of Pardubice], Faculty of Chemical Technology [University of Pardubice], University of Pardubice-University of Pardubice, Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER), Environnement, Ville, Société (EVS), École normale supérieure de Lyon (ENS de Lyon)-École des Mines de Saint-Étienne (Mines Saint-Étienne MSE), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT)-Université Lumière - Lyon 2 (UL2)-Université Jean Moulin - Lyon 3 (UJML), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université Jean Monnet - Saint-Étienne (UJM)-École Nationale des Travaux Publics de l'État (ENTPE)-École nationale supérieure d'architecture de Lyon (ENSAL)-Centre National de la Recherche Scientifique (CNRS), 16-17921S, Grantová Agentura České Republiky, Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU), Environnement Ville Société (EVS), Institut National des Sciences Appliquées de Lyon (INSA Lyon), Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-École nationale supérieure d'architecture de Lyon (ENSAL)-École des Mines de Saint-Étienne (Mines Saint-Étienne MSE), Institut Mines-Télécom [Paris] (IMT)-Institut Mines-Télécom [Paris] (IMT)-École Nationale des Travaux Publics de l'État (ENTPE)-Université Jean Monnet [Saint-Étienne] (UJM)-Université Jean Moulin - Lyon 3 (UJML), Université de Lyon-Université Lumière - Lyon 2 (UL2)-École normale supérieure - Lyon (ENS Lyon), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), École normale supérieure - Lyon (ENS Lyon)-École des Mines de Saint-Étienne (Mines Saint-Étienne MSE), and Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université Jean Monnet [Saint-Étienne] (UJM)-École Nationale des Travaux Publics de l'État (ENTPE)-École nationale supérieure d'architecture de Lyon (ENSAL)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
lcsh:Applied optics. Photonics ,Materials science ,Chalcogenide glasses ,02 engineering and technology ,01 natural sciences ,Waveguide (optics) ,010309 optics ,chemistry.chemical_compound ,Optics ,Selenide ,0103 physical sciences ,lcsh:TA401-492 ,Refractive index contrast ,Optical sensing and sensors ,Thin film ,Reactive-ion etching ,ComputingMilieux_MISCELLANEOUS ,business.industry ,lcsh:TA1501-1820 ,mid-infrared ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Cladding (fiber optics) ,integrated optics devices ,Psychiatry and Mental health ,Wavelength ,thin films ,chemistry ,13. Climate action ,lcsh:Materials of engineering and construction. Mechanics of materials ,Inductively coupled plasma ,0210 nano-technology ,business - Abstract
The detection of molecules dissolved in liquid medium can be envisaged by means of an optical integrated sensor operating in middle infrared range. The intended sensor is composed of a cladding and a guiding selenide sputtered layers transparent in middle infrared. Hence, Ge-Sb-Se thin films were selected in view of tailored refractive index contrast, successfully deposited by radio frequency magnetron sputtering and characterized. To maximize the evanescent field at a wavelength of 7.7 µm, a suitable selenide waveguide allowing measuring the optical transmitted power was designed by performing computer simulations based on the effective index method enabling single-mode propagation for a waveguide width between 8 and 12 µm. Selenide sputtered films were micro-patterned using reactive ion etching with inductively coupled plasma process. Finally, optical waveguide surface was functionalized by the deposition of a hydrophobic polymer, which will permit detection of organic molecules in water.
- Published
- 2017
34. Different designs and glass compositions of chalcogenide microstructured optical fibers for different applications (Conference Presentation)
- Author
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Johann Troles, Celine Caillaud, Jean-Luc Adam, and Laurent Brilland
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Multi-mode optical fiber ,Materials science ,Optical fiber ,business.industry ,Chalcogenide ,Single-mode optical fiber ,Physics::Optics ,Chalcogenide glass ,Laser ,Condensed Matter::Disordered Systems and Neural Networks ,law.invention ,Supercontinuum ,chemistry.chemical_compound ,Optics ,chemistry ,law ,business ,Quantum cascade laser ,Astrophysics::Galaxy Astrophysics - Abstract
Chalcogenide glasses are known for their large transparency in the mid-infrared (Mid-IR) and their high nonlinear optical properties. Indeed, chalcogenide glasses can present a high non-linear coefficient (n2), 100 to 1000 times larger than for silica glass, depending on the composition. An original way to obtain fibers is to design microstructured optical fibers (MOFs). These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. Various chalcogenide MOFs operating in the mid-IR range have been elaborated in order to associate the high nonlinear properties of these glasses and the original MOF properties. Different glass compositions and different designs have been achieved depending on the intended application. Indeed, chalcogenide MOFs might lead to new devices with unique optical properties in the Mid-IR domain like multimode or endlessly single mode transmission of light, small or large mode area fibers, non-linear properties for wavelength conversion or generation of supercontinuum sources. In the 1-12 µm window, single mode fibers, polarization maintaining fibers and exposed core fibers have been realized for Gaussian beams propagation and sensors applications. In this context, different applications such as Brillouin laser, all optical demultiplexing, mid-IR supercontinuum generation, quantum cascade laser pigtailing and mid-IR spectroscopy will be exposed.
- Published
- 2017
35. Dysprosium-doped chalcogenide Master Oscillator Power Amplifier (MOPA) for Mid-IR emission
- Author
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Jean-Luc Adam, Giuseppe Palma, Johann Troles, Francesco Prudenzano, Virginie Nazabal, Maurizio Ferrari, Stefano Taccheo, Mario Christian Falconi, Florent Starecki, Politecnico di Bari, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Caratterizzazione e Sviluppo di Materiali per la Fotonica e l'Optoelecttronica (CSMFO), CNR Istituto di Fotonica e Nanotecnologie [Trento] (IFN), Consiglio Nazionale delle Ricerche [Roma] (CNR)-Consiglio Nazionale delle Ricerche [Roma] (CNR), Ministero dell'Istruzione, dell'Universit e della Ricerca [PON01 01224, PONa3 00298, PON02 00576 3329762], EU COST Action [MP1401], Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR)-National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR)
- Subjects
Materials science ,Optical fiber ,Chalcogenide ,Chalcogenide glass ,Physics::Optics ,electromagnetic analysis ,02 engineering and technology ,7. Clean energy ,law.invention ,Optical pumping ,chemistry.chemical_compound ,020210 optoelectronics & photonics ,Electromagnetic analysis, dysprosium, laser, optical fiber amplifiers, chalcogenide glass, medium infrared, MOPA, photonic crystal fibers (PCFs) ,law ,Fiber laser ,dysprosium ,laser ,medium infrared ,MOPA ,optical fiber amplifiers ,photonic crystal fibers (PCFs) ,0202 electrical engineering, electronic engineering, information engineering ,[CHIM]Chemical Sciences ,Optical amplifier ,business.industry ,021001 nanoscience & nanotechnology ,Laser ,Atomic and Molecular Physics, and Optics ,chemistry ,13. Climate action ,Optoelectronics ,Atomic physics ,0210 nano-technology ,business ,Photonic-crystal fiber - Abstract
The paper describes the design of a medium infrared fiber laser based on a dysprosium-doped chalcogenide glass $\text{Dy}^{3+}: \text{Ga}_{5}\text{Ge}_{20}\text{Sb}_{10}\text{S}_{65}$ . To obtain a high efficiency, the fiber laser is followed by an optical amplifier. The optimized optical source exploits a master oscillator power amplifier (MOPA) configuration. The MOPA pump and signal wavelengths are 1709 and 4384 nm, respectively. Spectroscopic parameters measured on preliminary samples of chalcogenide glasses are taken into account to fulfill realistic simulations. The MOPA emission is maximized by applying a particle swarm optimization approach. For the dysprosium concentration ${\text{6}}\, \times\, {\text{10}}^{25}$ ions/ $\text{m}^{3}$ and the input pump power of 3 W, an output power of 637 mW can be obtained for optical fiber losses close to 1 dB $\text{m}^{-1}$ . The optimized MOPA configuration allows a laser efficiency larger than 21%. By considering the high beam quality provided by photonic crystal fibers, it is a good candidate for medium infrared light generation whose main applications include, but are not limited to, molecular spectroscopy and environmental monitoring.
- Published
- 2017
36. Photonic Bandgap Propagation in All-Solid Chalcogenide Microstructured Optical Fibers
- Author
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Laurent Calvez, David Mechin, Celine Caillaud, Jean-Luc Adam, Johann Troles, Laurent Brilland, Gilles Renversez, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), ATHENA (ATHENA), Institut FRESNEL (FRESNEL), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Centre National de la Recherche Scientifique (CNRS), France Télécom Recherche & Développement (FT R&D), France Télécom, Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), and Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Aix Marseille Université (AMU)
- Subjects
photonic bandgap fibers ,Materials science ,Optical fiber ,Chalcogenide ,Physics::Optics ,lcsh:Technology ,Article ,law.invention ,Matrix (mathematics) ,chemistry.chemical_compound ,Optics ,Zero-dispersion wavelength ,law ,General Materials Science ,lcsh:Microscopy ,lcsh:QC120-168.85 ,[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics] ,chalcogenide glasses ,infrared fibers ,microstructured optical fibers (MOFs) ,lcsh:QH201-278.5 ,business.industry ,lcsh:T ,Microstructured optical fiber ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Transmission (telecommunications) ,chemistry ,lcsh:TA1-2040 ,lcsh:Descriptive and experimental mechanics ,lcsh:Electrical engineering. Electronics. Nuclear engineering ,business ,lcsh:Engineering (General). Civil engineering (General) ,Refractive index ,lcsh:TK1-9971 ,Photonic-crystal fiber - Abstract
International audience; An original way to obtain fibers with special chromatic dispersion and single-mode behavior is to consider microstructured optical fibers (MOFs). These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. In this study, the first all-solid all-chalcogenide MOFs exhibiting photonic bandgap transmission have been achieved and optically characterized. The fibers are made of an As38Se62 matrix, with inclusions of Te20As30Se50 glass that shows a higher refractive index (n = 2.9). In those fibers, several transmission bands have been obsd. in mid IR depending on the geometry. In addn., for the first time, propagation by photonic bandgap effect in an all-chalcogenide MOF has been obsd. at 3.39 μm, 9.3 μm, and 10.6 μm. The numerical simulations based on the optogeometric properties of the fibers agree well with the exptl. characterizations.
- Published
- 2014
37. Tensile Properties of Treated and Untreated Ground Nut ShellFilled Natural Rubber Composites
- Author
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Y. B. Taura, Jean-Luc Adam, Magaji Ladan, Shehu Habibu, and SM Gumel
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Cellulose fiber ,Materials science ,Natural rubber ,visual_art ,Filler (materials) ,Composite number ,Ultimate tensile strength ,visual_art.visual_art_medium ,engineering ,Particle size ,Ground-nut ,engineering.material ,Composite material - Abstract
Groundnut shell was crushed in to particle size and given two surface treatments with alkali and 3chloro-2-hydroxylpropyltrimethylammoniumchloride respectively. The raw, alkali-treated and bonding agent treated groundnut shell cellulose fibers were used as natural rubber composites. The samples were used to produce fiber-reinforced natural rubber composite at varying filler loadings. Properties such as tensile, hardness and impact of the composites were investigated. The tensile strength of the composites varied such that both the alkali-treated and cationized fillers recorded higher values than untreated fillers. The impact hardness properties were also found to be better in the modified fillers than the untreated ones. This work has shown some general improvements arising from cauticization and cationization of cellulosic filler as reinforcing material for natural rubber.
- Published
- 2014
38. Synthesis of Cobalt-Complex Azo Dye from 2, 2[Benzene-1, 3-diyl di-(E)-diazene-2, 1-diyl] bis (4-nitroaniline)
- Author
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SM Gumel, Y. B. Taura, Jean-Luc Adam, Shehu Habibu, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
- Subjects
Materials science ,Absorption spectroscopy ,Ligand ,chemistry.chemical_element ,[CHIM.MATE]Chemical Sciences/Material chemistry ,4-Nitroaniline ,Metal ,chemistry.chemical_compound ,chemistry ,Phenylene ,visual_art ,Diamine ,Polymer chemistry ,visual_art.visual_art_medium ,Thermal stability ,Cobalt - Abstract
International audience; The aim of this investigation is to carry out the synthesis of bisazo dye 2,2[benzene-1,3-diyl di(E)diazene 2,1-diyl]bis(4-nitroaniline). The synthesis was conducted through the diazotization and coupling of m-phenylene diamine with 4-nitroanline leading to the prodn. of azo metal (II) complex of Cobalt. Characterization of the ligand and the metal complex was carried out using various 34hysic-chem. techniques. The metal chelates have a metal to ligand ratio of 1:1. The synthesized azo metal (II) complex dye had a potential application for high d. optical recording media due to their good absorption spectra and high thermal stability.
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- 2014
39. Luminescence at 2.8 μm: Er3+-doped chalcogenide micro-waveguide
- Author
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J.L. Doualan, Jean-Luc Adam, Virginie Nazabal, Loïc Bodiou, Petr Němec, Florent Starecki, Hervé Lhermite, Marie-Laure Anne, Joël Charrier, Patrice Camy, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Department of Graphic Arts and Photophysics [University of Pardubice], Faculty of Chemical Technology [University of Pardubice], University of Pardubice-University of Pardubice, Institut d'Électronique et des Technologies du numéRique (IETR), Université de Nantes (UN)-Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-CentraleSupélec-Centre National de la Recherche Scientifique (CNRS), Fonctions Optiques pour les Technologies de l'informatiON (FOTON), Université de Rennes (UR)-Université européenne de Bretagne - European University of Brittany (UEB)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Télécom Bretagne-Centre National de la Recherche Scientifique (CNRS), Conseil National de la Recherche Scientifique, 16-17921S, Grantová Agentura České Republiky, Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Nantes Université (NU)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-CentraleSupélec-Centre National de la Recherche Scientifique (CNRS), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Université européenne de Bretagne - European University of Brittany (UEB)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Centre National de la Recherche Scientifique (CNRS)-Télécom Bretagne, Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Université de Nantes (UN)-Université de Rennes 1 (UR1)
- Subjects
Materials science ,Photoluminescence ,Chalcogenide ,Thin films ,chemistry.chemical_element ,02 engineering and technology ,01 natural sciences ,010309 optics ,Inorganic Chemistry ,Erbium ,chemistry.chemical_compound ,Amorphous materials ,Optics ,0103 physical sciences ,[CHIM]Chemical Sciences ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Thin film ,Spectroscopy ,ComputingMilieux_MISCELLANEOUS ,Rare-earth doped materials ,business.industry ,Organic Chemistry ,Doping ,Sputter deposition ,021001 nanoscience & nanotechnology ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,chemistry ,integrated optics ,0210 nano-technology ,Luminescence ,business - Abstract
This paper reports the fabrication of luminescent optical rib/ridge waveguides made of erbium doped Ga-Ge-Sb-S films deposited by RF magnetron sputtering. Several fluorescence emissions of Er 3+ ions from the visible to the middle infrared spectral domain were clearly observed within the films. The study of the 4 I 13/2 level lifetime enabled development of a suitable annealing treatment of the films to reach the value of the bulk counterpart while the variation in surface roughness was limited, thus ensuring reasonable optical losses (0.7–0.9 dB/cm). Amplification experiments were carried out at 1.54 μm leading to complete characterization of the erbium-doped micro-waveguide with ∼3.4 dB/cm on/off gain. A demonstration of mid-IR photoluminescence from Er 3+ -doped chalcogenide micro-waveguide was recorded at ∼2.76 μm. The multi-luminescence from the visible to mid-IR generated using erbium doped chalcogenide waveguiding micro-structures might find easy-to-use applications concerning telecommunication technologies or on-chip optical sensors for which luminescent sources or amplifiers operating at different wavelengths are required.
- Published
- 2016
40. Original designs of chalcogenide microstructured optical fibers for mid-IR applications
- Author
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Mickael Brun, Jean-Luc Adam, Laurent Brilland, Celine Caillaud, Johann Troles, Mathieu Carras, Laurent Provino, Clement Gilles, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Supercontinuum sources ,Single mode fibers ,Materials science ,Optical fiber ,Geometrical structure ,Chalcogenide ,Infrared fibers ,Physics::Optics ,Chalcogenide glass ,02 engineering and technology ,Condensed Matter::Disordered Systems and Neural Networks ,01 natural sciences ,Degrees of freedom (mechanics) ,law.invention ,010309 optics ,chemistry.chemical_compound ,020210 optoelectronics & photonics ,Optics ,Zero-dispersion wavelength ,Transparent optical networks ,Micro-structured optical fibers ,Fiber optic networks ,law ,0103 physical sciences ,0202 electrical engineering, electronic engineering, information engineering ,[CHIM]Chemical Sciences ,Optical fibers ,Microstructure ,ComputingMilieux_MISCELLANEOUS ,High Degree of Freedom ,Highly birefringent fiber ,Optical properties ,business.industry ,Microstructured optical fiber ,Multimode fibers ,Supercontinuum ,Fibers ,Endlessly single modes ,chemistry ,Light transmission ,Optoelectronics ,Glass ,business ,Hard-clad silica optical fiber ,Photonic-crystal fiber ,Chalcogenides - Abstract
Compared to oxide based glasses, vitreous materials composed of chalcogen elements (S, Se, Te) show large transparency windows in the infrared. Indeed, chalcogenide glasses can be transparent from the visible up to 12 – 18 µm, depending on their compositions. In addition, chalcogenide glasses contain large polarisable atoms and external lone electron pairs which induce exceptional non-linear properties. Consequently, the non-linear properties can be 100 or 1000 times as high as the non-linearity of silica. An original way to obtain single-mode fibers is to design microstructured optical fibers (MOFs). These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. Our group has prepared various chalcogenide MOFs operating in the IR range in order to associate the high non-linear properties of these glasses and the original MOF properties. Indeed, chalcogenide MOFs might lead to new devices with unique optical properties in the mid-infrared domain like multimode or endlessly single-mode transmission of light, small or large mode area fibers, highly birefringent fibers and non-linear properties for wavelength conversion or generation of supercontinuum sources.
- Published
- 2016
41. Challenges and Future Trends in Fiber Lasers
- Author
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A. Klotzbach, Peter Hartmann, Angela B. Seddon, Francesco Prudenzano, Hovik V. Baghdasaryan, Daniela Comelli, Kay Schuster, Stefano Taccheo, Gianluca Valentini, Cosimo D'Andrea, Antonio Lucianetti, Jean-Luc Adam, Christopher Taudt, Mile Ivanda, Slawomir Sujecki, Tobias Baselt, M Jaeger, Marian Marciniak, J. Troles, Dominik Dorosz, Mariano Ferrari, Alessandro Chiasera, Pavel Peterka, Hrvoje Gebavi, Virginie Nazabal, National Institute of Telecommunications (NIT), Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Dipartimento di Fisica, Politecnico di Milano [Milan] (POLIMI), Politecnico di Bari, Institute of Photonics and Electronics of the Czech Academy of Sciences (UFE / CAS), Czech Academy of Sciences [Prague] (CAS), National Institute of Telecommunications - Warsaw, Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Optical fiber ,Computer science ,Fiber lasers ,mid-infrared lasers ,modelling ,soft-glasses ,supercontinuum sources ,visible laser ,Computer Networks and Communications ,Electrical and Electronic Engineering ,Electronic, Optical and Magnetic Materials ,Optical communication ,Physics::Optics ,02 engineering and technology ,01 natural sciences ,nm ,law.invention ,010309 optics ,law ,mu-m ,Fiber laser ,0103 physical sciences ,Electronic ,[CHIM]Chemical Sciences ,tissues ,Optical and Magnetic Materials ,Astrophysics::Galaxy Astrophysics ,ComputingMilieux_MISCELLANEOUS ,Flexibility (engineering) ,business.industry ,Amplifier ,Near-infrared spectroscopy ,021001 nanoscience & nanotechnology ,Laser ,optical-properties ,Wavelength ,Optoelectronics ,0210 nano-technology ,business - Abstract
Fiber lasers are a fast growing class of lasers due to their reliability, efficiency and flexibility. This has made fiber lasers a versatile tool for manufacturing, sensing and healthcare, not forgetting the contribution of Erbium-doped amplifiers to optical communications. Yet available wavelengths by direct emission are quite restricted to the visible and near infrared wavelength interval (500 nm to 2 micron), with very few offering high power and efficient operation, namely 1 micron, 1.5 micron and 2 micron wavelengths. In this paper we comment on the state of the art and future challenges in the field of fiber lasers to address new wavelength and new applications. In particular to extended the emission interval above 3 micron. This work collects the experience of the COST MP1401 Network on fiber lasers and their application and will present some of the areas were efforts have been focused. More exhaustive material will be presented at the conference.
- Published
- 2016
42. Highly birefringent chalcogenide optical fiber for polarization-maintaining in the 3-8.5 µm mid-IR window
- Author
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Mickael Brun, Mathieu Carras, Jean-Luc Adam, Johann Troles, Laurent Brilland, Thierry Jouan, Simon Ferré, David Mechin, Laurent Provino, Celine Caillaud, Clement Gilles, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Plate-Forme d'Etudes et de Recherche sur les Fibres Optiques Spéciales (PERFOS), association PERFOS, Centre National de la Recherche Scientifique (CNRS), Direction Générale de l’Armement (DGA), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
All-silica fiber ,Optical fiber ,Materials science ,business.industry ,Polarization-maintaining optical fiber ,02 engineering and technology ,Microstructured optical fiber ,021001 nanoscience & nanotechnology ,01 natural sciences ,Graded-index fiber ,Atomic and Molecular Physics, and Optics ,law.invention ,010309 optics ,Optics ,law ,0103 physical sciences ,Optoelectronics ,Dispersion-shifted fiber ,[CHIM]Chemical Sciences ,0210 nano-technology ,business ,Plastic optical fiber ,Photonic-crystal fiber - Abstract
International audience; A highly birefringent polarization-maintaining chalcogenide microstructured optical fiber (MOF) covering the 3-8.5 µm wavelength range has been realized for the first time. The fiber cross-section consists of 3 rings of circular air holes with 2 larger holes adjacent to the core. Birefringence properties are calculated by using the vector finite-element method and are compared to the experimental ones. The group birefringence is 1.5x10−3 and fiber losses are equal to 0.8 dB/m at 7.55 µm.
- Published
- 2016
43. Structural study by Raman spectroscopy and 77Se NMR of GeSe4 and 80GeSe2–20Ga2Se3 glasses synthesized by mechanical milling
- Author
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Laurent Calvez, Jean-Luc Adam, Bruno Bureau, Elena Petracovschi, Alain Moréac, Claire Roiland, Xianghua Zhang, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Institut de Physique de Rennes (IPR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS), Umicore IR Glass and Region Bretagne, Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Université de Rennes (UR)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Materials science ,chemistry.chemical_element ,Germanium ,Mechanical milling ,02 engineering and technology ,[CHIM.MATE]Chemical Sciences/Material chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Structural evolution ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,symbols.namesake ,Crystallography ,chemistry ,Chemical engineering ,Materials Chemistry ,Ceramics and Composites ,symbols ,Gallium ,0210 nano-technology ,Raman spectroscopy ,Selenium - Abstract
Amorphous powders of GeSe 4 and 80GeSe 2 –20Ga 2 Se 3 compositions have been prepared by mechanical alloying of raw Germanium, Selenium and Gallium. The amorphization process and structural evolution of the powder during mechanical alloying have been studied by XRD, DSC, Raman spectroscopy and 77 Se NMR. The role of Gallium in the amorphization process has been pointed out. Similar structures and thermal properties of amorphous powders and respective glasses synthesized by melt-quenching method have been observed.
- Published
- 2016
44. Sputtering and Pulsed Laser Deposition for Near- and Mid-Infrared Applications: A Comparative Study of Ge25Sb10S65 and Ge25Sb10Se65 Amorphous Thin Films
- Author
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Hervé Lhermite, Marie-Laure Brandily-Anne, Jean-Luc Adam, Alain Moréac, Jean-Pierre Guin, Virginie Nazabal, Frédéric Charpentier, Joël Charrier, and Petr Nemec
- Subjects
Marketing ,Materials science ,business.industry ,Analytical chemistry ,02 engineering and technology ,Sputter deposition ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Amorphous solid ,Pulsed laser deposition ,010309 optics ,chemistry.chemical_compound ,Carbon film ,chemistry ,Sputtering ,Selenide ,0103 physical sciences ,Materials Chemistry ,Ceramics and Composites ,Optoelectronics ,Thin film ,Reactive-ion etching ,0210 nano-technology ,business - Abstract
The deposition of Ge25Sb10S65 and Ge25Sb10Se65 amorphous chalcogenide thin films was performed by radio-frequency magnetron sputtering and pulsed laser deposition technique. The deposited layers were characterized by studying their morphology, topography, chemical composition, structure, and optical functions permitting a direct comparison of two deposition methods for obtaining attractive amorphous chalcogenide films. Reactive ion etching was then used to pattern rib/ridge waveguides in sulfide and selenide films with low surface roughness, vertical sidewalls, and reasonable etching rate. Optical losses of fabricated waveguides were measured at 1550 nm with values better than 1 dB/cm obtained for sulfide/selenide films deposited by both techniques.
- Published
- 2011
45. Fabrication of highly homogeneous As2Se3 glass under argon flow
- Author
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Hongli Ma, Xianghua Zhang, Erwan Guillevic, Hugues Tariel, Jacques Lucas, Jean-Luc Adam, Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), UMICORE, Umicore IR Glass, Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Controlled atmosphere ,Fabrication ,As2Se3 ,chemistry.chemical_element ,02 engineering and technology ,01 natural sciences ,Oxygen ,Annealing (glass) ,010309 optics ,Synthesis ,42.70.Km ,42.70.Ce ,Optics ,Differential scanning calorimetry ,0103 physical sciences ,Materials Chemistry ,81.05.Kf ,Composite material ,Moisture ,business.industry ,Magnesium ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,chemistry ,Ceramics and Composites ,Glass ,0210 nano-technology ,business ,Refractive index - Abstract
International audience; The present study relates to a new method for the synthesis of As2Se3 glass in a controlled atmosphere. The advantage of this technique is that it does not require sealing of the silica reaction container and therefore makes it likely to substitute the current industrial batch by batch synthesis which actually needs very expensive single-use sealed silica vessels. An experimental device has been developed for these purposes. It is equipped with a stirring mechanism to homogenize the molten bath. In order to avoid contamination by oxygen and moisture, the synthesis is carried out under argon flow (pressure of 1 bar). Material losses during synthesis can be reduced to less than 2% when temperature is progressively increased up to 430 °C. Bulk glass ingots are finally obtained according to a two-step annealing process. Their chemical composition is analyzed by EDS and shows a variation range of less than 0.2%. The excellent reproducibility of the given method is also confirmed by the refractive indexes, that do not differ for more than 1 * 10−3 from one another. Adverse absorption bands due to oxygen do not occur in the 8-12 μm spectral region when 1000 ppm of Mg is added. As no distilling operation has been carried out until now, the magnesium oxide partially keeps staying in the glass and leads to scattering losses at short wavelengths.
- Published
- 2011
46. Preparation of optical fibers based on Ge–Sb–S glass system
- Author
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L.A. Ketkova, Jean-Luc Adam, Vladimir Shiryaev, A. A. Sibirkin, Johann Troles, M. F. Churbanov, and Patrick Houizot
- Subjects
All-silica fiber ,Materials science ,Optical fiber ,business.industry ,Organic Chemistry ,Chalcogenide glass ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,law.invention ,Inorganic Chemistry ,Zero-dispersion wavelength ,Optics ,law ,Impurity ,Fiber ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Composite material ,business ,Hard-clad silica optical fiber ,Spectroscopy ,Photonic-crystal fiber - Abstract
Unclad optical fibers based on Ge–Sb–S glass systems were prepared by preform drawing. It was shown that optical losses in fibers depend on the content of limiting impurities in glass. The correlation between the level of optical losses in fibers and the content of gas-forming dissolved impurities and heterophase inclusions in glasses was established. The minimum optical losses were equal to 300 dB/km at 5.35 μm wavelength in fiber from Ge 25 Sb 10.5 S 64.5 glass prepared using chemical-distillation melt purification.
- Published
- 2009
47. Thermal properties of chalcogenide glasses in the GeSe2–As2Se3–CdSe system
- Author
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Jean-Luc Adam, Hua Wang, Hongli Ma, Xianghua Zhang, Donghui Zhao, Huidan Zeng, Guorong Chen, EAST CHINA UNIVERSITY, KEY LAB, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Sino-France Joint Research Project (PRA MX03-01), National Natural Science Foundation of China (NSFC 60578042, 50702021), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Thermal properties ,Chalcogenide ,Glass ceramics ,Nucleation ,Mineralogy ,Thermodynamics ,Crystal growth ,02 engineering and technology ,Calorimetry ,010402 general chemistry ,Condensed Matter::Disordered Systems and Neural Networks ,01 natural sciences ,law.invention ,chemistry.chemical_compound ,Differential scanning calorimetry ,law ,Materials Chemistry ,Thermal stability ,Crystallization ,Infrared glasses ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,61.10.Nz ,66.60.+a ,81.05.Kf ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Condensed Matter::Soft Condensed Matter ,chemistry ,Ceramics and Composites ,0210 nano-technology ,Glass transition ,Chalcogenides - Abstract
International audience; In the present work, thermal properties of GeSe2-As2Se3-CdSe glasses were investigated via DSC measurements. The dependences of glass transition temperature and thermal stability on glass composition were discussed. XRD measurement was also performed to validate the effect of cadmium on the thermal properties of glasses. The calculated Avrami exponent was used to demonstrate the three-dimensional growth of crystals in the glass matrices. The crystallization kinetics for the glasses was studied by using the modified Kissinger and Ozawa equations.
- Published
- 2008
48. Photoluminescence of PbS quantum dots embedded in glasses
- Author
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Jong Heo, Jean-Luc Adam, Chao Liu, Xianghua Zhang, POHANG UNIVERSITY, Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), the SRC/ERC and STAR programs of MOST/KOSEF (R11-2003-006 and M6-0501-00-0083), Korean Research Foundation Grant funded by the Korean Government (MOEHRD) (KRF-2005-005-J13101) and BK 21, Korea., Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
TEM/STEM ,Luminescence ,Photoluminescence ,Materials science ,Absorption spectroscopy ,Nanotechnology ,02 engineering and technology ,01 natural sciences ,chemistry.chemical_compound ,0103 physical sciences ,Materials Chemistry ,Lead sulfide ,Quantum well ,010302 applied physics ,78.40.Hc ,78.55.−m ,78.55.Qr ,78.67.Hc ,Doping ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,wires and dots ,Nanocrystals ,Electronic, Optical and Magnetic Materials ,Quantum wells ,Oxide glasses ,Nanocrystal ,chemistry ,Quantum dot ,Ceramics and Composites ,0210 nano-technology - Abstract
International audience; Optical properties and photoluminescence of PbS quantum dots (QDs) embedded in glasses were investigated. Formation and radius of PbS QDs were carefully controlled though heat-treatment and modification of host glass composition. Heat-treatment conditions for precipitation of 3-10 nm radius QDs for the tunable photoluminescence in the 1-2 μm wavelength range were identified. Glasses doped with PbS QDs provide potential as robust materials for broadband fiber-optic amplifiers.
- Published
- 2008
49. Chalcogenide fibers for infrared photonics: Recent developments
- Author
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Viriginie Nazabal, Catherine Boussard, Johann Troles, Jean-Luc Adam, Bruno Bureau, and Laurent Brilland
- Subjects
Materials science ,business.industry ,Infrared ,Chalcogenide ,Oxide ,Physics::Optics ,Chalcogenide glass ,Condensed Matter::Disordered Systems and Neural Networks ,Chalcogen ,chemistry.chemical_compound ,Optics ,chemistry ,Optoelectronics ,Light emission ,Photonics ,business ,Photonic-crystal fiber - Abstract
Compared to oxide based glasses, vitreous materials composed of chalcogen elements (S, Se, Te) show large transparency windows in the infrared. Indeed, chalcogenide glasses can be transparent from the visible up to 12 – 15 µm, depending on their compositions. This is due to the lower phonon energies of chalcogenides, which are also responsible for enhanced luminescence of rare-earth ions embedded in such matrices. Thus, sulphide glasses, for instance, allow light emission at wavelengths not accessible with silica. In addition, chalcogenide glasses contain large polarisable atoms and external lone electron pairs which induce exceptional non-linear properties. Consequently, the non-linear properties can be 100 or 1000 times as high as the non-linearity of silica. The presentation deals with the latest results in terms of optical properties and applications of chalcogenide glass fibers, including photonic crystal fibers and fibers for optical sensors. 1
- Published
- 2015
50. Optimization of Mid-IR microstructured fiber laser based on dysprosium doped chalcogenide glass
- Author
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Virginie Nazabal, Giuseppe Palma, Radwan Chahal, Mario Christian Falconi, Francesco Prudenzano, J. Troles, Jean-Luc Adam, W. Scarcia, and Florent Starecki
- Subjects
Materials science ,business.industry ,Infrared ,chemistry.chemical_element ,Chalcogenide glass ,Microstructured optical fiber ,Laser ,law.invention ,Wavelength ,Optics ,chemistry ,law ,Fiber laser ,Dysprosium ,business ,Photonic-crystal fiber - Abstract
The paper illustrates the design and the optimization of a medium infrared (Mid-IR) microstructured fiber laser based on dysprosium doped chalcogenide glass, Dy3+:Ga 5 Ge 20 Sb 10 S 65 . The investigation is performed realistically, by taking into account the spectroscopic parameters measured on samples of the aforesaid glasses. The aim is to investigate the feasibility of optical beam generation close to 4.4 µm wavelength. An output power of 107.2 mW with an input pump power of 1 W is calculated. This result indicates that the designed laser configuration can lead to a feasible medium infrared source which could find application in optical free propagation, biomedicine and sensing.
- Published
- 2015
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