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1. Synthesis and Structural Characterization of Macrocyclic α-ABpeptoids and Their DNA-Encoded Library.

Author

Lee S, Kwon H, Jee EK, Kim J, Lee KJ, Kim J, Ko N, Lee E, and Lim HS

Subjects
Amides chemistry, Crystallography, X-Ray, Gene Library, Macrocyclic Compounds chemistry, Molecular Conformation, DNA chemistry, Peptoids chemistry
Abstract

The first synthesis of macrocyclic α-ABpeptoids with varying lengths is described. X-ray crystal structures reveal that cyclic trimer displays a chair-like conformation with a cct amide sequence and cyclic tetramer has a saddle-like structure with an uncommon cccc amide arrangement. The creation of a DNA-encoded combinatorial library of macrocyclic α-ABpeptoids is described.

Published
2024
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